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Homochiral Dy2 single-molecule magnets with strong magneto-optical Faraday effect and strong third-harmonic generation

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00691G, Research Article
Cai-Ming Liu, Rong Sun, Xiang Hao, Xi-Li Li, Bingwu Wang
Four pairs of homochiral Dy2 complexes were directionally prepared using homochiral β-diketone ligands {D-Htfc/L-Htfc = (+)/(−)-3-trifluoroacetyl camphor, D-Hpfc/L-Hpfc = 3-(perfluorobutyryl)-(+)/(−)-camphor} and hydrazone Schiff base bridging ligands {H2L1 = (E)-N'-(2-hydroxy-3-methoxybenzylidene)pyrazine-2-carbohydrazide, H2L2...
The content of this RSS Feed (c) The Royal Society of Chemistry




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A wheel-like polyoxometalate for haloperoxidase inspired antibiofouling with H2O2 in-situ provided by electrocatalysis

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00482E, Research Article
Yumeng Bian, Runze Wang, xinxin xu, Jin Chen, Qiang Wang
Biofouling is adhering of micro-organisms on submerged surfaces, which is a common phenomenon presents serious hazard to industry and public health. Nanozymes with haloperoxidase mimic activity are promising options to...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Radiochromic Semiconductive MOF with High Sensitivity and Fast Photochromic Response for Dual-mode X-ray Direct Detection

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00771A, Research Article
Xuying Yu, Jia-Rong Mi, Qiu-Pei Qin, Xin-Ping Fang, Yong-Fang Han, Li-Zhen Cai, Ming-Sheng Wang, Guo-Cong Guo
X-ray direct detectors, which may directly convert X-rays into electrical signals through semiconductors, are highly desirable for early cancer screening and other applications. Prevailing commercial amorphous Se detectors still suffer...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Large enhancement of electrochemical biomass oxidation by optimizing the competitive adsorption of HMF and OH− on doped CoOx

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00519H, Research Article
Tianqi Nie, Guihao Liu, Ziheng Song, Tianyang Shen, Xiaoliang Sun, Tianrui Yu, Sha Bai, Lirong Zheng, Yu-Fei Song
By doping transition metals into CoOx, we can regulate the deintercalation capacity of OH. The CoCuOx with enriched oxygen vacancies allowed the optimization of the competitive adsorption between HMF and OH, and accelerated the kinetics of HMFOR.
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Phase switching and shape-memory effect in a molecular material: revisiting the Werner complex [Ni(4-MePy)4(NCS)2]

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00636D, Research Article
Open Access
Shi-Qiang Wang, Shaza Darwish, Catiucia Matos, Zicong Marvin Wong, Anjaiah Nalaparaju, Yifei Luo, Jun Zhu, Xiaofei Zhang, Zhengtao Xu, Michael Zaworotko
Shape-memory effects and stimuli-induced phase transformations are observed across many types of materials but remain understudied in molecular materials. In this contribution, we revisit the Werner complex, [Ni(4-MePy)4(NCS)2] (4-MePy =...
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Insights into the modulation mechanisms of multiple active sites in a conjugated small molecule towards organic cathode capacity from first-principles

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00547C, Research Article
Zhaopeng Sun, Hao Tian, Meng Zhang, Yi Zhang, Zhiping Li, Weiwei Huang
The modulation mechanisms of Na+ within the redox-active sites of the two-dimensional conjugated organic small-molecule 3BQ, and their impact on the initial capacity of a 3BQ cathode for Na-ion batteries, were investigated using first-principles calculations.
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Yolk-Shell type Carbon-Silica Nanoarchitecture Dispersed and Stabilized Ru Nanoparticles for Enhanced Hydrogenation of Aromatic Compounds

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00553H, Research Article
Lu Yan, Yue Shen, Zidan Zou, Xiao Zhang, Zhixin Yu, Guozhong Wang, Chun Chen
Hydrogenation of aromatic rings can be used not only for synthesis fine chemicals, but also for hydrogen storage and transportation using organic hydride. In this paper, yolk-shell structural SiO2@Ru@NC catalyst,...
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Anisotropic ZSM-5 nanorod assemblies: facile synthesis, epitaxial growth, and strikingly enhanced stability in benzene alkylation

