io Exploring the mechanism of the reductive amination of acetophenones via Borch approach: the role of the acid catalyst By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4OB00160E, PaperJoão Pedro Albuquerque Souza, Amanda Krauskopf Jacobs, Leandro Piovan, Renan Borsoi CamposThe energetic viability of several mechanistic variations of the reductive amination of acetophenones via the Borch approach was reexamined through density functional theory calculations. The crucial involvement of the acid...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io 3-Halo-5,6-dihydro-4H-1,2-oxazine N-oxides as synthetic equivalents of unsaturated nitrile oxides in the [3 + 2]-cycloaddition with arynes: synthesis of substituted 3-vinyl-1,2-benzisoxazoles By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Advance ArticleDOI: 10.1039/D4OB00391H, CommunicationAlexander A. Lukoyanov, Svetlana A. Aksenova, Andrey A. Tabolin, Alexey Yu. Sukhorukov3-Halo-1,2-oxazine N-oxide derivatives act as surrogates of vinyl nitrile oxides in tandem [3 + 2]-cycloaddition/[3 + 2]-cyclofragmentation with arynes leading to benzisoxazoles.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Cu(OTf)2/HFIP catalyzed regioselective cycloisomerization of indole-C3-functionalized alkynols to carbazoles By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Advance ArticleDOI: 10.1039/D4OB00421C, CommunicationSrinivasarao Yaragorla, Tabassum Khan, Sayonika ChakrobortyWe report here a simple and atom economic cycloisomerization reaction of indole-tethered alkynols for constructing diverse carbazoles via 1,2-alkly migration using Cu(OTf)2/HFIP as the excellent promoter system.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Dess–Martin periodinane-mediated oxidation of the primary alcohol of cytidine into a carboxylic acid By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Advance ArticleDOI: 10.1039/D4OB00240G, Communication Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Alexandra R. E. Serre, Vibhu Jha, Adèle Rivault, Leif A. Eriksson, Goreti Ribeiro Morais, Robert A. FalconerHerein we describe the first example of the conversion of the primary alcohol of cytidine into a carboxylic acid by use of the Dess–Martin periodinane oxidising agent.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Revisiting Biginelli-like Reactions: Solvent Effects, Mechanisms, Biological Applications and Correction of Several Literature Reports By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4OB00272E, PaperBrenno A. D. Neto, Pedro Beck, Arthur Leitão, Yasmin Santana, Jose R. Correa, Carime Vitória da Silva Rodrigues, Daniel Machado, Guilherme Matos, Luciana Machado Ramos, Claudia Cristina Gatto, Carlos Kleber Z. Andrade, Sarah CaldasThis study critically reevaluates reported Biginelli-like reactions using a Kamlet-Abboud-Taft-based solvent effect model. Surprisingly, structural misassignments were discovered in certain multicomponent reactions, leading to the identification of pseudo three-component derivatives...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Photoproperties of Favipiravir and their 6-Substituted Analogues: Fluorescence Controlled through Halogen Substitution and Tautomerism By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4OB00397G, PaperAngel H Romero, Marcos Couto, Ivan E Romero, German Fuentes, Matías N. MöllerHerein, we showed the photophysical properties of the favipiravir and their 6-substituted analogues. Also, we interpreted the origin of the fluorescence of the favipiravir and their 6-substituted analogues as function...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Design, synthesis, biological evaluation and molecular docking studies of quinoline-anthranilic acid hybrids as potent anti-inflammatory drugs By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Advance ArticleDOI: 10.1039/D4OB00040D, PaperSidra Siddique, Khalid Hussain, Naureen Shehzadi, Muhammad Arshad, Muhammad Nadeem Arshad, Sadaf Iftikhar, Farhat Saghir, Ayisha Shaukat, Muhammad Sarfraz, Nisar AhmedDespite the high global prevalence, rheumatoid arthritis lacks a satisfactory treatment.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Recent developments in the enzymatic modifications of steroid scaffolds By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Advance ArticleDOI: 10.1039/D4OB00327F, Review Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Huibin Wang, Ikuro AbeThis review highlights the recent advancements in the enzymatic modifications of steroid scaffolds, emphasizing enzymatic hydroxylation, ketoreduction, dehydrogenation, enzymatic cascade reactions, and other modifications.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Isothiocyanates: Happy-Go-Lucky Reagents in Organic Synthesis By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4OB00281D, Review ArticleBubul Das, Anjali Dahiya, Bhisma K Patel: Owing to their unique structural features, isothiocyanates (ITCs) are a class of highly useful and inimitable reagents as the N=C=S group serves both as electrophile and nucleophile in organic...