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Phosphorus-Doped Inverse Opal g-C3N4 for Efficient and Selective CO Generation from Photocatalytic Reduction of CO2

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00457J, Paper
xiaoyue huang, Wenyi Gu, Songchang Hu, Yan Hu, Liang Zhou, Juying Lei, Lingzhi Wang, Yongdi Liu, Jinlong Zhang
In this work, inverse opal (IO) structure construction and phosphorus doping were combined to modify carbon nitride (g-C3N4) for photocatalytic reduction of CO2. The inverse opal structure was fabricated by...
The content of this RSS Feed (c) The Royal Society of Chemistry




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CO activation and methanation mechanism on hexagonal close-packed Co catalysts: effect of functionals, carbon deposition and surface structure

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00499E, Paper
Hai-Yan Su, Changlin Yu, Jin-Xun Liu, Yonghui Zhao, Xiufang Ma, Jie Luo, Chenghua Sun, Wei-Xue Li, Keju Sun
Regardless of the functionals used and the presence of graphitic carbon, the CO methanation rate on Co(0001) is mainly controlled by CHO decomposition.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Bifunctional rhenium-copper nanostructures for intensified and stable ethanol synthesis via hydrogenation of dimethyl oxalate

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00579G, Communication
Zhongnan Du, Meng Chen, Xuepeng Wang, Xingkun Chen, Xiaolin Mou, Yuan Tan, Wenshao Yang, Chuanqi Huang, Hejun Zhu, Ronghe Lin, Yunjie Ding
Decorating small copper nanoparticles with isolated and/or clusted oxophilic rhenium species enables the first low-copper catalytic technology for intensified and stable ethanol production under mild conditions in dimethyl oxalate hydrogenation....
The content of this RSS Feed (c) The Royal Society of Chemistry




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Mesoporous Ce-doped ZnO hollow microspheres for oxidation of 1,2-dichlorobenzene

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00272K, Paper
Xiaodong Ma, Jiaxin Wen, Haiwei Guo, Zizhang Wei, Xu He, Longlong Zhang, BODONG LI, tao wang, YANHU CHENG
Mesoporous Ce-doped ZnO hollow microspheres were synthesized for the oxidative decomposition of 1,2-dichlorobenzene (o-DCB) as a model compound of polychlorinated aromatic hydrocarbons (PCAHs). The results showed that the molar ratios...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis of vinyl chloride monomer by acetylene hydrochlorination with a ruthenium-based N-heterocyclic carbene complex catalyst

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00512F, Paper
Ming Cai, Haiyang Zhang, Baochang Man, Jian Li, Linfeng Li, Yanqin Li, Dongyang Xie, Renpan Deng, Jinli Zhang
With the implementation of Minamata Convention and the urgent demand for green, and efficient mercury-free catalysts, the carbon-supported IPr-(Ru)/AC catalyst was synthesized and assessed for its successful application in acetylene...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Ligand photodissociation in Ru(II)–1,4,7-triazacyclononane complexes enhances water oxidation and enables electrochemical generation of surface active species

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/C9CY02575H, Paper
Hussein A. Younus, Nazir Ahmad, Ibrahim Yildiz, Serge Zhuiykov, Shiguo Zhang, Francis Verpoort
Ligand transformations involved in metal complexes during water oxidation (WO), such as ligand decomposition, partial oxidation, or complete dissociation have been reported, however, ligand photodissociation has not been reported yet.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Impact of edge structures on interfacial interactions and efficient visible-light photocatalytic activity of metal–semiconductor hybrid 2D materials

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00420K, Paper
Open Access
Deobrat Singh, Pritam Kumar Panda, Nabil Khossossi, Yogendra Kumar Mishra, Abdelmajid Ainane, Rajeev Ahuja
The present work systematically investigates the structural, electronic, and optical properties of MoS2/Si2BN heterostructures based on first-principles calculations.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Homogeneous vs. Heterogeneous: Mechanistic Insights into Iron Group Metal-Catalyzed Reductions from Poisoning Experiments

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00644K, Minireview
Axel Jacobi von Wangelin, Sebastian Sandl, Dominik Gärtner
Iron group metal catalysts constitute a promising alternative to well-established noble metal catalysts in reduction reactions. However, the development of effective 3d metal catalysts has largely been hampered by their...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Heterogenization for polyoxometalates as solid catalysts in aerobic oxidation of glycerol

