The present invention aims at improving a recovery rate of a positive-pole active substance and preventing a recovery loss of valuable metals when a positive-pole active substance is separated from a lithium ion battery. In the present invention, a material resulting from battery dismantling obtained by dismantling a lithium ion battery is stirred using a surfactant solution, whereby a positive-pole active substance is separated from a positive-electrode substrate. Also, it is preferable that an alkaline solution is added to a positive-electrode material of a material resulting from battery dismantling, thereby dissolving a positive-electrode substrate to which a positive-pole active substance adheres to obtain a slurry containing the positive-pole active substance, and a surfactant solution is added to the slurry to disperse the positive-pole active substance in the slurry, whereby the positive-pole active substance is separated from the alkaline solution.

The invention relates to methods and devices for breaking up ore. The methods and devices are characterized in particular in that ore mineral or ore minerals can be subsequently easily extracted. For this purpose coherent NIR radiation, non-coherent NIR radiation, at least one electric alternating field having a frequency greater than 300 GHz, at least one magnetic alternating field having a frequency greater than 300 GHz, at least one electromagnetic alternating field having a frequency greater than 300 GHz, or a combination thereof are respectively applied to the ore at least once by means of a device for generating the radiation, the at least one alternating field, or the radiation and the at least one alternating field, wherein ore mineral, ore minerals, absorbent components, or ore minerals and absorbent components of the ore absorb(s) energy from the radiation, the alternating field, or the radiation and the alternating field and said energy is not or is only slightly absorbed by the lode matter. Thus, advantageously, cracks are formed in the ore or the ore splits by means of the resulting stresses.

Seizure resistance and wear resistance of Cu—Bi—In copper-alloy sliding material are enhanced by forming a soft phase of as pure as possible Bi. Mixed powder of Cu—In cuprous alloy powder and Cu—Bi containing Cu-based alloy powder is used. A sintering condition is set such that Bi moves outside particles of said Cu—Bi containing Cu-based powder and forms a Bi grain-boundary phase free of In, and In diffuses from said Cu—In containing Cu-based powder to said Cu—Bi containing Cu-based powder.

A process for producing refractory metal alloy powders includes the steps of blending at least one powder with at least one solvent and at least one binder to form a slurry; forming a plurality of agglomerates from the slurry; screening the plurality of agglomerates; sintering the plurality of agglomerates; and melting said plurality of agglomerates to form a plurality of homogenous, densified powder particles.

The method for forming a 3-D metal object by 3-D printing or injection molding comprising providing as a feed material metal particles formed by establishing multiple metal components in a primary billet of a ductile material, working the primary billet through a series of reduction steps to form the components into elongated elements, leaching the ductile material from the elongated elements and reducing the length to short uniform lengths.

Novel systems and methods are described for reducing iron oxide to metallic iron in an integrated steel mill or the like that has a coke oven and/or an oxygen steelmaking furnace. More specifically, the present invention relates to novel systems and methods for reducing iron oxide to metallic iron using coke oven gas (COG) or COG and basic oxygen furnace gas (BOFG).

A method for making a metal-based nano-composite material is disclosed. In the method, a semi-solid state metal-based material is provided. The semi-solid state metal-based material is stirred and nano-sized reinforcements are added into the semi-solid state metal-based material to obtain a semi-solid state mixture. The semi-solid state mixture is heated to a temperature above a liquidus temperature of the metal-based material, to achieve a liquid-metal-nano-sized reinforcement mixture. The liquid-metal-nano-sized reinforcement mixture is ultrasonically processed at a temperature above the liquidus temperature by conducting ultrasonic vibrations to the liquid-metal-nano-sized reinforcement mixture along different directions at the same time.

In a method for producing a reduced iron pellet, when a powder formed article including iron oxide and carbon is heated and reduced in a rotary hearth furnace, a formed article produced using a raw material, in which an average diameter of the iron oxide is 50 microns or less and a ratio of carbon monoxide to carbon dioxide in a reduction zone is from 0.3 to 1, is reduced at a temperature of 1400° C. or less, thereby producing a reduced iron pellet in which a metallization ratio of iron is 50 to 85% and a ratio of residual carbon is 2% or less.

