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Direct alkene functionalization via photocatalytic hydrogen atom transfer from C(sp3)–H compounds: a route to pharmaceutically important molecules

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05026F, Highlight
Hangqian Fan, Yuxin Fang, Jingbo Yu
Direct functionalization of alkenes with C(sp3)–H substrates offers unique opportunities for the rapid construction of pharmaceuticals and natural products.
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Exploring the effect of pressure on the crystal structure and caloric properties of the molecular ionic hybrid [(CH3)3NOH]2[CoCl4]

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05125D, Communication
Open Access
Pedro Dafonte-Rodríguez, Ignacio Delgado-Ferreiro, Javier García-Ben, Angel Ferradanes-Martínez, María Gelpi, Julian Walker, Charles James McMonagle, Socorro Castro-García, María Antonia Señarís-Rodríguez, Juan Manuel Bermúdez-García, Manuel Sánchez-Andújar
The hybrid metal halide [(CH3)3NOH]2CoCl4 exhibits a first-order phase transition at T ∼ 343 K.
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Helical aromatic foldamers with tubular cavities capable of accommodating multiple halide ions

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05474A, Communication
Seungwon Lee, Byeung Ju Lee, Geunmoo Song, Kyu-Sung Jeong
A series of pyridinium–indolocarbazole oligomers has been synthesized, which fold into helical structures with tubular cavities capable of accommodating up to four iodide ions in a linear arrangement.
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Small-sized starch nanoparticles for efficient penetration of plant cells

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05493H, Communication
Yongxian Chen, Simin Jiang, Yang Wang, Fuxue Zhang, Liu Wang, Li Zhao, Siyu Liu, Junjun Tan, Staffan Persson, Bo Sun, Junsheng Chen, Andreas Blennow
Fluorescent starch nanoparticles used in live cell imaging in plants suggest that small-sized starch nanoparticles can efficiently penetrate plant cells, indicating great potential for applications in plant science and agriculture.
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Visible light-activated polyphenol–Al3+ coordination for ambient and quantitative xylose-to-furfural conversion

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04899G, Communication
Jinshu Huang, Qizhi Luo, Tengyu Liu, Song Yang, Hu Li
Visible light-enhanced coordination of polyphenol–Al3+ is uncovered to switch Lewis/Brønsted acid sites for room-temperature cascade upgrading of xylose to furfural in ultrahigh yields.
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Directed nucleophilic aromatic substitution reaction

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04912H, Communication
Yasuyuki Nitta, Takashi Nishikata, Michinori Sumimoto, Yusei Nakashima
In this study, we discovered a directed nucleophilic aromatic substitution reaction, "directed SNAr (dSNAr)", in the reaction of ortho-iodobezamides and amine in the presence of pyridine. The reaction proceeded ortho-specifically...
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Fabrication of gelatin hydrogels using pre-coordinated lanthanide complexes via imine crosslinking

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC03886J, Communication
Chen-Cheng Yu, Yu Yun Hsu, Yu-Chia Su, Yi-Chen Yang, Tzu-Ying Wang, Yi-Cheun Yeh
Precoordinated lanthanide-containing complexes are used to crosslink polyethyleneimine-modified gelatin to form gelatin hydrogel through imine bond formation.
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Hydrazone-linked Covalent Organic Frameworks for Fluorescence Detection of Hg2+

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05468G, Communication
Xuefeng Wang, Zhaowei Yang, Lingsuo Meng, Xuehui Li, Hongtao Wei, Jing Ning, Shitao Wang, Dapeng Cao, Long Hao
A hydrazone-linked COF (DvDf-C3XJ-COF) with hydrogen-bond reinforcement and abundant coordination sites was synthesized, exhibiting strong fluorescence and high sensitivity/selectivity for Hg²⁺ detection, with a detection limit of 1.65 × 10⁻⁶...
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From one to two: In-site constructing C3N5-Poly (triazine imide) heterojunction for enhanced O2 activation

