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Thermally resistant optical siloxane resin composition

The present disclosure relates to a thermally resistant optical siloxane resin composition including siloxane containing photo-cationically polymerizable epoxy group, a photo initiator, and an antioxidant.




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Ultra fast process for the preparation of polymer nanoparticles

A process for the preparation of polymer lattices comprising polymer nanoparticles by a photo-initiated heterophase polymerization includes preparing a heterophase medium comprising a dispersed phase and a continuous phase and at least one of at least one surfactant, at least one photoinitiator, and at least one polymerizable monomer. The at least one polymerizable monomer is polymerized by irradiating the heterophase medium with electromagnetic radiation so as to induce a generation of radicals. The at least one photoinitiator is selected from compounds comprising at least one phosphorous oxide group (P═O) or at least one phosphorous sulfide (P═S) group. The irradiating of the heterophase medium is effected so that a ratio of an irradiated surface of the heterophase medium to a volume of the heterophase medium is at least 200 m−1.




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Radiation curable temporary laminating adhesive for use in high temperature applications

A radiation curable temporary laminating adhesive composition for use in temperature applications at 150° C. or greater, and typically at 200° C. or greater, comprises (A) a hydrogenated polybutadiene diacrylate; (B) a radical photoinitiator; and (C) a diluent.




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Process for the modification of polymers, in particular polymer nanoparticles

A process for the preparation of modified polymers by a photo-initiated polymerization includes preparing a polymerization medium comprising at least one photoinitiator comprising at least one phosphorous oxide (P═O) group or at least one phosphorous sulfide (P═S) group, and at least one polymerizable monomer. The at least one polymerizable monomer is polymerized by irradiating the polymerization medium with electromagnetic radiation so as to induce a generation of radicals so as to obtain a polymer. The polymer is modified by irradiating the polymer with electromagnetic radiation so as to induce a generation of radicals from the polymer in a presence of at least one modifying agent.




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Silicone hydrogels having a structure formed via controlled reaction kinetics

The present invention relates to a process comprising the steps of reacting a reactive mixture comprising at least one silicone-containing component, at least one hydrophilic component, and at least one diluent to form an ophthalmic device having an advancing contact angle of less than about 80°; and contacting the ophthalmic device with an aqueous extraction solution at an elevated extraction temperature, wherein said at least one diluent has a boiling point at least about 10° higher than said extraction temperature.




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Processes for manufacturing electret fine particles or coarse powder

The present invention provides a process for producing electret fine particles or coarse powder that can be uniformly electrified and exhibits excellent electrophoretic properties. Specifically, the present invention relates to the production processes (1) and (2) below:(1) A process for producing electret fine particles, comprising emulsifying a fluorine-containing material that contains a vinylidene fluoride-hexafluoropropylene-tetrafluoroethylene terpolymer in a liquid that is incompatible with the fluorine-containing material to obtain emulsified particles; and subjecting the emulsified particles to electron ray irradiation, radial ray irradiation, or corona discharge treatment.(2) A process for producing electret coarse powder, comprising subjecting a resin sheet containing a vinylidene fluoride-hexafluoropropylene-tetrafluoroethylene terpolymer to electron ray irradiation, radial ray irradiation, or corona discharge treatment to process the resin sheet into an electret resin sheet; and pulverizing the electret resin sheet.




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Optical component, electronic board, method for producing the optical component, and method for producing the electronic board

An optical component and an electrical board that have a low coefficient of linear expansion and small mold shrinkage, a method for producing the optical component, and a method for producing the electronic board are provided. An optical component includes a polymer having a repeating structural unit represented by general formula (1) where R1 and R2 each independently represent —H or —CH3; m and n each independently represent an integer in the range of 0 to 3; asterisk denotes a dangling bond that bonds to one of Xa and Xb; and —H bonds to the other one of Xa and Xb.