Carbothermic reduction of magnesium oxide at approximately 2200 degrees Kelvin yields a high temperature mixture of magnesium vapors and carbon monoxide gas. Previous processes have sought to cool or alter the mixture to cause the yield of pure magnesium, which is then used in subsequent processes for its reducing properties. The present invention takes advantage of the stability and inertness of carbon monoxide at elevated temperatures enabling the magnesium vapor/carbon monoxide gas mixture from the carbothermic process to be used directly for the production of other metals at high temperatures. Chromium oxide, manganese oxide, zinc oxide and sulfide, and several other metal compounds can be reduced by the magnesium vapor/carbon monoxide gas mixture at temperatures high enough to prevent the gas mixture from back-reacting to magnesium oxide and carbon.

Embodiments relate to unidirectional TPMS utilizing information from a corresponding vehicle system in order to correlate with vehicle speed information to be used in a tire localization methodology. In an embodiment, the vehicle system is an anti-lock brake system (ABS), and the vehicle speed can be used in a localization scheme that reconstructs a +/−1 g ripple with waveform, amplitude, frequency and phase parameters. Because the waveform is known to be sinusoidal (due to the wheel rotation), the amplitude is known to be 2 g peak-to-peak (due to the gravitational +/−1 g), the frequency depends on vehicle speed (which can be estimated from centrifugal force measurements), and an algorithm is discussed herein for determining the phase by correlation, the +/−1 g ripple can be reconstructed and the wheels localized therefrom.

In a tire inflating station for inflating a tubeless tire arranged on a rim with a pressurized gas, arranged on a stand are a conveyor for receiving and conveying a wheel consisting of a wheel rim and a tire mounted on the wheel rim, and an inflation device above the conveyor and having an inflation opening which can be connected to a gas supply. The lower side of the inflation device has a carrier plate that is mounted to move backwards and forwards along an axis between at least two positions in a straight-line mechanism. There are inflation rings attached in tandem in a gas-tight manner to the lower side of a carrier plate. Inside the inflation rings, the carrier plate has a respective continuous opening. In each of the different working positions of the carrier plate, another of the continuous openings is connected to the inflation opening of the inflation device, which inflation opening is arranged on the upper side of the carrier plate.

Tire changing machines having force feedback and position control systems are described that may be used to control operation of one or more components of the machine during a tire change procedure. Information may be provided to a machine operator concerning detected operating conditions during the procedure. Excessive or abnormal forces or component positions can be detected and corrective action may be taken at any point in the tire change procedure. Successful component position profiles may be saved for future recall and execution by the machine.

A device for changing the rotational angle position of a pneumatic tire relative to a rim, on which the pneumatic tire is fitted to the rim, includes a manipulating device with a gripper adapted to be rotated by a positionable rotary drive mechanism and having radially adjustable gripper fingers with oppositely facing lift-off devices. Via the gripper it is possible to load a wheel into a clamping fixture, and following unseating of the tire beads from the clamped rim the pneumatic tire can be rotated relative to the rim through a computed angular difference.

An apparatus is configured to receive a tire having at least two bead portions, including a first bead portion and a second bead portion. The apparatus includes a plurality of members configured to engage the first bead portion of the tire, at least one expander configured to move the plurality of members outward, and a rotating device configured to rotate the plurality of members about an axis of the tire.

A slide hammer may be provided. The slide hammer may include: a body defining a through hole and a first attaching surface; an auxiliary weight having a second attaching surface configured to attach to the body at the first attaching surface, the auxiliary weight having a through hole located to align with the through hole in the body when the auxiliary weight is attached to the body; and a shaft located in the through holes in the body and auxiliary weight. A method of constructing a slide hammer is provided.

