co NN bond cleavage in diazirines by a cyclic diborane(4) compound By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,18048-18051DOI: 10.1039/D4SC04980B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Minling Zhong, Jie Zhang, Zuowei XieReactions of o-carborane-fused diborane(4) with 3H-diazirines lead to the complete cleavage of the NN bond, with one nitrogen atom being incorporated into the B–B bond.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Quadrupolar dinuclear hypervalent tin(IV) compounds with near-infrared emission consisting of Schiff bases based on π-conjugated scaffolds By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,17950-17961DOI: 10.1039/D4SC05006A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kazuya Tanimura, Kento Tanaka, Masayuki Gon, Kazuo TanakaThe study focuses on dinuclear hypervalent tin(IV) compounds with near-infrared (NIR) emission and unique quadrupolar orientations, showing potential for constructing electronic structures with narrow energy gaps.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co On-demand controlled bidirectional DNAzyme path for ultra-sensitive heavy metal ion detection By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,18170-18178DOI: 10.1039/D4SC04404E, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jing Xu, Yujin Li, Futing Wang, Xinqi Luo, Wei Zhang, Yifan Lyu, Hongfen Yang, Ren Cai, Weihong TanA bidirectional self-powered biosensor is constructed for the quasi-simultaneous detection of Pb2+ and Hg2+ based on MoS2@CuS heterostructures as an accelerator and hybridization chain reaction as a signal amplification strategy.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Double coordination shell modulation of nitrogen-free atomic manganese sites for enhancing oxygen reduction performance By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05998K, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xue Bai, Yin Wang, Jingyi Han, Siyu Chen, Xiaodi Niu, Jingqi GuanUtilizing double coordination shell modulation, we construct a novel nitrogen-free single-atom manganese coordination configuration catalyst on graphene oxide (Mn–S1O4G), which exhibits excellent ORR and zinc–air battery performances.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Dilute nanocomposites for capacitive energy storage: progress, challenges and prospects By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC05437G, Perspective Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Li Li, Wenhan Xu, Guanchun Rui, Shixian Zhang, Qiming Zhang, Qing WangElectrostatic capacitors (ECs) are critical components in advanced electronics and electric power systems due to their rapid charge-discharge rate and high power density. While polymers are ideal for ECs due...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co The Effect of gem-Difluorination on the Conformation and Properties of a Model Macrocyclic System By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC05424E, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Laurent Knerr, Thomas Cogswell, Marie. Ahlqvist, Richard James Lewis, Anneli Nordqvist, Christian SköldConformational control of drug candidates to engineer improved potency and ADME properties is an ongoing area of research. Macrocyclic rings tend to offer a greater degree of rigidity than non-cyclised...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Correction: Second-shell modulation on porphyrin-like Pt single atom catalysts for boosting oxygen reduction reaction By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC90219J, Correction Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Tayyaba Najam, Syed Shoaib Ahmad Shah, Hanqing Yin, Xin Xiao, Shamraiz Talib, Qianqian Ji, Yonggui Deng, Muhammad Sufyan Javed, Jie Hu, Ruo Zhao, Aijun Du, Xingke Cai, Qiang XuTo cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co The photo-isomerization of the cyclononatetraenyl ligand and related rare earth complexes By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC04767B, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Lucie Pedussaut, Nolwenn Mahieu, Camille Chartier, Thayalan Rajeshkumar, Maxime Tricoire, Iskander Douair, Nicolas Casaretto, Laurent Maron, Grégory Danoun, Grégory NoctonReversible light isomerization in organometallic complexes of lanthanides: the low-energy wavelengths favor the cis isomer, and the high-energy wavelengths favor the trans isomer.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Photo-triggered NO release of nitrosyl complexes bearing first-row transition metals and therapeutic applications By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC06820C, Review Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Seungwon Sun, Jisu Choe, Jaeheung ChoIn biological systems, nitric oxide (NO) is a crucial signaling molecule that regulates a wide range of physiological and pathological processes. Given the significance of NO, there has been considerable...