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Synthesis of Deuteriodifluoromethylthiolated Isocoumarins-1- imines and Isocoumarins Enabled by Multi-Component Reagents System (MCRS) By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4OB00328D, CommunicationXuemin Li, Haofeng Shi, Jiaxin He, Jialiang Wu, Fengxia Sun, Yunfei DuThe combining use of BnSCF2D, mCPBA and Tf2O serves as an efficient multi-component reagents system (MCRS) for the synthesis of deuteriodifluoromethylthiolated isocoumarins-1-imines/isocoumarins via intramolecular cyclization/ deuteriodifluoromethylthiolation of 2-alkynylbenzamide/2-alkynylbenzoates. The approach...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Natural products from human microbiome: an emergent frontier in organic synthesis and drug discovery By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4OB00236A, Review ArticleGoverdhan Mehta, Saumitra Sengupta, Srihari PabbarajaOften referred to as “second genome”, human microbiome is at the epicenter of a complex inter-habitat biochemical network, such as the “gut-brain axis”, which have emerged as significant determinant of...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io TEMPO/PhI(OAc)2 promotes the α-aminophosphinoylation of alcohols with amines and H-phosphine oxides in aqueous medium By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Advance ArticleDOI: 10.1039/D4OB00302K, CommunicationQiang Huang, Xin Jin, Lvjia Wu, Jiangdong Li, Qianlu Xing, Xianheng Wang, Changkuo ZhaoThe aminophosphinoylation of alcohols with amines and H-phosphine oxides provides an efficient and mild approach to access various α-aminoalkylphosphine oxides in good yields with good tolerance of functional groups using H2O as a clean solvent.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io An FeCl3-catalyzed three-component reaction for the synthesis of β-(1,2,3-triazolyl)-ketones using DMF as a one-carbon source By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Advance ArticleDOI: 10.1039/D4OB00207E, CommunicationRuilin Fang, Lei Zheng, Xuyang Chen, Can Wang, Yunfeng ChenFeCl3-catalyzed oxidative condensation of NH-1,2,3-triazoles and aryl methyl ketones and DMF has been reported.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Design, synthesis, and biological application of A–D–A-type boranil fluorescent dyes By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Advance ArticleDOI: 10.1039/D4OB00297K, PaperWei Luo, Yiling Li, Liang Wang, Yanhua Qin, Qiao Cheng, Guochang Hu, Chaoyi Yao, Xiangzhi SongAcceptor–donor–acceptor boranil fluorescent dyes, CSU-BF-R (R = H, CH3, and OCH3), were developed with strong red fluorescence and large Stokes shifts. CSU-BF-OCH3 could selectively sense intracellular hypochlorous acid in living cells and zebrafish.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Facile synthesis of tetrahydroquinoline containing dithiocarbamate derivatives via one-pot sequential multicomponent reaction By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4OB00490F, CommunicationSIDDHARTHA KUMAR SENAPATI, Anit Pal, Animesh DasAn efficient sequential multi-component method for the synthesis of tertrahydroquinoline containing dithiocarbamate has been developed. This reaction involved a boronic acid-catalyzed reduction of quinoline to tertrahydroquinoline, followed by nucleophilic addition...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io A Highly Diastereoselective One-Pot Ugi/Radical Spirocyclization/Aza-Michael Addition Sequence By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4OB00610K, CommunicationChandra Volla, Salman Khan, Abhradeep Chatterjee, Akshay Murali NairWe hereby report a highly diastereoselective synthesis of chalcogenated azaspirotricycles via a one-pot Ugi/spirocyclization/ aza-Michael addition sequence. The reaction proceeded via a key visible light mediated spirocyclization step under mild,...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io New Generation of Highly Reactive Allylborating Agents For Cu(I)-Catalyzed Allylation of Chiral Sulfinylimines By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4OB00291A, PaperMichael S. Alexeev, Tatyana V. Strelkova, Michail M. Ilyin, Jr., Yulia V. Nelyubina, Ivan A. Bespalov, Michael Medvedev, Victor N Khrustalev, Nikolai KuznetsovThe implementation of selective catalytic processes with highly active reagents is an attractive strategy that meets modern principles of sustainable development of chemistry. In the current study, we for the...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io N-Functionalization of beta-aminophosphonates; Cytotoxic effect of the new derivatives By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4OB00243A, PaperGyörgy Keglevich, Petra Regina Varga, Emőke Dinnyési, Zsuzsanna Szalai, Szilvia Bősze, Rita Oláhné Szabó, Laszlo Drahos, Konstantin KaraghiosoffBeta-Aminophosponates obtained by the Michael addition of primary amines to the double bond of diethyl vinylphosphonate proved to be suitable starting materials (amine components) in the Kabachnik–Fields reaction with formaldehyde...