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05077K, Communication
Shiling Xu, Ziheng Yang, Laiqing Zhang, Xiaorui Zhang, Zikang Zeng, Wenxuan Wang, Yujun Liang, Lan Yuan, Chuang Han
A novel C3N5-Poly (triazine imide) (PTI) heterojunction was designed and constructed by thermal polymerization process, which featured with intimated S-scheme interface coupling and exhibited a predominant performance for H2O2 production....
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Radical anions of 1,1-azoliumdithiocarboxylates

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05486E, Communication
Martin Simon Luff, Kai Oppel, Ivo Krummenacher, Holger Braunschweig, Udo Radius
The 1,1-azoliumdithiocarboxylate cAACMe-CS2 (1a) was prepared and its redox chemistry was evaluated and compared to NHC-based dithiocarboxylates IDipp CS2 (1b) and IMes-CS2 (1c). Radical anions [carbene CS2]·– were prepared by...
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Interlayer spacing expansion for V2O5 towards ultra-stable zinc anode-based flexible electrochromic displays in Zn2+/Li+-PC organic electrolyte

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04974H, Communication
Zhe Li, Zhaoyang Song, Linhua Liu, William Yu, Jingwei Chen, Qianqian Zhu, Haizeng Li
To enhance the electrochemical stability and kinetics of V2O5, 3,4-ethylenedioxythiophene (EDOT) was in-situ polymerized within V2O5 interlayers, rendering PEDOT@V2O5 with enlarged layer spacing, increased stability in organic electrolyte, superior electrochemical...
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Electrocatalytic reduction of N2 to NH3 by MIL-88 derived pod-like Fe7Se8/C nanomaterials under ambient conditions

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04683H, Communication
Gongyao Nie, Huanhuan Zhang, Lanhua Yi, Xiao Ma, Wei Yi, Jiawei Wan, Yebo Lu, Xingzhu Wang
In this paper, pod-like Fe7Se8/C nanocomposite catalyst materials were prepared by MIL-88 selenide annealing and the as-prepared Fe7Se8/C nanocatalyst exhibited excellent electrocatalytic performance in neutral electrolyte for electrocatalytic nitrogen reduction...
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Recent Advances in Photochemical Strain-Release Reactions of Bicyclo[1.1.0]butanes

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05108D, Highlight
Xiang Zhou, Ye Hu, Yao Huang, Yang Xiong
Bicyclo[1.1.0]butanes (BCBs) are attractive compounds for their beautiful “butterfly” conformations, distinctive properties, and novel reactivities. As soon as the first example had been synthesized, a wide range of strain-release reactions...
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Zirconium metal–organic framework photocatalysis with TEMPO for blue light-powered aerobic sulfoxidation

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05173D, Communication
Bing Zeng, Yuexin Wang, Kanghui Xiong, Keke Zhang, Siyu Zhang, Xianjun Lang
A catalytic amount of TEMPO, mobile in the reaction medium, enhances the hole transfer of NU-1003 photocatalysis for blue light-powered oxidation of organic sulfides with O2.
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Lipidic biomass as a renewable chemical building block for polymeric materials

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04993D, Feature Article
Rafael Turra Alarcon, Gabriel Iago Iago, Caroline Gaglieri, Aniele De Moura, Éder Tadeu Gomes Cavalheiro, Gilbert Bannach
Polymers are intrinsically connected to our modern society and are found and used in different technologies. Although polymers are worthwhile, concerns about synthetic polymers from non-renewable sources have arisen. Therefore,...
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Crystal-Facet Modulated Pathway of CO2 Photoreduction on Bi4NbO8Cl Nanosheets Boosting Production of Value-Added Solar Fuels

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05581K, Communication
Yong Zhou, Haoqiang Chi, Zhengdao Li, Yong Cai Zhang, Zhigang Zou, Yong Yang, Xinxin Lu, Peiting Hao
Two ultrathin nanosheets of Bi4NbO8Cl were successfully synthesized for photocatalytic conversion of CO2 into solar fuel. featuring differently exposed (001) and (201) facets. In contrast to bulk Bi4NbO8Cl, which produced...
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Tunable synthesis of magnetoelectric CoFe2O4–BaTiO3 core–shell nanowires