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Probing water adsorption and stability under steam flow of Zr-based metal-organic frameworks using 91Zr solid-state NMR spectroscopy By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC04589K, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Athulya Nadol, Florian Venel, Raynald Giovine, Maeva Leloire, Christophe Volkringer, Thierry Loiseau, Christel Gervais, Caroline Mellot-Draznieks, Bertrand Doumert, Julien Trébosc, Olivier Lafon, Frédérique PourpointThe stability of metal-organic frameworks (MOFs) in the presence of water is crucial for a wide range of applications, including the production of freshwater, desiccation, humidity control, heat pumps/chillers and...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Selective lignin depolymerization via transfer hydrogenolysis using Pd/hydrotalcite catalysts: model compounds to whole biomass By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC03942D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Darren Dolan, Rebekah Brucato, Christopher William Reid, Adam F. Lee, Karen Wilson, Adelina M Voutchkova-KostalCleavage of lignin ether bonds via transfer hydrogenolysis is a promising route to valorize lignin, but processes that use mild reaction conditions and exploit renewable hydrogen donor solvents (rather than...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co A metabologenomics strategy for rapid discovery of polyketides derived from modular polyketide synthases By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC04174G, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Run-Zhou Liu, Zhihan Zhang, Min Li, Lihan ZhangA metabologenomics workflow using mass defect filtering (MDF) and bioinformatics-based structural prediction was established for rapid screening of modular polyketide natural products, and led to the identification of 22 polyketides.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co PharmacoNet: deep learning-guided pharmacophore modeling for ultra-large-scale virtual screening By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC04854G, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Seonghwan Seo, Woo Youn KimPharmacoNet is developed for virtual screening, including deep learning-guided protein-based pharmacophore modeling, a parameterized analytical scoring function, and coarse-grained pose alignment. It is extremely fast yet reasonably accurate.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Light-assisted carbon dioxide reduction in an automated photoreactor system coupled to carbonylation chemistry By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC06660J, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jasper Schuurmans, Tom Masson, Stefan Zondag, Simone Pilon, Nicola Bragato, Miguel Claros, Tim den Hartog, Fransesc Sastre Calabuig, Jonathan van den Ham, Pascal Buskens, Giulia Fiorani, Timothy NoelContinuous-flow methodologies offer promising avenues for sustainable processing due to their precise process control, scalability, and efficient heat and mass transfer. The small dimensions of continuous-flow reactors render them highly...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Wiring proton gradients for energy conversion By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC04833D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xinchen Dai, Cesare Berton, Dong Jun Kim, Cristian PezzatoLight-switchable buffer solutions based on merocyanine photoacids can be used as efficient photoenergy harvesting systems. Varying the solvation environment of merocyanine photoacids in water-methanol mixtures allows one to carefully tune...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co M12L24 nanospheres as supramolecular templates for the controlled synthesis of Ir-nanoclusters and their use in the chemo-selective hydrogenation of nitro styrene By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC06324D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lotte L. Metz, Rens Ham, Eduard Bobylev, Kelly J. H. Brouwer, Alfons van Blaaderen, Rim van de Poll, Victor Drozhzhin, Emiel J. M. Hensen, Joost N. H. ReekControlled preparation of ultrafine metal nanoclusters (<2 nm) is challenging, yet important as the properties of these clusters are inherently linked to their size and local microenvironment. In the present...