it Quadrupolar dinuclear hypervalent tin(IV) compounds with near-infrared emission consisting of Schiff bases based on π-conjugated scaffolds By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,17950-17961DOI: 10.1039/D4SC05006A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kazuya Tanimura, Kento Tanaka, Masayuki Gon, Kazuo TanakaThe study focuses on dinuclear hypervalent tin(IV) compounds with near-infrared (NIR) emission and unique quadrupolar orientations, showing potential for constructing electronic structures with narrow energy gaps.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it On-demand controlled bidirectional DNAzyme path for ultra-sensitive heavy metal ion detection By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,18170-18178DOI: 10.1039/D4SC04404E, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jing Xu, Yujin Li, Futing Wang, Xinqi Luo, Wei Zhang, Yifan Lyu, Hongfen Yang, Ren Cai, Weihong TanA bidirectional self-powered biosensor is constructed for the quasi-simultaneous detection of Pb2+ and Hg2+ based on MoS2@CuS heterostructures as an accelerator and hybridization chain reaction as a signal amplification strategy.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Reactivities of tertiary phosphines towards allenic, acetylenic, and vinylic Michael acceptors By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,18111-18126DOI: 10.1039/D4SC04852K, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Feng An, Jan Brossette, Harish Jangra, Yin Wei, Min Shi, Hendrik Zipse, Armin R. OfialCombined experimental and quantum-chemical studies were used to characterise the philicity/fugality features of tertiary phosphines and Michael acceptors in phospha-Michael reactions, which are key steps in phosphine-catalysed organic reactions.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Enhancing hydrogen evolution reaction activity through defects and strain engineering in monolayer MoS2 By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,18127-18134DOI: 10.1039/D4SC04874A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Renjith Nadarajan, Sraboni Dey, Arijit Kayal, Joy Mitra, Manikoth M. ShaijumonThe synergistic creation of vacancy defects, along with strain-induced active sites is shown to enhance hydrogen evolution reaction (HER) performance of CVD-grown monolayer MoS2.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Unified enantiospecific synthesis of drimane meroterpenoids enabled by enzyme catalysis and transition metal catalysis By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06060A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yipeng You, Xue-Jie Zhang, Wen Xiao, Thittaya Kunthic, Zheng Xiang, Chen XuA unified synthetic strategy for drimane meroterpenoids was developed by combining heterologous biosynthesis, enzymatic oxidation, and transition metal catalysis. Six drimane meroterpenoids were synthesized in a concise and enantiospecific manner.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Double coordination shell modulation of nitrogen-free atomic manganese sites for enhancing oxygen reduction performance By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05998K, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xue Bai, Yin Wang, Jingyi Han, Siyu Chen, Xiaodi Niu, Jingqi GuanUtilizing double coordination shell modulation, we construct a novel nitrogen-free single-atom manganese coordination configuration catalyst on graphene oxide (Mn–S1O4G), which exhibits excellent ORR and zinc–air battery performances.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Dilute nanocomposites for capacitive energy storage: progress, challenges and prospects By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC05437G, Perspective Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Li Li, Wenhan Xu, Guanchun Rui, Shixian Zhang, Qiming Zhang, Qing WangElectrostatic capacitors (ECs) are critical components in advanced electronics and electric power systems due to their rapid charge-discharge rate and high power density. While polymers are ideal for ECs due...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it The chirality-induced spin selectivity effect in asymmetric spin transport: from solution to device applications By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05736H, Review Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ritu Gupta, Anujit Balo, Rabia Garg, Amit Kumar Mondal, Koyel Banerjee Ghosh, Prakash Chandra MondalThis review highlights recent experimental findings related to the chirality-induced spin selectivity effect. This effect is demonstrated to explain asymmetric electron's spin transport in chiral molecules for various technological applications.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Photo-triggered NO release of nitrosyl complexes bearing first-row transition metals and therapeutic applications By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC06820C, Review Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Seungwon Sun, Jisu Choe, Jaeheung ChoIn biological systems, nitric oxide (NO) is a crucial signaling molecule that regulates a wide range of physiological and pathological processes. Given the significance of NO, there has been considerable...