A roller platform for use in a tire inflation cage includes a frame and at least one roller assembly and facilitates the rotation of a rim-wheel within the tire inflation cage. The roller platform includes a frame having members that are spaced so that the tire stop on a tire inflation cage fits between the frame members. The roller platform includes cross members that are spaced so that the cross members fit between adjacent bars of a tire inflation cage and so a bar fits between the cross members.

A sealing tube is wrapped around the rim and inflated such as to seal the gap between tire and rim if the seal between the tire bead and rim has lost its integrity. After this, the tire can be inflated to specified pressure at a slow rate using a portable compressor. The repair can be done at roadside on any vehicle using inflatable tires usually without demounting the wheel or even jacking up the defective wheel.

A mounting device for mounting or dismounting a vehicle tire on a wheel rim, the wheel rim or the wheel being supported on a mounting table and a pressing-down device being provided for sliding the vehicle tire on the wheel rim. A movement of the pressing-down device is essentially parallel to the wheel axis for sliding the vehicle tire on the wheel rim or pulling off the vehicle tire from the wheel rim.

A device for automatic demounting of a tire from a rim having: a support arm (4); a demounting tool (10) articulated to the support arm (4); an attachment member (12) having one end articulated to the demounting tool (10) by a first articulation pin (13) and the other end thereof pivoted to the support arm (4) around a second articulation pin (14) extending substantially parallel to the first articulation pin (13); at least one extension appendage of the support arm (4) or a section (17) of the support arm (4), which extends beyond the second articulation pin (14); and at least one tie rod member (18) that is articulated on one side to the tool, and on the other side to the extension appendage or section (17) of the support arm (4).

An apparatus and method to seat a tire on a rim are described. Protrusions and a handle on the apparatus allow a user to brace the protrusions against the rim to prevent blow back when air is vented into the gap between the tire and the rim to seat the tire bead. The air is vented through a plurality of holes in the apparatus and the flow of the air into the apparatus is controlled by positioning a bridge handle of a flow control valve situated between the apparatus and a tank of air.

An inflator apparatus for inflating more than one un-inflated tire-wheel assembly is disclosed. The inflator apparatus includes a support structure; an interface portion rotatably-attached to the support structure, wherein the interface portion includes a plurality of inflator heads, wherein each inflator head of the plurality of inflator heads includes a fluid inlet; a plunger portion movably-connected to the support structure, wherein the plunger portion is movably-connected to the support structure to permit selectively coupling of the plunger portion with one inflator head of the plurality of inflator heads; and a fluid conduit connected to the plunger portion, wherein the fluid conduit is fluidly connectable with the fluid inlet of the one inflator head of the plurality of inflator heads. A system for processing more than one un-inflated tire-wheel assembly is also disclosed. A method for utilizing an inflator apparatus for inflating more than one un-inflated tire-wheel assembly is also disclosed.

An apparatus (1) for mounting and removing a tire (2) on and from a respective rim (3) comprises: a movement element (9) for moving a bead (2a) of the tire (2) in order to insert/remove the bead (2a) into/from a respective groove in the rim (3); means (4) for supporting and moving the rim (3), designed to rotationally drive the rim about its longitudinal axis; characterized in that the means (4) for supporting and moving the rim (3) comprise a sensor (252) for measuring the mechanical strain applied to the supporting and movement means (4) as a result of the mechanical stress on the bead (2a) of the tire (2) during mounting/removal of the latter on/from the rim (3).

An apparatus for processing a tire and a wheel for forming a tire wheel assembly is disclosed. The apparatus includes a tire support member including a first tire support member, a second tire support member and a third tire support member. Each of the first, second and third tire support members include an upper surface and a lower surface. The apparatus includes a plurality of tire engaging devices including a first tire tread engaging post and a second tire tread engaging post. A method for processing a tire and a wheel for forming a tire wheel assembly is also disclosed.