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Silicone rubber composition, silicone rubber molded article, and production method thereof

A UV curable silicone rubber composition is provided. The composition does not undergo curing failure, foaming, and other undesirable conditions even if a water-containing inorganic filler such as zeolite were added. A UV curable silicone rubber composition comprising (A) 100 parts by weight of an organopolysiloxane having at least 2 alkenyl groups per molecule represented by the average compositional formula (I): R1aSiO(4-a)/2 (I) (wherein R1 is independently a substituted or unsubstituted monovalent hydrocarbon group, and a is a positive number of 1.95 to 2.05); (B) 1 to 300 parts by weight of an inorganic filler having a water content of at least 0.5% by weight; (C) 0.1 to 50 parts by weight of an organohydrogenpolysiloxane having at least 2 silicon-bonded hydrogen atoms per molecule; and (D) a catalytic amount of a photoactive platinum complex curing catalyst.




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Semi-cured product, cured product and method of manufacturing these, optical component, curable resin composition

A heat-resistant cured product is efficiently produced by obtaining a semi-cured product where a curable resin composition containing a (meth)acrylate monomer, a non-conjugated vinylidene group-containing compound and a thermal radical-polymerization initiator is processed by at least one of photoirradiation and heating to give a semi-cured product having a complex viscosity of from 105 to 108 mPa·s at 25° C. and at a frequency of 10 Hz; and putting the semi-cured product in a forming die for pressure formation therein, and heating it therein for thermal polymerization to give a cured product.




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Surface modification method and surface-modified elastic body

The present invention aims to provide a surface modification method for a rubber vulcanizate or a thermoplastic elastomer, which can impart excellent sliding properties and excellent durability against repeated sliding motion and can allow the surface to maintain the sealing properties, without using expensive self-lubricating plastics. The present invention relates to a surface modification method for modifying a rubber vulcanizate or a thermoplastic elastomer as an object to be modified, the method including: step 1 of forming polymerization initiation points on the object to be modified; step 2 of radically polymerizing a monomer, starting from the polymerization initiation points, by irradiation with LED light at 300 nm to 400 nm to grow polymer chains on a surface of the object to be modified; and step 3 of esterifying, transesterifying or amidating side chains of the polymer chains.




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Electronic device and method for displaying resources

An electronic device, including: one or more hardware interfaces each for connecting to a signal source to receive at least one type of application resources; a control chip electrically connected to the one or more hardware interfaces, the control chip being configured to classify and integrate one or more types of application resources received through the one or more hardware interfaces, and generate a display signal for a main interface including a number of areas arranged according to a predetermined layout, wherein each area is configured to display information regarding a same type of the classified and integrated application resources, and different areas are configured to display information regarding different types of the classified and integrated application resources; and a display screen electrically connected to the control chip to display the main interface according to the display signal.




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Method and apparatus for obtaining equipment identification information

Embodiments of the present invention relate to a method and an apparatus for obtaining equipment identification information, where the method includes: detecting, by using a first GPIO port, a first discharging duration for a capacitor to discharge through a resistor to be tested; detecting, by using a second GPIO port, a second discharging duration for the capacitor to discharge through a fixed value resistor; and obtaining a resistance of the resistor to be tested according to the first discharging duration, the second discharging duration, and a resistance of the fixed value resistor. The embodiments of the present invention are capable of increasing identification efficiency of the GPIO port.




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Automatic pinning and unpinning of virtual pages for remote direct memory access

In one exemplary embodiment, a computer-implemented method includes receiving, at a remote direct memory access (RDMA) device, a plurality of RDMA requests referencing a plurality of virtual pages. Data transfers are scheduled for the plurality of virtual pages, wherein the scheduling occurs at the RDMA device. The number of the virtual pages that are currently pinned is limited for the RDMA requests based on a predetermined pinned page limit.




