ic Structure modification and luminescence regulation in new violet light excitable Sr(2−y)BayY4La4(SiO4)6O2:xEu2+ phosphors via cation substitution By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17989-18002DOI: 10.1039/D4DT02195A, PaperJie Zhang, Langping Dong, Feng Wang, Jingshan Hou, Yongzheng FangA series of violet light excitable Sr(2−y)BayY4La4(SiO4)6O2:xEu2+ phosphors with tunable luminescence for high-quality white LEDs was developed through cation regulation.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic Optimizing synergistic effects: creating oxygen vacancies in NiCoWO4via a solid-state grinding method for improved energy storage performance By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17948-17962DOI: 10.1039/D4DT02118E, PaperAnandhavalli Jeevarathinam, Arun Annamalai, Ramya Ravichandran, Kumaresan Annamalai, Sundaravadivel ElumalaiWe disclose, for the first time we report the synthesis of an oxygen vacancy-enriched NiCoWO4 electrode by a simple solid state grinding method using NaBH4 as a mild reducing agent without any solvents.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic Coinage metal(I) clusters supported by a 1,10-phenanthroline-phosphine: orange-to-NIR phosphorescence, metallophilic interactions and enhanced cytotoxicity By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18027-18036DOI: 10.1039/D4DT02642J, PaperAlexander V. Artem'ev, Maria P. Davydova, Lyubov S. Klyushova, Evgeniy H. Sadykov, Mariana I. Rakhmanova, Taisiya S. SukhikhBased on 2-(diphenylphosphino)-1,10-phenanthroline, a series of small metal(I) clusters, exhibiting orange to NIR phosphorescence and strong dose-dependent cytotoxicity.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic Tunability of triplet excited states and photophysical behaviour of bis-cyclometalated iridium(III) complexes with imidazo[4,5-f][1,10]phenanthroline By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17934-17947DOI: 10.1039/D4DT01996B, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Katarzyna Choroba, Joanna Palion-Gazda, Mateusz Penkala, Patrycja Rawicka, Barbara MachuraThe impact of cyclometalating ligands on the photophysical behaviour of heteroleptic Ir(III) complexes with imidazo[4,5-f][1,10]phenanthroline. [Ir(ppy)2(imphen)]+ is a 3MLLCT emitter, while [Ir(pybzth)2(imphen)]+ has a predominant 3LCN∩C character.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic Catalytic partial oxidation of methane over oxide-ion-conductive lanthanum silicate apatites By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18021-18026DOI: 10.1039/D4DT02421D, PaperAfif Pamungkas, Yuta Goto, Kazumasa Murata, Saburo Hosokawa, Satoshi Ogawa, Kosaku Ohishi, Tomohiro Matsumoto, Miwa Saito, Teruki MotohashiThe oxide-ion-conductive lanthanum silicate La9.33Si6O26 with an apatite-type structure exhibits high activity for the catalytic partial oxidation of methane (CPOX).The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic An acidity-triggered aggregation nanoplatform based on degradable mesoporous organosilica nanoparticles for precise drug delivery and phototherapy of focal bacterial infection By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17893-17901DOI: 10.1039/D4DT02111H, PaperYunhan Huang, Wei Guo, Xinyu Wang, Jingrui Chang, Bo LuAn acidity-triggered aggregation antibacterial nanoplatform based on biodegradable mesoporous organic silica nanoparticles, is reported. It enables precise drug release and spatial accuracy for photodynamic therapy and photothermal therapy.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic Gold nanoparticle-decorated amorphous carbon for oxidative cyclization of anthranilamide and aryl alcohols By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17976-17988DOI: 10.1039/D4DT02355B, PaperThe Thai Nguyen, Huyen-Tran Thi Nguyen, Thu Anh Nguyen, Khuong Quoc Vo, Phuong Hoang TranVarious 2-phenylquinazolin-4(3H)-ones were produced in moderate-to-good yields (44–80%) via the oxidative cyclization of anthranilamide and benzyl alcohols using gold nanoparticle-decorated amorphous carbon as an efficient catalyst.