A bead breaking unit for tire changing machines includes an arm having a bead breaking tool and associated rotatable with a supporting structure between an away position, wherein the tool is spaced out from the supporting structure, and a work position, wherein the tool is near the supporting structure, an actuator apparatus having a mobile element associated sliding with the arm, a dragging device for dragging the arm, associated with the mobile element and suitable for operating during movement of the mobile element from an extracted position to a retracted position to bring the arm to the work position, a coupling device between the mobile element and the arm, suitable for operating during movement of the mobile element from the retracted to the extracted position to bring the arm from the work position to the away position, and a selection device associated with, and suitable for operating/disconnecting the coupling device.

There is described a machine (1) for regeneration of pneumatic tires (2) comprising a beading device (5) for axial locking of the pneumatic tire to be regenerated in the direction of the revolving axis of the pneumatic tire (2) which provides an untranslatable bead (6) and a translatable bead (7) in said direction, a work rasp (9) mounted on a spindle (25), inflation means (66) of the pneumatic tire and a discharge cochlea (77). Said machine further comprises a roughing miller (8) suitable to prepare the pneumatic tire to a subsequent finishing by means of the rasp (9), said miller (8) being mounted on the same spindle (25) of the rasp (9) and after it, and constituted of a monoblock (27) with discharge channels (28) for chips produced by inserts (29) with a curved profile (30) providing a plurality of planar blades (31) joined by discharge grooves (32) of the chips produced.

A machine for fitting and removing wheel tires for vehicles includes a bearing structure, at least an apparatus for fastening and rotating the rim of a wheel for vehicles, a tool-carrier unit associated mobile with the bearing structure and having a removal tool, at least an adjustment apparatus suitable for adjusting the position of the tool-carrier unit with respect to the bearing structure, to place the tool-carrier unit into a work configuration wherein the removal tool is arranged in proximity of the apparatus for fastening and rotating, at least a memorisation device for memorising the position of the tool-carrier unit in the work configuration and at least a positioning device for positioning the tool-carrier unit with respect to the bearing structure between the work configuration and a configuration of minimum overall dimensions, wherein the tool-carrier unit is arranged in proximity of the bearing structure.

Apparatus including a wheel balancing device and a tire changing device, comprising a spindle shaft for rotatably supporting a vehicle wheel or rim, unbalance measuring means operatively connected to the spindle shaft and having a spatial unbalance measuring area in which unbalance forces of the wheel or rim are detected, tire changer tools for assembling a tire onto a rim, spindle supporting means supporting the spindle shaft in a force acting range in which forces are created between the tire changer tools and the tire during the assembling or disassembling of the tire, tool supporting means supporting the tire changer tools within the force acting range which is arranged outside of the spatial unbalance measuring area, and drive means driving the spindle shaft with a rotational speed and torque adapted for assembling and disassembling the tire or for measuring unbalance forces of the wheel or rim.

The present invention relates to a demounting device comprising a support member translatable along a movement axis (y-y), drive means for the support member, a tool-holder arm (3) borne by the support member (2), an abutment element (4) and a hook-like extraction member (5) both supported by the tool-holder arm (3), the abutment element (4) having a substantially flat work surface (4a), whereas the hook-like extraction member (5) is suitable for being moved in a substantially transverse direction with respect to the rotation axis (x-x) of a rim (W).

The present invention relates to a device for demounting a tire (T) from a rim (W) including at least one support element;an articulation pin element borne by the at least one support element;a spring shackle element having a first end and a second end articulated on the articulation pin;a demounting lever;an actuator borne by the at least one support element and set to act on the demounting lever in order to make the demounting lever angularly move during use; andfriction or elastic loading means designed to slow the angular movement of the spring shackle element around the articulation pin with respect to its angular movement around the first axis (x-x).

An apparatus for seating a bead of a tire adjacent a bead seat of a wheel is disclosed.

An apparatus for processing a tire and a wheel for forming a tire-wheel assembly is disclosed. The apparatus includes at least one linear mounter sub-station that couples the tire with the wheel for forming the tire-wheel assembly. The apparatus also includes a transporting device that transports one of the wheel and the tire along a linear path that traverses the at least one linear mounter sub-station. The component of the at least one linear mounter sub-station resists, but does not prevent, movement of one of the tire and the wheel relative the other of the tire and the wheel along the linear path in order to spatially manipulate one of the tire and the wheel relative the other of the tire and the wheel in order to at least partially couple the tire with the wheel for forming the tire-wheel assembly. A method is also disclosed.