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00403K, Paper
Meilin Tao, yue li, Yiming Li, Xueyan Zhang, Yurii Geletii, Xiaohong Wang, Craig L Hill
A series of heterogeneous catalysts based on phosphomolybdic salts with different Lewis metals in counter or substituent places LnPMo12O40 (L = Al3+, Fe3+, Cr3+, Ti4+, Zr4+ and Zn2+, abbreviated as...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Stability of the ketyl radical as a descriptor in the electrochemical coupling of benzaldehyde

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00282H, Paper
Jacob Anibal, Arnav Malkani, Bingjun Xu
Electroreductive coupling is an emerging pathway for the renewable upgrading of biomass derived oxygenates. This work investigates electrochemical benzaldehyde reduction on Au, Cu, Pt and Pd using reactivity testing and in situ spectroscopy.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Site-specific catalytic activities to facilitate solvent-free aerobic oxidation of cyclohexylamine to cyclohexanone oxime over highly efficient Nb-modified SBA-15 catalysts

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00479K, Paper
Wei Ding, Haoyu Peng, Wenzhou Zhong, Liqiu Mao, Dulin Yin
The development of highly active and selective heterogeneous catalysts for efficient oxidation of cyclohexylamine to cyclohexanone oxime is a challenge associated with the highly sensitive nitrogen center of cyclohexylamine.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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From cellulose to 1,2,4-benzenetriol via catalytic degradation over a wood-based activated carbon catalyst

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00424C, Paper
Qiong Wu, Baozheng Zhao, Shiwei Liu, Shitao Yu, Lang Huang, Arthur J. Ragauskas
1,2,4-Benzenetriol was obtained from cellulose hydrothermal degradation using phosphoric acid-activated wood-based AC as the catalyst.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Photocatalytic asymmetric epoxidation of trans-stilbene with manganese–porphyrin/graphene-oxide nanocomposite and molecular oxygen: axial ligand effect

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00441C, Paper
Elahe Ahadi, Hassan Hosseini-Monfared, Alex Spieß, Christoph Janiak
An efficient, visible light-driven manganese–porphyrin photocatalyst was developed for the asymmetric epoxidation of trans-stilbene by molecular oxygen under mild conditions.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Does the structure of CuZn hydroxycarbonate precursors affect the intrinsic hydrogenolysis activity of CuZn catalysts?

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00143K, Paper
Violetta Pospelova, Jaroslav Aubrecht, Kateřina Pacultová, Miloslav Lhotka, Oleg Kikhtyanin, David Kubička
A comparative study of the properties and activity of catalysts derived from single-phase CuZn precursors to elucidate the effect of the precursor structure on the catalyst activity in DMA hydrogenolysis and to examine replacement of CuCr catalysts.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Phosphine-catalyzed [3 + 2] annulation of 2-aminoacrylates with allenoates and mechanistic studies

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00092B, Paper
Xiao-Yun Wu, Hou-Ze Gui, Harish Jangra, Yin Wei, Min Shi, Hendrik Zipse
A convenient and efficient strategy for the synthesis of 3-pyrrolines containing an amino quaternary stereogenic center via phosphine-catalyzed formal [3 + 2] annulation of allenoates with 2-aminoacrylates is disclosed. A...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Influence of gold on the reactivity behaviour of ceria nanorods in CO oxidation: Combining operando spectroscopies and DFT calculations

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00392A, Paper
Marc Ziemba, Christian Hess
Au/CeO2 catalysts are commonly used for low-temperature CO oxidation. While many studies focus on the properties of gold and their relevance for the activity, the influence of the support properties...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Photocatalytic degradation of tetracycline hydrochloride over rugby-like β-Ga2O3 with a 3D hierarchically assembled porous structure for environmental remediation

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00562B, Paper
Lingxing Zeng, Jiaqi Wang, Qingrong Qian, Qinghua Chen, Xin-Ping Liu, Yongjin Luo, Hun Xue, Zhaohui Li
A novel rugby ball-like β-Ga2O3 photocatalyst with a 3D hierarchically assembled porous structure was constructed via a facile precipitation–calcination method. The as-synthesized Ga2O3 exhibits a high photocatalytic efficiency compared to commercial Ga2O3 and Degussa P25.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Photoswitchable catalysis using organometallic complexes

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00431F, Minireview
Zoraida Freixa
Photoswitchable catalysis using organometallic complexes: a ligand design perspective.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Facet-Dependent Activity of Hematite Nanocrystals toward Oxygen Evolution Reaction

