science and technology

Antimony-doped tin oxide as an efficient electrocatalyst toward the VO2+/VO2+ redox couple of the vanadium redox flow battery

Catal. Sci. Technol., 2020, 10,2484-2490
DOI: 10.1039/C9CY01793C, Paper
Yang Lv, Chunmei Yang, Haining Wang, Jin Zhang, Yan Xiang, Shanfu Lu
Enhanced electrocatalytic activity of ATO toward the VO2+/VO2+ redox reaction by adjusting electronic conductivity.
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science and technology

Path of electron transfer created in S-doped NH2-UiO-66 bridged ZnIn2S4/MoS2 nanosheet heterostructure for boosting photocatalytic hydrogen evolution

Catal. Sci. Technol., 2020, 10,2531-2539
DOI: 10.1039/D0CY00127A, Paper
Qi Ran, Zebin Yu, Ronghua Jiang, Lun Qian, Yanping Hou, Fei Yang, Fengyuan Li, Mingjie Li, Qianqian Sun, Heqing Zhang
This work introduces the synthesis of ZnIn2S4/NH2-UiO-66/MoS2 sheet heterostructure photocatalysts and their application to photocatalytic hydrogen evolution.
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science and technology

Hourglass-type polyoxometalate-based crystalline materials as efficient cooperating photocatalysts for the reduction of Cr(VI) and oxidation of dyes

Catal. Sci. Technol., 2020, 10,2593-2601
DOI: 10.1039/D0CY00208A, Paper
Xuerui Tian, Yaqi Zhang, Yuanyuan Ma, Qing Zhao, Zhangang Han
Hourglass-type polyoxometalate-based crystalline materials exhibit efficient photocatalytic activities towards simultaneous photocatalytic Cr(VI) reduction and organic MB oxidation.
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science and technology

Hydroxyl groups attached to Co2+ on the surface of Co3O4: a promising structure for propane catalytic oxidation

Catal. Sci. Technol., 2020, 10,2573-2582
DOI: 10.1039/D0CY00265H, Paper
Kun Chen, Wenzhi Li, Zean Zhou, Qifu Huang, Yang Liu, Qiuyan Duan
Co3O4 catalysts with three specific morphologies (nanocubes, nanosheets, and nanooctahedra) were prepared using simple preparation methods and tested for catalytic combustion of propane under the same reaction conditions.
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science and technology

The direct decomposition of NO into N2 and O2 over copper doped Ba3Y4O9

Catal. Sci. Technol., 2020, 10,2513-2522
DOI: 10.1039/D0CY00194E, Paper
Siman Fang, Atsushi Takagaki, Motonori Watanabe, Tatsumi Ishihara
Both NO decomposition activity and long-term stability increase significantly after the introduction of Cu into Ba3Y4O9.
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science and technology

Trace amounts of Cu(OAc)2 boost the efficiency of cumene oxidation catalyzed by carbon nanotubes washed with HCl

Catal. Sci. Technol., 2020, 10,2523-2530
DOI: 10.1039/C9CY02536G, Paper
Jie Deng, Yuhang Li, Yonghai Cao, Hongjuan Wang, Hao Yu, Qiao Zhang, Jiangliang Zuo, Feng Peng
Trace amounts of Cu(OAc)2 significantly improve the activity and selectivity of cumene oxidation catalyzed by HCl-washed carbon nanotubes.
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science and technology

Mechanism of selective and complete oxidation in La2O3-catalyzed oxidative coupling of methane

Catal. Sci. Technol., 2020, 10,2602-2614
DOI: 10.1039/D0CY00141D, Paper
Shibin Wang, Shenggang Li, David A. Dixon
The catalytic mechanism and reaction network of oxidative coupling of methane over La2O3 are thoroughly investigated by density functional theory calculations.
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science and technology

980 nm NIR light driven overall water splitting over a combined CdS–RGO–NaYF4–Yb3+/Er3+ photocatalyst

Catal. Sci. Technol., 2020, 10,2389-2397
DOI: 10.1039/D0CY00256A, Paper
Wei Gao, Yuqi Wu, Gongxuan Lu
Infrared light (NIR) accounts for more than 50% of the energy donated by the Sun to the Earth, but most of this type of energy is not utilized in photocatalytic reactions.
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science and technology

Single-step benzene hydroxylation by cobalt(II) catalysts via a cobalt(III)-hydroperoxo intermediate