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Cyclic peptides targeting the SARS-CoV-2 programmed ribosomal frameshifting RNA from a multiplexed phage display library By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC04026K, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jacob A. Iannuzzelli, Rachel Bonn, Andrew S. Hong, Abhijith Saseendran Anitha, Jermaine L. Jenkins, Joseph E. Wedekind, Rudi FasanCyclopeptide agents targeted against the −1 programmed ribosomal frameshifting stimulatory sequence RNA pseudoknot of SARS-CoV-2 were discovered by screening a multiplexed phage display library of genetically encoded peptide macrocycles.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Steering N/S coordination number to accelerate catecholase-like catalysis over low-coordinated Cu site By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05014B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Meng Yuan, Nannan Xia, Ziheng Huang, Chaofeng Huang, Xun Hu, Fei HeModulating the coordination configuration of metal Cu center through steering the N/S coordination number around Cu center boosted the catalytic activity of catechol oxidase-mimicking nanozyme.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Large second harmonic generation and birefringence from extended octupolar π-conjugated structures By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05756B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Danyang Dou, Bingbing Zhang, Daqing Yang, Ying WangBy adopting an extended octupolar π-conjugation strategy, two excellent optical functional materials with a strong SHG response and large birefringence were prepared.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Three in one: engineering MOF channels via coordinated water arrays for regulated separation of alkanes and alkenes By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05286B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lu-Lu Ma, Pavel N. Zolotarev, Kang Zhou, Xin Zhou, Jiaqi Liu, Jiafeng Miao, Shenfang Li, Guo-Ping Yang, Yao-Yu Wang, Davide M. Proserpio, Jing Li, Hao WangRegulated adsorptive separation of alkane/alkenes has been achieved through engineering the coordinated water arrays in MOF channels.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Merging nucleophilic phosphine catalysis and photocatalysis for the rapid assembly of 2-oxabicyclo-[2.1.1]hexane scaffolds from feedstock allyl alcohols By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06684G, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.David M. Whalley, Luca Carlino, Okky Dwichandra Putra, Niall A. Anderson, Susannah C. Coote, Olivier LorthioirA synthesis of 2-oxabicyclo-[2.1.1]hexanes from readily available allyl alcohols and electron-poor arylalkynes. The transformation utilises phosphine catalysis and energy transfer catalysis for rapid assembly of these diverse scaffolds.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Analysis of the cryptic biosynthetic gene cluster encoding the RiPP curacozole reveals a phenylalanine-specific peptide hydroxylase By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC02262A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Samantha Hollands, Julia Tasch, David J. Simon, Dimah Wassouf, Isobel Barber, Arne Gessner, Andreas Bechthold, David L. ZechelThe noncanonical biosynthesis of curacozole by Streptomyces curacoi is shown to be dependent on the bldA-encoded Leu-tRNAUUA. The minimal biosynthetic gene cluster is defined, and the functions of key biosynthetic enzymes are established in vitro.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co From small changes to big gains: pyridinium-based tetralactam macrocycle for enhanced sugar recognition in water By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06190J, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Canjia Zhai, Ethan Cross Zulueta, Alexander Mariscal, Chengkai Xu, Yunpeng Cui, Xudong Wang, Huang Wu, Carson Doan, Lukasz Wojtas, Haixin Zhang, Jianfeng Cai, Libin Ye, Kun Wang, Wenqi LiuIncorporating pyridinium into an anthracene-based macrocycle significantly enhances its sugar binding affinity by increasing hydrogen bonding and expanding the contact surface area.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Structural constraint at a P–P bond: phosphinophosphination of alkenes, alkynes, and carbonyls by a concerted mechanism By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06581F, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Lijun You, Daniel Roth, Lutz GrebA structural constraint approach at a P–P bond is presented that enables the phosphinophosphination of alkynes, alkenes, and carbonyls with high regio- and diastereoselectivity. The apolar nature of the P–P bond facilitates a concerted mechanism.