is Market capitalization of privately listed companies surged 6.4 times, PSUs grew 5 times over last 10 years: Motilal Oswal By www.newkerala.com Published On :: Tue, 12 Nov 2024 17:02:01 +0530 Full Article
is India is leading in AI adoption at 30%, surpassing global average of 26%: BCG report By www.newkerala.com Published On :: Tue, 12 Nov 2024 17:04:02 +0530 Full Article
is FPI can go beyond 10% in listed company by reclassifying investment as FDI: RBI By www.newkerala.com Published On :: Tue, 12 Nov 2024 17:18:02 +0530 Full Article
is Union Finance Minister Nirmala Sitharaman meets AIIB Board of Directors in Delhi By www.newkerala.com Published On :: Tue, 12 Nov 2024 17:22:02 +0530 Full Article
is Centre directs officials to speed up resolution of industrial disputes cases By www.newkerala.com Published On :: Tue, 12 Nov 2024 18:36:01 +0530 Full Article
is Visible-light-responsive hybrid photocatalysts for quantitative conversion of CO2 to highly concentrated formate solutions By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,18146-18160DOI: 10.1039/D4SC05289G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ewan McQueen, Noritaka Sakakibara, Kei Kamogawa, Martijn A. Zwijnenburg, Yusuke Tamaki, Osamu Ishitani, Reiner Sebastian SprickThis highly efficient hybrid photocatalytic system can quantitatively convert CO2 to formate and produce 0.4 M of formate solution without additional concentration enrichment.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Chemoenzymatic multistep retrosynthesis with transformer loops By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,18031-18047DOI: 10.1039/D4SC02408G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.David Kreutter, Jean-Louis ReymondIntegrating enzymatic reactions into computer-aided synthesis planning (CASP) should help devise more selective, economical, and greener synthetic routes.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is A critical factor in reactive oxygen species (ROS) studies: the need to understand the chemistry of the solvent used: the case of DMSO By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,17843-17851DOI: 10.1039/D4SC05038J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Shubham Bansal, Binghe WangReactive oxygen species (ROS) play critical roles in normal physiological processes including cellular signaling and immune responses.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Is aromaticity loss necessary for transition-metal promoted arene–alkene cycloadditions? By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,18093-18098DOI: 10.1039/D4SC05337K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.João V. Schober, Croix J. Laconsay, Judy I. WuDiene- and ene-like reactivity in transition metal coordinated arenes can be expected when there is a notable degree of aromaticity loss at the complexed arene.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Diverse quantum interference regimes in intramolecular singlet fission chromophores with thiophene-based linkers By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,17823-17830DOI: 10.1039/D4SC03546A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jonghwan Lee, Sungsik Eom, Hyungjun KimThis work explores intramolecular singlet fission chromophores having diverse thiophene-based linkers and highlights the relation between quantum interference and nonadiabatic coupling in the multiexciton formation step of singlet fission.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Automated electrosynthesis reaction mining with multimodal large language models (MLLMs) By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,17881-17891DOI: 10.1039/D4SC04630G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Shi Xuan Leong, Sergio Pablo-García, Zijian Zhang, Alán Aspuru-GuzikLeveraging multimodal large language models (MLLMs) to process multimodal data inputs and complex inter-modality data dependencies for automated (electro)chemical data mining from scientific literature.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Quadrupolar dinuclear hypervalent tin(IV) compounds with near-infrared emission consisting of Schiff bases based on π-conjugated scaffolds By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,17950-17961DOI: 10.1039/D4SC05006A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kazuya Tanimura, Kento Tanaka, Masayuki Gon, Kazuo TanakaThe study focuses on dinuclear hypervalent tin(IV) compounds with near-infrared (NIR) emission and unique quadrupolar orientations, showing potential for constructing electronic structures with narrow energy gaps.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is MR-TADF liquid crystals: towards self assembling host–guest mixtures showing narrowband emission from the mesophase By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,18022-18030DOI: 10.1039/D4SC04429K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Julius A. Knöller, Franziska Müller, Tomas Matulaitis, John M. dos Santos, Abhishek Kumar Gupta, Eli Zysman-Colman, Sabine LaschatWe developed a MR-TADF based, columnar liquid crystalline host system and doped it with a MR-TADF guest. Efficient FRET allowed us to construct the first columnar liquid crystal with narrowband MR-TADF from the strongly aggregated mesophase.