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Medicinal plant resin natural products: structural diversity and biological activities

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Nat. Prod. Rep., 2024, 41,1471-1542
DOI: 10.1039/D4NP00007B, Review Article
Madhu Babu Sura, Yong-Xian Cheng
This review explores medicinal plant resin natural products from six genera, encompassing 1115 structures and their biological activities, offering insights into the chemical and biological profiling of plant resins produced under various stress.
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Advances, opportunities, and challenges in methods for interrogating the structure activity relationships of natural products

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Nat. Prod. Rep., 2024, 41,1543-1578
DOI: 10.1039/D4NP00009A, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Christine Mae F. Ancajas, Abiodun S. Oyedele, Caitlin M. Butt, Allison S. Walker
This review highlights methods for studying structure activity relationships of natural products and proposes that these methods are complementary and could be used to build an iterative computational-experimental workflow.
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The dichapetalins and dichapetalin-type compounds: structural diversity, bioactivity, and future research perspectives

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Nat. Prod. Rep., 2024, 41,1579-1603
DOI: 10.1039/D3NP00039G, Review Article
Ivan Addae-Mensah, Godwin Akpeko Dziwornu, Mary Anti Chama, Dorcas Osei-Safo
This review discusses the structural diversity of the dichapetalins and related compounds from the genera Dichapetalum and Phyllanthus, their manifestation in the diversity of their biological activities, and areas of potential future research.
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Estimating the extent of adulteration of the popular herbs black cohosh, echinacea, elder berry, ginkgo, and turmeric – its challenges and limitations

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Nat. Prod. Rep., 2024, 41,1604-1621
DOI: 10.1039/D4NP00014E, Review Article
Open Access
Nilüfer Orhan, Stefan Gafner, Mark Blumenthal
This review article focuses on the challenges and limitations of estimating the prevalence of adulteration in preparations made from black cohosh, echinacea, elder berry, ginkgo, and turmeric.
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Volatile organic compounds (VOCs) in terrestrial extreme environments: implications for life detection beyond Earth

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Nat. Prod. Rep., 2024, Advance Article
DOI: 10.1039/D4NP00037D, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Claire A. Batty, Victoria K. Pearson, Karen Olsson-Francis, Geraint Morgan
This review highlights how discovering and analysing VOCs in extreme environments on Earth can help identify biosignatures and unravel complex patterns in metabolic data that could help identify life on other planetary bodies.
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Synthetic-bioinformatic natural product-inspired peptides

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Nat. Prod. Rep., 2024, Advance Article
DOI: 10.1039/D4NP00043A, Review Article
Open Access
Samantha Nelson, Elizabeth I. Parkinson
Synthetic-bioinformatic natural product inspired peptides (syn-BNPs) are predicted peptides from biosynthetic gene clusters that are synthetically accessed. This method enables easier access to natural product-like peptides for bioactivity screening.
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Siccanin-related drimane meroterpenoids: biological activities and synthesis

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Nat. Prod. Rep., 2024, Advance Article
DOI: 10.1039/D4NP00025K, Review Article
Shengxin Sun, Xia Wang, Nvdan Hu, Shiqi Fu, Shengkun Li
This review describes the isolation, structural characteristics, bioactivities and divergent synthetic strategies of siccanin-related drimane meroterpenoids.
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Highly stable chiral Cr(III)-based metal–organic frameworks for enantioadsorption separation of aromatic alcohols

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Inorg. Chem. Front., 2024, 11,1998-2006
DOI: 10.1039/D4QI00113C, Research Article
Mengna Li, Benlai Wu, Maochun Hong
Highly stable Cr-HMOFs Cr-HMOF-1 and Cr-HMOF-2 were synthesized for the first time directly using enantiomerically pure chiral ligands, showing excellent enantioselective separation performance for aromatic alcohol racemates.
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Efficient catalysis of Knoevenagel condensation by 1D copper-containing heteropolyoxoniobate at room temperature

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Inorg. Chem. Front., 2024, 11,1993-1997
DOI: 10.1039/D4QI00260A, Research Article
Ya-Kun Zuo, Yan-Ru Li, Yan-Qiong Sun, Xin-Xiong Li, Cai Sun, Shou-Tian Zheng
A 1D copper-containing organic–inorganic hybrid heteropolyoxoniobate catalyst for efficient catalysis of Knoevenagel condensation at room temperature.
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Carbon dots induce abundant oxygen vacancies in CeVO4 for promoting photocatalytic selective hydrogenation of functionalized nitroarenes

