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the Advances, opportunities, and challenges in methods for interrogating the structure activity relationships of natural products By pubs.rsc.org Published On :: Nat. Prod. Rep., 2024, 41,1543-1578DOI: 10.1039/D4NP00009A, Review Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Christine Mae F. Ancajas, Abiodun S. Oyedele, Caitlin M. Butt, Allison S. WalkerThis review highlights methods for studying structure activity relationships of natural products and proposes that these methods are complementary and could be used to build an iterative computational-experimental workflow.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
the The dichapetalins and dichapetalin-type compounds: structural diversity, bioactivity, and future research perspectives By pubs.rsc.org Published On :: Nat. Prod. Rep., 2024, 41,1579-1603DOI: 10.1039/D3NP00039G, Review ArticleIvan Addae-Mensah, Godwin Akpeko Dziwornu, Mary Anti Chama, Dorcas Osei-SafoThis review discusses the structural diversity of the dichapetalins and related compounds from the genera Dichapetalum and Phyllanthus, their manifestation in the diversity of their biological activities, and areas of potential future research.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
the Estimating the extent of adulteration of the popular herbs black cohosh, echinacea, elder berry, ginkgo, and turmeric – its challenges and limitations By pubs.rsc.org Published On :: Nat. Prod. Rep., 2024, 41,1604-1621DOI: 10.1039/D4NP00014E, Review Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Nilüfer Orhan, Stefan Gafner, Mark BlumenthalThis review article focuses on the challenges and limitations of estimating the prevalence of adulteration in preparations made from black cohosh, echinacea, elder berry, ginkgo, and turmeric.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
the Hot off the Press By pubs.rsc.org Published On :: Nat. Prod. Rep., 2024, 41,1466-1470DOI: 10.1039/D4NP90043J, Hot off the Press ArticleRobert A. Hill, Andrew SutherlandA personal selection of 32 recent papers is presented covering various aspects of current developments in bioorganic chemistry and novel natural products such as asperochone A from Aspergillus sp. MMC-2.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
the Synthetic-bioinformatic natural product-inspired peptides By pubs.rsc.org Published On :: Nat. Prod. Rep., 2024, Advance ArticleDOI: 10.1039/D4NP00043A, Review Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Samantha Nelson, Elizabeth I. ParkinsonSynthetic-bioinformatic natural product inspired peptides (syn-BNPs) are predicted peptides from biosynthetic gene clusters that are synthetically accessed. This method enables easier access to natural product-like peptides for bioactivity screening.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
the Siccanin-related drimane meroterpenoids: biological activities and synthesis By pubs.rsc.org Published On :: Nat. Prod. Rep., 2024, Advance ArticleDOI: 10.1039/D4NP00025K, Review ArticleShengxin Sun, Xia Wang, Nvdan Hu, Shiqi Fu, Shengkun LiThis review describes the isolation, structural characteristics, bioactivities and divergent synthetic strategies of siccanin-related drimane meroterpenoids.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
the Small animals with unique chemistry – the natural product chemistry of Collembola By pubs.rsc.org Published On :: Nat. Prod. Rep., 2024, Advance ArticleDOI: 10.1039/D4NP00049H, Highlight Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Anton Möllerke, Stefan SchulzThe secondary metabolites of springtails (Collembola) include defensive compounds, cuticular lipids, and semiochemicals, many of which are not known from other natural sources. The springtail chemistry differs largely from that of insects.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
the Gelation-induced controlled synthesis of TiO2 with tunable phase transition for efficient photocatalytic hydrogen evolution By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2178-2186DOI: 10.1039/D4QI00193A, Research ArticleWenwei Lei, Ying Wang, Hongji Wang, Norihiro Suzuki, Chiaki Terashima, Akira FujishimaA facile gelation-assisted coordination self-assembly method for mediated fabrication of TiO2 photocatalysts with controlled phase structures and morphologies is presented, showing excellent photocatalytic hydrogen production performance.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