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Porous liquids: an integrated platform for gas storage and catalysis By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,17720-17738DOI: 10.1039/D4SC04288C, Perspective Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Errui Li, Kevin M. Siniard, Zhenzhen Yang, Sheng DaiIn this perspective, recent discoveries in the integration of gas storage and catalysis by leveraging PL platforms have been summarized, highlighting the unique features different from those of traditional homogeneous or heterogeneous procedures.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Unified enantiospecific synthesis of drimane meroterpenoids enabled by enzyme catalysis and transition metal catalysis By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06060A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yipeng You, Xue-Jie Zhang, Wen Xiao, Thittaya Kunthic, Zheng Xiang, Chen XuA unified synthetic strategy for drimane meroterpenoids was developed by combining heterologous biosynthesis, enzymatic oxidation, and transition metal catalysis. Six drimane meroterpenoids were synthesized in a concise and enantiospecific manner.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Boronic ester-templated pre-rotaxanes as versatile intermediates for rotaxane endo-functionalisation By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC04879B, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jingjing Yu, Marius Gaedke, Satyajit Das, Daniel L. Stares, Christoph A. Schalley, Fredrik SchaufelbergerDynamic covalent boronic ester bonds can pre-organise diol-containing threads and V-shaped boronic acid ligands towards mechanical interlocking. After interlocking, the pre-rotaxane could be modified to create many unique [2]rotaxanes architectures.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is The photo-isomerization of the cyclononatetraenyl ligand and related rare earth complexes By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC04767B, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Lucie Pedussaut, Nolwenn Mahieu, Camille Chartier, Thayalan Rajeshkumar, Maxime Tricoire, Iskander Douair, Nicolas Casaretto, Laurent Maron, Grégory Danoun, Grégory NoctonReversible light isomerization in organometallic complexes of lanthanides: the low-energy wavelengths favor the cis isomer, and the high-energy wavelengths favor the trans isomer.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Selective lignin depolymerization via transfer hydrogenolysis using Pd/hydrotalcite catalysts: model compounds to whole biomass By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC03942D, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Darren Dolan, Rebekah Brucato, Christopher William Reid, Adam F. Lee, Karen Wilson, Adelina M Voutchkova-KostalCleavage of lignin ether bonds via transfer hydrogenolysis is a promising route to valorize lignin, but processes that use mild reaction conditions and exploit renewable hydrogen donor solvents (rather than...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is A metabologenomics strategy for rapid discovery of polyketides derived from modular polyketide synthases By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC04174G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Run-Zhou Liu, Zhihan Zhang, Min Li, Lihan ZhangA metabologenomics workflow using mass defect filtering (MDF) and bioinformatics-based structural prediction was established for rapid screening of modular polyketide natural products, and led to the identification of 22 polyketides.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Light-assisted carbon dioxide reduction in an automated photoreactor system coupled to carbonylation chemistry By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC06660J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jasper Schuurmans, Tom Masson, Stefan Zondag, Simone Pilon, Nicola Bragato, Miguel Claros, Tim den Hartog, Fransesc Sastre Calabuig, Jonathan van den Ham, Pascal Buskens, Giulia Fiorani, Timothy NoelContinuous-flow methodologies offer promising avenues for sustainable processing due to their precise process control, scalability, and efficient heat and mass transfer. The small dimensions of continuous-flow reactors render them highly...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is M12L24 nanospheres as supramolecular templates for the controlled synthesis of Ir-nanoclusters and their use in the chemo-selective hydrogenation of nitro styrene By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC06324D, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lotte L. Metz, Rens Ham, Eduard Bobylev, Kelly J. H. Brouwer, Alfons van Blaaderen, Rim van de Poll, Victor Drozhzhin, Emiel J. M. Hensen, Joost N. H. ReekControlled preparation of ultrafine metal nanoclusters (<2 nm) is challenging, yet important as the properties of these clusters are inherently linked to their size and local microenvironment. In the present...