The invention relates to a method for controlling a current fed to an electric motor during an operation to mount a tire on a rim of a wheel including the tire and the rim, or to demount the tire from the rim. The wheel is rotated by an electric motor about an axis, and the motor current fed to the electric motor is controlled dependent on the rotational speed and torque required for the mounting and/or demounting operation. The motor current is automatically changed to cause the electric motor to apply a high torque peak to rotate the wheel, when the motor current is measured to be greater than a preset limit at a low rotational speed during a preset time. Furthermore, the invention relates to an apparatus for mounting a tire on a rim or demounting the tire from the rim.

An apparatus for processing a tire and a wheel for forming a tire wheel assembly is disclosed. The apparatus includes a tire support member including a first tire support member, a second tire support member and a third tire support member. Each of the first, second and third tire support members include an upper surface and a lower surface. The apparatus includes a plurality of tire engaging devices including a first tire tread engaging post and a second tire tread engaging post. A method for processing a tire and a wheel for forming a tire wheel assembly is also disclosed.

A tire changer machine and tire demounting methodology includes a demount tool assembly having a demount tool selectively positionable relative to a support and configured to extract a bead of the tire from the wheel rim. A guide element is mounted to the support, and the guide element is operable to provide a limited degree of freedom of the distal end from a predetermined path of motion in a tire demount procedure, thereby allowing the distal end to reliably grip the tire bead while the support arm is maintained in a stationary position relative to the wheel rim.

Automated tire changer machines, control systems and methods therefor utilize positive contact and contact force generation between wheel rims and bead breaker devices to break tire bead seals. The bead breaker devices may accordingly follow different geometries of wheel rims without prior knowledge or identification of the specific rim configuration by the machine.

An apparatus for processing a tire and a wheel for forming a tire wheel assembly is disclosed. The apparatus includes a tire support member including a first tire support member, a second tire support member and a third tire support member. Each of the first, second and third tire support members include an upper surface and a lower surface. The apparatus includes a plurality of tire engaging devices including a first tire tread engaging post and a second tire tread engaging post. A method for processing a tire and a wheel for forming a tire wheel assembly is also disclosed.

An apparatus for processing a tire and a wheel for forming a tire wheel assembly is disclosed. The apparatus includes a tire support member including a first tire support member, a second tire support member and a third tire support member. Each of the first, second and third tire support members include an upper surface and a lower surface. The apparatus includes a plurality of tire engaging devices including a first tire tread engaging post and a second tire tread engaging post. A method for processing a tire and a wheel for forming a tire wheel assembly is also disclosed.

An apparatus for processing a tire and a wheel for forming a tire wheel assembly is disclosed. The apparatus includes a tire support member including a first tire support member, a second tire support member and a third tire support member. Each of the first, second and third tire support members include an upper surface and a lower surface. The apparatus includes a plurality of tire engaging devices including a first tire tread engaging post and a second tire tread engaging post. A method for processing a tire and a wheel for forming a tire wheel assembly is also disclosed.

The present invention concerns a wheel-clamping device for wheels on wheel-service-machines with only one drive unit and further a method for clamping wheels on a wheel-clamping device of wheel-service-machines with only one drive unit. The innovative wheel-clamping device for a wheel-service-machine according to the present invention comprises a frame 20 having a through-opening 22, and a spindle 30 being rotatably supported in the through-opening 22. Further, the spindle 30 has a through-hole 32 with a mounting-side end 30b and a driving-side end 30a, which is connectable to a drive means which is provided for a rotary movement for the spindle 30, wherein the spindle 30 has an external thread 34 on an external circumferential portion. Moreover, the wheel-clamping device comprises a sleeve 50 with a turntable 58 for the wheel to be clamped, wherein the sleeve 50 has an internal thread portion 52 which is in threaded engagement with the external thread-portion 34 of the spindle 30. Furthermore, a stopping or holding means 70 is able to temporarily hold the sleeve 50, and a clamping means 60 for the temporarily fixation of a fixing element 40 which is inserted through the mounting-side end 30b, to the spindle 30 is also provided in the innovative wheel-clamping device.