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC03701D, Communication
Noah D. Ferson, John R. Ganiban, David P. Arnold, Jennifer S. Andrew
CoFe2O4–BaTiO3 core–shell nanowires with tunable magnetic anisotropy and magnetoelectric coupling are generated using a template-assisted synthetic procedure providing composition control.
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Engineering biotin anchored-MWCNTs as a superb carrier for facile delivery of the potent Ru(II)-N^N scaffold in breast cancer cells

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Chem. Commun., 2024, 60,13376-13379
DOI: 10.1039/D4CC04276J, Communication
Lavanya Thilak Babu, Nilmadhab Roy, Tiasha Dasgupta, Sreejani Ghosh, Ramasamy Tamizhselvi, Priyankar Paira
This article portrays the construction of biotinylated-MWCNTs for SMVT-guided delivery of a potent Ru(II)-scaffold into MCF7 cells.
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Fluorination of antimonene hexagons

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Chem. Commun., 2024, 60,13336-13339
DOI: 10.1039/D4CC03423F, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Michael Fickert, Rebeca Martinez-Haya, Diego López-Alcalá, Frank Hauke, José J. Baldoví, Andreas Hirsch, Gonzalo Abellán
Fluorination of two-dimensional antimonene hexagons synthesized through colloidal synthesis has been reached using CF4 plasma through a reactive ion etching process.
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Revealing the structural influence mechanism of intrinsic potassium/calcium elements on bio-waste-derived hard carbon for sodium-ion batteries

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Chem. Commun., 2024, 60,13380-13383
DOI: 10.1039/D4CC03546A, Communication
Yinghao Zhang, Chun Wu, Qinghang Chen, Chuangchuang Li, Wenjie Huang, Qianxiong Wen, Xiang-Xi He, Xingqiao Wu, Shu-Lei Chou
The evolution mechanism of hard carbon structures in terms of graphitization and pore structure caused by K/Ca has been clarified.
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Catalytic applications of organic–inorganic hybrid porous materials

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Chem. Commun., 2024, 60,13325-13335
DOI: 10.1039/D4CC04284K, Feature Article
Maodi Wang, Huicong Dai, Qihua Yang
Insights into the synergistic effects of different active sites of organic–inorganic hybrid porous materials for thermal- and photo-catalysis were discussed.
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Nitrogen-doped graphene quantum dot-intensified tungsten oxide nanosheets as a SERS substrate for antibiotics detection

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Chem. Commun., 2024, 60,13360-13363
DOI: 10.1039/D4CC05052E, Communication
Lu Tan, Xuanzhao Lu, Shuzhen Yue, Yue Cao, Yang Zhou, Baokang Jin, Jun-Jie Zhu
Tungsten oxide nanosheets loaded with nitrogen-doped graphene oxide quantum dots (NGQDs/WO3 NSs) were fabricated as SERS substrates.
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Catalytic asymmetric Michael and Nef-type sequential reaction of nitroolefin with azlactone to construct oxazole-fused succinimide

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Chem. Commun., 2024, 60,13384-13387
DOI: 10.1039/D4CC04858J, Communication
Rui Weng, Yuqiao Zhou, Yaqin Zhang, Xiaoming Feng, Xiaohua Liu
A series of oxazole-fused succinimides bearing vicinal quaternary carbon centers were synthesized via catalytic asymmetric Michael addition and Nef-type sequential reactions of nitroolefins with azlactones.
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Employing a PhI(OAc)2-mediated domino reaction to assemble nitrogen-containing heterocyclic derivatives and assessing their anti-inflammatory activity

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Chem. Commun., 2024, 60,13352-13355
DOI: 10.1039/D4CC03245D, Communication
Xinyue Li, Yuhua Fang, Yuanyuan Zhao, Shenshen Luo, Yuhui Xue, Tingting Yong, Bin Wang
Metal-free radical cascade synthesis of substituted pyrazole derivatives was initiated by PhI(OAc)2 at 23 °C.
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Mn and Mo co-doped NiS nanosheets induce abundant Ni3+–O bonds for efficient electro-oxidation of biomass