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Inorg. Chem. Front., 2024, 11,2128-2135
DOI: 10.1039/D4QI00002A, Research Article
Ernan Pang, Shijia Li, Jie Wu, Qing Chang, Ning Li, Jinlong Yang, Shengliang Hu
Carbon dots create the appropriate oxygen vacancies (OVs) in CeVO4 for the chemoselective hydrogenation of functionalized nitroarenes under light irradiation.
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Defect-engineered WSxSe2−x nanocrystals anchored on selenized polyacrylonitrile fibers toward high-performance sodium/potassium-ion batteries with a wide working temperature range

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Inorg. Chem. Front., 2024, 11,2164-2177
DOI: 10.1039/D3QI02640J, Research Article
Fuyu Xiao, Jingran Zhang, Weiming Zhou, Yixing Fang, Xiaotong He, Wenbin Lai, Chuyuan Lin, Mingyang Ge, Haosen Fan, Qingrong Qian, Mingdeng Wei, Qinghua Chen, Lingxing Zeng
WSSe-Se@PAN was fabricated by the electrospinning route combined with selenization treatment. It exhibited a wide working temperature range for SIB/PIB applications.
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Te doped 1T/2H-MoSe2 nanosheets with rich defects as advanced anode materials for high-rate sodium ion half/full batteries

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Inorg. Chem. Front., 2024, 11,2017-2028
DOI: 10.1039/D4QI00259H, Research Article
Zhiqi Li, Jiawen Yan, Qiming Li, Ao Xu, Jianchao Sun, Yijing Wang, Xiaoyu Zhang, Xueqin Sun, Fuyi Jiang, Yanli Zhou
MoSe2 with a two-dimensional layer-like structure has been considered a promising anode material for sodium-ion batteries (SIBs) on account of its high capacity and rich reserves on Earth.
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Gelation-induced controlled synthesis of TiO2 with tunable phase transition for efficient photocatalytic hydrogen evolution

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Inorg. Chem. Front., 2024, 11,2178-2186
DOI: 10.1039/D4QI00193A, Research Article
Wenwei Lei, Ying Wang, Hongji Wang, Norihiro Suzuki, Chiaki Terashima, Akira Fujishima
A facile gelation-assisted coordination self-assembly method for mediated fabrication of TiO2 photocatalysts with controlled phase structures and morphologies is presented, showing excellent photocatalytic hydrogen production performance.
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Electron-deficient Co modulated by the construction of heterojunctions Co@NC boosts the electroreduction of nitrate to ammonia

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Inorg. Chem. Front., 2024, 11,2144-2151
DOI: 10.1039/D4QI00110A, Research Article
Bo Zhang, Fengshou Yu, Yaohua Hong, Yuzhuo Zhou, Yaheng Wang, Shaobo Zhang, Lu-Hua Zhang
Formation of electron-deficient Co by the construction of heterojunctions to promote the electroreduction of nitrate to ammonia.
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Slow magnetization relaxation of a high-spin iron(III) in mayenite Ca12Al14O33

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Inorg. Chem. Front., 2024, 11,2098-2104
DOI: 10.1039/D4QI00480A, Research Article
Timur Z. Sharifullin, Alexander V. Vasiliev, Vladimir D. Dolzhenko, Sebastian Bette, Robert E. Dinnebier, Reinhard K. Kremer, Pavel E. Kazin
High-spin Fe3+ ion imbedded in the extended solid displays field-induced slow relaxation of magnetization with enhanced relaxation time values.
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Structural isomerism-tuned magnetisation relaxation dynamics in lanthanide coordination complexes

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Inorg. Chem. Front., 2024, 11,2116-2127
DOI: 10.1039/D4QI00161C, Research Article
Steen H. Hansen, Christian D. Buch, Stergios Piligkos
Control of the composition of molecular magnetic materials by chemical modification leads to tuning of their magnetization dynamics. We show that two structural isomers display such differences with respect to each other and to their parent complex.
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Combination of dimensional reduction and active site addition strategies for preparing unique {RE9}-cluster-based MOFs: efficient CO2 fixation and Knoevenagel condensation