Catal. Sci. Technol., 2020, 10,2540-2548
DOI: 10.1039/C9CY02601K, Paper
Karunanithi Anandababu, Sethuraman Muthuramalingam, Marappan Velusamy, Ramasamy Mayilmurugan
Cobalt(II) complexes reported as efficient and selective catalysts for single-step phenol formation from benzene using H2O2. The catalysis proceeds likely via cobalt(III)-hydroperoxo species.
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science and technology

New findings and current controversies in the reaction of ruthenium red and ammonium cerium(IV) nitrate: focus on the precipitated compound

Catal. Sci. Technol., 2020, 10,2491-2502
DOI: 10.1039/C9CY02499A, Paper
Bahram Sarvi, Seyedeh Maedeh Hosseini, Bahareh Deljoo, Abdelhamid El-Sawy, Alireza Shirazi Amin, Mark Aindow, Steven L. Suib, Mohammad Mahdi Najafpour
During water-oxidation reaction in the presence of RuR and CAN, a heterogeneous nano-sized Ru-Ce compound is detected, which is formed by the interaction of [(NH3)5RuORu(NH3)4ORu(NH3)5],6+/7+ nitrate ions, and the products of the reduction of CAN.
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science and technology

Direct synthesis of hydrogen peroxide without the use of acids or halide promoters in dissolution

Catal. Sci. Technol., 2020, 10,2333-2336
DOI: 10.1039/D0CY00416B, Communication
Open Access
G. Blanco-Brieva, F. Desmedt, P. Miquel, J. M. Campos-Martin, J. L. G. Fierro
We show the first catalyst family able to produce hydrogen peroxide at concentrations higher than 5 wt% in the absence of any promoter or stabilizing agent in dissolution.
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science and technology

Effects of Ni loading on the physicochemical properties of NiOx/CeO2 catalysts and catalytic activity for NO reduction by CO

Catal. Sci. Technol., 2020, 10,2359-2368
DOI: 10.1039/C9CY02619C, Paper
Shuhao Zhang, Jaeha Lee, Do Heui Kim, Taejin Kim
The NO reduction by CO reaction was investigated using NiOx/CeO2 catalysts with different Ni loadings. Surface NiOx controls the catalytic activity which was related to the molecular structure and reducibility of the catalysts.
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science and technology

Alumina grafted SBA-15 sustainable bifunctional catalysts for direct cross-coupling of benzylic alcohols to diarylmethanes

Catal. Sci. Technol., 2020, 10,2583-2592
DOI: 10.1039/D0CY00471E, Paper
Chandran Rajendran, Govindaswamy Satishkumar, Charlotte Lang, Eric M. Gaigneaux
AlSBA-15 catalysts possessing Brønsted acid and Lewis acid–base bifunctionalities catalyze the direct arylation of benzyl alcohols to diarylmethanes with an 85% product yield through C–O bond activation.
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science and technology

Facile sulfolane-modified resins for enhanced dimethoxymethane carbonylation

Catal. Sci. Technol., 2020, 10,2561-2572
DOI: 10.1039/D0CY00201A, Paper
Jie Yao, Lei Shi, Wenjie Deng, Jiaqi Fan, Yan Wang, Weizhe Gao, Dongxi Zhang, Wenliang Zhu, Zhongmin Liu
A simple resin modification method for 50 h DMM carbonylation with a high STY of 3.15 mmolMMAc (gcat h)−1 and 100% MMAc selectivity.
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science and technology

Kinetic study of the methane dry (CO2) reforming reaction over the Ce0.70La0.20Ni0.10O2−δ catalyst

Catal. Sci. Technol., 2020, 10,2652-2662
DOI: 10.1039/C9CY02192B, Paper
Lidia Pino, Cristina Italiano, Massimo Laganà, Antonio Vita, Vincenzo Recupero
The kinetic behaviour of the Ce0.70La0.20Ni0.10O2−δ catalyst during the methane dry reforming reaction was investigated in a fixed bed reactor in the temperature range of 923–1023 K with the partial pressure of CH4 and CO2 ranging between 5 and 50 kPa.
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science and technology

Construction of heterostructure based on hierarchical Bi2MoO6 and g-C3N4 with ease for impressive performance in photoelectrocatalytic water splitting and supercapacitor

Catal. Sci. Technol., 2020, 10,2427-2442
DOI: 10.1039/D0CY00211A, Paper
C. Murugan, M. Karnan, M. Sathish, A. Pandikumar
This work demonstrates the formation of g-C3N4/Bi2MoO6 heterostructure for water splitting and supercapacitor; which shows highest PEC efficiency and symmetric device delivered a energy density and power density of 47 W h kg−1 and 4.5 kW kg−1.
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science and technology