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Chem. Commun., 2024, 60,13392-13395
DOI: 10.1039/D4CC04818K, Communication
Pengfei Ren, Zixuan Wang, Wenchao Zhang, Fang Duan, Shuanglong Lu, Mingliang Du, Han Zhu
MnMo–NiS were synthesized for electro-oxidizing ethylene glycol (EG), glycerol (GLY), and 5-hydroxymethylfurfural (HMF), achieving faradaic efficiencies of 97.5%, 98.6%, and 99.2%, and yield rates of 615.7, 475.5, and 333.9 μmol h−1 cm−2.
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PVDF nanocomposites with aligned boron nitride nanosheets and dispersed BaTiO3@PEG nanoparticles by a superspreading strategy towards high energy density

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Chem. Commun., 2024, 60,13344-13347
DOI: 10.1039/D4CC04430D, Communication
Dajun Hou, Jingjing Zhou, Wen Chen, Jing Zhou, Pengchao Zhang
The limited improvement in discharge energy density (Ue) of polyvinylidene fluoride (PVDF) nanocomposites filled with low-dielectric-constant (εr) nanosheets has been addressed by using a superspreading layering strategy.
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Ion induced ultra-tough single-network ionogel

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Chem. Commun., 2024, 60,13388-13391
DOI: 10.1039/D4CC04732J, Communication
Zhenchuan Yu, Biaolong Ma, Jiqiang Wang
A strategy to fabricate ultra-tough ionogels by ionic induction is proposed, which provides a simple and general method for tuning ionogel properties.
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Sulfonated hierarchical ZSM-5 zeolite monoliths as solid acid catalyst for esterification of oleic acid

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Chem. Commun., 2024, 60,13356-13359
DOI: 10.1039/D4CC05044D, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Binhang Zhao, Pan Yang, Nan Zhang, Donald R. Inns, Elena F. Kozhevnikova, Alexandros P. Katsoulidis, Ivan V. Kozhevnikov, Alexander Steiner, Haifei Zhang
Sulfonated hierarchical H-ZSM-5 monoliths were synthesized via ice-templating as solid acid catalysts for biodiesel production.
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Expedient (3+3)-annulation of carbonyl ylides with azaoxyallyl cations: formal access to oxa-benzo[c]azepin-3-ones

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Chem. Commun., 2024, 60,13368-13371
DOI: 10.1039/D4CC04946B, Communication
Kshitiz Verma, Hemanga Bhattacharyya, Sharajit Saha, Tharmalingam Punniyamurthy
Cascade C–C/C–N bond formation of carbonyl ylides with azaoxyallyl cations generated in situ using Rh-catalysis has been accomplished in the presence of a base at room temperature.
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Solution plasma synthesis of α-amino acids

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Chem. Commun., 2024, 60,13408-13411
DOI: 10.1039/D4CC04482G, Communication
Changhua Wang, Yutong Zhang, Yuanyuan Li, Yinhe Rong, Xintong Zhang
This work uses solution plasma for easier control of amino acid synthesis, successfully producing rare serine, achieving green and low-carbon synthesis from small molecules to amino acids.
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Polymeric membrane ion-selective electrode based on potential-modulated ion transfer: ultrasensitive measurement of oceanic pH

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Chem. Commun., 2024, 60,13404-13407
DOI: 10.1039/D4CC04807E, Communication
Lu Liu, Yuanxin Liu, Tianjia Jiang, Rongning Liang, Wei Qin
A simple approach to improve the precision of potentiometric sensors is proposed based on potential-modulated ion transfer without memory effects.
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Bipyridine-based conjugated microporous polymers for boosted photocatalytic U(VI) separation

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Chem. Commun., 2024, 60,13348-13351
DOI: 10.1039/D4CC04456H, Communication
Yun Xie, Zifan Li, Chenchen Liu, Qiming Song, Yunhai Liu, Zhibin Zhang, Bin Han
Incorporating bipyridine (BPY) units into conjugated microporous polymers (CMPs) boosts exciton dissociation, charge separation, and oxidation capacity, thereby exhibiting an admired U(VI) separation rate under sacrificial agent-free conditions.
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Universal synthesis of pure-phase IB-group Sn-based alloys with modulable electrocatalytic CO2 reduction products