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic The effect of second coordination sphere interactions on the magnetic anisotropy of transition metals By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02873B, PaperSofie S. Leiszner, Mauro Perfetti, Emil Damgaard-Møller, Yu-Sheng Chen, Bo B. IversenBy investigating second coordination sphere effects on the magnetic anisotropy of a Co(II) single molecule magnet (SMM), we aim to clarify their role in magneto-structural correlations to enhance the performance of transition metal SMMs.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic A mechanistic study of chiral manganese porphyrin-catalyzed enantioselective C–H hydroxylation reaction By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02452D, PaperJing-Kun Gao, Wandong Chen, Junjie Tai, Zhengwei Chen, Hang Liu, Yuxin Du, Yiting Jiang, Yuanbin She, Yun-Fang YangThis study uses DFT to explain the enantioselectivity of C–H hydroxylation by a chiral manganese porphyrin. A two-point hydrogen bonding favors pro-(S) C–H bond abstraction by 1.9 kcal mol−1, leading to (S)-hydroxylated products.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic Heats of formation on the way from B2H6 to B20H16: thermochemical consequences of multicenter bonding in ab initio and DFT methods By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02589J, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jindřich Fanfrlík, Jan Řezáč, Drahomír Hnyk, Josef HolubThe objective of this study is to evaluate the effectiveness of various computational methods in reproducing the experimental heats of formation of boron hydrides using the atomization energy approach.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic Mechanistic studies of NOx reduction reactions involving copper complexes: encouragement of DFT calculations By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02420F, Frontier Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yohei Kametani, Yoshihito ShiotaMechanistic analysis of nitrite (NO2−) and nitric oxide (NO) reduction reactions promoted by copper complexes provides a reliable view of electron transfer and atom movement.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic Modular synthesis of triphenylphosphine-derived cage ligands for rhodium-catalyzed hydroformylation applications By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02627F, PaperWenlong Wang, Cunyao Li, Wenhao Wang, Yuqin Qiu, Hongguang Liu, Jinlong Lu, Yizhou Zhan, Li Yan, Yunjie DingCage ligands can be easily synthesized via dynamic imine chemistry, and a specific cage ligand exhibits excellent performance in Rh-catalyzed hydroformylation reaction (TOF up to 2665 h−1 and the l/b ratio reaches 2.6).To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic Cationic first-row transition metal saccharinate complexes with tris(2-pyridylmethyl)amine: synthesis, structures and anticancer studies By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02258K, PaperCeyda Icsel, Seyma Aydinlik, Muhittin Aygun, Veysel T. YilmazHighly cytotoxic dinuclear oxo-bridged Fe(III) saccharinate complex with tris(2-pyridylmethyl)amine induces excessive ROS generation, mitochondrial and DNA damage in HT29 colon cancer cells.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic Asymmetric triply bridged lanthanide binuclear clusters with distinctly different magnetic behaviors By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02652G, CommunicationYue Yang, Yu-Xia Wang, Yu-Zhe Lei, Peng ChengIsomorphic binuclear clusters Gd and Dy with antiferromagnetic and ferromagnetic couplings are separately exhibiting single-molecule magnetic behavior and strong magnetocaloric entropy.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic Thieno[3,2-b]thiophene based-bridged BODIPY dimer: synthesis, e-chem, one- and two-photon photophysical properties By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02655A, PaperZ. Chai, Tingting Gu, Annaelle Beau, Frederic Bolze, Claude P Gros, Liang Xu, Donghai Shi, Hai-Jun XuFour BODIPY dyes (6a ~ 6d) with electron-donating or electron-withdrawing groups at the meso-position were synthesized by Sonogashira coupling reaction of thieno[3,2-b]thiophene with mono-iodo-BODIPY moiety. All compounds were fully characterized...