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35-yr-old Indian worker found dead in Singapore



  • DO NOT USE Indians Abroad
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US apex court denies former Goldman Sachs director Rajat Gupta’s appeal against lifetime ban



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Indian-American appointed minority floor leader in Michigan



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Indian priest launches organ donation drive ‘Upahaar’ in United Kingdom



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US President Barack Obama appoints Indian-American executive Ajay Banga to key administrative post



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3 Indian-origin men arrested in Singapore



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Tulsi Gabbard to marry in April in Vedic ceremony



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Indian-origin counsel appointed as Judicial Commissioner to Singapore Supreme Court



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Video: Two Indian labours awarded by Singapore for saving a toddler



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Sikh group lauds USCIRF for recognising violation against them



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Tulsi Gabbard features in ’25 Most Influential Women in Congress’



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Indian doctor fined for professional misconduct in Singapore



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Bobby Jindal gains ground in Iowa, nationally low: polls



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Bobby Jindal’s campaign gains ground in Iowa, reveals latest internal survey



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Singapore: Indian man acquitted of drug charges



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Chromium lands Flexbox gap

I mentioned this the other day via Michelle Barker’s coverage, but here I’ll link to the official announcement. The main thing is that we’ll be getting gap with flexbox, which means:

.flex-parent {
  display: flex;
  gap: 1rem;
}
.flex-child {
  flex: 1;
}

That’s excellent, as putting space in between flex items has been tough in the past. We have justify-content: space-between, which is nice sometimes, but that doesn’t allow you to explicitly tell the flex container how Read article “Chromium lands Flexbox gap”

The post Chromium lands Flexbox gap appeared first on CSS-Tricks.




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PIX: Ganguly visits Belur Math, donates 2000kgs rice

Ganguly had earlier announced a donation of Rs 50 lakh worth rice for the sufferers of COVID-19, which has left the world in disarray.




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PIX: How Gambhir is making most of lockdown

Cricketer-turned-politician Gautam Gambhir seems to be making most of the lockdown across the country. The lockdown across India was extended till May 3 to contain the spread of the coronavirus pandemic and East Delhi MP Gambhir is getting to spending time with his kids at home, even though they are not letting him catch up with his sleep.




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Engagement - Best Practices - Private

Available Sessions for this Seminar:

ipwebinar.aspx?tab=1&smid=1460, December 29, 2014




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Engagement - General A&A - Private

Available Sessions for this Seminar:

ipwebinar.aspx?tab=1&smid=1236, December 22, 2014
ipwebinar.aspx?tab=1&smid=1236, January 07, 2015




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La Liga knocks down talk of June 20 restart

Leganes coach Javier Aguirre had said that the Spanish football season will re-start on June 20.




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Navigation for Design Systems and Style Guides

A key part of my job for the past year has been contributing to design systems. To benefit from those contributions though, users need to be able to find them. That’s why it’s not only the content of a design system that’s important but also its usability. Design systems should be easy to navigate, especially […]




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Overlay gap

I think a lot about Danielle’s talk at Patterns Day last year.

Around about the six minute mark she starts talking about gaps and overlaps.

Gaps are where hidden complexity live. If we don’t have a category to cover it, in effect it becomes invisible. But that doesn’t mean it’s not there. Unidentified gaps cause inconsistency and confusion.

Overlaps occur when two separate categories encompass some of the same areas of responsibility. They cause conflict, duplication of effort, and unnecessary friction.

This is the bit I keep thinking about. It’s such an insightful lens to view things through. On just about any project, tensions are almost due to either gaps (“I thought someone else was doing that”) or overlaps (“Oh, you’re doing that? I thought we were doing that”).

When I was talking to Gerry on his new podcast recently, we were trying to figure out why web performance is in such a woeful state. I mused that there may be a gap. Perhaps designers think it’s a technical problem and developers think it’s a design problem. I guess you could try to bridge this gap by having someone whose job is to focus entirely on performance. But I suspect the better—but harder—solution is to create a shared culture of performance, of the kind Lara wrote about in her book:

Performance is truly everyone’s responsibility. Anyone who affects the user experience of a site has a relationship to how it performs. While it’s possible for you to single-handedly build and maintain an incredibly fast experience, you’d be constantly fighting an uphill battle when other contributors touch the site and make changes, or as the Web continues to evolve.