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Inorg. Chem. Front., 2024, 11,2071-2080
DOI: 10.1039/D3QI02527F, Research Article
Ying Zhao, Dan Wu, Yidan Qiao, Guo-Ping Yang, Lu-Fang Ma, Yao-Yu Wang
A series of 2D {RE9}-cluster-based rare-earth MOFs were built by dimensional reduction and active site addition strategies. They exhibit excellent catalytic activity in CO2 fixation and Knoevenagel condensation under mild conditions.
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Reasonable regulation of flexible sulfur-based bifunctional catalytic electrodes for efficient seawater splitting

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Inorg. Chem. Front., 2024, 11,2152-2163
DOI: 10.1039/D3QI02575F, Research Article
Fengjing Lei, Xunwei Ma, Xinyun Shao, Ziyan Fang, Yuqin Wang, Weiju Hao
An iron-regulated three-dimensional nano-conical, economical, and flexible Fe-NiS@HA electrode exhibiting high intrinsic activity is prepared by gentle one-step electroless plating for efficient, durable hydrogen production in alkaline seawater.
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Correction: In situ construction of a continuous ionic conductive coating for a high-performance Li3VO4 anode

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Inorg. Chem. Front., 2024, 11,2187-2187
DOI: 10.1039/D4QI90020K, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lulu Wang, Cheng Zeng, Jianing Liang, Chun Zhai, Hao Liu, Tianyou Zhai, Huiqiao Li
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Crystal structure, Bi3+ yellow luminescence, and high quantum efficiency of Ba3SbAl3Ge2O14:Bi3+ phosphor for white light-emitting diodes

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00240G, Research Article
Huihui Fei, Baolong Jing, Jin Han, Kaian Shan, Dongming Cheng, Xueqing Xu, Xinmin Zhang, Jing Wang
Bi3+ ions occupy Ba site to form one Bi3+ luminescent center, which is consistent with the trigonal structure of BSAG. This phosphor has a high quantum efficiency of 95.3% and can be used in WLEDs.
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Harnessing nanoscale spatial effects in inner-modified zeolitic imidazolate framework-8 for enhanced Knoevenagel condensation reaction

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D3QI02190D, Research Article
Semi Kim, Seojeong Woo, Cheongwon Bae, Yuri Jeon, Yeeun Seong, Song Li, Juyeong Kim
Precise carving of ZIF nanocrystals generates heterogeneous internal mesoporosity, providing effective mass transport and uncoordinated active sites for enhanced heterogeneous catalysis.
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Synthesis and characterization of a CsPbCl3 perovskite doped with Nd3+: structural, optical, and energy transfer properties

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00171K, Research Article
Mariusz Stefanski, Bartosz Bondzior, Adam Basinski, Maciej Ptak, Bibo Lou, Chong-Geng Ma
The levels of Nd3+ in CsPbCl3 lie below the top of the host's VB. Consequently, Nd3+ luminescence is not observed.
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Sodium ion pre-intercalation regulates the electron density and structural stability of vanadium oxide nanowires for Ca–ion batteries

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00218K, Research Article
Huajie Feng, Yize Wang, Wenda Qiu, Zixi Liu, Yaping Tao, Xihong Lu
Benefiting from the abundant resource, low cost, and high operating potential, calcium–ion batteries (CIBs) have attracted great attention as emerging energy storage devices over lithium-based systems.
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Defect-rich Pd@PdOs nanobelts for electrocatalytic oxidation of ethylene glycol

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00319E, Research Article
Xianlong Wang, Xuewen Wei, Ruifan Zhang, Min Yan, Ranran Wei, Xiaoying Zhang, Zhaoyou Zhu, Yinglong Wang, Xinling Zhao, Shuli Yin
Reasonable design and development of catalysts with specific components and morphologies can effectively improve the catalytic performance of nanomaterials.
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Adhesion, stability, structural and electronic properties of perovskite/BaWO4 heterostructures: first-principles and experimental characterizations

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00231H, Research Article
Yao Guo, Shiding Zhang, Zhaoyu Zhang, Yuanbin Xue, Jianxin Li, Haixiang Song, Yuhua Wang, Qing Shen
The interfacial behavior and mechanism of the CsPbBr3/BaWO4 and MAPbBr3/BaWO4 heterostructures have been extensively investigated by a combined first-principles and experimental analysis.
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Rapid Joule heating synthesis of Ni doped into porous honeycomb C3N4 with greatly improved photocatalytic H2 production