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Cyclic peptides targeting the SARS-CoV-2 programmed ribosomal frameshifting RNA from a multiplexed phage display library By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC04026K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jacob A. Iannuzzelli, Rachel Bonn, Andrew S. Hong, Abhijith Saseendran Anitha, Jermaine L. Jenkins, Joseph E. Wedekind, Rudi FasanCyclopeptide agents targeted against the −1 programmed ribosomal frameshifting stimulatory sequence RNA pseudoknot of SARS-CoV-2 were discovered by screening a multiplexed phage display library of genetically encoded peptide macrocycles.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Steering N/S coordination number to accelerate catecholase-like catalysis over low-coordinated Cu site By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05014B, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Meng Yuan, Nannan Xia, Ziheng Huang, Chaofeng Huang, Xun Hu, Fei HeModulating the coordination configuration of metal Cu center through steering the N/S coordination number around Cu center boosted the catalytic activity of catechol oxidase-mimicking nanozyme.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Pd/NHC sequentially catalyzed atroposelective synthesis of planar-chiral macrocycles By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05482B, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Gongming Yang, Shangde Liu, Shujie Ji, Xingsen Wu, Jian WangThe unprecedented non-enzymatically atroposelective synthesis of planar-chiral macrocycles via a Pd/NHC sequential catalytic intermolecular macrocyclization is reported.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Strain-induced charge delocalization achieves ultralow exciton binding energy toward efficient photocatalysis By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05873A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Junyuan Duan, Yinghe Zhao, Yu Wu, Youwen Liu, Junnian Chen, Ruoou Yang, Jiazhao Huang, Chuanqi Luo, Mao Wu, Xiaodong Zheng, Pengyu Li, Xueliang Jiang, Jianguo Guan, Tianyou ZhaiA novel approach of strain-induced charge delocalization is developed to significantly reduce the exciton binding energy of Ta2O5 nanorods to below ambient thermal energy, leading to a remarkable enhancement in photocatalytic hydrogen evolution.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Merging nucleophilic phosphine catalysis and photocatalysis for the rapid assembly of 2-oxabicyclo-[2.1.1]hexane scaffolds from feedstock allyl alcohols By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06684G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.David M. Whalley, Luca Carlino, Okky Dwichandra Putra, Niall A. Anderson, Susannah C. Coote, Olivier LorthioirA synthesis of 2-oxabicyclo-[2.1.1]hexanes from readily available allyl alcohols and electron-poor arylalkynes. The transformation utilises phosphine catalysis and energy transfer catalysis for rapid assembly of these diverse scaffolds.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Analysis of the cryptic biosynthetic gene cluster encoding the RiPP curacozole reveals a phenylalanine-specific peptide hydroxylase By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC02262A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Samantha Hollands, Julia Tasch, David J. Simon, Dimah Wassouf, Isobel Barber, Arne Gessner, Andreas Bechthold, David L. ZechelThe noncanonical biosynthesis of curacozole by Streptomyces curacoi is shown to be dependent on the bldA-encoded Leu-tRNAUUA. The minimal biosynthetic gene cluster is defined, and the functions of key biosynthetic enzymes are established in vitro.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Structural constraint at a P–P bond: phosphinophosphination of alkenes, alkynes, and carbonyls by a concerted mechanism By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06581F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Lijun You, Daniel Roth, Lutz GrebA structural constraint approach at a P–P bond is presented that enables the phosphinophosphination of alkynes, alkenes, and carbonyls with high regio- and diastereoselectivity. The apolar nature of the P–P bond facilitates a concerted mechanism.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Regioselectivity switches between anthraquinone precursor fissions involved in bioactive xanthone biosynthesis By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06369D, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xiao Jing Lv, Chun Zhi Ai, Li Rong Zhang, Xiu Xiu Ma, Juan Juan Zhang, Jia Peng Zhu, Ren Xiang TanBruN and BTG13 cleave chrysophanol hydroquinone into monodictyphenone and cephalanone F, respectively, with the regioselectivities found tunable via the key amino acid (AA) substitution strategy.