I suspect there’s a similar ownership gap at play when it comes to the ubiquitous obtrusive overlays that are plastered on so many websites these days.

Kirill Grouchnikov recently published a gallery of screenshots showcasing the beauty of modern mobile websites:

There are two things common between the websites in these screenshots that I took yesterday.

  1. They are beautifully designed, with great typography, clear branding, all optimized for readability.
  2. I had to install Firefox, Adblock Plus and uBlock Origin, as well as manually select and remove additional elements such as subscription overlays.

The web can be beautiful. Except it’s not right now.

How is this dissonance possible? How can designers and developers who clearly care about the user experience be responsible for unleashing such user-hostile interfaces?

PM/Legal/Marketing made me do it

I get that. But surely the solution can’t be to shrug our shoulders, pass the buck, and say “not my job.” Somebody designed each one of those obtrusive overlays. Somebody coded up each one and pushed them into production.

It’s clear that this is a problem of communication and understanding, rather than a technical problem. As always. We like to talk about how hard and complex our technical work is, but frankly, it’s a lot easier to get a computer to do what you want than to convince a human. Not least because you also need to understand what that other human wants. As Danielle says:

Recognising the gaps and overlaps is only half the battle. If we apply tools to a people problem, we will only end up moving the problem somewhere else.

Some issues can be solved with better tools or better processes. In most of our workplaces, we tend to reach for tools and processes by default, because they feel easier to implement. But as often as not, it’s not a technology problem. It’s a people problem. And the solution actually involves communication skills, or effective dialogue.

So let’s say it is someone in the marketing department who is pushing to have an obtrusive newsletter sign-up form get shoved in the user’s face. Talk to them. Figure out what their goals are—what outcome are they hoping to get to. If they don’t seem to understand the user-experience implications, talk to them about that. But it needs to be a two-way conversation. You need to understand what they need before you start telling them what you want.

I realise that makes it sound patronisingly simple, and I know that in actuality it’s a sisyphean task. It may be that genuine understanding between people is the wickedest of design problems. But even if this problem seems insurmoutable, at least you’d be tackling the right problem.

Because the web can’t survive like this.




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Community ecology / Gary G. Mittelbach (Michigan State University, USA), Brian J. McGill (University of Maine, USA)

Mittelbach, Gary George, author




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Noongar bush tucker : bush food plants and fungi of the south-west of Western Australia / Vivienne Hansen and John Horsfall

Hansen, Vivienne, author




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Animal physiology / Richard W. Hill (Michigan State University), Gordon A. Wyse (University of Massachusetts, Amherst), Margaret Anderson (Smith College)

Hill, Richard W., author




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The Wiley Handbook of Healthcare Treatment Engagement: Theory, Research, and Clinical Practice


 

Against a global backdrop of problematic adherence to medical treatment, this volume addresses and provides practical solutions to the simple question: “Why don’t patients take treatments that could save their lives?”

The Wiley handbook of Healthcare Treatment Engagementoffers a guide to the theory, research and clinical practice of promoting patient engagement in healthcare treatment at individual, organizational and systems levels. The concept of



Read More...




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Efficient bifunctional catalysts synthesized from three-dimensional Ni/Fe bimetallic organic frameworks for overall urea electrolysis

Dalton Trans., 2020, 49,5646-5652
DOI: 10.1039/D0DT00605J, Paper
Huizhu Xu, Ke Ye, Kai Zhu, Jinling Yin, Jun Yan, Guiling Wang, Dianxue Cao
MOF-Ni@MOF-Fe–S which has a structure of interwoven and folding nanosheets shows superior electrochemical performance towards urea electrolysis.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Responsive ruthenium complex probe for phosphorescence and time-gated luminescence detection of bisulfite

