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sp2–sp cross-carbanion coupling at a rare-earth center leading to the formation of carbon–carbon double bonds

Inorg. Chem. Front., 2024, 11,2312-2318
DOI: 10.1039/D4QI00178H, Research Article
Zhengqi Chai, Ze-Jie Lv, Wei Liu, Jinxiao Yang, Junnian Wei, Wen-Xiong Zhang
The reaction of rare-earth azametallacyclopentadienes with terminal alkynes provides rare-earth metallacycles with cumulated double bonds in three steps: alkynyl C–H bond activation, sp2–sp cross-carbanion coupling and subsequent isomerization.
The content of this RSS Feed (c) The Royal Society of Chemistry




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N-heterocyclic carbene-stabilized Cu9 clusters with combined thermally activated delayed fluorescence and phosphorescence

Inorg. Chem. Front., 2024, 11,2498-2507
DOI: 10.1039/D4QI00160E, Research Article
Lin-Mei Zhang, Mo Xie, Hui-Zhi Wei, Shang-Fu Yuan, Dong-Sheng Li, Tao Wu
Two NHC-stabilized Cu9 clusters showcase both TADF and direct phosphorescence in thermal equilibrium. The combined harvesting mechanism arises from the simultaneous presence of a small ΔE(S1 − T1) gap and relatively strong spin–orbit coupling.
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Recent progress in aluminum anodes for high-performance rechargeable aqueous Al-ion batteries

Inorg. Chem. Front., 2024, 11,2246-2259
DOI: 10.1039/D4QI00468J, Review Article
Le Li, Shaofeng Jia, Yue Shi, Conghui Wang, Hengwei Qiu, Yongqiang Ji, Minghui Cao, Dan Zhang
This review discusses the recent advances in the aluminum metal anodes, alloy anodes, and intercalated anodes used for rechargeable aqueous Al-ion batteries.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A composite electrolyte based on aluminum oxide filler/polyester polymer via in situ thermal polymerization for long-cycle sodium metal batteries

Inorg. Chem. Front., 2024, 11,2300-2311
DOI: 10.1039/D4QI00391H, Research Article
Qiujun Wang, Xin He, Di Zhang, Zhaojin Li, Huilan Sun, Qujiang Sun, Bo Wang, Li-Zhen Fan
The introduction of Al2O3 regulates the solvation structure of Na+, which is conducive to the formation of inorganic-rich SEI. Na|THFA-5|Na cell maintains low polarization voltage, indicating that uniform Na depositions was successfully achieved.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Energetic copper(II) quadridentate chelate: a novel green laser-sensitive primary explosive

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00489B, Research Article
Qi Zhang, Ruibing Lv, Ying Wang, Zhenghang Luo, Pengyang Pan, Tingwei Wang, Quancheng Liu
A copper(II)-based quadridentate chelate [Cu(BNATE)·2H2O] has been prepared and systematically studied. It has excellent near-infrared laser sensitivity and detonation performance, and low mechanical sensitivity.
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Stable Calcium Ellagate Metal-Organic Framework as High Performance Green Memorizer Bearing High Working Temperature

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00038B, Research Article
Ting-Bo Liu, Jing-Wen Deng, Li Yi, Hai-Ying Fu, Liang-Wen Shi, Shi-Ying Lin, Yue Liu, Hao-Hong Li, Jing-Bo Liu, Jian-Zhi Liu
The development of green memorizers with distinct mechanism is significant. In this work, renewable polyphenol ellagic acid (EA) and environmentally friendly calcium were used to construct a unique 3D interpenetrated...
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CDs "inserted" abundant FeB based electrode via "local photothermal effect" strategy toward efficient overall seawater splitting

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00415A, Research Article
Shiheng Liang, Liugang Wu, Yiming Wang, Yuqi Shao, Hongyuan Song, Ziliang Chen, Weiju Hao
Construction of high-efficiency, long-stable catalytic electrodes for hydrogen by seawater splitting is a huge challenge in the field of green hydrogen. Herein, a matrix-type titanium dioxide nanorod (Ti/TiO2) is constructed...
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Effect of -OH on the Thermal Enhancement Properties of NIR-II Lanthanide Doped Nanoparticles in Water

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00147H, Research Article
Yingping Huang, Jie Hu, Yongwei Guo, Zihao Wang, Fulin Lin, Haomiao Zhu
Thermal enhanced nanothermometry has attracted great attention due to its high thermal sensitivity, however, most of studies are focused on the upconversion nanoparticles (NPs) in forms of powder. In the...
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Homochiral Dy2 single-molecule magnets with strong magneto-optical Faraday effect and strong third-harmonic generation

