it Coinage metal(I) clusters supported by a 1,10-phenanthroline-phosphine: orange-to-NIR phosphorescence, metallophilic interactions and enhanced cytotoxicity By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18027-18036DOI: 10.1039/D4DT02642J, PaperAlexander V. Artem'ev, Maria P. Davydova, Lyubov S. Klyushova, Evgeniy H. Sadykov, Mariana I. Rakhmanova, Taisiya S. SukhikhBased on 2-(diphenylphosphino)-1,10-phenanthroline, a series of small metal(I) clusters, exhibiting orange to NIR phosphorescence and strong dose-dependent cytotoxicity.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Tunability of triplet excited states and photophysical behaviour of bis-cyclometalated iridium(III) complexes with imidazo[4,5-f][1,10]phenanthroline By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17934-17947DOI: 10.1039/D4DT01996B, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Katarzyna Choroba, Joanna Palion-Gazda, Mateusz Penkala, Patrycja Rawicka, Barbara MachuraThe impact of cyclometalating ligands on the photophysical behaviour of heteroleptic Ir(III) complexes with imidazo[4,5-f][1,10]phenanthroline. [Ir(ppy)2(imphen)]+ is a 3MLLCT emitter, while [Ir(pybzth)2(imphen)]+ has a predominant 3LCN∩C character.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Neutral mononuclear indium(III) photosensitizers for CO2 photoreduction By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17772-17776DOI: 10.1039/D4DT02595D, CommunicationZaichao Zhang, Li-Zhi Fu, Piao He, Xiao-Yi YiNeutral mononuclear indium(III) complexes (In-1–In-3) containing 2,6-di(1H-pyrrol-2-yl)pyridine and substituted dipyridylpyrrole pincer ligands are employed as photosensitizers in photocatalytic CO2 reduction.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Catalytic partial oxidation of methane over oxide-ion-conductive lanthanum silicate apatites By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18021-18026DOI: 10.1039/D4DT02421D, PaperAfif Pamungkas, Yuta Goto, Kazumasa Murata, Saburo Hosokawa, Satoshi Ogawa, Kosaku Ohishi, Tomohiro Matsumoto, Miwa Saito, Teruki MotohashiThe oxide-ion-conductive lanthanum silicate La9.33Si6O26 with an apatite-type structure exhibits high activity for the catalytic partial oxidation of methane (CPOX).The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it An acidity-triggered aggregation nanoplatform based on degradable mesoporous organosilica nanoparticles for precise drug delivery and phototherapy of focal bacterial infection By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17893-17901DOI: 10.1039/D4DT02111H, PaperYunhan Huang, Wei Guo, Xinyu Wang, Jingrui Chang, Bo LuAn acidity-triggered aggregation antibacterial nanoplatform based on biodegradable mesoporous organic silica nanoparticles, is reported. It enables precise drug release and spatial accuracy for photodynamic therapy and photothermal therapy.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Synthesis and relaxivity of gadolinium-based DOTAGA conjugated 3-phosphoglycerate By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17777-17782DOI: 10.1039/D4DT02766C, Communication Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Andrew R. Brotherton, Shifa Noor Mohamed, Thomas J. MeadeA Gd-DOTAGA based MR contrast agent conjugated to 3-phosphoglycerate for enhanced relaxivity and investigation into its metabolism.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it A bioinspired water oxidation catalyst that is ∼1/10th as active as the photosystem II oxygen evolving center at pH 7: a study of activity and stability factors By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17783-17788DOI: 10.1039/D4DT02336F, CommunicationDanijel Boskovic, Richard Terrett, Matthew Longhurst, Sabeel Basheer, Alireza Ariafard, Pawel Wagner, Ronald J. Pace, Rob Stranger, Gerhard F. SwiegersCa-doped birnessite MnOx on liquid crystalline reduced graphene oxide exhibits unprecedented performance for an abiological catalyst at pH 7, including a very low onset overpotential of 0.52 V and high activity per unit area at 0.56 V overpotential.