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System and method for generating a virtual PCI-type configuration space for a device

An electronic data tablet has a controller and transition manager. The controller is to store in a memory of the tablet virtual configuration space information for a peripheral device of a computer, and the transition manager is to control the controller to operate in a first mode and a second mode. The virtual configuration space information is stored in the tablet memory when the first mode is to be switched to the second mode. When the second mode is switched to the first mode, the virtual configuration space information is accessed to control recognition of the peripheral device of the computer without performing a re-scanning operation.




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Portable computing device as control mechanism

A portable or mobile computing device, such as a smart phone or portable media player, can be used to control one or more electronic devices over an appropriate wireless channel. In one example, a user can utilize a smart phone as a mouse for a notebook computer or Internet-capable television. The user can move the portable device on a surface and press appropriate selectable elements on the portable device, as if the user is using a wireless mouse. The portable device can send the commands over the wireless channel to the electronic device, which can provide inputs and/or control signals to the electronic device. In some embodiments, the user can take advantage of the processing capability of the portable device to work directly with elements such as a wireless keyboard and wireless monitor, without the need for a notebook or other such computing element therebetween.




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System and method of interacting with data at a wireless communication device

A method of interacting with data at a wireless communication device is provided. The wireless communication device has access to a first set of capabilities. Data is received at the wireless communication device via a wireless transmission. The data represents visual content that is viewable via a display device. A graphical user interface, including a delayed action selector, is provided via the display device. An input is received within a limited period of time after displaying the delayed action selector. The input is associated with a command to delay execution of an action with respect to the data until the wireless communication device has access to a second set of capabilities. The action is not supported by the first set of capabilities but is supported by the second set of capabilities. An indication of receipt of the input is provided at the wireless communication device.




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Semiconductor memory device and operation method thereof

A semiconductor memory device includes a selection signal generation unit configured to generate a plurality of selection signals that are sequentially activated, a path selection unit configured to select a transmission path of sequentially input information data in response to the plurality of selection signals, a plurality of first storage units, each configured to have a first storage completion time and store an output signal of the path selection unit, and a plurality of second storage units, each configured to have a second storage completion time, which is longer than the first storage completion time, and store a respective output signal of the plurality of first storage units.




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Data transfer device and method

A transfer control circuit stores data in a FIFO memory, outputs data in the FIFO memory in response to a data request signal, and outputs a state signal in accordance with an amount of stored data in the FIFO memory. An output data generating unit outputs image data having a horizontal image size in accordance with a horizontal count value and a horizontal synchronizing signal, and thereafter, outputs blank data. When the state signal indicates that the FIFO memory is in a “EMPTY” or “MODERATE” storage state, a blank control unit outputs a blank addition signal until the FIFO memory changes to a “FULL” storage state.




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Data storage device and operating method thereof

A data storage device includes a first memory device configured to store data having a first property, a second memory device configured to store data having a second property, and a controller. The controller selects data stored in the first memory device, and transfers the selected data to the second memory device or stores the selected data in another physical location of the first memory device selectively depending on an update count (UC) of an address at which the selected data is stored.




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Interrupt control method and multicore processor system

In an interrupt control method of a multicore processor system including cores, a cache coherency mechanism, and a device, a first core detecting an interrupt signal from the device writes into an area prescribing an interrupt flag in the cache memory of the first core, first data indicating detection of the interrupt signal, and notifies the other cores of an execution request for interrupt processing corresponding to the interrupt signal, consequent to the cache coherency mechanism establishing coherency among at least cache memories of the other cores when the first data is written; and a second core different from the first core, maintaining the first data written as the interrupt flag, and notified of the execution request executes the interrupt processing, and writes over the area prescribing the interrupt flag written in the cache memory of the second core, with second data indicating no-detection of the interrupt signal.




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Technique for communicating interrupts in a computer system

A technique to enable efficient interrupt communication within a computer system. In one embodiment, an advanced programmable interrupt controller (APIC) is interfaced via a set of bits within an APIC interface register using various interface instructions or operations, without using memory-mapped input/output (MMIO).