Dalton Trans., 2020, 49,5531-5538
DOI: 10.1039/C9DT04614C, Paper
Wenzhu Zhang, Xiuyan Xi, Yong-Lei Wang, Zhongbo Du, Chaolong Liu, Jianping Liu, Bo Song, Jingli Yuan, Run Zhang
We report the design, synthesis, and characterization of a responsive Ru(II) complex probe for background-free time-gated luminescence detection of bisulfite.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Reversible luminescent humidity chromism of organic–inorganic hybrid PEA2MnBr4 single crystals

Dalton Trans., 2020, 49,5662-5668
DOI: 10.1039/D0DT00514B, Paper
Wanru Gao, Meiying Leng, Zhixiang Hu, Junze Li, Dehui Li, Huan Liu, Liang Gao, Guangda Niu, Jiang Tang
Reversible luminescent humidity chromism was found on PEA2MnBr4 between green emission and pink emission through water adsorption and desorption.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Three metal–organic framework isomers of different pore sizes for selective CO2 adsorption and isomerization studies

Dalton Trans., 2020, 49,5618-5624
DOI: 10.1039/D0DT00793E, Paper
Rui Zhang, Ju-Hua Huang, De-Xian Meng, Fa-Yuan Ge, Li-Fei Wang, Yong-Kai Xu, Xing-Gui Liu, Mei-Mei Meng, Zhen-Zhong Lu, He-Gen Zheng, Wei Huang
Three MOF isomers including framework-catenation and framework-topological isomers were synthesized for adsorbing carbon dioxide with high selectivity.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Carbazole-based green and blue-BODIPY dyads and triads as donors for bulk heterojunction organic solar cells

Dalton Trans., 2020, 49,5606-5617
DOI: 10.1039/D0DT00637H, Paper
Jian Yang, Charles H. Devillers, Paul Fleurat-Lessard, Hao Jiang, Shifa Wang, Claude P. Gros, Gaurav Gupta, Ganesh D. Sharma, Haijun Xu
Two BODIPY derivatives with one (B2) and two (B3) carbazole moieties were synthesized and applied as electron-donor materials in organic photovoltaic cells (OPV), showing an overall PCE of 6.41% and 7.47%, respectively.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Diamidophosphites from β-hydroxyamides: readily assembled ligands for Pd-catalyzed asymmetric allylic substitution

Dalton Trans., 2020, 49,5625-5635
DOI: 10.1039/D0DT00741B, Paper
Ilya V. Chuchelkin, Konstantin N. Gavrilov, Nataliya E. Borisova, Alexander M. Perepukhov, Alexander V. Maximychev, Sergey V. Zheglov, Vladislav K. Gavrilov, Ilya D. Firsin, Vladislav S. Zimarev, Igor S. Mikhel, Victor A. Tafeenko, Elena V. Murashova, Vladimir V. Chernyshev, Nataliya S. Goulioukina
Novel diamidophosphites based on β-hydroxyamides were prepared, and their individual and in situ formed complexes were tested in Pd-mediated allylations.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Time-resolved infra-red spectroscopy reveals competitive water and dinitrogen coordination to a manganese(I) carbonyl complex

Dalton Trans., 2020, 49,5463-5470
DOI: 10.1039/C9DT04878B, Paper
Jonathan B. Eastwood, L. Anders Hammarback, Matthew T. McRobie, Ian P. Clark, Michael Towrie, Ian. J. S. Fairlamb, Jason M. Lynam
Photolysis of [Mn(C^N)(CO)4] (C^N = bis-(4-methoxyphenyl)methanimine) in heptane solution results in ultra-fast CO dissociation and ultimate formation of a rare Mn-containing dinitrogen complex fac-[Mn(C^N)(CO)3(N2)].
The content of this RSS Feed (c) The Royal Society of Chemistry




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Design and synthesis of photoluminescent active interpenetrating metal–organic frameworks using N-2-aryl-1,2,3-triazole ligands

Dalton Trans., 2020, 49,5429-5433
DOI: 10.1039/D0DT00933D, Communication
Jingyang Li, Ying He, Li Wang, Qinhe Pan, Zhiguang Song, Xiaodong Shi
N-2-aryl-1,2,3-triazole derivatives were synthesized as new ligand systems for the construction of photoluminescent active metal–organic frameworks (MOFs).
The content of this RSS Feed (c) The Royal Society of Chemistry




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Chemoselective oxidative addition of vinyl sulfones mediated by palladium complexes bearing picolyl-N-heterocyclic carbene ligands.