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Resonance Plasmonic Coupling: Selective Enhancement of Band Edge Emission over Trap State Emission of CdSe Quantum Dots By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC04960H, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Livin Paul, Elizabeth Mariam Thomas, Akshaya Chemmangat, Stephen Gray, K. George ThomasThe photoluminescence properties of quantum dots (QDs) are often enhanced by eliminating surface trap states through chemical methods. Alternatively, a physical approach is presented here for improving photoluminescence purity in...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Understanding ketone hydrogenation catalysis with anionic iridium(III) complexes: The crucial role of counterion and solvation By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC04629C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Paven Kisten, Sandrine Vincendeau, Eric Manoury, Jason Martin Lynam, John M. Slattery, Simon B Duckett, Agusti Lledos, Rinaldo PoliThe catalytic asymmetric hydrogenation of ketones reflect an important way to prepare valuable chiral alcohols. Understanding how transition metals promote these reactions is key to the rational design of more...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Delocalization error poisons the density-functional many-body expansion By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05955G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Dustin R. Broderick, John M. HerbertSelf-interaction error leads to runaway error accumulation when density functional theory is used in conjunction with the many-body expansion.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Differentiating carrier protein interactions in biosynthetic pathways using dapoxyl solvatochromism By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05499G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Matthew G. Miyada, Yuran Choi, Kyle Rich, James J. La Clair, Michael D. BurkartA highly sensitive solvatochromic system was developed to monitor the loading and interactivity of carrier proteins associated with fatty acid, polyketide and non-ribosomal peptide biosynthesis.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Electrochemical reconstruction of metal–organic gels into crystalline oxy-hydroxide heterostructures for efficient oxygen evolution electrocatalysis By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05799F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kang Liu, Haikuo Lan, Yuting Chen, Weicheng Tang, Zhenyu Xiao, Yunmei Du, Jun Xing, Zexing Wu, Lei WangAn amorphous MOG electrochemically reconstitutes to a crystalline NiOOH/FeOOH heterostructure with the morphology changed from nanofibers to nanosheets as a high-performance OER electrocatalyst.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Dual ligand-enabled iron and halogen-containing carboxylate-based photocatalysis for chloro/fluoro-polyhaloalkylation of alkenes By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC04038D, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Wanru Han, Zhenyan Zhao, Kui Jiang, Yu Lan, Xuehan Yu, Xiaoyu Jiang, Wei Yang, Donghui Wei, Shi-Jun Li, Linbin NiuDual ligand-enabled iron photocatalysis for the conversion of all kinds of halogen-containing carboxylates (CnXmCOO−, X: F, Cl, Br) to CnXm radicals is disclosed for chloro/fluoro-polyhaloalkylation of non-activated alkenes.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is An interactive dual energy storage mechanism boosts high-performance aqueous zinc-ion batteries By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05710D, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Shengen Gong, Meihua Zhu, Yan Zhou, Runan Li, Jianhua Zhang, Xiaoteng Jia, Danming Chao, Caiyun WangA conductive polymer cathode with high redox potential is realized by pre-doping Mn2+ into PANI, which demonstrates an interactive dual energy storage mechanism of reversible doping of multiple cations and dissolution–deposition of Mn2+.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Direct synthesis of N-perfluoro-tert-butyl secondary amines from N-trifluoromethyl secondary amines By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06335J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Leibing Wang, Zhongyu Feng, Zhen Luo, Zihao Guo, Jieping Wang, Wenbin YiThe one-step direct synthesis of N-perfluoro-tert-butyl secondary amines utilizes TMSCF3 as the sole CF3 source and the starting material N-CF3 secondary amine itself as the hydrogen source. PFtB amines can be effectively employed in 19F MRI.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Mechanism of action and evaluation of ratiometric probes for uric acid using lanthanide complexes with tetraazatriphenylene sensitisers By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05743K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Xinyi Wen, Huishan Li, Zhijie Ju, Renren Deng, David ParkerSix Eu(III) and Tb(III) complexes are evaluated for the rapid ratiometric analysis of urate in diluted serum, together with mechanistic studies probing the intermediate exciplex and the excited state dynamics by transient absorption spectroscopy.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Direct Ladderization of Cyclooctatetraene-containing, Processable Conjugated Ladder Polymers from Annulated bis-Zirconacyclopentadienes By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC06902A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.August J. Rothenberger, Harrison M. Bergman, He Li, Miao Qi, Yunfei Wang, Yi Liu, T. Don TilleyConjugated ladder polymers (CLPs) are difficult yet captivating synthetic targets due to their fully unsaturated fused backbones. Inherent challenges associated with their synthesis often lead to low yields, structural defects,...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Rapid, Potent, and Persistent Covalent Chemical Probes to Deconvolute PI3Kα Signaling By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC05459H, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lukas Bissegger, Theodora Alexandra Alexandra Constantin, Erhan Keles, Luka Raguž, Isobel Barlow-Busch, Clara Orbegozo, Thorsten Schaefer, Valentina Borlandelli, Thomas Bohnacker, Rohitha SriRamaratnam, Alexander Schäfer, Matthias Gstaiger, John E. Burke, Chiara Borsari, Matthias WymannChemical probes have gained importance in the elucidation of signal transduction in biology. Insufficient selectivity and potency, lack of cellular activity and inappropriate use of chemical probes has major consequences...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Discovery of penicillic acid as a chemical probe against tau aggregation in Alzheimer’s Disease By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC05469E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jennifer Shyong, Jinliang Wang, Tran Quoc Dung Huynh, Marina Fayzullina, Bo Yuan, Ching-Kuo Lee, Thomas Minehan, Paul M. Seidler, Clay WangAlzheimer’s Disease (AD) is a neurodegenerative disorder proven to be caused by the aggregation of protein tau into fibrils, resulting in neuronal death. The irreparable neuronal damage leads to irreversible...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Sequence-dependent Conformational Transitions of Disordered Proteins During Condensation By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC05004E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jiahui Wang, Dinesh Devarajan, Keerthivasan Muthukumar, Youngchan Kim, Arash Nikoubashman, Jeetain MittalIntrinsically disordered proteins (IDPs) can form biomolecular condensates through phase separation. It is recognized that the conformation of IDPs in the dense and dilute phases, as well as at the...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Depolymerisation of Poly(Lactide) Under Continuous Flow Conditions By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC05891G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Sophie Ellis, Antoine Buchard, Tanja JunkersPoly(L-lactic acid) (PLLA) is commercially successful bio-based plastic, where end-of-life materials can undergo industrial composting. To create a circular economy, a desirable alternative to composting is chemical recycling to monomer...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Spin State Modulation and Kinetic Control of Thermal Contraction in a [Fe2Co2] Discrete Prussian Blue Analogue By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC05792A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jyoti Yadav, Sanjit KonarStimuli-responsive switchable molecules represent an important category of magnetic materials with significant potential for functional devices. However, engineering complexes with controlled switchability remains challenging due to their sensitivity to lattice...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Curating history through cinema By www.thehindu.com Published On :: Thu, 27 Oct 2016 00:00:00 +0530 The New Medium, which debuted at MAMI, showcased a history of the moving picture and its formal innovation Full Article Mumbai
is Bollywood’s divisive Diwali By www.thehindu.com Published On :: Thu, 03 Nov 2016 00:00:00 +0530 It was a close battle at the box office with a romantic drama taking a slight financial edge over an action blockbuster. Full Article Mumbai
is Who is Doctor Strange? By www.thehindu.com Published On :: Thu, 03 Nov 2016 00:00:00 +0530 Here’s a primer to get acquainted with the Marvel’s superhero universe’s most unique character Full Article Mumbai
is Rediscovering repositories of heritage By www.thehindu.com Published On :: Sun, 06 Nov 2016 00:00:00 +0530 Often considered dull and uninviting, Indian museums are storehouses of history and culture, and deserve repeat visits saysShailaja Tripathi Full Article Mumbai
is Fall, rise, repeat By www.thehindu.com Published On :: Tue, 08 Nov 2016 00:00:00 +0530 After eight years, Dhruvi Acharya presents an achingly intimate solo show that explores her ownloss and looks at women as independent individuals Full Article Mumbai
is An obstinate vision of music By www.thehindu.com Published On :: Wed, 09 Nov 2016 00:00:00 +0530 Rahul Das of Sundog Project talks about the band’s upcoming album and the role that art plays in society Full Article Mumbai