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co CuBr-mediated surface-initiated controlled radical polymerization in air By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06012A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Menglu Chen, Shuai You, Tingting Guo, Haohao Ren, Longzu Zhu, Peize Wang, Wenbo Sheng, Chenliang Gong, Wei LiCuBr-mediated surface-initiated controlled radical polymerization for polymer brushes with patterned and block architectures over large areas in air is reported.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Resonance Plasmonic Coupling: Selective Enhancement of Band Edge Emission over Trap State Emission of CdSe Quantum Dots By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC04960H, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Livin Paul, Elizabeth Mariam Thomas, Akshaya Chemmangat, Stephen Gray, K. George ThomasThe photoluminescence properties of quantum dots (QDs) are often enhanced by eliminating surface trap states through chemical methods. Alternatively, a physical approach is presented here for improving photoluminescence purity in...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Understanding ketone hydrogenation catalysis with anionic iridium(III) complexes: The crucial role of counterion and solvation By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC04629C, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Paven Kisten, Sandrine Vincendeau, Eric Manoury, Jason Martin Lynam, John M. Slattery, Simon B Duckett, Agusti Lledos, Rinaldo PoliThe catalytic asymmetric hydrogenation of ketones reflect an important way to prepare valuable chiral alcohols. Understanding how transition metals promote these reactions is key to the rational design of more...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Simultaneous generation of hydroxyl and hydrogen radicals from H+/OH− pairs caused by water–solid contact electrification By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06227B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Fengjie Chen, Jingde Wu, Dou Wang, Yu Xia, Qingyuan Song, Ying Liang, Pu Wang, Bolei Chen, Yong Liang, Yongguang Yin, Yawei Wang, Maoyong Song, Guibin JiangWater–solid contact electrification is a common physical phenomenon involving interfacial electron and ion transfer, recently discovered to trigger unique redox reactions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Low temperature decoherence dynamics in molecular spin systems using the Lindblad master equation By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC05627B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Timothy Krogmeier, Anthony W Schlimgen, Kade Head-MarsdenUnderstanding the spin dynamics in low-temperature settings is crucial to designing and optimizing molecular spin systems for use in emerging quantum technologies. At low temperatures, irreversible loss occurs due to...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Electrochemical reconstruction of metal–organic gels into crystalline oxy-hydroxide heterostructures for efficient oxygen evolution electrocatalysis By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05799F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kang Liu, Haikuo Lan, Yuting Chen, Weicheng Tang, Zhenyu Xiao, Yunmei Du, Jun Xing, Zexing Wu, Lei WangAn amorphous MOG electrochemically reconstitutes to a crystalline NiOOH/FeOOH heterostructure with the morphology changed from nanofibers to nanosheets as a high-performance OER electrocatalyst.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Pnictogen-based vanadacyclobutadiene complexes By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05884D, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Mehrafshan G. Jafari, John B. Russell, Hwan Myung, Seongyeon Kwon, Patrick J. Carroll, Michael R. Gau, Mu-Hyun Baik, Daniel J. MindiolaThe reactivity of a [VV] alkylidyne with unsaturated substrates such as NCR (R = Ad or Ph) and PCAd leads to the formation of rare transition metal complexes featuring an α-aza-vanadacyclobutadiene and a β-phospha-vanadacyclobutadiene moieties.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Dual ligand-enabled iron and halogen-containing carboxylate-based photocatalysis for chloro/fluoro-polyhaloalkylation of alkenes By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC04038D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Wanru Han, Zhenyan Zhao, Kui Jiang, Yu Lan, Xuehan Yu, Xiaoyu Jiang, Wei Yang, Donghui Wei, Shi-Jun Li, Linbin NiuDual ligand-enabled iron photocatalysis for the conversion of all kinds of halogen-containing carboxylates (CnXmCOO−, X: F, Cl, Br) to CnXm radicals is disclosed for chloro/fluoro-polyhaloalkylation of non-activated alkenes.