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it The effect of second coordination sphere interactions on the magnetic anisotropy of transition metals By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02873B, PaperSofie S. Leiszner, Mauro Perfetti, Emil Damgaard-Møller, Yu-Sheng Chen, Bo B. IversenBy investigating second coordination sphere effects on the magnetic anisotropy of a Co(II) single molecule magnet (SMM), we aim to clarify their role in magneto-structural correlations to enhance the performance of transition metal SMMs.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Beyond the triple bond: unlocking dinitrogen activation with tailored superbase phosphines By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02703E, PaperVilakkathala U. Krishnapriya, Cherumuttathu H. SureshDinitrogen activation has long been a challenging goal in chemistry. Tailored superbase phosphines offer a promising approach to overcome this challenge by going beyond the traditional triple bond.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Heats of formation on the way from B2H6 to B20H16: thermochemical consequences of multicenter bonding in ab initio and DFT methods By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02589J, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jindřich Fanfrlík, Jan Řezáč, Drahomír Hnyk, Josef HolubThe objective of this study is to evaluate the effectiveness of various computational methods in reproducing the experimental heats of formation of boron hydrides using the atomization energy approach.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Reactions of a geminal Sc/P Lewis pair with pyridotetrazole and beyond By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02838D, PaperYiwen Guan, Xian Xu, Xin XuAn FLP pyridyl nitrene adduct was isolated from the denitrogenative reaction of the Sc/P complex with pyridotetrazole. FLP reactivity of the Sc/P complex with many small molecules were investigated with the generation of metallacyclic complexes.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Synthesis of organo-uranium(II) species in the gas-phase using reactions between [UH]+ and nitriles By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02508C, PaperJustin G. Terhorst, Theodore A. Corcovilos, Samuel J. Lenze, Michael J. van StipdonkA series of gas-phase, σ-bonded [U–R]+ species (R = CH3, C2H3, C2H5, C3H7, or C5H6) can be generated by using preparative tandem mass spectrometry (PTMSn) via ion-molecule reactions between [UH]+ and neutral nitriles.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Cationic first-row transition metal saccharinate complexes with tris(2-pyridylmethyl)amine: synthesis, structures and anticancer studies By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02258K, PaperCeyda Icsel, Seyma Aydinlik, Muhittin Aygun, Veysel T. YilmazHighly cytotoxic dinuclear oxo-bridged Fe(III) saccharinate complex with tris(2-pyridylmethyl)amine induces excessive ROS generation, mitochondrial and DNA damage in HT29 colon cancer cells.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Asymmetric triply bridged lanthanide binuclear clusters with distinctly different magnetic behaviors By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02652G, CommunicationYue Yang, Yu-Xia Wang, Yu-Zhe Lei, Peng ChengIsomorphic binuclear clusters Gd and Dy with antiferromagnetic and ferromagnetic couplings are separately exhibiting single-molecule magnetic behavior and strong magnetocaloric entropy.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Recent Advances in Syntheses and Emerging Applications of 2D Borophene based Nanomaterials with a Focus on Supercapacitors By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02573C, FrontierPrashanta Pal, Mahasweta NandiTwo dimensional (2D) nanosheet of boron i.e. borophene, triggered interest in progressive research as a result of the vast field of opportunities to explore, from its innovative synthetic techniques to...