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Probing water adsorption and stability under steam flow of Zr-based metal-organic frameworks using 91Zr solid-state NMR spectroscopy By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC04589K, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Athulya Nadol, Florian Venel, Raynald Giovine, Maeva Leloire, Christophe Volkringer, Thierry Loiseau, Christel Gervais, Caroline Mellot-Draznieks, Bertrand Doumert, Julien Trébosc, Olivier Lafon, Frédérique PourpointThe stability of metal-organic frameworks (MOFs) in the presence of water is crucial for a wide range of applications, including the production of freshwater, desiccation, humidity control, heat pumps/chillers and...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Selective lignin depolymerization via transfer hydrogenolysis using Pd/hydrotalcite catalysts: model compounds to whole biomass By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC03942D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Darren Dolan, Rebekah Brucato, Christopher William Reid, Adam F. Lee, Karen Wilson, Adelina M Voutchkova-KostalCleavage of lignin ether bonds via transfer hydrogenolysis is a promising route to valorize lignin, but processes that use mild reaction conditions and exploit renewable hydrogen donor solvents (rather than...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Enhanced efficiency in plastic waste upcycling: the role of mesoporosity and acidity in zeolites By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05121A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Saideep Singh, Joaquín Martínez-Ortigosa, Nuria Ortuño, Vivek Polshettiwar, Javier García-MartínezBy optimizing zeolite pore confinement, polymer diffusion and up-cycling efficiency in hierarchical catalysts are significantly enhanced, reducing plastic degradation temperatures and providing a suitable route to sustainable plastic-to-fuel pathways.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Enantioselective dearomative formal (3+3) cycloadditions of bicyclobutanes with aromatic azomethine imines: access to fused 2,3-diazabicyclo[3.1.1]heptanes By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06334A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xue-Chun Yang, Feng Wu, Wen-Biao Wu, Xu Zhang, Jian-Jun FengWe present the first enantioselective dearomative (3+3) cycloadditions of bicyclobutanes (BCBs) utilizing a chiral Lewis acid catalyst and bidentate chelating BCB substrates.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it M12L24 nanospheres as supramolecular templates for the controlled synthesis of Ir-nanoclusters and their use in the chemo-selective hydrogenation of nitro styrene By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC06324D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lotte L. Metz, Rens Ham, Eduard Bobylev, Kelly J. H. Brouwer, Alfons van Blaaderen, Rim van de Poll, Victor Drozhzhin, Emiel J. M. Hensen, Joost N. H. ReekControlled preparation of ultrafine metal nanoclusters (<2 nm) is challenging, yet important as the properties of these clusters are inherently linked to their size and local microenvironment. In the present...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Steering N/S coordination number to accelerate catecholase-like catalysis over low-coordinated Cu site By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05014B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Meng Yuan, Nannan Xia, Ziheng Huang, Chaofeng Huang, Xun Hu, Fei HeModulating the coordination configuration of metal Cu center through steering the N/S coordination number around Cu center boosted the catalytic activity of catechol oxidase-mimicking nanozyme.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it A polymer deposition-mediated surface-charge reformation strategy: reversing the MOF biomineralization behavior By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05935B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yanbin Xu, Huangsheng Yang, Anlian Huang, Linjing Tong, Wei Huang, Guosheng Chen, Wei Yi, Siming Huang, Gangfeng OuyangA biocompatible polymer deposition-mediated surface-charge reformation strategy is reported that enables the in-place MOF biomineralization onto different enzyme templates.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it An ultrasensitive 2,4,6-trinitrophenol nanofluidic sensor inspired by olfactory sensory neurons in sniffer dogs By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05493H, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xin Li, Zhanfang Liu, Linsen Yang, Shengyang Zhou, Yongchao Qian, Yuge Wu, Zidi Yan, Zhehua Zhang, Tingyang Li, Qingchen Wang, Congcong Zhu, Xiang-Yu Kong, Liping WenInspired by sniffer dog olfactory sensory neurons, an ultrasensitive TNP detection sensor was developed by in situ growing UiO-66-NH2 layers on AAO. It exhibits a limit of detection with 6.5 × 10−16 g mL−1, offering a new method for rapid detection.