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic Recent Advances in Syntheses and Emerging Applications of 2D Borophene based Nanomaterials with a Focus on Supercapacitors By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02573C, FrontierPrashanta Pal, Mahasweta NandiTwo dimensional (2D) nanosheet of boron i.e. borophene, triggered interest in progressive research as a result of the vast field of opportunities to explore, from its innovative synthetic techniques to...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic Alleviating hypoxia by integrating MnO2 with metal-organic frameworks coated upconversion nanocomposites for enhanced photodynamic therapy in vitro By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02605E, PaperJunxun Zhou, Mengyue Jiang, Qiangqiang Zhang, Yuan Jiang, Haifang Wang, Lining SunPhotodynamic therapy (PDT) requires the participation of abundant oxygen while the hypoxic tumor microenvironment limits the efficacy of PDT. Here, upconversion luminescent nanocomposites coated with metal-organic frameworks (MOFs) were synthesized...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic Study of CanUO2(CO3)3(4–2n)– complexes using CE-ICP-MS with polyetheretherketone (PEEK) capillaries By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02781G, PaperRuopei Sun, Erwan Dupuis, Jean Aupiais, Pascal ReillerThe formation constants of CanUO2(CO3)3(4–2n)– complexes have been determined directly using capillary electrophoresis coupled with inductively coupled plasma mass spectrometry (CE-ICP-MS) in 0.1 M NaCl and at room temperature. Instead...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic Price pooling mantra: Wake up to expensive electricity By www.thehindubusinessline.com Published On :: Tue, 02 Apr 2013 13:15:05 +0530 Full Article Siddhartha P Saikia
ic Sword swinging in the civic body By www.thehindubusinessline.com Published On :: Thu, 30 May 2013 15:24:50 +0530 Full Article S Madhavan
ic Unfurling a mythological gem By www.thehindubusinessline.com Published On :: Sun, 30 Jun 2013 01:46:01 +0530 Full Article S Madhavan
ic Looking for the hidden logic By www.thehindubusinessline.com Published On :: Thu, 12 Sep 2013 16:48:29 +0530 Full Article S Madhavan
ic Off-field cricket ‘rituals’ By www.thehindu.com Published On :: Sun, 11 Aug 2024 01:47:00 +0530 ‘Commentator curse’ and other reigning superstitions that fans have immense belief in Full Article Open Page
ic The richness of Indian languages By www.thehindu.com Published On :: Sun, 25 Aug 2024 03:48:00 +0530 The idioms in everyday usage display the creativity and punch of the tongues Full Article Open Page
ic Confessions of an impractical person By www.thehindu.com Published On :: Sun, 15 Sep 2024 00:52:29 +0530 How one ignored the imperfection of life by finding solace in the perfection of art Full Article Open Page
ic A dictionary at hand By www.thehindu.com Published On :: Sun, 29 Sep 2024 01:07:43 +0530 Consult it regularly to develop your own vocabulary Full Article Open Page
ic Freewheeling exploration with a bicycle By www.thehindu.com Published On :: Sun, 06 Oct 2024 03:25:08 +0530 The machine was a precious possession, a symbol of hard work and determination Full Article Open Page
ic Navigating public spaces as a woman By www.thehindu.com Published On :: Sun, 27 Oct 2024 02:12:00 +0530 When public transport is inadequate or absent, it can heighten risks of violence and restrict access Full Article Open Page
ic The bookaholic By www.thehindu.com Published On :: Sun, 27 Oct 2024 02:24:00 +0530 Worried over why the unread collection is larger than the read ones Full Article Open Page
ic A case for public transport By www.thehindu.com Published On :: Sun, 27 Oct 2024 02:53:00 +0530 Aspirational India likes to flaunt snazzy cars, unmindful of the cost to environment Full Article Open Page
ic Rising stars: Sadie Witkowski and Michael Graw By physicsworld.com Published On :: 2017-12-01T09:00:34Z Interview with early-career scientists in psychology and oceanography Full Article
ic Modelling the thermoelectric effect By physicsworld.com Published On :: 2018-01-18T14:33:00Z Register now: 28 February 2018 A webinar sponsored by COMSOL Full Article
ic NanoRaman: correlated tip-enhanced optical spectroscopy and scanning-probe microscopy By physicsworld.com Published On :: 2018-01-19T14:46:48Z Register now: 8 March 2018 A webinar sponsored by HORIBA Scientific Full Article