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00225C, Research Article
Zehui Zhao, Guangmin Ren, Zisheng Zhang, Xiangchao Meng, Zizhen Li
Photocatalytic water splitting is one of the sustainable and environmentally-friendly methods for producing hydrogen.
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Recent progress on the photocatalytic hydrogen evolution reaction over a metal sulfide cocatalyst-mediated carbon nitride system

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00255E, Review Article
Xunhuai Huang, Junpeng Song, Guanyu Wu, Zhihuan Miao, Yanhua Song, Zhao Mo
Modification strategy and synthesis method of a metal sulfide-mediated carbon nitride photocatalytic H2 production system.
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Pb3.5GeS4Br3: the first phase-matching thiogermanate halide infrared nonlinear optical material

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00293H, Research Article
Jiazheng Zhou, Hongshan Wang, Junjie Liu, Xin Su, Yu Chu, Jiale Qu, Xiangzhan Jiang
Pb3.5GeS4Br3 is the first phase-matching thiogermanate halide infrared nonlinear optical material.
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Effects of weak intramolecular interactions and distortions from trigonal prismatic coordination on the magnetic properties of zero-field Co(II) single-ion magnets

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D3QI02507A, Research Article
Ben Zhang, Yang Zhou, Hao-Yi Huang, Xiao-Le Zhang, Yi Xiang, Yanbo Shi, Chennan Zhang, Aihua Yuan, Xingwei Cai, Lei Chen, Yi-Quan Zhang, Zhao-Bo Hu
The change of counter anions significantly affects the environment around Co(II) ions, leading to two zero-field single-ion magnets possessing different uniaxial anisotropies and dynamic magnetic properties.
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Facile access to tetra-substituted FeIIFeII biomimetics for the oxidized state active site of [FeFe]-hydrogenases

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00773E, Research Article
Xin-Ping Gao, Shu-Fen Bai, Yan-Lan Wang, Shuang Lü, Qian-Li Li
This study presents a convenient approach to obtain two distinct types of novel tetra-substituted Fe/Se salts through a dehalogenation reaction. The objective is to advance research in mimicking the FeIIFeII oxidation state in [FeFe]-H2ases.
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Modulating Mn self-reduction and multimodal luminescence in CaSb2O6 through La3+ doping for quadruple-mode dynamic anti-counterfeiting and optical temperature sensing applications

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00493K, Research Article
Fenzhong Long, Lu Xie, Jiawei Fu, Kaian Shan, Huihui Fei, Xinmin Zhang
The co-doping La3+strategy was employed to modulate Mn self-reduction and multimodal luminescence in CaS2O6:Mn. CaS2O6:Mn has potential application in optical anti-counterfeiting and high-sensitivity temperature sensing applications.
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NH3 plasma-etching-derived porous N-doped carbon nanotubes with FeP nanoparticles and intrinsic carbon defects for boosting oxygen reduction in rechargeable Zn–air batteries

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00182F, Research Article
Bing Chen, Minjie Zhou, Na Zhang, Xianglin Deng, HaiHua Yang
The formation of intrinsic carbon defects and phase engineered FeP nanoparticles regulated by NH3 plasma etching significantly enhanced the oxygen reduction reaction performance of N-doped carbon nanotubes.
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Synergistic role of hydrogen bonding and band degeneracy leads to enhanced X-ray detection in HPIP-(NH4)0.7Cs0.3Br3·H2O perovskites

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00272E, Research Article
Pengxiang Dong, Chensheng Lin, Xin Zhao, Yicong Lv, Ning Ye, Min Luo
This work shows the innovative introduction of Cs+ into molecular perovskites to co-occupy with NH4+, synthesis of the HPIP-(NH4)0.7Cs0.3Br3·H2O perovskite, and fabrication of an X-ray detector with excellent overall performance and superior environmental stability.
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Rational design for broad near-infrared emission from a two-sited Rb2LiAlF6:Cr3+ phosphor with high efficiency and thermal stability for spectroscopic applications