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Strain-induced charge delocalization achieves ultralow exciton binding energy toward efficient photocatalysis By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05873A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Junyuan Duan, Yinghe Zhao, Yu Wu, Youwen Liu, Junnian Chen, Ruoou Yang, Jiazhao Huang, Chuanqi Luo, Mao Wu, Xiaodong Zheng, Pengyu Li, Xueliang Jiang, Jianguo Guan, Tianyou ZhaiA novel approach of strain-induced charge delocalization is developed to significantly reduce the exciton binding energy of Ta2O5 nanorods to below ambient thermal energy, leading to a remarkable enhancement in photocatalytic hydrogen evolution.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Cyclo[4]pyrrole with α–β direct linkages By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06670G, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yuhua Sun, Riku Kitahara, Tomoya Ichino, Yuki Ide, Hisanori Senboku, Soji Shimizu, Takayuki Tanaka, Yasuhide InokumaA cyclo[4]pyrrole bearing pyrrole(α)–pyrrole(β) direct linkages was synthesized from an oligoketone precursor. Cyclo[4]pyrrole exhibited a non-planar macrocyclic structure whose global π-conjugation was altered depending on the dihedral angles.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it From small changes to big gains: pyridinium-based tetralactam macrocycle for enhanced sugar recognition in water By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06190J, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Canjia Zhai, Ethan Cross Zulueta, Alexander Mariscal, Chengkai Xu, Yunpeng Cui, Xudong Wang, Huang Wu, Carson Doan, Lukasz Wojtas, Haixin Zhang, Jianfeng Cai, Libin Ye, Kun Wang, Wenqi LiuIncorporating pyridinium into an anthracene-based macrocycle significantly enhances its sugar binding affinity by increasing hydrogen bonding and expanding the contact surface area.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Regioselectivity switches between anthraquinone precursor fissions involved in bioactive xanthone biosynthesis By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06369D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xiao Jing Lv, Chun Zhi Ai, Li Rong Zhang, Xiu Xiu Ma, Juan Juan Zhang, Jia Peng Zhu, Ren Xiang TanBruN and BTG13 cleave chrysophanol hydroquinone into monodictyphenone and cephalanone F, respectively, with the regioselectivities found tunable via the key amino acid (AA) substitution strategy.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Dynamic satellite–parent liposome networks for quantitative microreactions By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC04925J, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jia-Qi Tian, Nan-Nan DengA dynamic satellite–parent liposome network was developed to explore molecular transfer and quantitative microreactions through environmental stimuli, offering a platform to mimic multicellular systems in vitro.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it CuBr-mediated surface-initiated controlled radical polymerization in air By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06012A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Menglu Chen, Shuai You, Tingting Guo, Haohao Ren, Longzu Zhu, Peize Wang, Wenbo Sheng, Chenliang Gong, Wei LiCuBr-mediated surface-initiated controlled radical polymerization for polymer brushes with patterned and block architectures over large areas in air is reported.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Deep Learning Enabled Ultra-high Quality NMR Chemical Shift Resolved Spectra By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC04742G, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Zhengxian Yang, Weigang Cai, Wen Zhu, Xiaoxu Zheng, Xiaoqi Shi, Mengjie Qiu, Zhong Chen, Maili Liu, Yanqin LinHigh quality chemical shift resolved spectra have long been pursued in nuclear magnetic resonance (NMR). In order to obtain chemical shift information with high resolution and sensitivity, a neural network...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Bridge Editing of Spin-Flip Emitters gives Insight into Excited State Energies and Dynamics By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC05860G, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Florian Reichenauer, Robert Naumann, Christoph Förster, Winald Robert Robert Kitzmann, Antti-Pekka M. Reponen, Sascha Feldmann, Katja HeinzeSix-coordinate chromium(III) complexes with high spin-flip (SF) photoluminescence quantum yields and lifetimes (molecular rubies) have attracted huge interest in the past years due to their applicability in sensing, photocatalysis or...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Surfing the Limits of Cyanine Photocages One Step at a Time By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC07165D, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Hana Janeková, Sergey Fisher, Tomas Solomek, Peter StackoNear-infrared light-activated photocages enable controlling molecules with tissue penetrating light. Understanding the structural aspects that govern the photouncaging process is essential to enhancing their efficacy, crucial for practical applications. Here...