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00691G, Research Article
Cai-Ming Liu, Rong Sun, Xiang Hao, Xi-Li Li, Bingwu Wang
Four pairs of homochiral Dy2 complexes were directionally prepared using homochiral β-diketone ligands {D-Htfc/L-Htfc = (+)/(−)-3-trifluoroacetyl camphor, D-Hpfc/L-Hpfc = 3-(perfluorobutyryl)-(+)/(−)-camphor} and hydrazone Schiff base bridging ligands {H2L1 = (E)-N'-(2-hydroxy-3-methoxybenzylidene)pyrazine-2-carbohydrazide, H2L2...
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Large enhancement of electrochemical biomass oxidation by optimizing the competitive adsorption of HMF and OH− on doped CoOx

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00519H, Research Article
Tianqi Nie, Guihao Liu, Ziheng Song, Tianyang Shen, Xiaoliang Sun, Tianrui Yu, Sha Bai, Lirong Zheng, Yu-Fei Song
By doping transition metals into CoOx, we can regulate the deintercalation capacity of OH. The CoCuOx with enriched oxygen vacancies allowed the optimization of the competitive adsorption between HMF and OH, and accelerated the kinetics of HMFOR.
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Phase switching and shape-memory effect in a molecular material: revisiting the Werner complex [Ni(4-MePy)4(NCS)2]

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00636D, Research Article
Open Access
Shi-Qiang Wang, Shaza Darwish, Catiucia Matos, Zicong Marvin Wong, Anjaiah Nalaparaju, Yifei Luo, Jun Zhu, Xiaofei Zhang, Zhengtao Xu, Michael Zaworotko
Shape-memory effects and stimuli-induced phase transformations are observed across many types of materials but remain understudied in molecular materials. In this contribution, we revisit the Werner complex, [Ni(4-MePy)4(NCS)2] (4-MePy =...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Insights into the modulation mechanisms of multiple active sites in a conjugated small molecule towards organic cathode capacity from first-principles

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00547C, Research Article
Zhaopeng Sun, Hao Tian, Meng Zhang, Yi Zhang, Zhiping Li, Weiwei Huang
The modulation mechanisms of Na+ within the redox-active sites of the two-dimensional conjugated organic small-molecule 3BQ, and their impact on the initial capacity of a 3BQ cathode for Na-ion batteries, were investigated using first-principles calculations.
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Structural and electrochemical properties of Tan+1Cn MXene anode materials for metal-ion batteries

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D3QI02335D, Research Article
Jiayi Guo, Danni Hu, Chenqi Bai, Lina Xu, Hongping Xiao, Qian Shi, Xinhua Li, Xi'an Chen, Yingjin Ma, Guoyong Fang
Density functional theory calculations show that Tan+1Cn and Tan+1CnO2 MXenes have excellent open circuit voltages and maximum storage capacities for use in alkali metal-ion batteries.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Yolk-Shell type Carbon-Silica Nanoarchitecture Dispersed and Stabilized Ru Nanoparticles for Enhanced Hydrogenation of Aromatic Compounds

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00553H, Research Article
Lu Yan, Yue Shen, Zidan Zou, Xiao Zhang, Zhixin Yu, Guozhong Wang, Chun Chen
Hydrogenation of aromatic rings can be used not only for synthesis fine chemicals, but also for hydrogen storage and transportation using organic hydride. In this paper, yolk-shell structural SiO2@Ru@NC catalyst,...
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NaVSeO5: Synergistic Combinations to Excellent Birefringent Materials

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00513A, Research Article
Qiuyuan Feng, Jialong Wang, Changyou Liu, Qun Jing, Xiaoyu Dong
The novel NaVSeO5 birefringent crystals were successfully synthesized using a multifunctional group synergistic strategy, which combines a two-dimensional layered structure, consisting of stereochemically active lone pairs [SeO3], and anomalous [VO6]...
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Govt directs major steel players to use iron ore fines also for steel making

The country is heavily dependent on imports for coking coal.




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AgCare Tech launches digital marketplace for agri inputs

‘Golden Farms’ is designed to digitise the agricultural input supply chain




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Zinc futures may bounce off ₹275

Traders can buy on a dip and look for a target of ₹290 




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Optimism in global commodities market over Chinese measures may be short-lived, say analysts

Subdued demand, struggling property sector may exert downward pressure on metals




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Row over ISMA’s suggestion to regulate khandsari units

Opposing curbs, traditional sweeteners body BHAKTI says Centre should not be swayed by false narratives




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Shift toward EVs could disrupt global oil market: International Energy Agency report

As China's rapid switch to electricity plays a significant role in disrupting the oil market, oil companies find they can sell more of their product to India