Highly-efficient Ru/Al–SBA-15 catalysts with strong Lewis acid sites for the water-assisted hydrogenation of p-phthalic acid

Catal. Sci. Technol., 2020, 10,2443-2451
DOI: 10.1039/D0CY00047G, Paper
Cong Mao, Jingwei Zheng, Babasaheb M. Matsagar, Ranjith Kumar Kankala, Tansir Ahamad, Yucheng Yang, Kevin C.-W. Wu, Xueqin Zhang
A Ru/Al–SBA-15 catalyst with excess Lewis acid sites displayed excellent efficiency (100%), high cis-isomer selectivity (84%), and exceptional stability towards hydrogenation of p-phthalic acid in water.
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science and technology

Carbon deposits during catalytic combustion of toluene on Pd–Pt-based catalysts

Catal. Sci. Technol., 2020, 10,2452-2461
DOI: 10.1039/D0CY00101E, Paper
Yu Yang, Gang Wang, Peng Zheng, Falu Dang, Jiannian Han
Carbon is easily deposited on a catalyst during the catalytic combustion of toluene, resulting in catalyst deactivation.
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science and technology

Gold-catalyzed domino cyclization enabling construction of diverse fused azaspiro tetracyclic scaffolds: a cascade catalysis mechanism due to a substrate and counterion

Catal. Sci. Technol., 2020, 10,2415-2426
DOI: 10.1039/D0CY00120A, Paper
Yunhe Li, Xiang Zhao
The detailed mechanism and origins of gold-catalyzed domino cyclization to diverse fused azaspiro tetracyclic scaffolds by cooperative dual catalysis and cascade catalysis are systematically studied.
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science and technology

Acetate-catalyzed hydroboration of CO2 for the selective formation of methanol-equivalent products

Catal. Sci. Technol., 2020, 10,2407-2414
DOI: 10.1039/D0CY00118J, Paper
Yuri C. A. Sokolovicz, Olalla Nieto Faza, David Specklin, Béatrice Jacques, Carlos Silva López, João H. Z. dos Santos, Henri S. Schrekker, Samuel Dagorne
The acetate anion is a highly robust and effective catalyst for the selective hydroboration of CO2 to methanol-equivalent products.
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science and technology

Integrated adsorption and photocatalytic degradation of VOCs using a TiO2/diatomite composite: effects of relative humidity and reaction atmosphere

Catal. Sci. Technol., 2020, 10,2378-2388
DOI: 10.1039/D0CY00168F, Paper
Guangxin Zhang, Arman Peyravi, Zaher Hashisho, Zhiming Sun, Yangyu Liu, Shuilin Zheng, Lexuan Zhong
The optimal relative humidity condition for VOC degradation is related to the length of the carbon chain of VOCs.
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science and technology

Enhanced and selective photocatalytic reduction of CO2 by H2O over strategically doped Fe and Cr into porous boron carbon nitride

Catal. Sci. Technol., 2020, 10,2663-2680
DOI: 10.1039/D0CY00343C, Paper
Niwesh Ojha, Abhinav Bajpai, Sushant Kumar
Strategic doping of metals and non-metals into a photocatalyst can help in tuning the band gap and alignment of band structure.
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science and technology

Loop engineering of aryl sulfotransferase B for improving catalytic performance in regioselective sulfation

Catal. Sci. Technol., 2020, 10,2369-2377
DOI: 10.1039/D0CY00063A, Paper
Yu Ji, Shohana Islam, Haiyang Cui, Gaurao V. Dhoke, Mehdi D. Davari, Alan M. Mertens, Ulrich Schwaneberg
Loop engineering of aryl sulfotransferase B improves catalytic performance in regioselective sulfation.
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science and technology

Carbon nanotube-supported Cu-based catalysts for oxidative carbonylation of methanol to methyl carbonate: effect of nanotube pore size

Catal. Sci. Technol., 2020, 10,2615-2626
DOI: 10.1039/C9CY02407G, Paper
Dan Zhao, Guoqiang Zhang, Lifei Yan, Lingqi Kong, Huayan Zheng, Jie Mi, Zhong Li
The inner diameter of CNTs significantly affected the location, dispersion, autoreduction and stability of Cu species and thus the catalytic activity and stability for oxidative carbonylation of methanol to dimethyl carbonate.
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science and technology

Adjustable anchoring of Ni/Co cations by oxygen-containing functional groups on functionalized graphite paper and accelerated mass/electron transfer for overall water splitting

Catal. Sci. Technol., 2020, 10,2627-2643
DOI: 10.1039/D0CY00181C, Paper
Yiyi Huang, Lei Sun, Zebin Yu, Ronghua Jiang, Jun Huang, Yanping Hou, Fei Yang, Boge Zhang, Runzhi Zhang, Yalan Zhang
NCS–NCO/FGP0.44 with a cellular network of porous nanosheets and close-contact heterointerface reveals accelerated interfacial mass/electron transportation for overall water splitting.
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science and technology

Aerobic oxidation of 1,6-hexanediol to adipic acid over Au-based catalysts: the role of basic supports

Catal. Sci. Technol., 2020, 10,2644-2651
DOI: 10.1039/D0CY00183J, Paper
Open Access
Noemi Capece, Achraf Sadier, Camila Palombo Ferraz, Joëlle Thuriot-Roukos, Mariusz Pietrowski, Michał Zieliński, Sébastien Paul, Fabrizio Cavani, Robert Wojcieszak
1,6-Hexanediol is a relevant building blocks that could be obtained from biomass and transformed under base free conditions into adipic acid used for polymer synthesis.
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science and technology

Mechanistic insights into photocatalysis and over two days of stable H2 generation in electrocatalysis by a molecular cobalt catalyst immobilized on TiO2

Catal. Sci. Technol., 2020, 10,2549-2560
DOI: 10.1039/D0CY00330A, Paper
Open Access
Nicola Weder, Benjamin Probst, Laurent Sévery, Ricardo J. Fernández-Terán, Jan Beckord, Olivier Blacque, S. David Tilley, Peter Hamm, Jürg Osterwalder, Roger Alberto
Molecular and heterogeneous water reduction combined: Over 2 days of electrocatalysis of a cobalt polypyridyl catalyst immobilized on TiO2.
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science and technology

Enhanced oxygen evolution catalysis by aluminium-doped cobalt phosphide through in situ surface area increase

Catal. Sci. Technol., 2020, 10,2398-2406
DOI: 10.1039/D0CY00123F, Paper
Timothy E. Rosser, Juliana P. S. Sousa, Yasmine Ziouani, Oleksandr Bondarchuk, Dmitri Y. Petrovykh, Xian-Kui Wei, Jo J. L. Humphrey, Marc Heggen, Yury V. Kolen'ko, Andrew J. Wain
Al-doping of cobalt phosphide oxygen evolution catalysts results in enhanced performance which, based on in situ and operando analysis, is shown to result from a surface area increase associated with modified oxidation behaviour.
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science and technology

Synthesis and molecular structure of model silica-supported tungsten oxide catalysts for oxidative coupling of methane (OCM)

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00289E, Paper
Daniyal Kiani, Sagar Sourav, Israel E. Wachs, Jonas Baltrusaitis
Catalysts with only dispersed phase Na–WO4 sites where Na/W < 2 are slightly less active but significantly more C2 selective than the traditional Na2WO4/SiO2 catalysts that contain a crystalline phase where Na/W = 2.
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science and technology

Enhancing hydrogen evolution reaction through modulating electronic structure of self-supported NiFe LDH

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00315H, Paper
Xiao-Peng Li, Wen-Kai Han, Kang Xiao, Ting Ouyang, Nan Li, Feng Peng, Zhao-Qing Liu
NiFe-layered double hydroxide (NiFe LDH), as an efficient oxygen evolution reaction (OER) electrocatalyst, has emerged as a promising electrocatalyst for catalyzing overall water splitting in alkaline electrolyte.
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science and technology

Outstanding Reviewers for Catalysis Science & Technology in 2019

Catal. Sci. Technol., 2020, 10,2328-2328
DOI: 10.1039/D0CY90032J, Editorial

We would like to take this opportunity to highlight the Outstanding Reviewers for Catalysis Science & Technology in 2019, as selected by the editorial team for their significant contribution to the journal.
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science and technology

Optimized preparation and regeneration of MFI type base catalysts for D-glucose isomerization in water

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00188K, Paper
Margarida M. Antunes, Auguste Fernandes, Diogo Falcão, Martyn Pillinger, Filipa Ribeiro, Anabela A. Valente
Eco-friendly solid bases possessing hierarchical MFI structure for D-glucose isomerization to D-fructose. Optimizing catalyst synthesis and composition for enhanced stability.
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science and technology

Development of BiOI as an effective photocatalyst for oxygen evolution reaction under simulated solar irradiation

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00266F, Paper
Tzu-Hsin Chen, Masaaki Yoshida, Shun Tsunekawa, Jia-Hao Wu, Kun-Yi Andrew Lin, Chechia Hu
In this study, crystalline BiOI powders were prepared for photocatalytic O2 evolution in the presence of NaIO3 as the electron mediator.
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science and technology

Mechanistic insights into the oxidation of copper(I) species during NH3–SCR over Cu-CHA zeolites: A DFT study

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00379D, Paper
Chong Liu, Hiroe Kubota, Takashi Toyao, Zen Maeno, Ken-ichi Shimizu
Selective catalytic reduction of nitrogen oxides using ammonia (NH3–SCR) over Cu-exchanged zeolites proceeds via reduction of Cu(II) to Cu(I) and subsequent reoxidation of Cu(I) to Cu(II). Although the mechanism of...
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science and technology

Selenium-catalyzed oxidation of alkenes: insight into the mechanisms and developing trend

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00400F, Perspective
Hongen Cao, Rongrong Qian, Lei Yu
Recent progresses of the selenium-catalyzed oxidation of alkenes are summarized at the mechanism level. It may be beneficial for designing novel selenium-containing catalysts and alkene oxidation protocols for the next phase of studies.
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science and technology

An in situ grown lanthanum sulfide/molybdenum sulfide hybrid catalyst for electrochemical hydrogen evolution

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00425A, Paper
Xinran Ding, Tao Yang, Wenxian Wei, Yihui Wang, Kai Xu, Zizheng Zhu, Hong Zhao, Tingting Yu, Dongen Zhang
An La2S3–MoS2 catalyst with expanded interlayer spacing and engineered nano-interfaces was facilely synthesized, demonstrating enhanced catalytic activity for electrochemical hydrogen evolution.
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science and technology

Carbon nanotube/PTFE as a hybrid platform for lipase B from Candida antarctica in transformation of α-angelica lactone into alkyl levulinates

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00545B, Paper
Anna Szelwicka, Anna Kolanowska, Piotr Latos, Sebastian Jurczyk, Slawomir Boncel, Anna Chrobok
A highly active biocatalyst based on a hybrid platform was designed for the conversion of α-angelica lactone to alkyl levulinates.
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science and technology

Origin of CO2 as the main carbon source in syngas-to-methanol process over Cu: theoretical evidence from a combined DFT and microkinetic modeling study

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00602E, Paper
Dongyang Xu, Panpan Wu, Bo Yang
A theoretical study combining DFT and microkinetic modeling provides evidence that CO2 is the main carbon source in methanol synthesis from syngas (CO, CO2 and H2) over Cu.
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science and technology

Heterogeneous iron-containing nanocatalysts – promising systems for selective hydrogenation and hydrogenolysis

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00086H, Minireview
Anastasiya A. Shesterkina, Leonid M. Kustov, Anna A. Strekalova, Vladimir B. Kazansky
Bimetallic catalytic systems Fe–Me (Pt, Pd, Cu) demonstrate synergy in the activity/selectivity pattern in reactions involving hydrogen: selective hydrogenation of CC bonds, NO2 and carbonyl groups and hydrogenolysis of C–O bonds.
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science and technology

MOFs based on 1D structural sub-domains with Brønsted acid and redox active sites as effective bi-functional catalysts

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00235F, Paper
José María Moreno, Alexandra Velty, Urbano Díaz
Low-dimensional MOF-type catalysts containing Brønsted acid and redox active sites, based on assembled 1D organic–inorganic nanoribbons, for one-pot two-step reactions.
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science and technology

Bimetallic scorpionate-based helical organoaluminum complexes for efficient carbon dioxide fixation into a variety of cyclic carbonates

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00593B, Paper
Marta Navarro, Luis F. Sánchez-Barba, Andrés Garcés, Juan Fernández-Baeza, Israel Fernández, Agustín Lara-Sánchez, Ana M. Rodríguez
The binuclear aluminum complexes [AlR22-NN';κ2-NN')AlR2] with TBAB/PPNCl behave as excellent systems for cyclic carbonate formation from CO2 with challenging epoxides.
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science and technology

Insights into isothiourea-catalyzed asymmetric [3 + 3] annulation of α,β-unsaturated aryl esters with 2-acylbenzazoles:Mechani-sm, origin of stereoselectivity and switchable chemoselectivity

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00295J, Paper
Congcong Wang, Shi-Jun Li, Qiao-Chu Zhang, Donghui Wei, Lina Ding
Recently, isothiourea-catalyzed asymmetric [3 + 3] annulation reactions of α,β-unsaturated aryl esters with 2-acylbenzothiazole (or 2-acylbenzoxazole) were reported with switchable chemoselectivity to form either dihydropyridone or dihydropyrone, but predicting the...
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science and technology

Regulation of rutile/anatase TiO2 heterophase interface by Ni12P5 to improve photocatalytic hydrogen evolution

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00634C, Paper
Qiu Chengwei, Jinjin Lin, Jinni Shen, Dan Liu, Zizhong Zhang, Huaxiang Lin, Xuxu wang
Anatase/rutile TiO2 heterophase junction composite has been documented to have much higher photocatalytic activity than single phase TiO2 (nude anatase or nude rutile) for various chemical reactions including the hydrogen...
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science and technology

Photocatalytic hydrogen evolution over nickel cobalt bimetallic phosphate anchored graphitic carbon nitrides by regulation of d-band electronic structure

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00556H, Paper
Yuanzheng Zhang, Yunrong Dai, Lifeng Yin, Huihui Li, Xiang Chen, Bin Chen
Non-precious metal co-catalysts with high activity and stability are extremely desirable for economically viable photocatalytic molecular hydrogen (H2) evolution. Herein, nickel cobalt phosphate (NiCo-Pi) was introduced into graphitic carbon nitride...
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science and technology

Two-way desorption coupling to enhance the conversion of syngas into aromatics by MnO/H-ZSM-5

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00275E, Paper
Syed Zulfiqar Ali Gilani, Le Lu, Muhammad Tahir Arslan, Babar Ali, Qi Wang, Fei Wei
We herein report a composite catalyst containing partially reducible and highly active manganese oxide and nano-size H-ZSM-5 with short b-axis, prepared for the direct conversion of syngas into aromatics.
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science and technology

Pt-Ligand single-atom catalysts: tuning activity by oxide support defect density

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/C9CY02594D, Paper
Xuemei Zhou, Linxiao Chen, George E. Sterbinsky, Debangshu Mukherjee, Raymond R. Unocic, Steven L. Tait
Metal–ligand coordination stabilizes single atom Pt on pristine and defective TiO2 supports to impact local coordination and catalytic hydrosilylation activity.
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science and technology

Surface reconstruction and effect of Ni-modification in the selective hydrogenation of 1,3-butadiene over Mo2C-based catalysts

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00402B, Paper
Qiuchen Yang, Rui Qiu, Xixi Ma, Ruijun Hou, Kening Sun
In the current study, Mo2C, NiMo2C, H-Mo2C and H-NiMo2C were synthesized to understand the effects of Ni modification and synthesis route. The catalysts were characterized by XRD, N2-physisorption, SEM, TEM,...
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science and technology

Ru nanoparticles supported on amorphous ZrO2 for CO2 methanation

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00233J, Paper
Hironori Nagase, Rei Naito, Shohei Tada, Ryuji Kikuchi, Kakeru Fujiwara, Masahiko Nishijima, Tetsuo Honma
The influence of support materials and preparation methods on CO2 methanation activity was investigated using Ru nanoparticles supported on amorphous ZrO2 (am-ZrO2), crystalline ZrO2 (cr-ZrO2), and SiO2. Among them, Ru/am-ZrO2...
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science and technology

Facile synthesis of oxygen-deficient nano-TiO2 coordinated by acetate ligands for enhanced visible-light photocatalytic performance

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00592D, Paper
Shaohua Pang, Yunfei Lu, Lin Cheng, Juming Liu, Huiyan Ma, Jucai Yang, Qiancheng Zhang
To date, various methods have been adopted to enhance the visible-light photocatalytic activity of nano-TiO2. However, a more facile and moderate method is still highly desirable. In this work, a...
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science and technology

Importance of the decoration in shaped cobalt nanoparticles in the acceptor-less secondary alcohol dehydrogenation

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00390E, Paper
Kamila Kaźmierczak, Raj Kumar Ramamoorthy, Arthur Moisset, Guillaume Viau, Arnaud Viola, Marion Giraud, Jennifer Peron, Lorette Sicard, Jean-Yves Piquemal, Michèle Besson, Noémie Perret, Carine Michel
Ligands matter for shaped decorated Co nanoparticles, at the frontier between homogeneous and heterogeneous catalysis.
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