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Understanding ketone hydrogenation catalysis with anionic iridium(III) complexes: The crucial role of counterion and solvation By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC04629C, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Paven Kisten, Sandrine Vincendeau, Eric Manoury, Jason Martin Lynam, John M. Slattery, Simon B Duckett, Agusti Lledos, Rinaldo PoliThe catalytic asymmetric hydrogenation of ketones reflect an important way to prepare valuable chiral alcohols. Understanding how transition metals promote these reactions is key to the rational design of more...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Understanding the Formation of Nitrate from Nitrogen at the Interface of Gas-Water Microbubbles By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC06989G, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sandeep Bose, Yu Xia, Richard N. ZareUnderstanding the Formation of Nitrate from Nitrogen at the Interface of Gas-Water MicrobubblesWater microbubbles containing Fe2+ ion has been found to efficiently transform nitrogen (N2) to nitrate (NO3-) by initiating...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Delocalization error poisons the density-functional many-body expansion By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05955G, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Dustin R. Broderick, John M. HerbertSelf-interaction error leads to runaway error accumulation when density functional theory is used in conjunction with the many-body expansion.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Noncentrosymmetric tellurite halides created by a depolymerization strategy: toward strong SHG intensity and wide bandgap By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06403H, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Dan-Dan Zhou, Chun-Li Hu, Xin-Wei Zhang, Jiang-Gao Mao, Fang KongSuccessful synthesis of centrosymmetric Ga(Te3O7)Br and non-centrosymmetric M2(OH)(TeO3)(Te2O5)X (M = Al, Ga; X = Br, Cl) using a depolymerization strategy.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Allosteric release of cucurbit[6]uril from a rotaxane using a molecular signal By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC03970J, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Aneta Závodná, Petr Janovský, Václav Kolařík, Jas S. Ward, Zdeňka Prucková, Michal Rouchal, Kari Rissanen, Robert VíchaRepulsions between portals of cucurbit[n]urils are sufficiently strong to unlock the rotaxane structure.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Pathway control in metallosupramolecular polymerization of a monoalkynylplatinum(II) terpyridine complex through competitive complex formation By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06083K, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Minhye Kim, Heekyoung Choi, Minjoo Kim, Seonghan Kim, Seohyeon Yun, Eunji Lee, Jaeheung Cho, Sung Ho Jung, Jong Hwa JungThe modification of metalloligands based on bis-type amideterpyridine platinum(II) complexes not only induces the formation of helical supramolecular polymers but also introduces a kinetic trapping strategy in competitive conditions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Photochemical carboborylation and three-component difunctionalization of α,β-unsaturated ketones with boronic acids via tosylhydrazones By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06537A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Álvaro Valdés-Maqueda, Manuel Plaza, Carlos ValdésThe photochemical carboborylation of α,β-unsaturated tosylhydrazones with boronic acids gives tertiary allylboronates. A one pot sequence involving an aldehyde allylation provides a powerful three-component method for diversity oriented synthesis.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Mechanism of action and evaluation of ratiometric probes for uric acid using lanthanide complexes with tetraazatriphenylene sensitisers By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05743K, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Xinyi Wen, Huishan Li, Zhijie Ju, Renren Deng, David ParkerSix Eu(III) and Tb(III) complexes are evaluated for the rapid ratiometric analysis of urate in diluted serum, together with mechanistic studies probing the intermediate exciplex and the excited state dynamics by transient absorption spectroscopy.