the Electron-deficient Co modulated by the construction of heterojunctions Co@NC boosts the electroreduction of nitrate to ammonia By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2144-2151DOI: 10.1039/D4QI00110A, Research ArticleBo Zhang, Fengshou Yu, Yaohua Hong, Yuzhuo Zhou, Yaheng Wang, Shaobo Zhang, Lu-Hua ZhangFormation of electron-deficient Co by the construction of heterojunctions to promote the electroreduction of nitrate to ammonia.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
the Contributors to the Inorganic Chemistry Frontiers Emerging Investigator Series 2022–2023 By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI90021A, ProfileThis profile article showcases researchers who have contributed an article to the Inorganic Chemistry Frontiers Emerging Investigator Series.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
the Synthesis and characterization of a CsPbCl3 perovskite doped with Nd3+: structural, optical, and energy transfer properties By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00171K, Research ArticleMariusz Stefanski, Bartosz Bondzior, Adam Basinski, Maciej Ptak, Bibo Lou, Chong-Geng MaThe levels of Nd3+ in CsPbCl3 lie below the top of the host's VB. Consequently, Nd3+ luminescence is not observed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
the Sodium ion pre-intercalation regulates the electron density and structural stability of vanadium oxide nanowires for Ca–ion batteries By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00218K, Research ArticleHuajie Feng, Yize Wang, Wenda Qiu, Zixi Liu, Yaping Tao, Xihong LuBenefiting from the abundant resource, low cost, and high operating potential, calcium–ion batteries (CIBs) have attracted great attention as emerging energy storage devices over lithium-based systems.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
the Rapid Joule heating synthesis of Ni doped into porous honeycomb C3N4 with greatly improved photocatalytic H2 production By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00225C, Research ArticleZehui Zhao, Guangmin Ren, Zisheng Zhang, Xiangchao Meng, Zizhen LiPhotocatalytic water splitting is one of the sustainable and environmentally-friendly methods for producing hydrogen.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
the Recent progress on the photocatalytic hydrogen evolution reaction over a metal sulfide cocatalyst-mediated carbon nitride system By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00255E, Review ArticleXunhuai Huang, Junpeng Song, Guanyu Wu, Zhihuan Miao, Yanhua Song, Zhao MoModification strategy and synthesis method of a metal sulfide-mediated carbon nitride photocatalytic H2 production system.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
the Pb3.5GeS4Br3: the first phase-matching thiogermanate halide infrared nonlinear optical material By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00293H, Research ArticleJiazheng Zhou, Hongshan Wang, Junjie Liu, Xin Su, Yu Chu, Jiale Qu, Xiangzhan JiangPb3.5GeS4Br3 is the first phase-matching thiogermanate halide infrared nonlinear optical material.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
the Effects of weak intramolecular interactions and distortions from trigonal prismatic coordination on the magnetic properties of zero-field Co(II) single-ion magnets By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D3QI02507A, Research ArticleBen Zhang, Yang Zhou, Hao-Yi Huang, Xiao-Le Zhang, Yi Xiang, Yanbo Shi, Chennan Zhang, Aihua Yuan, Xingwei Cai, Lei Chen, Yi-Quan Zhang, Zhao-Bo HuThe change of counter anions significantly affects the environment around Co(II) ions, leading to two zero-field single-ion magnets possessing different uniaxial anisotropies and dynamic magnetic properties.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
the Facile access to tetra-substituted FeIIFeII biomimetics for the oxidized state active site of [FeFe]-hydrogenases By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00773E, Research ArticleXin-Ping Gao, Shu-Fen Bai, Yan-Lan Wang, Shuang Lü, Qian-Li LiThis study presents a convenient approach to obtain two distinct types of novel tetra-substituted Fe/Se salts through a dehalogenation reaction. The objective is to advance research in mimicking the FeIIFeII oxidation state in [FeFe]-H2ases.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
the Rational design for broad near-infrared emission from a two-sited Rb2LiAlF6:Cr3+ phosphor with high efficiency and thermal stability for spectroscopic applications By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00429A, Research ArticleSong Qing, Jing Wan, Tao Yang, Qiang Zhou, Yayun Zhou, Zhengliang Wang, Dawei Wen, Mingmei WuA comparative investigation of broadband near-infrared luminescence from two different occupation sites in Rb2LiAlF6:Cr3+ with high efficiency and excellent thermal stability.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