Dalton Trans., 2020, 49,5684-5694
DOI: 10.1039/D0DT01144D, Paper
Thomas Scattolin, Claudio Santo, Nicola Demitri, Luciano Canovese, Fabiano Visentin
We have examined in depth the features of oxidative addition of (E)-1,2 ditosylethene on palladium(0) complexes bearing picolyl-N-heterocyclic carbenes.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Ultrabroadband red luminescence of Mn4+ in MgAl2O4 peaking at 651 nm

Dalton Trans., 2020, 49,5711-5721
DOI: 10.1039/D0DT00931H, Paper
Haipeng Ji, Xinghui Hou, Maxim S. Molokeev, Jumpei Ueda, Setsuhisa Tanabe, Mikhail G. Brik, Zongtao Zhang, Yu Wang, Deliang Chen
Mn4+ 2Eg4A2g transition exhibits thermally robust, ultrabroadband luminescence peaking at 651 nm in MgAl2O4 under λex = 440 nm excitation.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Two novel lead-based coordination polymers for luminescence sensing of anions, cations and small organic molecules

Dalton Trans., 2020, 49,5695-5702
DOI: 10.1039/D0DT00533A, Paper
Xue-Yan Zhao, Bing Liang, Ke-Cai Xiong, Yu-Wen Shi, Si-Lei Yang, Ting-Yu Wei, Hui Zhang, Qing-Fu Zhang, Yan-Li Gai
A novel lead-based compound is reported as a multi-responsive luminescent sensor for detecting anions, cations and small organic molecules, especially Cr2O72−, CrO42−, Fe3+ and nitrobenzene.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Comment on “Investigation on the structure and thermoelectric properties of CuxTe binary compounds” by Shriparna Mukherjee et al., Dalton Trans., 2019, 48, 1040

Dalton Trans., 2020, 49,5736-5737
DOI: 10.1039/C9DT03607E, Comment
Aarón H. Barajas-Aguilar, A. M. Garay-Tapia, Sergio J. Jiménez-Sandoval
Copper telluride sensitivity to laser power: effect on the Raman spectra.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Reply to the ‘Comment on “Investigation on the structure and thermoelectric properties of CuxTe binary compounds”’ by A. H. Barajas-Aguilar, A. M. Garay-Tapia, and S. J. Jiménez-Sandoval, Dalton Trans., 2020, 49, DOI: 10.1039/C9DT03607E

Dalton Trans., 2020, 49,5738-5740
DOI: 10.1039/D0DT00412J, Comment
Shriparna Mukherjee, Raju Chetty, P. V. Prakash Madduri, Ajaya K. Nayak, Krzysztof Wojciechowski, Tanmoy Ghosh, Kamanio Chattopadhyay, Satyam Suwas, Ramesh Chandra Mallik
In a communication to Dalton Transaction and in a paper in Journal of Physics: Condensed Matter, Aarón H. Barajas-Aguilar et al. have raised comments on our paper published earlier in Dalton Transactions.
The content of this RSS Feed (c) The Royal Society of Chemistry




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NHC–Au(I) complexes bearing trispyrazolyl borate (Tp) ligands: efficient platforms for bimetallic species

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00908C, Paper
Carlos Ángel-Jijón, David Rendón-Nava, Jose M. Vazques-Pérez, Alejandro Álvarez-Hernández, Daniel Mendoza-Espinosa, Verónica Salazar-Pereda
Treatment of NHC–AuCl (NHC = IPr and IMes) complexes with equimolar amounts of KTpR2 (R = Me, H) salts in tetrahydrofuran produces in high yields the heteroleptic complexes 3–6 with the general formula NHC–Au–TpR2.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Retraction: Determination of chemical affinity of graphene oxide nanosheets with radionuclides investigated by macroscopic, spectroscopic and modeling techniques

Dalton Trans., 2020, 49,5741-5741
DOI: 10.1039/D0DT90074E, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Congcong Ding, Wencai Cheng, Yubing Sun, Xiangke Wang
The content of this RSS Feed (c) The Royal Society of Chemistry