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00429A, Research Article
Song Qing, Jing Wan, Tao Yang, Qiang Zhou, Yayun Zhou, Zhengliang Wang, Dawei Wen, Mingmei Wu
A comparative investigation of broadband near-infrared luminescence from two different occupation sites in Rb2LiAlF6:Cr3+ with high efficiency and excellent thermal stability.
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Large-scale fabrication of ZIF-derived electrocatalysts for industrial oxygen evolution

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00458B, Research Article
Liangjun Chen, Zhuowen Huangfu, Xuelin Yang, Hang Lei, Zilong Wang, Wenjie Mai
This study presents a methodology that enables the development of efficient and scalable ZIF-derived electrocatalysts for industrial water electrolysis, resulting in significant time and energy savings.
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Controlling the structural and adsorption features of polyoxovanadate-based metal–organic clusters by adjustable template effect

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00254G, Research Article
Yan-Hu Wang, Ke-Wei Tong, Chao-Qin Chen, Jing Du, Guo-Ping Yang, Peng Yang
An adjustable template effect was employed to activate the evolution of polyoxovanadate-based metal–organic clusters, resulting in unprecedented structural archetypes as well as customized dye and iodine adsorption features.
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Discovery of excellent ultraviolet nonlinear optical materials in chlorates and bromates with highly stereochemically active lone pairs

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00462K, Research Article
Chun-Li Hu, Qian-Qian Chen, Fang Kong, Jiang-Gao Mao
The long-neglected stereochemically active lone pair groups ClO3− and BrO3− are demonstrated to be important UV NLO functional motifs based on the fact that AClO3 and ABrO3 possess high SHG effects and short λPM and are promising UV NLO materials.
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The smallest endohedral borafullerene: structural isomerization, electronic properties, aromaticity and reactivity of U@C27B

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00186A, Research Article
Xinde Li, Lei Lou, Peng Jin
U@C27B has three interconvertible isomers with the highest metal oxidation state and strong covalency, obeying the 32-electron principle and Hirsch's aromaticity rule.
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An unusual reaction in nitromethane solution: use of the Cp*Rh moiety to form Prussian blue analogues

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00343H, Research Article
Huirong Ma, Liangchen Liu, Yuluan Liao, Huatian Shi, Po Sun, Weibin Yu
The direct decomposition of nitromethane into nitrile compounds is a significant challenge due to the occurrence of severe side-reactions.
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Near-infrared-photoinduced metamagnet based on a layered cyanido-bridged Co–W assembly with π–π interactions

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00511B, Research Article
Open Access
Kazuki Nakamura, Koji Nakabayashi, Shota Kobayashi, Shin-ichi Ohkoshi
A cyanido-bridged Co–W assembly with π–π interactions showed a thermal phase transition and a photo–induced metamagnetism based on a charge transfer–induced spin transition.
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Integrating multiple regulatory strategies: phase, morphology and interface engineering to construct a hierarchical Ni2P–MoS2/rGO heterostructure catalyst for efficient oxygen reduction reaction

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00262H, Research Article
Xinyi Wang, Jing Jin, Zeyuan Gao, Li Hou, Xiwen Tao, Jing Wang, Yueqi Zhao, Faming Gao
Two-dimensional (2D) molybdenum disulfide (MoS2) with a large surface area and unique electronic properties has emerged as a promising noble metal-free catalyst for electrochemical energy storage/conversion applications.
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Efficient doped and non-doped light-emitting diodes based on a TADF-emitting Cu4Br4 cluster

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00210E, Research Article
Xin Lu, Shao-Jie Wu, Ya-Shu Wang, Shan-Yue Wei, Lingyi Meng, Xi-He Huang, Xu-Lin Chen, Can-Zhong Lu
A sublimable Cu4Br4 cluster, chelated by bidentate N^P ligands with a donor–acceptor configuration, realizes highly efficient doped and non-doped cluster light-emitting diodes.
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Metal– and covalent organic frameworks for photocatalytic CO2 reduction coupled with H2O oxidation

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00304G, Review Article
Xiao-Xiang Zhou, Yongshi Ye, Qia-Chun Lin, Wei-Ming Liao, Jun He
It outlines influencing factors of photocatalytic CO2 reduction coupled with water oxidation, along with catalytic mechanisms and performance enhancement strategies.
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Achieving high-sensitivity dual-mode optical thermometry via phonon-assisted cross-relaxation in a double-perovskite structured up-conversion phosphor