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00287C, Research Article
Peng Zhu, Yiren Yu, Guoshu Gao, Yumeng Zhao, Yuting Jiao, Haiou Liu, Guodong Liu, Xiongfu Zhang, Guohui Yang
A novel bundle-like ZSM-5 nanorod assembly was facilely synthesized by adopting a CTAB-aided seed-induced strategy for highly efficient alkylation of benzene with ethanol.
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Advances in technical strategies for monitoring the reduction of platinum(IV) complexes

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00459K, Review Article
Open Access
Shu Chen, Qiyuan Zhou, Ka-Yan Ng, Zoufeng Xu, Weikang Xu, Guangyu Zhu
The reduction of Pt(IV) complexes can be monitored by various analytical techniques. These techniques hold significant promise in elucidating the mechanisms of Pt(IV) prodrug activation, aiding in the rational design of novel Pt(IV) prodrugs.
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Solar heating catalytic formic acid dehydrogenation by graphene-porous foam-supported tungsten nitride nanoparticles

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00590B, Research Article
Jiarong Chang, Tianhua Hao, Cuncai Lv, Maoyu Xu, Deyi Zhang, Linjie Gao, Shangbo Ning, Yaguang Li, Jinhua Ye
WN/Gr PF exhibits significant solar heating catalytic formic acid dehydrogenation and the rate exceeds those of other reported photocatalysts.
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Tuning lithium–yttrium chloride local structure through coordination control and mixing during synthesis

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00559G, Research Article
Open Access
Teerth Brahmbhatt, Cheng Li, Mounesha N. Garaga, Wan-Yu Tsai, Steve G. Greenbaum, Jagjit Nanda, Robert L. Sacci
Synthesis of Li3YCl6 is facilitated by the addition of NH4Cl. Synthesis method affects local ordering and Li+ dynamics as determined by neutron diffraction, impedance and NMR spectroscopy.
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Trifluoroacetic acid molecules confined into/onto metal–organic frameworks using H2btzip for efficiently improving proton conductivity using a synergistic effect

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00605D, Research Article
Xiaoxue Ma, Xin Li, Xueke Han, Lu Zhang, Ronghua Liu, Hongguo Hao, Hui Yan, Xin Zhao, Xiangjin Kong, Huawei Zhou, Xia Li, Hongjie Zhu, Suna Wang, Yunwu Li, Dichang Zhong, Fangna Dai
Two outstanding proton conducting materials have been obtained by loading TFA molecules onto/into the surface or pores of MOFs. After post-treatment, their proton conductivity values are greatly increased under the same conditions.
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AgCare Tech launches digital marketplace for agri inputs

‘Golden Farms’ is designed to digitise the agricultural input supply chain




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Crude oil futures down due to profit-booking after recent surge

Market fears that the escalating tensions could disrupt crude oil supplies from West Asia as Iran is a major producer of crude oil in the world market




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SEBI explores feasibility of introducing crude oil ETFs

Such ETFs own futures contracts on crude oil instead of the commodity itself. The ETF price will mimic the spot price.




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Optimism in global commodities market over Chinese measures may be short-lived, say analysts

Subdued demand, struggling property sector may exert downward pressure on metals




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SEBI panel mulls new category of commodity funds

MF investment in ETCDs is estimated to be under ₹10,000 crore




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Row over ISMA’s suggestion to regulate khandsari units

Opposing curbs, traditional sweeteners body BHAKTI says Centre should not be swayed by false narratives




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Aluminium futures retain positive bias

The price region between ₹228 and ₹230 is a demand zone




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Kandla Customs Commissioner orders release of ship detained in organic rice export irregularities

Tells Kandla traffic manager to allow another ship to set sail after getting release order from Gujarat HC




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Reservoirs with less than 50% storage down to single digit

Key dams’ water level unchanged at 87% of capacity this week




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Stronger monsoon winds bringing more rainfall to arid regions of north-west India: Southampton varsity study

The study reports 40% increase in south-west monsoon rainfall over north-west India in recent years  




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Spinning mills in Gujarat, N. India seek quality cotton from Raichur region

Ongoing rains raise concern over quality, crop size across key producing regions




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Crude oil trades higher as market monitors developments in West Asia 