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Dongle device with video encoding and methods for use therewith

A universal serial bus (USB) dongle device includes a USB interface that receives selection data from a host device that indicates a selection of a first video format from a plurality of available formats. The USB interface also receives an input video signal from the host device in the first video format and a power signal from the host device. An encoding module generates a processed video signal in a second video format based on the input video signal, wherein the first video format differs from the second video format. The USB interface transfers the processed video signal to the host device.




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Bridge between a peripheral component interconnect express interface and a universal serial bus 3.0 device

A bridge includes a Peripheral Component Interconnect Express interface supporting at least two lanes, an Extensible Host Controller Interface, and a Universal Serial Bus 3.0 root hub. The Peripheral Component Interconnect Express interface is used for coupling to a host. Each lane of the at least two lanes provides a highest data transmission speed. The Extensible Host Controller Interface is coupled to the Peripheral Component Interconnect Express interface for storing data transmitted by the Peripheral Component Interconnect Express interface. The Universal Serial Bus 3.0 root hub includes a first controller and a second controller. The first controller and the second controller are used for controlling data transmission of four ports, and a highest data transmission speed provided by each port of the four ports is not more than the highest data transmission speed provided by the lane.




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System and method for detecting accidental peripheral device disconnection

A detection device for detecting the manner in which a peripheral device is removed from an electronic device is proposed. The detection device can be on the peripheral device or the electronic device and detects whether the peripheral device was removed in a manner that indicates the removal was intentional or unintentional.




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Apparatuses enabling concurrent communication between an interface die and a plurality of dice stacks, interleaved conductive paths in stacked devices, and methods for forming and operating the same

Various embodiments include apparatuses, stacked devices and methods of forming dice stacks on an interface die. In one such apparatus, a dice stack includes at least a first die and a second die, and conductive paths coupling the first die and the second die to the common control die. In some embodiments, the conductive paths may be arranged to connect with circuitry on alternating dice of the stack. In other embodiments, a plurality of dice stacks may be arranged on a single interface die, and some or all of the dice may have interleaving conductive paths.




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Electronic devices and methods for sharing peripheral devices in dual operating systems

A method for sharing peripheral devices in dual operating systems for an electronic device having at least one peripheral device is provided. The method includes: receiving a setting value for the peripheral device under the first operating system from a user; activating a second operating system; transmitting the setting value to the second operating system; and switching from the first operating system to the second operating system, wherein the second operating system sets the peripheral device with the setting value and enables the electronic device to operate under the second operating system.




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Determination of physical connectivity status of devices based on electrical measurement

Embodiments of the invention are generally directed to determination of physical connectivity status of devices based on electrical measurement. An embodiment of a method includes discovering a connection of a first device with a second device, and performing an electrical measurement of the second device by the first device via the connection between the first device and the second device, where performing the electrical measurement includes sensing by the first device of an element of the second device. The method further includes, if the sensing by the first device fails to detect the element of the second device and a predetermined condition for the electrical measurement is enabled, then determining by the first device that the connection with the second device has been lost.




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Virtual machine provisioning based on tagged physical resources in a cloud computing environment

A cloud system may create physical resource tags to store relationships between cloud computing offerings, such as computing service offerings, storage offerings, and network offerings, and the specific physical resources in the cloud computing environment. Cloud computing offerings may be presented to cloud customers, the offerings corresponding to various combinations of computing services, storage, networking, and other hardware or software resources. After a customer selects one or more cloud computing offerings, a cloud resource manager or other component within the cloud infrastructure may retrieve a set of tags and determine a set of physical hardware resources associated with the selected offerings. The physical hardware resources associated with the selected offerings may be subsequently used to provision and create the new virtual machine and its operating environment.




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Managing utilization of physical processors of a shared processor pool in a virtualized processor environment

Systems, methods and computer program products may provide managing utilization of one or more physical processors in a shared processor pool. A method of managing utilization of one or more physical processors in a shared processor pool may include determining a current amount of utilization of the one or more physical processors and generating an instruction message. The instruction message may be at least partially determined by the current amount of utilization. The method may further include sending the instruction message to a guest operating system, the guest operating system having a number of enabled virtual processors.




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System and method for automated assignment of virtual machines and physical machines to hosts

A system and method for reconfiguring a computing environment comprising a consumption analysis server, a placement server, an infrastructure management client and a data warehouse in communication with a set of data collection agents and a database. The consumption analysis server operates on measured resource utilization data to yield a set of resource consumptions in regularized time blocks, collects host and virtual machine configurations from the computing environment and determines available capacity for a set of target hosts. The placement server assigns a set of target virtual machines to the target set of hosts in a new placement. In one mode of operation the new placement is nearly optimal. In another mode of operation, the new placement is “good enough” to achieve a threshold score based on an objective function of resource capacity headroom. The new placement is implemented in the computing environment.




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Managing safe removal of a passthrough device in a virtualization system

Methods and systems for managing a removal of a passthrough device from a guest managed by a hypervisor in virtualized computing environment. A hypervisor receives a request from the guest for access to a passthrough device. The hypervisor sets, in a memory, a last accessed state associated with a virtual machine executing the guest. The hypervisor forwards the request to the passthrough device and configures the host CPU to send a subsequent access request directly to the passthrough device. In response to a virtual machine reset, the hypervisor clears the last accessed state and instructs the host CPU to send a post-reset access request to the hypervisor.




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Virtualization and dynamic resource allocation aware storage level reordering

A system and method for reordering storage levels in a virtualized environment includes identifying a virtual machine (VM) to be transitioned and determining a new storage level order for the VM. The new storage level order reduces a VM live state during a transition, and accounts for hierarchical shared storage memory and criteria imposed by an application to reduce recovery operations after dynamic resource allocation actions. The new storage level order recommendation is propagated to VMs. The new storage level order applied in the VMs. A different storage-level order is recommended after the transition.




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Method and system for providing storage services

Method and system are provided for managing components of a storage operating environment having a plurality of virtual machines that can access a storage device managed by a storage system. The virtual machines are executed by a host platform that also executes a processor-executable host services module that interfaces with at least a processor-executable plug-in module for providing information regarding the virtual machines and assists in storage related services, for example, replicating the virtual machines.




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Verification of controls in information technology infrastructure via obligation assertion

A processing device comprises a processor coupled to a memory and implements an obligation management system for information technology infrastructure, with the obligation management system being configured to process a plurality of obligations on behalf of a relying party to verify implementation of corresponding controls in information technology infrastructure of a claimant. A given one of the obligations has an associated obligation fulfiller that is inserted or otherwise deployed as a component within the information technology infrastructure of the claimant and is configured to provide evidence of the implementation of one or more of the controls responsive to an obligation assertion so as to establish an associated trust aspect of the claimant. The information technology infrastructure may comprise distributed virtual infrastructure of a cloud service provider. The claimant may comprise the cloud service provider and the relying party may comprise a tenant of the cloud service provider.




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Apparatus and methods for adaptive thread scheduling on asymmetric multiprocessor

Techniques for adaptive thread scheduling on a plurality of cores for reducing system energy are described. In one embodiment, a thread scheduler receives leakage current information associated with the plurality of cores. The leakage current information is employed to schedule a thread on one of the plurality of cores to reduce system energy usage. On chip calibration of the sensors is also described.




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Using pause on an electronic device to manage resources

An electronic device for using pause to manage resources is described. The electronic device includes a processor and instructions stored in memory. The electronic device monitors a pause duration and determines whether to perform a resource management operation based on the pause duration. The electronic device performs the resource management operation based on the pause duration.




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Two-tiered dynamic load balancing using sets of distributed thread pools

By employing a two-tier load balancing scheme, embodiments of the present invention may reduce the overhead of shared resource management, while increasing the potential aggregate throughput of a thread pool. As a result, the techniques presented herein may lead to increased performance in many computing environments, such as graphics intensive gaming.




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Information processing device and task switching method

Disclosed is an information processing device and a task switching method that can reduce the time required for switching of tasks in a plurality of coprocessors. The information processing device (30) includes a processor core (301); coprocessors (311 to 31n) including operation units (321 to 32n) that perform operation in response to a request from the processor core (301) and operation storage units (331 to 22n) that store the contents of operation of the operation units (321 to 32n), save storage units (351 to 35n) that store the saved contents of operation, a task switching control unit (302) that outputs a save/restore request signal when switching a task on which operation is performed by the coprocessors (311 to 31n), and save/restore units (341 to 34n) that perform at least one of saving of the contents of operation in the operation storage units (331 to 33n) to the save storage units (351 to 35n) and restoration of the contents of operation in the save storage units (351 to 35 n) to the operation storage units (331 to 33n) in response to the save/restore request signal.




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Policy enforcement in virtualized environment

Policy enforcement in an environment that includes virtualized systems is disclosed. Virtual machine information associated with a first virtual machine instance executing on a host machine is received. The information can be received from a variety of sources, including an agent, a log server, and a management infrastructure associated with the host machine. A policy is applied based at least in part on the received virtual machine information.




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1,4-fullerene addends in photovoltaic cells

1,4 fullerene deriatives useful for solar cells are provided, where their structures allow for straightforward functionalizations to tune their properties in terms of solubility and LUMO energy levels.




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Liquid crystal compound having fluorovinyl group, liquid crystal composition and liquid crystal display device

A liquid crystal compound having a high stability to heat, light and so forth, a high clearing point, a low minimum temperature of a liquid crystal phase, a small viscosity, a suitable optical anisotropy, a large dielectric anisotropy, a suitable elastic constant and an excellent solubility in other liquid crystal compounds, a liquid crystal composition containing the compound, and a liquid crystal display device including the composition. The compound is represented by formula (1): wherein, for example, R1 is fluorine or alkyl having 1 to 10 carbons; ring A1 and ring A2 are 1,4-phenylene, or 1,4-phenylene in which at least one of hydrogen is replaced by fluorine; Z1, Z2 and Z3 are a single bond; L1 and L2 are hydrogen or fluorine; X1 is fluorine or —CF3; and m is 1, and n is 0.




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Cyclohexene-3,6-diyl compound, liquid crystal composition and liquid crystal display device

To provide a compound, when the compound has both a high clearing point and a low crystallization temperature, having a wide temperature range of a liquid crystal phase and also an excellent solubility in other liquid crystal compounds, and further having general physical properties necessary for the compound, namely, stability to heat, light and so forth, a suitable optical anisotropy and a suitable dielectric anisotropy. A compound is represented by formula (1): wherein, for example, Ra and Rb are alkyl having 1 to 10 carbons; A1, A2, A3 and A4 are 1,4-phenylene; Z1, Z2, Z3 and Z4 are a single bond or alkylene having 1 to 4 carbons; and m, n, q and r are independently 0, 1, or 2, and a sum of m, n, q and r is 1, 2, 3 or 4.




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Optically active ammonium salt compound, production intermediate thereof, and production method thereof

An optically active bisbenzyl compound or a racemic bisbenzyl compound represented by formula (2) that has axial chirality: where: R1 represents a halogen, or an optionally substituted: linear, branched, or cyclic C1-8 alkyl, C2-8 alkenyl, C2-8 alkynyl, C6-14 aryl, C3-8 heteroaryl, linear, branched, or cyclic C1-8 alkoxy, or C7-16 aralkyl;R21 each independently represents hydrogen, halogen, nitro, or an optionally substituted: linear, branched, or cyclic C1-8 alkyl, C2-8 alkenyl, C2-8 alkynyl, C6-14 aryl, linear, branched, or cyclic C1-8 alkoxy, or a C7-16 aralkyl;R3 represents hydrogen, or an optionally substituted: C6-14 aryl, a C3-8 heteroaryl, or a C7-16 aralkyl; andY2 represents a halogen, or an optionally substituted: C1-8 alkylsulfonyloxy, C6-14 arylsulfonyloxy, or C7-16 aralkylsulfonyloxy.