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00655F, Paper
Toshihiro Takashima, Shota Hemmi, Qingyu Liu, Hiroshi Irie
Electrocatalytic activity of hematite exposed with different facets toward the oxygen evolution reaction (OER) was investigated. Hematite nanoparticles with pseudo cubic, hexagonal bipyramid, and plate morphologies were prepared, which predominantly...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis of FeCo-N@N-doped carbon oxygen reduction catalysts via microwave-assisted ammoxidation

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00376J, Paper
Hung-Chih Kuo, Shou-Heng Liu, Yan-Gu Lin, Chao-Lung Chiang, Dan CW Tsang
A core-shell structured FeCo-N@N-doped carbon derived from biomass wastes (sugarcane and palm kernel shell) is facilely prepared by hydrothermal carbonization and NH3 microwave ammoxidation method. The fabricated carbons are thoroughly...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Interfacial Effect of Co4S3-Co9S8 Nanoparticles Hosted onto rGO Sheets Derived from Molecular Precursor Pyrolysis on Enhancing Electrochemical Behaviour†

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00564A, Paper
Mengmeng He, Linchao Zhu, Yanyan Liu, Hao Wen, Yunxia Hu, Baojun Li
The reasonable design and synthesis of Co-based compound with superior electrochemical activity and durability have aroused tremendous research interests. Herein, a simple molecular precursor pyrolysis strategy is proposed to fabricate...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Selective synthesis of α-olefins by dehydration of fatty alcohols over alumina–thoria mixed catalysts

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00551G, Paper
Arif Ali, Chen Zhao
The selective and high-yield production of α-olefins by alcohol dehydration is challenging because the isomerization and polymerization olefin products are more thermodynamically stable. In this study, we prepared a physical...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Hierarchical Z-scheme 1D/2D architecture with TiO2 nanowires decorated by MnO2 nanosheets for efficient adsorption and full spectrum photocatalytic degradation of organic pollutants

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00419G, Paper
Jiejing Zhang, Yajie Hu, Hong Zheng, Pengyi Zhang
Constructing composite photocatalysts with efficient photocatalytic activity, wide optical response range and excellent stability has great significance for the removal of organic pollutants in water. Herein, we report a novel...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Color Multiple Registration Buttons

I have multiple registration buttons and I’m looking for a way to use CSS for coloring the buttons rather than inline Style=background-color.
This is my html code.

form action=”registration.php” method=”post” name=”ApplicationsForm” id=”ApplicationsForm” align=”left”
input type=”submit” name=”ApplicationForm” id=”ApplicationForm” value=”Register for a Class”
span style=”color: blue;”>To Register: Click “Register for a Class” and complete the form.
/form

Thanks much
Dub




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Horizontal Scroll in Firefox

Hi,

I’m playing with this horizontal scroll, but having trouble getting it to work with Firefox. Chrome and Safari handle it fine. I have no way to test IE. Any tips or ideas?

codepen https://codepen.io/sarcodes/pen/XWJoBGy




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Reply To: Jquery / Javascript Education Help

fvgz




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Change SASS variable depending of subdomain

Hi,

I have a WordPress multi site (site.com / subdomain1.site.com / subdomain2.site.com), and I want to change the primary color depending of the subdomain.
I have assigned a class to the body depending of the subdomain.

I tried this :
.subdomain-1
$primary : #5E1B3C
.subdomain-2
$primary: #BE0050

But it doesn’t work. Have you got an idea of how to do this ?

Thank you !




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Reply To: .last-child or???

Hello there. Interesting thread, thanks for the information.




c

Reply To: [Solved] Background Image Not Showing

Hey guys,

Having the same issue.

Wondering if someone can confirm this,

my filepath

file:///Users/asaule/Dropbox/html5theme_1/assets/css/images/banner.jpg

HTML code;

CSS code;

#banner {

background-image: url(/images/banner.jpg);
background-attachment: fixed;
background-position: center;
/* border-top: solid 1px #005782; */
box-shadow: inset 0px 1px 5px 0px #3e484f;
padding: 35px 0 35px 0;
display: block;

}

Please let me know if you have any tips




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centered heading over multible lines, underline just the last words

Hey everyone!

I have invested much time, but I cannot find a solution to make the CSS underline like the following picture:

Here how it should look: https://i.stack.imgur.com/CPqMl.jpg

It is a heading with centered text. At bigger screens, the text is displayed in just one line.

It would be nice if the red underline isn´t directly connected with the words (so that it is responsively).

Have you a CSS snippet or a link?

Thanks in advance!