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Direct synthesis of N-perfluoro-tert-butyl secondary amines from N-trifluoromethyl secondary amines By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06335J, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Leibing Wang, Zhongyu Feng, Zhen Luo, Zihao Guo, Jieping Wang, Wenbin YiThe one-step direct synthesis of N-perfluoro-tert-butyl secondary amines utilizes TMSCF3 as the sole CF3 source and the starting material N-CF3 secondary amine itself as the hydrogen source. PFtB amines can be effectively employed in 19F MRI.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Pathway control in metallosupramolecular polymerization of a monoalkynylplatinum(II) terpyridine complex through competitive complex formation By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06083K, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Minhye Kim, Heekyoung Choi, Minjoo Kim, Seonghan Kim, Seohyeon Yun, Eunji Lee, Jaeheung Cho, Sung Ho Jung, Jong Hwa JungThe modification of metalloligands based on bis-type amideterpyridine platinum(II) complexes not only induces the formation of helical supramolecular polymers but also introduces a kinetic trapping strategy in competitive conditions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Photochemical carboborylation and three-component difunctionalization of α,β-unsaturated ketones with boronic acids via tosylhydrazones By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06537A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Álvaro Valdés-Maqueda, Manuel Plaza, Carlos ValdésThe photochemical carboborylation of α,β-unsaturated tosylhydrazones with boronic acids gives tertiary allylboronates. A one pot sequence involving an aldehyde allylation provides a powerful three-component method for diversity oriented synthesis.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Mechanism of action and evaluation of ratiometric probes for uric acid using lanthanide complexes with tetraazatriphenylene sensitisers By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05743K, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Xinyi Wen, Huishan Li, Zhijie Ju, Renren Deng, David ParkerSix Eu(III) and Tb(III) complexes are evaluated for the rapid ratiometric analysis of urate in diluted serum, together with mechanistic studies probing the intermediate exciplex and the excited state dynamics by transient absorption spectroscopy.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Direct Ladderization of Cyclooctatetraene-containing, Processable Conjugated Ladder Polymers from Annulated bis-Zirconacyclopentadienes By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC06902A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.August J. Rothenberger, Harrison M. Bergman, He Li, Miao Qi, Yunfei Wang, Yi Liu, T. Don TilleyConjugated ladder polymers (CLPs) are difficult yet captivating synthetic targets due to their fully unsaturated fused backbones. Inherent challenges associated with their synthesis often lead to low yields, structural defects,...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Synergetic effect of mild hypothermia and antioxidant treatment on ROS-mediated neuron injury under oxygen-glucose deprivation investigated by scanning electrochemical microscopy By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC05977H, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Junjie Zhang, Yulin Liu, Yuxiang Zhao, Siyu Zhang, Feng Xu, Fei LiIschemic stroke and reperfusion injury result in neuronal damage and dysfunction associated with oxidative stress, leading to overproduction of cellular reactive oxygen species (ROS) and reactive nitrogen species (RNS). In...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Triple-Function Porphyrin in Glycopolymeric Photosensitizer: From PhotoATRP to Targeted PDT By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC06466F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jiahui Lin, Zhiyuan Ma, Weiwei Zuo, Meifang ZhuPorphyrin derivatives serve as photocatalysts in reversible-deactivation radical polymerization and as photosensitizers in photodynamic therapy (PDT). Herein, a triple function porphyrin, ZnTPPC6Br, was synthesized as photocatalyst and initiator for photoATRP....The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Rapid, Potent, and Persistent Covalent Chemical Probes to Deconvolute PI3Kα Signaling By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC05459H, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lukas Bissegger, Theodora Alexandra Alexandra Constantin, Erhan Keles, Luka Raguž, Isobel Barlow-Busch, Clara Orbegozo, Thorsten Schaefer, Valentina Borlandelli, Thomas Bohnacker, Rohitha SriRamaratnam, Alexander Schäfer, Matthias Gstaiger, John E. Burke, Chiara Borsari, Matthias WymannChemical probes have gained importance in the elucidation of signal transduction in biology. Insufficient selectivity and potency, lack of cellular activity and inappropriate use of chemical probes has major consequences...