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Detailed mechanism of DNA/RNA nucleobase substituting bridging ligand in diruthenium (II,III) and dirhodium (II,II) tetraacetato paddlewheel complexes: Protonation of the leaving acetate is crucial By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02621G, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Iogann Tolbatov, Tiziano Marzo, Paolo Umari, Diego La Mendola, Alessandro MarronePaddlewheel complexes of bimetallic scaffolds are emerging metallic agents in the bioinorganic chemistry landscape. In the most commonly employed construct, these complexes are decorated by carboxylate moiety, prompting their possible...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Alleviating hypoxia by integrating MnO2 with metal-organic frameworks coated upconversion nanocomposites for enhanced photodynamic therapy in vitro By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02605E, PaperJunxun Zhou, Mengyue Jiang, Qiangqiang Zhang, Yuan Jiang, Haifang Wang, Lining SunPhotodynamic therapy (PDT) requires the participation of abundant oxygen while the hypoxic tumor microenvironment limits the efficacy of PDT. Here, upconversion luminescent nanocomposites coated with metal-organic frameworks (MOFs) were synthesized...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Study of CanUO2(CO3)3(4–2n)– complexes using CE-ICP-MS with polyetheretherketone (PEEK) capillaries By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02781G, PaperRuopei Sun, Erwan Dupuis, Jean Aupiais, Pascal ReillerThe formation constants of CanUO2(CO3)3(4–2n)– complexes have been determined directly using capillary electrophoresis coupled with inductively coupled plasma mass spectrometry (CE-ICP-MS) in 0.1 M NaCl and at room temperature. Instead...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Fourth wave scare: Covid-19 cases in Asia surpass 100 million, India, Japan, South Korea worst-hit By Published On :: Wednesday, March 30, 2022, 13:23 +0530 The highly contagious but less deadly BA.2 sub-variant of Omicron has pushed the figures to greater highs in recent weeks in South Korea, China and Vietnam. Full Article
it Price pooling mantra: Wake up to expensive electricity By www.thehindubusinessline.com Published On :: Tue, 02 Apr 2013 13:15:05 +0530 Full Article Siddhartha P Saikia
it Media invited but not welcomed! By www.thehindubusinessline.com Published On :: Fri, 19 Apr 2013 15:11:49 +0530 Full Article Siddhartha P Saikia
it Virtual reality By www.thehindubusinessline.com Published On :: Wed, 05 Jun 2013 12:22:22 +0530 Full Article S Madhavan
it It's all in the interpretation By www.thehindubusinessline.com Published On :: Sun, 25 Aug 2013 16:22:29 +0530 Full Article S Madhavan
it Writing a requiem to handwriting By www.thehindu.com Published On :: Sun, 11 Aug 2024 00:12:00 +0530 The decline started with the advent of photocopiers and word processors Full Article Open Page
it Off-field cricket ‘rituals’ By www.thehindu.com Published On :: Sun, 11 Aug 2024 01:47:00 +0530 ‘Commentator curse’ and other reigning superstitions that fans have immense belief in Full Article Open Page
it A way with birds By www.thehindu.com Published On :: Sun, 11 Aug 2024 02:47:00 +0530 As the world became deafeningly silent during the lockdown, birdsong was the only solace Full Article Open Page
it Jackfruit tales By www.thehindu.com Published On :: Sun, 11 Aug 2024 03:02:00 +0530 Lovers of the fruit go to any extent to get their fix Full Article Open Page
it Shed certitudes By www.thehindu.com Published On :: Sun, 18 Aug 2024 02:30:00 +0530 Growing older, pre-conceived notions make one more judgmental Full Article Open Page
it It’s time to unwind By www.thehindu.com Published On :: Sun, 25 Aug 2024 02:30:00 +0530 Make the most of the silver years as it is the most relaxing phase of life Full Article Open Page
it Achieving gender parity is still a dream By www.thehindu.com Published On :: Sun, 25 Aug 2024 03:03:00 +0530 Antiquated stereotypes about the roles and responsibilities of women are a pain Full Article Open Page
it The dark side of digital dependence By www.thehindu.com Published On :: Sun, 01 Sep 2024 04:35:00 +0530 The dreaded blue screen can throw life out gear in the most unlikeliest of places Full Article Open Page