An article, system and method related to a magnetomechanical marker used to mark stationary assets. Magnetomechanical markers can be arranged in clusters and associated with stationary assets, including assets buried underground. Markers can be associated with an asset by being attached to the asset, arranged in a particular spatial relationship with the asset, or in any other appropriate way. A portable locating device can be used to generate an alternating magnetic field to activate the magnetomechanical marker and thus locate the asset.

The method for surface inclusions detection, enhancement of endothelial and osteoblast cells adhesion and proliferation and sterilization of electropolished and magnetoelectropolished Nitinol implantable medical device surfaces uses an aqueous solution of chemical compounds containing halogenous oxyanions as hypochlorite (ClO−) and hypobromite (BrO−) preferentially 6% sodium hypochlorite (NaClO).

A high strength, corrosion resistant alloy suitable for use in oil and gas environments includes, in weight %: 0-12% Fe, 18-24% Cr, 3-6.2% Mo, 0.05-3.0% Cu, 4.0-6.5% Nb, 1.1-2.2% Ti, 0.05-0.4% 0.05-0.2% Al, 0.005-0.040% C, balance Ni plus incidental impurities and deoxidizers. A ratio of Nb/(Ti+Al) is equal to 2.5-7.5 to provide a desired volume fraction of γ' and γ″ phases. The alloy has a minimum yield strength of 145 ksi.

A hot-forged copper alloy part which has a tubular shape, in which an alloy composition contains 59.0 mass % to 84.0 mass % of Cu and 0.003 mass % to 0.3 mass % of Pb with a remainder of Zn and inevitable impurities, a content of Cu [Cu] mass % and a content of Pb [Pb] mass % have a relationship of 59≦([Cu]+0.5×[Pb])≦64, a shape of the forged part satisfies a formula of 0.4≦(average inner diameter)/(average outer diameter)≦0.92, 0.04≦(average thickness)/(average outer diameter)≦0.3, and 1≦(tube axis direction length)/(average thickness))≦10, a forging material which is to be hot-forged has a tubular shape and satisfies 0.3≦(average inner diameter/average outer diameter)≦0.88, 0.06≦(average thickness)/(average outer diameter)≦0.35, and 0.8≦(tube axis direction length)/(average thickness))≦12, and 0%≦(degree of uneven thickness)≦30%, 0≦(degree of uneven thickness)≦75×1/((tube axis direction length)/(average thickness))1/2 in any location in a tube axis direction.

The present invention provides ultralow carbon thin gauge steel sheet and a method for producing the same where coalescence and growth of inclusions in the molten steel are prevented and the inclusions are finely dispersed in the steel sheet, whereby surface defects and cracks at the time of press forming are prevented, growth of recrystallized grains at the time of continuous annealing is promoted, and a high r value (r value≧2.0) and elongation (total elongation≧50%) are exhibited, that is, ultralow carbon thin gauge steel sheet excellent in surface conditions, formability, and workability comprised of, by mass %, 0.00030.003%≦C≦0.003%, Si≦0.01%, Mn≦0.1%, P≦0.02%, S≦0.01%, 0.0005%≦N≦0.0025%, 0.01%≦acid soluble Ti≦0.07%, acid soluble Al≦0.003%, and 0.002%≦La+Ce+Nd≦0.02% and a balance of iron and unavoidable impurities, said steel sheet characterized by containing at least cerium oxysulfite, lanthanum oxysulfite, and neodymium oxysulfite.