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Help with php if/then code

<?php
        if( get_post_type() == 'tribe_courses' ) {
           echo '<a href="/courses/passion-and-provision-course-2018/"><h1>Passion & Provision<sup>®</sup></h1>
                <h2>– COURSE –</h2></a><br>';
        } else {
             echo  '<a href="/"><h1>HaBO Village</h1>
                    <h2>Helping Leaders Build Passion & Provision<sup>®</sup> Companies</h2></a><br>';
        }
?>




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Extend ::before background in fixed element

Hi!

Does anyone have any idea how I can make the background gradient to continue when scrolling?

Code: https://jsfiddle.net/Lfpb8woa/1/

Thanks in advance!




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Reliance General Insurance scraps IPO plan; withdraws draft offer documents

Markets regulator Sebi had received draft red herring prospectus for the proposed IPO on February 8




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Shapoorji Pallonji group subsidiary announces plan to list Eureka Forbes

Forbes & Company, a Shapoorji Pallonji group firm on Tuesday announced plans to list its subsidiary Eureka Forbes to unlock value for shareholders. The company's board has authorised the management to evaluate any such scheme in this regard, Forbes & Company said in a regulatory filing. "The Board of Directors of the company has authorised the management...to evaluate a scheme of arrangement and/or other appropriate mechanisms to enable an eventual listing of Eureka Forbes with an intention to unlock value in the hands of all the shareholders of the company," it said. These may also include listing, dilution/sale or combination thereof of Eureka Forbes, it added. Eureka Forbes is a wholly-owned subsidiary of Forbes & Company. "The Board will consider the above (schemes) when the relevant proposals are placed before it in the near future, but in principle has approved supporting the endeavours of the management in this regard," it said. It operates in water purifier, air ...




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Saudi Aramco IPO: 25 banks hired as bookrunners face pared pay of $90 mn

The banks will be paid 35 basis points of the money raised, according to the three sources




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Puranik Builders re-files IPO papers, plans to raise Rs 1k-cr to pare debt

Edelweiss Financial Services Ltd and Axis Capital will manage the company's initial share-sale. Shares of the company will be listed on the BSE and NSE.




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Aramco IPO: Institutional tranche gains $17 bn in orders, says Al Arabiya

The retail portion of the planned deal had received 10 billion riyals, it also said.




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CSB Bank IPO subscribed 79.72 times; raises Rs 184 cr from anchor investors

The company, which aims to raise up to Rs 410 crore, has fixed a price of Rs 193-195 per share for the IPO.




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Ujjivan Small Finance Bank eyes Rs 750 cr via IPO; issue to open on Dec 2

The lender commenced operations in February 2017 and the bank will also have to bring the promoters' holding to 40 percent by 2022




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From Byju's to Swiggy: Next wave of tech unicorn listings could be in India

Mohandas Pai expects food delivery platforms Swiggy and Zomato, as well as PhonePe and Myntra to list in local markets in next few years




c

Prince Pipes IPO price band at Rs 177-178 per share; to raise Rs 500 crore

It has set a price band of Rs 177-178 per equity share for the IPO




c

Equitas Small Finance Bank files draft papers for IPO, to raise Rs 550 cr

The equity shares of the company will be listed on the BSE and the NSE.




c

Prince Pipes and Fittings IPO opens today. Should you subscribe?

Price band of the offer has been fixed at Rs 177-178




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UTI MF files draft papers for IPO; issue size likely to be up to Rs 4000 cr

The issue size is expected to be Rs 3,000-4,000 crore, valuing the AMC at Rs 10,000-11,000 crore




c

Karuna Therapeutics, little-known firm is yr's best US IPO with 420% surge

Early Karuna holders saw more than 420 per cent returns since the June IPO at $16 a share




c

Park Hotels files draft papers with Sebi for IPO to raise up to Rs 1000 cr

The shares of the company are proposed to be listed on the BSE and NSE




c

NSE approaches Sebi for IPO, hopes to launch public issue by September

The entire IPO would be offer-for-sale (OFS), wherein existing shareholders will sell NSE's shares




c

Association of stock brokers ANMI to mobilise 10 mn investors for LIC IPO

The proposed listing will help the government in achieving its disinvestment target of Rs 2.1 trillion for 2020-21




c

Yet to receive proposal from LIC for IPO, says Irdai Chairman S C Khuntia

Khuntia also asked insurance companies to "weed out" loss-making products and concentrate only on the better paying ones




c

SBI Cards and Payment Services' $1.25 billion-IPO to open on March 2

The company plans to issue new shares worth Rs 500 crore and will offer up to 130.5 million shares for sale