At 9.56 am on Friday, December Brent oil futures were at $74.50, up by 0.16 per cent, and December crude oil futures on WTI (West Texas Intermediate) were at $70.28, up by 0.13 per cent




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Festivals, agriculture, elections set to boost India's oil demand: S&P Global Commodity Insights

According to the commodities information services provider, India's oil demand decreased in September on a yearly basis, due to above normal rainfall, which affected road movement, construction, and mining activities




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Crude oil futures dip after Israeli attack avoids Iranian oil facilities 

November natural gas futures were trading at ₹254.50 on MCX during the initial hour of trading on Monday against the previous close of ₹258.20, down by 1.43 per cent




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Down the AI rabbit hole, strewn with health benefits and ethical pitfalls 

Regulatory frameworks covering AI need fine-tuning to harness its potential without halting growth 




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Coconut water, evening walks & meditation




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Communities lead

The theme on World AIDS Day (December 1) is ‘Let Communities Lead’




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COPing with cascading health concerns that climate change brings to our doorstep

Climate and Health: A global challenge needs a local solution to build resilient health systems




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Making the right choice on organs — ‘pass it on’

Organ Donation: A tightly regulated practice tainted by acts of fraud, gifts someone a chance at a better health




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Nutrition, hydration & neighbourhood runs

Marathoner shares 20-year fitness regime of cardio, strength, and stability, prioritising training and recovery for marathon success




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A pitch to walk the fine line between innovation and access

 Ahead of USTR’s Special 301 report, India campaigns for flexibilities in international trade laws




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Morning run, nutritious meals and unwinding

Prioritise mornings with running, balanced diet, revitalizing workouts and meditation for mental health, says Nishant Pitti, CEO and Co-Founder, EaseMyTrip




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Private capital, a catalyst to Universal Health Coverage

India is committed to achieving Universal Health Coverage (UHC) for all by 2030. For India to achieve thisUHC, it is essential that both private enterprises and the government come together.




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Tennis, yoga and unwinding with a book

Ritesh Kumar’s daily routine includes yoga, a plant-based diet, contemplation, tennis, and unwinding with a good book.




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Pharmacies journey through litigations and another election

Chemists’ manifesto: Call for fair play gets louder amidst deep discounts from online pharmacies




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MMA, Wim Hof breathing and intermittent fasting

Boost your day with Wim Hof breathing, meditation, MMA, fasting, and outdoor exercise for optimal health and wellness




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Intellectual property for positive change

In a rapidly evolving world, leveraging intellectual property (IP) for greater good has become a priority and its importance will continue to grow as humanity addresses pivotal global challenges




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Walks, conscious nutrition and switching off with Buzo

Akshay Chaturvedi, Founder CEO of Leverage.biz, shares tips on health, fitness and his beloved German shepherd




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Mountain hikes, for fitness and zen

Uma R Krishnan, MD, Optum India, on her exercise routine, favourite cuisines and tips to manage stress




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Data integrity alarm sounded for CROs, the backbone to pharma industry

USFDA cautions CROs; says such incidents “undermine the reputation of generic industry”




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Breaking down ‘patent thickets’ without smothering innovation

With recent patent-linked rejections, governments push back on big pharma’s strategy




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Act on hepatitis infections

Deaths from viral hepatitis-related causes are increasing, with around one hepatitis death every 30 seconds, says the WHO, ahead of World Hepatitis Day (July 28).




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Reviewing TRIPS, an opportunity for evidence-based policies

Colombia calls for review of TRIPS Agreement implementation, highlighting need for evidence-based IP law and policy




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World Mosquito Day

The World Mosquito Day (August 20) raises awareness on mosquito-borne diseases.




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Paralympic’s equity campaign

The World Health Organization and International Paralympic Committee have launched the ‘Equipped for equity’ campaign at the Paris 2024 Paralympic Games




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Code grey: Hospitals as safe zones for medical practitioners, patients

Amid rising violence, medicos call for a stringent Central Act to ensure safe workspaces and speedy action




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Why maternal nutrition is blue-chip investment

Guaranteed maternal nutrition can break the cycle of malnutrition passed from one generation to the next




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Subdued blenders’ demand hits Coonoor tea auctions sales 

Sales drop to less than 70 per cent in leaf and dust