it A tussle with white shoes By www.thehindu.com Published On :: Sun, 15 Sep 2024 04:45:00 +0530 Soon after the school reopens, the pair turns brown in the slush and mud Full Article Open Page
it Doctors and handwriting By www.thehindu.com Published On :: Sun, 22 Sep 2024 00:57:00 +0530 A running joke is that a student with sloppy handwriting will probably become a doctor Full Article Open Page
it The City of Literature By www.thehindu.com Published On :: Sun, 29 Sep 2024 04:00:00 +0530 Kozhikode’s history has deep literary roots Full Article Open Page
it The annual ‘whitewash’ By www.thehindu.com Published On :: Sun, 06 Oct 2024 03:13:48 +0530 Not glossing over defects, but making a building stand out Full Article Open Page
it Saying it with an emoji By www.thehindu.com Published On :: Sun, 06 Oct 2024 03:16:59 +0530 The efficient and expressive symbols have led to a decline in the use of formal communication techniques Full Article Open Page
it Freewheeling exploration with a bicycle By www.thehindu.com Published On :: Sun, 06 Oct 2024 03:25:08 +0530 The machine was a precious possession, a symbol of hard work and determination Full Article Open Page
it United by food and festival By www.thehindu.com Published On :: Sun, 13 Oct 2024 01:04:18 +0530 A Bengali raised in Jharkhand with a yen for celebrating Onam Full Article Open Page
it A lie and its deleterious effects By www.thehindu.com Published On :: Sun, 13 Oct 2024 03:23:00 +0530 Lying often results in guilt, anxiety, or the fear of being caught Full Article Open Page
it Learning it the hard way By www.thehindu.com Published On :: Sun, 27 Oct 2024 01:48:00 +0530 How a simple fix was given the go-by and how it led to worries Full Article Open Page
it Rising stars: Sadie Witkowski and Michael Graw By physicsworld.com Published On :: 2017-12-01T09:00:34Z Interview with early-career scientists in psychology and oceanography Full Article
it Enhancing radiotherapy with MRI By physicsworld.com Published On :: 2018-01-25T14:58:04Z Bas Raaymakers describes how MRI can help target tumours with improved accuracy Full Article
it Tracking proton therapy with acoustic waves By physicsworld.com Published On :: 2018-02-01T10:39:31Z Katia Parodi describes an innovative technique for improving ion-beam therapy Full Article
it Karnataka byelection: It is a proxy war between Lad and Reddy in mineral-rich Sandur By www.thehindu.com Published On :: Sun, 10 Nov 2024 08:01:00 +0530 Though Sandur has been the hotbed of mining activities, often hitting the headlines for illegal mining, this issue is barely resonating in the campaign Full Article Karnataka
it Karnataka makes online applications mandatory for private aided school teacher recruitment By www.thehindu.com Published On :: Sun, 10 Nov 2024 18:03:16 +0530 DSEL has developed a separate app to conduct aided schools teachers’ recruitment transparently Full Article Karnataka
it AITUC celebrates 105th Foundation Day in Mysuru By www.thehindu.com Published On :: Sun, 10 Nov 2024 20:34:13 +0530 Full Article Karnataka
it Digital drive soon to encourage passengers to make QR code-based payments for railway tickets By www.thehindu.com Published On :: Sun, 10 Nov 2024 20:41:25 +0530 The drive will entail establishing special ‘May I Help You’ counters manned by railway staff near ticket booking counters Full Article Karnataka
it Tobacco crop hit by rain; farmers complain of poor prices By www.thehindu.com Published On :: Sun, 10 Nov 2024 21:09:10 +0530 Usually, low grade tobacco accounts for about 25 to 30% of the total yield. This year, low grade tobacco is about 10% more than normal Full Article Karnataka
it BJP should sack BSY and Vijayendra from party posts over irregularities in purchases during pandemic, demands Congress By www.thehindu.com Published On :: Sun, 10 Nov 2024 21:11:04 +0530 Full Article Karnataka
it Dalit family assaulted for entering temple in Arakalgud village By www.thehindu.com Published On :: Sun, 10 Nov 2024 21:15:39 +0530 Full Article Karnataka