the Controlling the structural and adsorption features of polyoxovanadate-based metal–organic clusters by adjustable template effect By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00254G, Research ArticleYan-Hu Wang, Ke-Wei Tong, Chao-Qin Chen, Jing Du, Guo-Ping Yang, Peng YangAn adjustable template effect was employed to activate the evolution of polyoxovanadate-based metal–organic clusters, resulting in unprecedented structural archetypes as well as customized dye and iodine adsorption features.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
the The smallest endohedral borafullerene: structural isomerization, electronic properties, aromaticity and reactivity of U@C27B By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00186A, Research ArticleXinde Li, Lei Lou, Peng JinU@C27B has three interconvertible isomers with the highest metal oxidation state and strong covalency, obeying the 32-electron principle and Hirsch's aromaticity rule.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
the An unusual reaction in nitromethane solution: use of the Cp*Rh moiety to form Prussian blue analogues By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00343H, Research ArticleHuirong Ma, Liangchen Liu, Yuluan Liao, Huatian Shi, Po Sun, Weibin YuThe direct decomposition of nitromethane into nitrile compounds is a significant challenge due to the occurrence of severe side-reactions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
the Achieving high-sensitivity dual-mode optical thermometry via phonon-assisted cross-relaxation in a double-perovskite structured up-conversion phosphor By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00395K, Research ArticleHouhe Dong, Zonghao Lei, Shikun Su, Wenhua Yang, Xuyang Zhang, Wenying Teng, Guangyue Zu, Bing Teng, Degao ZhongBy adjusting the phonon energy of the host crystal (Ca2+/Sr2+/Ba2+) LaLiTeO6:Yb3+, Tm3+ phosphor, combined with the cross-relaxation phenomenon, a high-sensitivity thermometer for dual-mode temperature measurement was constructed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
the Development of In–Cu binary oxide catalysts for hydrogenating CO2via thermocatalytic and electrocatalytic routes By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2319-2338DOI: 10.1039/D3QI02499G, Research Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Marco Pietro Mezzapesa, Fabio Salomone, Hilmar Guzmán, Federica Zammillo, Roberto Millini, Letizia Bua, Gianluigi Marra, Alessandra Tacca, Rosamaria Marrazzo, Nunzio Russo, Raffaele Pirone, Simelys Hernández, Samir BensaidCarbon dioxide (CO2) hydrogenation to obtain valuable chemicals and fuels via thermocatalysis or electrocatalysis is a promising and sustainable method for CO2 utilization.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
the Selenium doping induced phase transformation and interlayer expansion boost the zinc storage performance of molybdenum disulfide By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2272-2280DOI: 10.1039/D4QI00344F, Research ArticleMengfan Niu, Wenli Xin, Lei Zhang, Min Yang, Yaheng Geng, Xilin Xiao, Hui Zhang, Zhiqiang ZhuThis work synthesized Se-doped MoS2 nanosheets as a cathode for aqueous zinc-ion batteries, and they exhibited largely improved electrochemical performance owing to their high content of the 1T phase (64%) and expanded interlayer spacing (0.65 nm).The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
the High-efficiency ammonia synthesis via electrochemical nitrate reduction over Co3O4 nanoarrays by B doping By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2339-2345DOI: 10.1039/D4QI00310A, Research ArticleZhiqin Deng, Heng Liu, Huiyong Wang, Chaoqun Ma, Juan Du, Baozhan ZhengB acts as an effective dopant to boost the catalytic activity of Co3O4 for the nitrate reduction reaction towards NH3 synthesis. Such B-Co3O4/TM achieves a high faradaic efficiency of 94.7% and a large NH3 yield rate of 407.3 μmol h−1 cm−2.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
the Understanding the synthesis mechanism, chemical structures and optical properties of aromatic carbon nitride By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2346-2354DOI: 10.1039/D4QI00355A, Research ArticleYunhu Wang, Fangxu Dai, Yafei Tao, Kai Zhang, Bingjie Li, Mingming Zhang, Kang Liu, Jixiang Xu, Lei Wang, Jun XingThe chemical structures and optical properties of aromatic carbon nitride and intermediates have been systematically studied; hereby the detailed synthesis mechanism of aromatic carbon nitride is explicitly proposed.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article