A high-strength seamless steel pipe for oil wells excellent in sulfide stress cracking resistance which comprises, on the percent by mass basis, C: 0.1 to 0.20%, Si: 0.05 to 1.0%, Mn: 0.05 to 1.0%, Cr: 0.05 to 1.5%, Mo: 0.05 to 1.0%, Al: 0.10% or less, Ti: 0.002 to 0.05% and B: 0.0003 to 0.005%, with a value of equation “C+(Mn/6)+(Cr/5)+(Mo/3)” of 0.43 or more, with the balance being Fe and impurities, and in the impurities P: 0.025% or less, S: 0.010% or less and N: 0.007% or less. The seamless steel pipe may contain a specified amount of one or more element(s) of V and Nb, and/or a specified amount of one or more element(s) of Ca, Mg and REM. The seamless steel pipe can be produced at a low cost by adapting an in-line tube making and heat treatment process having a high production efficiency since a reheating treatment for refinement of grains is not required.

In various embodiments, planar sputtering targets are produced by forming a billet at least by pressing molybdenum powder in a mold and sintering the pressed powder, working the billet to form a worked billet, heat treating the worked billet, working the worked billet to form a final billet, and heat treating the final billet.

A method of forming a wrought material having a refined grain structure is provided. The method comprises providing a metal alloy material having a depressed solidus temperature and a low temperature eutectic phase transformation. The metal alloy material is molded and rapidly solidified to form a fine grain precursor that has fine grains surrounded by a eutectic phase with fine dendritic arm spacing. The fine grain precursor is plastic deformed at a high strain rate to cause recrystallization without substantial shear banding to form a fine grain structural wrought form. The wrought form is then thermally treated to precipitate the eutectic phase into nanometer sized dispersoids within the fine grains and grain boundaries and to define a thermally treated fine grain structure wrought form having grains finer than the fine grains and the fine dendritic arm spacing of the fine grain precursor.

An annealing process for a TMR or GMR sensor having an amorphous free layer is disclosed and employs at least two annealing steps. A first anneal at a temperature T1 of 200° C. to 270° C. and for a t1 of 0.5 to 15 hours is employed to develop the pinning in the AFM and pinned layers. A second anneal at a temperature T2 of 260° C. to 400° C. where T2>T1 and t1>t2 is used to crystallize the amorphous free layer and complete the pinning. An applied magnetic field of about 8000 Oe is used during both anneal steps. The mechanism for forming a sensor with high MR and robust pinning may involve structural change in the tunnel barrier or at an interface between two of the layers in the spin valve stack. A MgO tunnel barrier and a CoFe/CoB free layer are preferred.

A steel for heat treatment, which exhibits high strength and high toughness even when the heat treatment (such as quenching and tempering) of the steel is conducted under conventional conditions in an after stage. The steel for heat treatment contains C: 0.10 to 0.70 mass %, Mn: 0.1 to 3.0 mass %, Al: 0.005 to 2.0 mass %, P: 0.050 mass % or less, S: 0.50 mass % or less, O: 0.0030 mass or less, N: 0.0200 mass % or less, and one or more selected from the group consisting of Ti: 0.30 mass % or less and Nb: 0.30 mass or less with the balance being Fe and unavoidable impurities, and has a TH value of 1.0 or above as calculated according to the formula: ({Ti}/48+{Nb}/93) 104 and grain diameters of 10 μm or below. {Ti} and {Nb} refer respectively to the contents of Ti and Nb in precipitates of 5 to 100 nm in size as determined about their respective extraction residues.

Provided is a NdFeB sintered magnet which can be used in the grain boundary diffusion method as a base material in which RH can be easily diffused through the rare-earth rich phase and which itself has a high coercive force, a high maximum energy product and a high squareness ratio, as well as a method for producing such a magnet. A NdFeB system sintered has an average grain size of the main-phase grains magnet is equal to or smaller than 4.5 μm, the carbon content of the entire NdFeB system sintered magnet is equal to or lower than 1000 ppm, and the percentage of the total volume of a carbon rich phase in a rare-earth rich phase at a grain-boundary triple point in the NdFeB system sintered magnet to the total volume of the rare-earth rich phase is equal to or lower than 50%.