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Chem. Commun., 2024, 60,13436-13439
DOI: 10.1039/D4CC05317F, Communication
Luyao Yang, Wenqing Zhang, Ximei Lv, Qianqian Zhao, Xiaojing Liu, Shulin Zhao, Yuhui Chen
A universal method for synthesizing a range of pure-phase IB-group Sn-based alloy catalysts (Cu3Sn, Ag4Sn, and AuSn) for electrochemical reduction of CO2.
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Site-specific acetyl modification of 2'-OH of RNA by an oligonucleotide acetylating reagent

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Chem. Commun., 2024, 60,13440-13442
DOI: 10.1039/D4CC04672B, Communication
Hirotaka Murase, Mio Eto, Jeongsu Lee, Yosuke Taniguchi, Shuhei Imoto, Shigeki Sasaki
A novel oligonucleotide acetylating-reagent that induces a site-specific RNA acetylation through duplex formation has been developed.
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Ultrafine PtCo alloy nanoparticles integrated into porous N-doped nanosheets for durable oxygen reduction reaction

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Chem. Commun., 2024, 60,13432-13435
DOI: 10.1039/D4CC04661G, Communication
Baoliang Chen, Lei Zhao, Zhaozhao Zhu, Pei Xiong, Zhao Li, Jun Song Chen, Lanlan Li, Rui Wu
The PtCo–CoNC–P catalyst, featuring sub-3 nm small-size PtCo alloy nanoparticles integrated into a porous nitrogen-doped nanosheet, exhibits exceptional durability after 30 000 cycles of accelerated durability tests.
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Functional metal–organic frameworks derived electrode materials for electrochemical energy storage: a review

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Chem. Commun., 2024, 60,13292-13313
DOI: 10.1039/D4CC04086D, Highlight
Basree, Arif Ali, Khusboo Kumari, Musheer Ahmad, Ganesh Chandra Nayak
Pristine MOFs and their derivatives have been proven for supercapacitor as well as energy storage due to their versatile features like huge specific surface area, high porosity, redox active metal centre, high thermal stability, and so on.
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Enhancing the performance of ionic conductivity for solid-state electrolytes: an effective strategy of injecting lithium ions within anionic metal–organic frameworks

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Chem. Commun., 2024, 60,13416-13419
DOI: 10.1039/D4CC04515G, Communication
Lu Shi, Xin Wang, Zhiliang Liu
An ionotropic MOF (Li+[Cu-BTC]) with lithium ions in the pores of the lattice was synthesized, which displays outstanding lithium ionic conducting properties over a wide temperature range.
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On site portable detection of gaseous I2 using green and pollution-free electrochemical methods

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05418K, Communication
Xiao-Lan Yang, Qiu-Hong Zhu, Guo-Hao Zhang, Shuang-Long Wang, Lijian Ma, Song Qin, Guo-Hong Tao, Ling He
A poly(ionic liquid) (PIL) probe material that is rich in I2 interaction sites was developed, and a green and pollution-free electrochemical method was used to detect gaseous I2 using PIL-based film sensors.
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Bioinspired hydrogels: polymeric designs towards artificial photosynthesis

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Chem. Commun., 2024, 60,13314-13324
DOI: 10.1039/D4CC04033C, Feature Article
Open Access
Reina Hagiwara, Ryo Yoshida, Kosuke Okeyoshi
This Feature Article outlines the design of polymer networks for water splitting induced by visible light to develop artificial chloroplasts. The network serves as a mediator for photoinduced electron transfer among precisely organised molecules.
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Investigations of the interactions between ZnO nanorods and H2 with 17O NMR spectroscopy

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05371K, Communication
Benteng Song, Fang Wang, Qin Zhu, Ling-Hai Xie, Luming Peng
Schematic diagram for the interaction of H2 with ZnO nanorods under different conditions.
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Intramolecular cyclization of N-aryl amides for the synthesis of 3-amino oxindoles

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05259E, Communication
Haitao Yang, Yu Pan, Yijing Tian, Kaili Yu, Yifeng Bai, Yonggang Jiang, Hongbin Zhang, Guogang Deng, Xiaodong Yang
A mild and efficient strategy to synthesize pharmaceutically important 3-amino oxindoles from readily available N-aryl amides has been developed.
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An effective orange-red solution-processed circularly polarized organic light-emitting diode