ic Physics in 2018 By physicsworld.com Published On :: 2018-01-23T15:51:48Z Physics World journalists discuss what excites them about the year ahead Full Article
ic Tracking proton therapy with acoustic waves By physicsworld.com Published On :: 2018-02-01T10:39:31Z Katia Parodi describes an innovative technique for improving ion-beam therapy Full Article
ic Karnataka byelection: It is a proxy war between Lad and Reddy in mineral-rich Sandur By www.thehindu.com Published On :: Sun, 10 Nov 2024 08:01:00 +0530 Though Sandur has been the hotbed of mining activities, often hitting the headlines for illegal mining, this issue is barely resonating in the campaign Full Article Karnataka
ic Channapatna bypolls: Micro-management of OBCs and MBCs might hold the key By www.thehindu.com Published On :: Sun, 10 Nov 2024 17:05:55 +0530 BJP leaders from various backward class communities are entrusted with the task of micro-managing voters, since JD (S) lacks many such leaders in its ranks Full Article Karnataka
ic Appeal to Karnataka government to officially celebrate Shankar Nag’s birthday as ‘Driver’s Day’ By www.thehindu.com Published On :: Sun, 10 Nov 2024 17:22:47 +0530 Several auto drivers’ unions made an appeal to Transport Minister Ramalinga Reddy Full Article Karnataka
ic Karnataka makes online applications mandatory for private aided school teacher recruitment By www.thehindu.com Published On :: Sun, 10 Nov 2024 18:03:16 +0530 DSEL has developed a separate app to conduct aided schools teachers’ recruitment transparently Full Article Karnataka
ic Digital drive soon to encourage passengers to make QR code-based payments for railway tickets By www.thehindu.com Published On :: Sun, 10 Nov 2024 20:41:25 +0530 The drive will entail establishing special ‘May I Help You’ counters manned by railway staff near ticket booking counters Full Article Karnataka
ic Tobacco crop hit by rain; farmers complain of poor prices By www.thehindu.com Published On :: Sun, 10 Nov 2024 21:09:10 +0530 Usually, low grade tobacco accounts for about 25 to 30% of the total yield. This year, low grade tobacco is about 10% more than normal Full Article Karnataka
ic BJP should sack BSY and Vijayendra from party posts over irregularities in purchases during pandemic, demands Congress By www.thehindu.com Published On :: Sun, 10 Nov 2024 21:11:04 +0530 Full Article Karnataka
ic CCB cracks down on fake degree certificate racket By www.thehindu.com Published On :: Sun, 10 Nov 2024 21:33:12 +0530 Full Article Karnataka
ic Public campaigning for bypolls to end on November 11 By www.thehindu.com Published On :: Mon, 11 Nov 2024 03:52:34 +0530 The final day of public canvassing will see the Chief Minister and the Deputy Chief Minister besides top leaders of JD(S) and BJP seeking votes in Channapatna Full Article Karnataka
ic Medical malpractice destroys profession’s nobility, says BLDE Vice-Chancellor By www.thehindu.com Published On :: Mon, 11 Nov 2024 07:00:00 +0530 Full Article Karnataka
ic Guarantee money is deposited to beneficiaries’ bank accounts when election is around the corner, alleges B.Y. Vijayendra By www.thehindu.com Published On :: Mon, 11 Nov 2024 07:00:00 +0530 Full Article Karnataka
ic Karnataka Minister Zameer Ahmed Khan kicks up another row with ‘racist’ remark about Union Minister H.D. Kumaraswamy By www.thehindu.com Published On :: Mon, 11 Nov 2024 16:39:36 +0530 The Housing Minister is already facing flak for the wakf controversy that has snowballed into a big issue in Karnataka Full Article Karnataka
ic Karnataka Ministers seek action against Union Minister Pralhad Joshi for ‘agent’ comment on retired high court judge Michael D’Cunha By www.thehindu.com Published On :: Mon, 11 Nov 2024 17:14:22 +0530 The two Ministers told the Governor that Mr. Joshi made a deliberate attempt to politicise and taint a constitutionally sanctioned inquiry, betraying public trust in the process Full Article Karnataka
ic BJP MLA B.P. Yatnal walks out of event after crowd objects to political speech over mention of Waqf land row By www.thehindu.com Published On :: Mon, 11 Nov 2024 18:33:09 +0530 Mr. Yatnal raised the issue of waqf during an Allammaprabhu temple event Full Article Karnataka
ic Yaduveer flays DKS for his remarks on Bandipur night traffic ban By www.thehindu.com Published On :: Mon, 11 Nov 2024 20:25:56 +0530 Full Article Karnataka