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Triple-Function Porphyrin in Glycopolymeric Photosensitizer: From PhotoATRP to Targeted PDT By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC06466F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jiahui Lin, Zhiyuan Ma, Weiwei Zuo, Meifang ZhuPorphyrin derivatives serve as photocatalysts in reversible-deactivation radical polymerization and as photosensitizers in photodynamic therapy (PDT). Herein, a triple function porphyrin, ZnTPPC6Br, was synthesized as photocatalyst and initiator for photoATRP....The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Morphology of Lithium Halides in Tetrahydrofuran from Molecular Dynamics with Machine Learning Potentials By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC04957H, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Marinella de Giovanetti, Sondre H. Hopen Eliasson, Sigbjørn L. Bore, Odile Eisenstein, Michele CascellaThe preferred structures of lithium halides (LiX, with X = Cl, Br, I) in organic solvents have been the subject of a wide scientific debate, and a large variety of...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Rare-earth metal complexes bearing electrophilic and nucleophilic carbon centres and their unique reactivity patterns towards pyridine derivatives By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC04197F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.weikang Wu, Thayalan Rajeshkumar, Shan Zhu, Fuxiang Chai, Dongjing Hong, ZeMing Huang, Qingbing Yuan, Laurent Maron, Shaowu WangThe rare-earth metal dialkyl complexes (κ2-L1)RE(CH2SiMe3)2(THF)2 [RE = Lu(1a), Yb(1b), Er(1c), Y(1d), Dy(1e)] (L1 = 1-(2-N-C5H10NCH2CH2)-3-(2,6-iPr2C6H3N=CH)-C8H4N) and the rare-earth metal monoalkyl complexes (κ2-L1)2RE(CH2SiMe3)(THF)n [n = 0, RE = Lu(2a), Yb(2b);...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Sequence-dependent Conformational Transitions of Disordered Proteins During Condensation By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC05004E, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jiahui Wang, Dinesh Devarajan, Keerthivasan Muthukumar, Youngchan Kim, Arash Nikoubashman, Jeetain MittalIntrinsically disordered proteins (IDPs) can form biomolecular condensates through phase separation. It is recognized that the conformation of IDPs in the dense and dilute phases, as well as at the...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Depolymerisation of Poly(Lactide) Under Continuous Flow Conditions By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC05891G, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Sophie Ellis, Antoine Buchard, Tanja JunkersPoly(L-lactic acid) (PLLA) is commercially successful bio-based plastic, where end-of-life materials can undergo industrial composting. To create a circular economy, a desirable alternative to composting is chemical recycling to monomer...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it The seven qualities of successful male playback singers By www.thehindu.com Published On :: Thu, 27 Oct 2016 00:00:00 +0530 Full Article Mumbai
it When a drummer sits down to write music By www.thehindu.com Published On :: Thu, 27 Oct 2016 00:00:00 +0530 Rijul Victor’s experiments with EDM led him to start a solo project, which is now releasing his debut album as an electronic music producer Full Article Mumbai
it Spicing it up further By www.thehindu.com Published On :: Wed, 02 Nov 2016 00:00:00 +0530 Chef Anees Khan’s Bandra patisserie is now a café with a must try theccha burger, small eats, galangal ice tea and thick smoothies Full Article Mumbai
it Rediscovering repositories of heritage By www.thehindu.com Published On :: Sun, 06 Nov 2016 00:00:00 +0530 Often considered dull and uninviting, Indian museums are storehouses of history and culture, and deserve repeat visits saysShailaja Tripathi Full Article Mumbai
it The Majrooh Sultanpuri of writers By www.thehindu.com Published On :: Sun, 06 Nov 2016 00:00:00 +0530 Best known for musical blockbusters, legendary filmmaker Nasir Husain also wrote dialogues for his films. His words were true to the syntax of the timesthey were written in, whether it was forMunimjiorPaying Guestin the mid-1950s or forJo Jeeta Wohi Sikanderin the ’90s Full Article Mumbai
it Writer calling writer By www.thehindu.com Published On :: Mon, 07 Nov 2016 00:00:00 +0530 Hatufim creator Gideon Raff speaks to Aniruddha Guha about the cultural variances of different versions of the same story Full Article Mumbai
it From Sarita Devi’s corner By www.thehindu.com Published On :: Mon, 07 Nov 2016 00:00:00 +0530 Suprita Das’s latest book captures the tale of boxer Sarita Devi, who refused to receive the bronze medal at the Incheon Asian Games 2014 Full Article Mumbai
it Progressive forces to unite at Goa meet By www.thehindu.com Published On :: Wed, 09 Nov 2016 00:00:00 +0530 Full Article Mumbai
it Shape-shifting with dance By www.thehindu.com Published On :: Thu, 10 Nov 2016 00:00:00 +0530 Sanjukta Sinha dwells on belonging and relationships in Kin , her new contemporary Kathak production Full Article Mumbai
it Entertainment with a finesse By www.thehindu.com Published On :: Thu, 10 Nov 2016 00:00:00 +0530 Filmmaker Mansoor Khanon the cinema of his illustrious father and his comeback plans Full Article Mumbai
it Stupiditties: Once a Punk… By www.thehindu.com Published On :: Thu, 10 Nov 2016 00:00:00 +0530 Rishu Singh, the brains behind Ennui.Bomb, discusses his annual indie music compilation and the gig he’s hosting to celebrate its release Full Article Mumbai