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00395K, Research Article
Houhe Dong, Zonghao Lei, Shikun Su, Wenhua Yang, Xuyang Zhang, Wenying Teng, Guangyue Zu, Bing Teng, Degao Zhong
By adjusting the phonon energy of the host crystal (Ca2+/Sr2+/Ba2+) LaLiTeO6:Yb3+, Tm3+ phosphor, combined with the cross-relaxation phenomenon, a high-sensitivity thermometer for dual-mode temperature measurement was constructed.
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Porphyrin-based MOFs for photocatalysis in water: advancements in solar fuels generation and pollutants degradation

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Inorg. Chem. Front., 2024, 11,2212-2245
DOI: 10.1039/D3QI01996A, Review Article
Open Access
Fangbing Liu, Irene Rincón, Herme G. Baldoví, Amarajothi Dhakshinamoorthy, Patricia Horcajada, Sara Rojas, Sergio Navalón, Alexandra Fateeva
This review highlights the recent advances in the photocatalytic applications of porphyrin-based MOFs in aqueous environments for solar fuel generation and water remediation.
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Carboxylate trapping engineering to fabricate monodispersed dual-atom iron sites for efficient oxygen reduction

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Inorg. Chem. Front., 2024, 11,2260-2271
DOI: 10.1039/D4QI00124A, Research Article
Hailiang Chu, Yilong Wu, Shujun Qiu, Chunfeng Shao, Yongpeng Xia, Yongjin Zou, Baitao Li, Kai Dai, Lixian Sun
Atomically dispersed catalysts with dense accessible Fe–Fe binary active sites supported on hierarchically ordered porous N-doped carbon are prepared via a general carboxylate-assisted strategy and they display drastically enhanced ORR activity.
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Selenium doping induced phase transformation and interlayer expansion boost the zinc storage performance of molybdenum disulfide

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Inorg. Chem. Front., 2024, 11,2272-2280
DOI: 10.1039/D4QI00344F, Research Article
Mengfan Niu, Wenli Xin, Lei Zhang, Min Yang, Yaheng Geng, Xilin Xiao, Hui Zhang, Zhiqiang Zhu
This work synthesized Se-doped MoS2 nanosheets as a cathode for aqueous zinc-ion batteries, and they exhibited largely improved electrochemical performance owing to their high content of the 1T phase (64%) and expanded interlayer spacing (0.65 nm).
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Solvent-modulated assembly of peptide and cerium functionalized gigantic {Mo120Ce6}2 dimers for high-efficiency photocatalytic oxidation

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Inorg. Chem. Front., 2024, 11,2355-2364
DOI: 10.1039/D4QI00339J, Research Article
Dexiang Zhou, Bingbing Li, Qixin Zhao, Xinyu Tang, Tingya Lan, Heyang Su, Guoping Yang, Weimin Xuan
Two gigantic peptide and cerium functionalized {Mo120Ce6}2 dimers have been constructed via a solvent-modulated assembly and applied for effective photocatalytic aerobic oxidation of sulfides to sulfoxides.
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High-efficiency ammonia synthesis via electrochemical nitrate reduction over Co3O4 nanoarrays by B doping

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Inorg. Chem. Front., 2024, 11,2339-2345
DOI: 10.1039/D4QI00310A, Research Article
Zhiqin Deng, Heng Liu, Huiyong Wang, Chaoqun Ma, Juan Du, Baozhan Zheng
B acts as an effective dopant to boost the catalytic activity of Co3O4 for the nitrate reduction reaction towards NH3 synthesis. Such B-Co3O4/TM achieves a high faradaic efficiency of 94.7% and a large NH3 yield rate of 407.3 μmol h−1 cm−2.
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Regulation of polyaniline thickness and substitution position on Cu foams to optimize hydrogen evolution and ethanol oxidation performance

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Inorg. Chem. Front., 2024, 11,2373-2383
DOI: 10.1039/D4QI00085D, Research Article
Haiqiang Mu, Pengyue Shan, Min Zhu, Zhenli Lv, Guorui Ma, Jiaxing Guo, Junzhuo Fang, Jin Zhang, Feng Li, Jing Li
The Cu foam decorated with integrated polyaniline (PANI/CF-210) based on direct electro-grafting technique has been successfully designed to develop for efficient hydrogen evolution and ethanol oxidation reaction.
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