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Global steel demand to drop a tad in 2024, rebound in 2025: worldsteel

Ongoing weakness in housing construction, driven by tight financing conditions and high costs, cited as reason for the fall in demand




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SEA survey estimates 27% increase in Gujarat groundnut production this season

Good rains this year and the increase in acreage might help Gujarat achieve a record groundnut production of 42.19 lakh tonnes this year, surpassing the previous record of 38.55 lakh tonnes set in 2021-22




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Nickel prices likely to be under pressure on market surplus

Analysts peg its average price for 2024 at around $17,000/tonne




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Crude oil down due to concerns over slowing demand in China 

Market is also cautious about a potential increase in global oil supply as the OPEC+ is planning to restore production output in December




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Diesel, petrol demand to grow 50,000-55,000 barrels per day Y-o-Y in Oct-Dec

India’s appetite for oil products in October-December is set to get a boost from the upcoming festival season as well as the agricultural season




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Crude oil trades higher as market monitors developments in West Asia 

At 9.56 am on Friday, December Brent oil futures were at $74.50, up by 0.16 per cent, and December crude oil futures on WTI (West Texas Intermediate) were at $70.28, up by 0.13 per cent




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Part of India’s sugar export quota to Maldives ‘diverted’ to Sri Lanka, Malaysia

Though exports are banned, shipments of 64,000 tonnes were allowed under special bilateral pact




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Festivals, agriculture, elections set to boost India's oil demand: S&P Global Commodity Insights

According to the commodities information services provider, India's oil demand decreased in September on a yearly basis, due to above normal rainfall, which affected road movement, construction, and mining activities




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Crude oil posts marginal gains following US SPR refill plans

November crude oil futures were trading at ₹5,686 on MCX during the initial hour of trading on Tuesday




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India’s iron ore, manganese, aluminium output rises in H1 FY25 amid strong demand

Iron ore production rose by 5.5% to 135 million tonnes, while manganese ore output increased by 6.2% to 1.7 million tonnes




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Manufacturing method of lab grown diamonds should be declared before export and import: CBIC

The new norms, which will help in quick processing and inspection of consignments, are to be effective from December 1




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Crude oil gains as market analyses Trump’s victory in US Presidential election

The Trump administration could stimulate economic growth in the US, which could help boost consumption demand in that country, say analysts




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Trump effect: Base metal prices surge on demand spike after slumping post-Trump win

Aluminium, zinc and copper futures climb on November 7, the day after Trump’s election, say PTI reports




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Why drugmakers are dialing C for current good manufacturing practices

For the industry under scrutiny over quality concerns, cGMP requires immediate attention




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COPing with cascading health concerns that climate change brings to our doorstep

Climate and Health: A global challenge needs a local solution to build resilient health systems




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Making the right choice on organs — ‘pass it on’

Organ Donation: A tightly regulated practice tainted by acts of fraud, gifts someone a chance at a better health




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Drugmakers chart a specialised course to navigate choppy waters

India’s pharma industry is moving from volume to value, investing in quality manufacturing 




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Funding healthcare: Stable investment in a volatile market

Investors are increasingly focusing on India’s healthcare sector for stable returns, with promising growth and investment opportunities




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Gen AI: Pharma’s new frontier

From clinical trials to cures, AI is set to transform lives faster with underutilized health data




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Is health on your manifesto this election?

Vote for health: As India approaches election season, will health reforms become a rallying point?




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PLI, plugging chinks in the country’s manufacturing armour for drugs and devices

 Call for simplification of licencing regimes gets louder even as benefits become tangible 




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Health and climate @work

April 28 is World safety and health at work day




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Pharmacies journey through litigations and another election

Chemists’ manifesto: Call for fair play gets louder amidst deep discounts from online pharmacies




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MMA, Wim Hof breathing and intermittent fasting

Boost your day with Wim Hof breathing, meditation, MMA, fasting, and outdoor exercise for optimal health and wellness




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Making India a go-to for medical treatment

India stands at the crossroads of innovation and tradition, offering medical solutions for the world, where life-saving treatments are delivered with precision and care




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Redefining the regulatory pathway for nutraceutical and pharmaceutical products

As the nutraceutical landscape grows, experts call for clarity in the manufacturing debate




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Data integrity alarm sounded for CROs, the backbone to pharma industry

USFDA cautions CROs; says such incidents “undermine the reputation of generic industry”




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Health and climate meet

The ‘Health argument for climate action’ meet on the sidelines of the High-Level Political Forum on Sustainable Development (July 9) — will review SDG Goal 13




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Why maternal nutrition is blue-chip investment

Guaranteed maternal nutrition can break the cycle of malnutrition passed from one generation to the next