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04938A, Communication
Junqing Wang, Xiaoyi Lai, Yongzhi Zhou, Lei Hua, Weiguo Zhu, Pengfei Duan, Yafei Wang
Two orange-red emission circularly polarized thermally activated delayed fluorescence emitters (R)-ad-PXZ/(S)-ad-PXZ were synthesized. The solution processable device exhibits the maximum external quantum efficiency of 9.0% and gEL value of 10−3.
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A MOF-derived CuO/TiO2 photocatalyst for methanol production from CO2 reduction in an AI-assisted continuous flow reactor

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05008H, Communication
Bhavya Jaksani, Ruchi Chauhan, Switi Dattatraya Kshirsagar, Abhilash Rana, Ujjwal Pal, Ajay K. Singh
An AI-assisted continuous flow reactor for CO2 reduction to methanol using a MOF-derived CuO/TiO2 photocatalyst.
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Synthesis of substituent-free dioxadiaza[8]circulene to investigate intermolecular interactions and photophysical properties

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05539J, Communication
Aoi Nakagawa, Wataru Ota, Takumi Ehara, Yusuke Matsuo, Kiyoshi Miyata, Ken Onda, Tohru Sato, Shu Seki, Takayuki Tanaka
Substituent-free dioxadiaza[8]circulene has been synthesized and its dense packing structure and optical properties were analyzed in detail.
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Rapid identification of P–C bonds in phosphorus–carbon anode materials

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC03317E, Communication
Yadong Ye, Qiang Xiao, Huanyu Xie, Hongchang Jin, Hengxing Ji
This work presents a simple, rapid, and convenient spectroscopic analysis method for characterizing the bonding state in phosphorus-carbon composites.
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Polarizable AMOEBA force field predicts thin and dense hydration layer around monosaccharides.

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04415K, Communication
Open Access
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Luke A Newman, Mackenzie G Patton, Breyanna A Rodriguez, Ethan W Sumner, Valerie Vaissier Welborn
Polarizable force fields crucially enhance the modeling of macromolecules in polar media. Here, we present new parameters to model six common monosaccharides with the polarizable AMOEBA force field. These parameters...
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Rapid and sensitive detection of vanillylmandelic acid based on a luminescent fourteen-metal Tb(III) planar nanocluster

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC03667K, Communication
Yanheng Meng, Shiqing Wang, Xiaoli Lv, Xianfeng Huang, Wei-Bing Zhang, Xiaojun Wu, Desmond Schipper, Xiaoping Yang
A 14-metal Tb(III) nanocluster with four CO32- anions as templates was constructed for the quantitative and qualitative detection of vanillylmandelic acid (VMA) with high sensitivity and selectivity. The luminescence response...
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Palladium catalyzed C(sp3)-H alkylation of 8-methylquinolines with aziridines: access to functionalized γ-quinolinylpropylamines

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05275G, Communication
Anita Sahoo, Tripti Paul, Shubhajit Basak, Tharmalingam Punniyamurthy
Palladium-catalyzed directed site-selective C(sp3)-H alkylation of 8-methylquinolines has been accomplished using aziridine as an alkylating source via a sequential C-H and C-N bond activation. Site selectivity, funtional group tolerance and...
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Metal-free photocatalysts with charge-transfer excited states enable visible light-driven atom transfer radical polymerization

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04470C, Communication
Yuchen Huang, Yangxin Liu, Yingde Yan, Yanjun Gong, Yifan Zhang, Yanke Che, Jincai Zhao
Photoredox-catalyzed atom transfer radical polymerization (O-ATRP) offers powerful tools for the precise control of polymer synthesis. Metal-free photocatalysts are particularly desirable due to their high level of control in O-ATRP...
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Ceria-based supported metal catalysts for the low-temperature water-gas shift reaction

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04072D, Feature Article
Xin-Pu Fu, hui zhao, Chun-Jiang Jia
Water-gas shift (WGS) reaction is a crucial step for the industrial production of hydrogen or upgrading hydrogen generated from fossil or biomass sources by removing the residual CO. However, current...
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