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Rare-earth metal complexes bearing electrophilic and nucleophilic carbon centres and their unique reactivity patterns towards pyridine derivatives By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC04197F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.weikang Wu, Thayalan Rajeshkumar, Shan Zhu, Fuxiang Chai, Dongjing Hong, ZeMing Huang, Qingbing Yuan, Laurent Maron, Shaowu WangThe rare-earth metal dialkyl complexes (κ2-L1)RE(CH2SiMe3)2(THF)2 [RE = Lu(1a), Yb(1b), Er(1c), Y(1d), Dy(1e)] (L1 = 1-(2-N-C5H10NCH2CH2)-3-(2,6-iPr2C6H3N=CH)-C8H4N) and the rare-earth metal monoalkyl complexes (κ2-L1)2RE(CH2SiMe3)(THF)n [n = 0, RE = Lu(2a), Yb(2b);...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Discovery of penicillic acid as a chemical probe against tau aggregation in Alzheimer’s Disease By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC05469E, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jennifer Shyong, Jinliang Wang, Tran Quoc Dung Huynh, Marina Fayzullina, Bo Yuan, Ching-Kuo Lee, Thomas Minehan, Paul M. Seidler, Clay WangAlzheimer’s Disease (AD) is a neurodegenerative disorder proven to be caused by the aggregation of protein tau into fibrils, resulting in neuronal death. The irreparable neuronal damage leads to irreversible...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Sequence-dependent Conformational Transitions of Disordered Proteins During Condensation By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC05004E, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jiahui Wang, Dinesh Devarajan, Keerthivasan Muthukumar, Youngchan Kim, Arash Nikoubashman, Jeetain MittalIntrinsically disordered proteins (IDPs) can form biomolecular condensates through phase separation. It is recognized that the conformation of IDPs in the dense and dilute phases, as well as at the...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Depolymerisation of Poly(Lactide) Under Continuous Flow Conditions By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC05891G, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Sophie Ellis, Antoine Buchard, Tanja JunkersPoly(L-lactic acid) (PLLA) is commercially successful bio-based plastic, where end-of-life materials can undergo industrial composting. To create a circular economy, a desirable alternative to composting is chemical recycling to monomer...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Spin State Modulation and Kinetic Control of Thermal Contraction in a [Fe2Co2] Discrete Prussian Blue Analogue By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC05792A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jyoti Yadav, Sanjit KonarStimuli-responsive switchable molecules represent an important category of magnetic materials with significant potential for functional devices. However, engineering complexes with controlled switchability remains challenging due to their sensitivity to lattice...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
co Curtains come down on MAMI By www.thehindu.com Published On :: Fri, 28 Oct 2016 00:00:00 +0530 Diamond Island,Godless,Everything Else,Lady of the LakeandThe Narrow Pathamong big winners Full Article Mumbai
co When imagination and real life collide By www.thehindu.com Published On :: Mon, 31 Oct 2016 00:00:00 +0530 Nidhi Dalmia’sHarpbrings to the fore the real-life conflicts faced by people in ’60s India Full Article Mumbai
co Incongruent to their motive By www.thehindu.com Published On :: Wed, 02 Nov 2016 00:00:00 +0530 Deepa and Dilip Mehta’s latest films are well-intentioned but ineffective attempts to look at sexual crimes and the adult film industry respectively to analyse the increase in rape in the country Full Article Mumbai
co Rediscovering repositories of heritage By www.thehindu.com Published On :: Sun, 06 Nov 2016 00:00:00 +0530 Often considered dull and uninviting, Indian museums are storehouses of history and culture, and deserve repeat visits saysShailaja Tripathi Full Article Mumbai
co From Sarita Devi’s corner By www.thehindu.com Published On :: Mon, 07 Nov 2016 00:00:00 +0530 Suprita Das’s latest book captures the tale of boxer Sarita Devi, who refused to receive the bronze medal at the Incheon Asian Games 2014 Full Article Mumbai