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Retraction: Enhanced adsorption of Eu(III) on mesoporous Al2O3/expanded graphite composites investigated by macroscopic and microscopic techniques

Dalton Trans., 2020, 49,5742-5742
DOI: 10.1039/D0DT90075C, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yubing Sun, Changlun Chen, Xiaoli Tan, Dadong Shao, Jiaxing Li, Guixia Zhao, Shubin Yang, Qi Wang, Xiangke Wang
The content of this RSS Feed (c) The Royal Society of Chemistry




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Theoretical rationalization for the equilibrium between (μ–η2:η2-peroxido)CuIICuII and bis(μ-oxido)CuIIICuIII complexes: perturbational effects from ligand frameworks

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01001D, Paper
Tsukasa Abe, Yoshihito Shiota, Shinobu Itoh, Kazunari Yoshizawa
DFT calculations are carried out to investigate the geometric effects of the supporting ligands in the relative energies of the (μ–η22-peroxido)CuIICuII complex 1 and the bis(μ-oxido)CuIIICuIII complex 2.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Highly covalent metal–ligand π bonding in chelated bis- and tris(iminoxolene) complexes of osmium and ruthenium

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01287D, Paper
Jacqueline Gianino, Seth N. Brown
Describing the π bonding in ruthenium and osmium iminoxolenes as highly covalent allows one to experimentally dissect the electron distribution in these compounds.
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Structural, spectroscopic and electronic properties of a family of bi-octahedral Ru25+/6+ complexes with a bridging 2,5-di(2-pyridyl)pyrrolide ligand

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01325K, Paper
Shi-Rui Kang, Qin Zi Zhou, Chang-Fang Xiong, Bin Liu, John E. McGrady, Mohammed Obies, Chao Liu, Piao He, Xiao-Yi Yi
A family of Ru2 dimers, [Ru2(μ-κ2N,N’:κ2N’,N’’-dpp)2(μ-X)(X)2]q+ (X = Cl, Br, q = 0 and X = I, q = 1) is synthesized from a [Ru2(OAc)4Cl] paddlewheel starting material. The neutral...
The content of this RSS Feed (c) The Royal Society of Chemistry




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The role of the excited state dynamic of the antenna ligand in the Lanthanide sensitization mechanism

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01132K, Paper
María Joaquina Beltrán Leiva, Eduardo Solis Céspedes, Dayan Paez-Hernandez
A fragmentation scheme combined with a series of theoretical approximations like TD-DFT, and multiconfigurational CASSCF/NEVPT2 methods, have been used to describe the photophysical phenomena associated with the antenna effect and...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Luminescent organic dyes containing a phenanthro[9,10-D]imidazole core and [Ir(N^C)(N^N)]+ complexes based on the cyclometalating and diimine ligands of this type

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00568A, Paper
Anastasia I. Solomatina, Kirill M. Kuznetsov, Vladislav V. Gurzhiy, Vladimir V. Pavlovskiy, Vitaly V. Porsev, Robert A. Evarestov, Sergey P. Tunik
New N^N and N^C luminescent ligands with solvatochromic behavior and their iridium complexes were synthesized, characterized and investigated.
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Dehydrogenation of amines in aryl-amine functionalized pincer-like nitrogen-donor redox non-innocent ligands via ligand reduction on a Ni(II) template

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00466A, Paper
Manas Khatua, Bappaditya Goswami, Subhas Samanta
A Ni(II)-template directed dehydrogenative imine formation reaction via ligand reduction leading to the formation of new pincer-like azo imine ligands is described.
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Effects of ligand substituents on the single-molecule magnetic behavior of quinonoid-bridged dicobalt compounds

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00033G, Paper
Xiao-Quan Zhu, Wen-Hai Cao, Shao-Dong Su, Xin-Tao Wu, Tian-Lu Sheng
The SMM behavior weakens until its disappearance with the substituent changing from Br, H to OMe in the quinonoid-bridged dicobalt compounds [(N4Co)2LX](ClO4)2, (X = H, Cl, Br, and OMe).
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry