A new genetic analysis has revealed that many Amazon tree species are likely to survive human-caused climate warming in the coming century, contrary to previous findings that temperature increases would cause them to die out.

The post Warming climate unlikely to cause near-term extinction of ancient Amazon trees, study says appeared first on Smithsonian Insider.

Non-native plant species pose a significant threat to the natural ecosystems of the United States. Many of these invasive plants are escapees from gardens and […]

The post Escape of the invasives: Top six invasive plant species in the United States appeared first on Smithsonian Insider.

The post Smithsonian scientists work to ensure survival of North America’s wild orchids appeared first on Smithsonian Insider.

Soon after a dirt road through the forests of Lambir Hills National Park in Borneo was improved in 1987, local markets selling the meat of […]

The post Loss of animals spells doom for diversity of rainforest trees appeared first on Smithsonian Insider.

Hidden in the thick foliage of tropical forests a subfamily of colorful beetles–the Chrysomelidae–may be hiding the secrets to the earliest stages of social behavior. […]

The post Beetle moms show clear signs of maternal instincts and care appeared first on Smithsonian Insider.

When scientists discuss global change, they often focus on the amount of carbon in the atmosphere and vegetation. But soil contains more carbon than air […]

The post Fungi may determine the future of soil carbon appeared first on Smithsonian Insider.

One way to avoid a cold or the flu, doctors say, is to stay away from crowded places. Viruses spread fast in places where people […]

The post Sugar is key ingredient to evolutionary success of ants, researchers find appeared first on Smithsonian Insider.

A 57-acre research plot at a University of Michigan forest preserve northwest of Ann Arbor has been added to a Smithsonian Institution global network used […]

The post University of Michigan forest preserve joins Smithsonian global network appeared first on Smithsonian Insider.

Scientists have long known that in the tropics shade-grown coffee plantations provide critical habitat for migratory and resident birds. Now a new survey conducted in […]

The post Shade-grown coffee plantations are mammal friendly as well, study shows appeared first on Smithsonian Insider.

Invertebrate Zoology Scientists studying pollinators of the yellow poppy (Meconopsis integrifolia) in the highlands of southern China have discovered a striking new species of flower fly […]

The post New species of poppy pollinating fly discovered in China appeared first on Smithsonian Insider.

We know some types of fungi turn ants into zombies, but fungi are not always the bad guys. In the case of orchids, fungi are […]

The post The Secret Life of Orchids – Part I: Fungi appeared first on Smithsonian Insider.

Orchids are beautiful, but their beauty can be deceiving. Most orchids don’t have any nectar, yet they cheat their pollinators into thinking that they do […]

The post The Secret Life of Orchids – Part II: Pollinators appeared first on Smithsonian Insider.

Orchids account for 10 percent of the world’s plant species, making them the largest plant family. They act as indicators of the health of ecosystems […]

The post The Secret Life of Orchids – Part III: Conservation appeared first on Smithsonian Insider.

The National Ecological Observatory (NEON) is a large-facility project managed by NEON, Inc., and funded by the National Science Foundation (NSF). NEON is a continental-scale […]

The post NEON begins to monitor changing ecology of U.S. appeared first on Smithsonian Insider.

How much is a wetland worth? It’s a question that has plagued policymakers, scientists and other leaders looking to protect their communities and slow down […]

The post New report enables creation of carbon credits for restored wetlands appeared first on Smithsonian Insider.

By charting the slopes and crags on animals’ teeth as if they were mountain ranges, scientists at the Smithsonian’s National Museum of Natural History have […]

The post 3D study of teeth in modern mammals opens window to extinct animal diets appeared first on Smithsonian Insider.

Spending time in a beautiful garden can be transformative. In fact, some visitors to the Smithsonian’s Mary Livingston Ripley Garden in Washington D.C. have taken […]

The post Monarch Butterflies Make the Most of the Smithsonian’s Gardens appeared first on Smithsonian Insider.

Living trees can rot from the inside out, leaving only a hollowed trunk. Wood rot in living trees can cause overestimates of global carbon pools, […]

The post Measuring trees with the speed of sound appeared first on Smithsonian Insider.

The Smithsonian-Mason School of Conservation offers a range of compelling residential, hands-on, interdisciplinary programs in conservation biology for undergraduate and graduate students and professionals at […]

The post Field Research: Smithsonian-Mason School of Conservation appeared first on Smithsonian Insider.

The Smithsonian is joining with local communities and the Nigerian Montane Forest Project to better understand and conserve montane forests in Nigeria.

The post Taking the Pulse of Our Planet’s Forests: appeared first on Smithsonian Insider.

Finding a mouse in your morning coffee might give you an unwelcome jolt, but there’s a strong connection between small mammals, birds and the plantations […]

The post Of mice and macchiato: Bird Friendly coffee gives a paw-up to small mammals as well appeared first on Smithsonian Insider.

What might lure someone away from the sunny beaches and lush forests of Brazil to the concrete jungle of Washington, D.C.? For wood anatomist Marcelo […]

The post Rigid yet flexible: Anatomy of woody vines has its grip on botanist Marcelo Pace appeared first on Smithsonian Insider.

Most of us can’t begin the day without a cup of coffee. Coffee is a major agricultural crop in many Central and South American countries […]

The post A Cup of Joe That’s Also Good for the Birds appeared first on Smithsonian Insider.

If you’ve seen the movie Jurassic Park, you know that amber played a significant role in rebuilding a lost world: A mosquito trapped within its […]

The post Resin from shipwreck hints at trade routes and botany of ancient Asia appeared first on Smithsonian Insider.

The post Global forest network cracks the case of tropical biodiversity appeared first on Smithsonian Insider.

Visitors to the tropics are amazed by the huge variety of colorful, complex and sometimes ferocious creatures living near the equator. Smithsonian scientists and colleagues […]

The post Is This the Long-Sought Answer to the Question of Tropical Biodiversity? appeared first on Smithsonian Insider.

For the first time, a new public database will link genetic data with records of where and when the samples it was taken from were […]

The post A first: New website reveals origin of genetic samples and date collected appeared first on Smithsonian Insider.

The Earth’s changing climate could cause the extinction of up to a third of its parasite species by 2070, according to a global analysis reported […]

The post Study shows parasites may be among earliest victims of climate change appeared first on Smithsonian Insider.

How specific fungi interact with seeds in tropical forest soils may be the ultimate arbiter in the struggle for survival among tropical trees. “Depending on […]

The post Study reveals soil fungi has final say in survival of seeds from tropical trees appeared first on Smithsonian Insider.

White-tailed deer don’t like to eat the invasive plants Japanese stilt grass, garlic mustard or barberry. Native oak seedlings and tulip poplar, on the other […]

The post Too many hungry deer are lowering diversity of native plants in eastern U.S. forests appeared first on Smithsonian Insider.

According to a new study by biologists at the Smithsonian Migratory Bird Center and Virginia Tech the offspring of a certain songbird, the wood thrush, […]

The post Study: Large shady forest plots essential to survival of post-fledgling songbirds during drought appeared first on Smithsonian Insider.

A new paper published in Behavioral Ecology finds that some ant colonies defend more gallantly than others, revealing that colonies themselves may have personalities. Trees that have […]

The post Ant colony ‘personality’ may play role in survival of its host plant appeared first on Smithsonian Insider.

Camouflage is a valuable survival strategy—just ask a chameleon. Scientists have just discovered a new form of mimicry camouflage: beetles that hide by chewing beetle-shaped […]

The post For millions of years these tiny beetles have chewed their way out of sight appeared first on Smithsonian Insider.

Life and the Earth have always evolved together. When it opens on June 8, 2019, the David H. Koch Hall of Fossils — Deep Time […]

The post Sneak Peek: David H. Koch Hall of Fossils appeared first on Smithsonian Insider.

No green thumb? You don’t need to water these dazzling orchids to enjoy them. More than 8,000 living specimens in the Smithsonian Gardens Orchid Collection […]

The post See thousands of orchids in incredible detail in the Smithsonian’s newly digitized collection appeared first on Smithsonian Insider.

The addition of tert-butyl hydro­peroxide (tBuOOH) to two MnII complexes, differing by a small synthetic alteration from an ethyl to a propyl linker in the ligand scaffold, results in the formation of the high-valent bis-oxo complexes, {[MnIV{N4(6-Me-DPEN)}]2(μ-O)2}2+ (1) and {[MnIV{N4(6-Me-DPPN)}]2(μ-O)2}2+ (2).

This article aims to encourage practitioners, young and seasoned, by enhancing their structure-determination toolboxes with a selection of tips and tricks on recognizing and handling aspects of data collection, structure modelling and refinement, and the interpretation of results.

In the first reported crystal structure involving the potential ligand N,N',N''-tris­(2-pyridin­yl)-1,3,5-benzene­tricarboxamide, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules via their amide groups into slanted ladder-like chains. Only two of the three amide groups in the mol­ecule are involved in hydrogen bonding, which influences the degree of out-of-plane twisting at each amide group.

In the structure of the title salt, second-order Jahn–Teller distortion of the coordination octa­hedra around V ions is reflected by coexistence of short V—O bonds and trans-positioned long V—F bonds, with four equatorial V—F distances being inter­mediate in magnitude. Hydrogen bonding of the anions is restricted to F-atom acceptors only, with particularly strong N–H⋯F inter­actions [N⋯F = 2.5072 (15) Å] established by axial and cis-positioned equatorial F atoms.

The crystal structure of vanthoffite, Na6Mg(SO4)4, was redetermined and refined with anisotropic displacement parameters for all atoms. Here, for the first time, we give its detailed description.

The cationic cyclo­metallated iridium(III) complex [Ir(C9H7N2)2(C12H8N2)](PF6) has been synthesized and crystallized by the inter-diffusion method. It contains an unknown number of solvent mol­ecules and has a different space-group symmetry (C2/c) structure than its solvatomorph (P21/c).

The new copper(II) complex [CuLCl2]2, where L is a product of Schiff base condensation between methyl­amine and 2-pyridine­carbaldehyde, is built of discrete centrosymmetric dimers.

The asymmetric unit of the title compound contains two independent mol­ecules, consisting of perimidine and phenol units, which are linked through an N—H⋯O hydrogen bond. Intra­molecular O—H⋯N hydrogen bonds are observed in both independent mol­ecules.

The title compound, 1-(2,5-di­meth­oxy­phen­yl)-2,2,6,6-tetra­methyl­piperidine, was synthesized as a side-product during the synthesis of the inter­mediate, methyl 3,6-dimeth­oxy-2-(2-meth­oxy-2-oxoeth­yl)benzoate, necessary for the total synthesis of the isocoumarin 5,8-dimeth­oxy-3-methyl-1H-isochromen-1-one.

The title compound exhibits exceptionally weak inter­molecular C—H⋯π hydrogen bonding of the ethynyl groups, with the corresponding H⋯π separations [2.91 (2) and 3.12 (2) Å] exceeding normal vdW distances. This bonding compliments distal contacts of the CH (aliphatic)⋯π type [H⋯π = 3.12 (2)–3.14 (2) Å] to sustain supra­molecular layers.

The dihedral angle between the two aromatic rings of the title compound is 64.12 (14)°. The crystal structure is stabilized by a short Cl⋯H contact, C—Cl⋯π and van der Waals inter­actions.

The title complex, Cu(L)2 or [Cu(C15HF10O2)2], comprising one copper ion and two fully fluorinated ligands (L−), was crystallized with 3,4-ethyl­ene­dioxy­thio­phene (EDOT, C6H6O2S) as a guest mol­ecule to give in a di­chloro­methane solution a unique co-crystal, Cu(L)2·3C6H6O2S.

The report of the Executive Committee for 2017 is presented.

This work presents a technique for extracting the detailed shape of peaks with extended, overlapping tails in an X-ray powder diffraction pattern. The application discussed here concerns crystallite size broadening, though the technique can be applied to spectra of any origin and without regard to how the profiles are to be subsequently analyzed. Historically, the extraction of profile shapes has been difficult due to the complexity of determining the background under the peak, resulting in an offset of the low-frequency components of the Fourier transform of the peak known as the `hook' problem. The use of a carefully considered statistical weighting function in a non-linear least-squares fit, followed by summing the residuals from such a fit with the fit itself, allows one to extract the full shape of an isolated peak, without contributions from either the background or adjacent peaks. The extracted shape, consisting of the fit function recombined with the residuals, is not dependent on any specific shape model. The application of this to analysis of microstructure is performed independently of global parametric models, which would reduce the number of refined parameters; therefore the technique requires high-quality data to produce results of interest. The effectiveness of the technique is demonstrated by extraction of Fourier transforms of peaks from two sets of size-broadened materials with two differing pieces of equipment.

The structural and nonlinear optical properties of a new anilinium hybrid crystal of chemical formula (C6H7NCl+·NO3−)3 have been investigated. The crystal structure was determined from single-crystal X-ray diffraction measurements performed at a temperature of 100 K which show that the compound crystallizes in a noncentrosymmetric space group (Pna21). The structural analysis was coupled with Hirshfeld surface analysis to evaluate the contribution of the different intermolecular interactions to the formation of supramolecular assemblies in the solid state that exhibit nonlinear optical features. This analysis reveals that the studied compound is characterized by a three-dimensional network of hydrogen bonds and the main contributions are provided by the O...H, C...H, H...H and Cl...H interactions, which alone represent ∼85% of the total contributions to the Hirshfeld surfaces. It is noteworthy that the halogen...H contributions are quite comparable with those of the H...H contacts. The nonlinear optical properties were investigated by nonlinear diffuse femtosecond-pulse reflectometry and the obtained results were compared with those of the reference material LiNbO3. The hybrid crystals exhibit notable second (SHG) and third (THG) harmonic generation which confirms its polarity is generated by the different intermolecular interactions. These measurements also highlight that the THG signal of the new anilinium compound normalized to its SHG counterpart is more pronounced than for LiNbO3.