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Sustainable preparation of 2-acylbenzothiazoles under the cooperation of ionic liquids and microwave irradiation By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Advance ArticleDOI: 10.1039/D4OB00315B, PaperShoushun Wang, Mengjie Liu, Yiyuan Yue, Xiude Hu, Yalin Zhang, Guodong Shen, Ruiguo Dong, Lilong Shi, Bing Yu, Xianqiang HuangA series of 2-acylbenzothiazole derivatives were sustainably synthesized for the first time under the cooperation of ionic liquids and microwave irradiation, metal- and extra-additives-free conditions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Regioselective synthesis of 4-arylamino-1,2-naphthoquinones in eutectogel as a confined reaction medium using LED light By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Advance ArticleDOI: 10.1039/D4OB00140K, CommunicationR. Vara Prasad, Yogendra Kumar, R. Arun Kumar, Tohira Banoo, Subbiah NagarajanThe use of a simple carbohydrate-derived eutectogel facilitating a LED-light-induced regioselective synthesis of 4-arylamino-1,2-naphthoquinones in good yields is reported.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Efficient synthesis of SCF3-containing 3-alkenylquinoxalinones via three-component radical cascade reaction By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Advance ArticleDOI: 10.1039/D4OB00363B, PaperSi-Yu Wang, Chu Liu, Wei Yang, Zhong-Ying Tian, Lin Yuan, Long-Yong XieA three-component cascade reaction of quinoxalinones, alkynes and AgSCF3 toward complete E-selective SCF3-containing 3-alkenylquinoxalinones was developed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Base- and sulfur-promoted oxidative lactonization of chalcone-acetate Michael adducts: access to pyran-2-ones By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Advance ArticleDOI: 10.1039/D4OB00479E, CommunicationCao Nguyen Nguyen, Duc Toan Nguyen, Ha An Tran, Dinh Hung Mac, Thi Thu Tram Nguyen, Pascal Retailleau, Thanh Binh NguyenA cost-effective, practical, straightforward and scalable synthesis of α-pyrones via base- and sulfur-promoted annulation of phenylacetates and chalcones is reported.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Visible light-driven photocatalytic sulfonative oxidation of benzyl secondary amines By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4OB00348A, PaperYong-Xiang Lü, Xinqian Wang, Ying-Ming Pan, Keyume AblajanA method for the α-oxidation and sulfonation of benzyl secondary amines was developed utilizing Ir(III) or Eosin Y as the photocatalyst in the presence of O2 as a green oxidant....The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io K2CO3-Mediated (3+3-1) Annulation of 1,3-Acetonedicarboxylates with 2-Fluoro-1-nitroarenes: Synthesis of Indoles By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4OB00488D, PaperMeng-Yang Chang, Chin-Huey Ho, Hsing-Yin ChenThe K2CO3-mediated one-pot reaction of 1,3-acetonedicarboxylates with 2 equiv. of substituted 2-fluoro-1-nitrobenzenes has been developed to synthesize various 2,3-dicarboxylate indoles via a tandem (3 + 3 − 1) annulation pathway....The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Introduction to Service Worker: How to use Service Worker By www.html5rocks.com Published On :: Mon, 01 Dec 2014 00:00:00 +0000 Service Worker will revolutionize the way we build for the web. Learn about what it is, why it is important and how to use it. Full Article
io History API: Scroll Restoration By developers.google.com Published On :: Wed, 02 Sep 2015 00:00:00 +0000 Full Article
io The EME Logger extension By developers.google.com Published On :: Thu, 17 Sep 2015 00:00:00 +0000 Full Article
io As the price of aviation turbine fuel soars, airlines’ finances spin out of control By www.thehindubusinessline.com Published On :: Sun, 25 Jul 2021 16:35:44 +0530 Full Article Flight Plan
io Regional airlines fly into rough weather By www.thehindubusinessline.com Published On :: Sun, 08 Aug 2021 21:02:06 +0530 From poor applicability of policy to lack of quality manpower and capital, problems plaguing them are manifold Full Article Flight Plan
io Indian aviation: A study in paradox By www.thehindubusinessline.com Published On :: Sun, 05 Sep 2021 17:15:12 +0530 Accurate reading of the market is critical Full Article Flight Plan
io Tech adoption will not lead to loss of jobs By www.thehindubusinessline.com Published On :: Sun, 28 Nov 2021 18:17:53 +0530 Every half per cent increase in GDP requires 10 per cent growth in travel Full Article Flight Plan