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Organic compound and organic light-emitting device

A novel organic compound suitable for emitting green light and an organic light-emitting device including the organic compound are provided. The organic compound is represented by general formula (1). In general formula (1), R1 to R18 are each independently selected from a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted amino group, a substituted or unsubstituted aryl group, and a substituted or unsubstituted heterocyclic group.




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Process for producing 1,2-dichloro-3,3,3-trifluoropropene

Disclosed is a process for producing 1,2-dichloro-3,3,3-trifluoropropene, which is characterized by that 1-halogeno-3,3,3-trifluoropropene represented by the general formula [1]: (In the formula, X represents a fluorine atom, chlorine atom or bromine atom.) is reacted with chlorine in a gas phase in the presence of a catalyst. It is possible by this process to produce 1,2-dichloro-3,3,3-trifluoropropene in an industrial scale with good yield by using 1-halogeno-3,3,3-trifluoropropene, which is available with a low price, as the raw material.




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Liquid crystal compound having perfluoroalkyl chain, and liquid crystal composition and liquid crystal display device

The invention is to provide a new liquid crystal compound having a high clearing point, a good compatibility with other compounds, a small viscosity, and a high stability to heat, light and so forth; compound (1) is provided: R1CF2nR2 (1) wherein, for example, R1 is alkyl having 4 to 10 carbons or —(CH2)2—CH═CH2, R2 is alkyl having 2 to 10 carbons, n is 8, and R1 and R2 are not allowed to be straight-chain alkyl having an identical number of carbons.




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Processes for separation of fluoroolefins from hydrogen fluoride by azeotropic distillation

The present disclosure relates to a process for separating a fluoroolefin from a mixture comprising hydrogen fluoride and fluoroolefin, comprising azeotropic distillation both with and without an entrainer. In particular are disclosed processes for separating any of HFC-1225ye, HFC-1234ze, HFC-1234yf or HFC-1243zf from HF.




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Use of copper-nickel catalysts for dehlogenation of chlorofluorocompounds

The disclosure describes a process for dehalogenation of chlorofluorocompounds. The process comprises contacting a saturated chlorofluorocompound with hydrogen in the presence of a catalyst at a temperature sufficient to remove chlorine and/or fluorine substituents to produce a fluorine containing terminal olefin.




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Catalytic gas phase fluorination of 1,1,2-trichloroethane and/or 1,2-dichloroethene to produce 1-chloro-2,2-difluoroethane

The invention is directed to a catalyst for the gas phase fluorination of 1,1,2-trichloroethane and/or 1,2-dichloroethene with HF to give 1-chloro-2,2-difluoroethane which catalyst is prepared by co-depositing FeCl3 and MgCl2 on chromia-alumina, or co-depositing Cr(NO3)3 and Ni(NO3)2 on active carbon, or by doping alumina with ZnCl2, and to a process for the preparation of 1-chloro-2,2-difluoroethane comprising a catalytic gas phase fluorination of 1,1,2-trichloroethane and/or 1,2-dichloroethene wherein one of the catalysts according to claim 2 or 3 is used.




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Catalytic dehydrochlorination of hydrochlorofluorocarbons

A dehydrochlorination process is disclosed. The process involves contacting RfCFClCH2X with a catalyst in a reaction zone to produce a product mixture comprising RfCF═CHX, wherein said catalyst comprises MY supported on carbon, and wherein Rf is a perfluorinated alkyl group, X ═H, F, Cl, Br or I, M=K, Na or Cs, and Y═F, Cl or Br.