io Deep tech is helping airlines sustain operations during Covid By www.thehindubusinessline.com Published On :: Mon, 24 Jan 2022 09:51:21 +0530 Integrated biometric-enabled frameworks for real-time test results, travel details and vaccine status are key to making air travel safe Full Article Flight Plan
io From geopolitics strife to a war of words between two aviation giants By www.thehindubusinessline.com Published On :: Sun, 20 Feb 2022 22:00:00 +0530 Qatar Airways and Airbus lock horns over safety concerns Full Article Flight Plan
io Aviation industry shifts focus to digital By www.thehindubusinessline.com Published On :: Sun, 03 Apr 2022 18:39:12 +0530 The pandemic has helped usher in automated touchpoints for tech-savvy flight passengers Full Article Flight Plan
io Sustainable aviation fuels could be a game-changer By www.thehindubusinessline.com Published On :: Sun, 01 May 2022 18:55:45 +0530 But adopting it in Indian aviation could take time Full Article Flight Plan
io Evolution of security in aviation By www.thehindubusinessline.com Published On :: Sun, 01 May 2022 18:56:29 +0530 Data and technology need to be adopted Full Article Flight Plan
io Blockchain: Piloting the future of aviation By www.thehindubusinessline.com Published On :: Sun, 07 Aug 2022 22:30:00 +0530 Enables effective solutions that positively impact industry players and end consumers Full Article Flight Plan
io Mission to Net Zero: Aviation’s focus on making sustainable connections By www.thehindubusinessline.com Published On :: Sun, 21 Aug 2022 21:00:00 +0530 Flying the cleanest, greenest, youngest fleet possible can be a way towards the goal Full Article Flight Plan
io Navigating newer disruptions with maximum agility By www.thehindubusinessline.com Published On :: Sun, 02 Oct 2022 21:00:00 +0530 Focusing on hyper-personalisation, using the right communication tools and platforms, engaging with the customers at the right time and place will give a much-needed fillip to the industry Full Article Flight Plan
io Compliance with regulation: Staying ahead is key By www.thehindubusinessline.com Published On :: Sun, 30 Oct 2022 21:00:00 +0530 Full Article Flight Plan
io Why has private capital not been taken to Indian aviation By www.thehindubusinessline.com Published On :: Sun, 30 Oct 2022 21:00:00 +0530 With banks becoming increasingly cautious and credit flows tightening, private capital must be explored and enticed Full Article Flight Plan
io OpenAI chair's AI startup Sierra gets $4.5 billion valuation in latest funding round By www.thehindu.com Published On :: Tue, 29 Oct 2024 09:42:25 +0530 One-year-old Sierra focuses on selling artificial intelligence-powered customer service chatbots to enterprises Full Article Technology
io Meta builds AI search engine to cut Google, Bing reliance, the Information reports By www.thehindu.com Published On :: Tue, 29 Oct 2024 10:00:06 +0530 The Facebook-owner currently relies on Google and Bing search engines to give users answers on news, stocks and sports Full Article Technology
io Microsoft Teams to launch threaded conversations, combined chats and channels features By www.thehindu.com Published On :: Tue, 29 Oct 2024 11:28:42 +0530 The app has also added other changes in the interface so users can organise their chats better Full Article Technology
io Jio’s Diwali Dhamaka plan offers year-long prepaid plan for ₹3,599 By www.thehindu.com Published On :: Tue, 29 Oct 2024 13:14:07 +0530 Jio is offering a prepaid plan of 2.5 GB of data per day for an entire year, priced at₹3,599, as part of a Diwali offer Full Article Technology
io OpenAI builds first chip with Broadcom and TSMC, scales back foundry ambition By www.thehindu.com Published On :: Wed, 30 Oct 2024 08:32:52 +0530 OpenAI is working with Broadcom and TSMC to build its first in-house chip designed to support its artificial intelligence systems, per sources Full Article Technology
io Google ad change could affect millions of small businesses By www.thehindu.com Published On :: Wed, 30 Oct 2024 09:22:43 +0530 Google is changing the way its Google Local Services ads work, which could affect millions of small businesses Full Article Technology
io Elon Musk's xAI in talks to raise funding valuing it at $40 billion: Report By www.thehindu.com Published On :: Wed, 30 Oct 2024 09:57:24 +0530 Earlier in October, OpenAI raised $6.6 billion in funding from investors which could value the company at $157 billion Full Article Technology
io Microsoft, Meta, Apple, Amazon, and the burden of expectations knock Wall Street sharply lower By www.thehindu.com Published On :: Fri, 01 Nov 2024 09:27:41 +0530 Drops for Big Tech companies including Microsoft and Facebook’s parent company Meta Platforms led Wall Street lower Full Article Technology
io Perplexity AI CEO says “still haven’t gotten” a green card amid immigration debate ahead of U.S. Presidential Election 2024 By www.thehindu.com Published On :: Fri, 01 Nov 2024 16:12:23 +0530 Srinivas went on to work with OpenAI for a year before co-founding Perplexity AI in 2022 Full Article Technology
