The invention relates to a process for the preparation of formula (I) which process comprises pyrolyzing a compound of formula (II) wherein X is chloro or bromo, and to compounds which may be used as intermediates for the manufacture of the compound of formula I and to the preparation of said intermediates.

To provide a method for efficiently separating 2,3,3,3-tetrafluoropropene (HFO-1234yf) and chloromethane (R40) from a composition comprising HFO-1234yf and R40. An azeotrope-like composition comprising from 58 to 78 mol % of HFO-1234yf and from 22 to 42 mol % of R40, and a method for producing HFO-1234yf, which comprises steps of distilling an initial mixture containing HFO-1234yf in a content exceeding 63 mol % in the total amount of HFO-1234yf and R40, thereby to separate the initial mixture into a first fraction in which the content of HFO-1234yf in the total amount of HFO-1234yf and R40 is lower than the content of HFO-1234yf in the total amount of HFO-1234yf and R40 in the initial mixture, and a second fraction in which the content of HFO-1234yf in the total amount of HFO-1234yf and R40 is higher than the content of HFO-1234yf in the total amount of HFO-1234yf and R40 in the initial mixture, and then obtaining HFO-1234yf having a reduced R40 concentration, from the second fraction.

Provided is a process for making 2-chloro-1,1,1,2-tetrafluoropropane. The process has the step of hydrofluorinating 2-chloro-3,3,3-trifluoropropene in the presence of a catalyst selected from the group consisting of SbCl3, SbCl5, SbF5, TiCl4, SnCl4, Cr2O3, and fluorinated Cr2O3.

Methods for fluorinating organic compounds are described herein.

Fluorinated aromatic materials, their synthesis and their use in optoelectronics. In some cases, the fluorinated aromatic materials are perfluoroalkylated aromatic materials that may include perfluoropolyether substituents.

A method for producing fluorinated organic compounds, including hydrofluoropropenes, which preferably comprises converting at least one compound of formula (I): CF3(—CX2X2)nCX1═H2 (I) to at least one compound of formula (II): CF3(CX2X2)nCX1═H2 (II), where X1 is Cl, Br or I, each X2 is independently selected from the group consisting of H, Cl, F, Br or J, and n is 0, 1, or 2.

A process for making a fluorinated olefin having the step of dehydrochlorinating a hydrochlorofluorocarbon having at least one hydrogen atom and at least one chlorine atom on adjacent carbon atoms, preferably carried out in the presence of a catalyst selected from the group consisting of (i) one or more metal halides, (ii) one or more halogenated metal oxides, (iii) one or more zero-valent metals/metal alloys, (iv) a combination of two or more of the foregoing.

A solvent that reversibly converts from a hydrophobic liquid form to hydrophilic liquid form upon contact with water and a selected trigger, e.g., contact with CO2, is described. The hydrophilic liquid form is readily converted back to the hydrophobic liquid form and water. The hydrophobic liquid is an amidine or amine. The hydrophilic liquid form comprises an amidinium salt or an ammonium salt.

Process for producing silica-comprising dispersions comprising a polyetherol or a polyether amine, which comprises the steps of (i) admixing an aqueous silica sol (K) having an average particle diameter of from 1 to 150 nm and a silica content, calculated as SiO2, of from 1 to 60% by weight and a pH of from 1 to 6 with at least one polyetherol (b1) and/or polyether amine (b2) based on ethylene oxide and/or propylene oxide and having an average OH or amine functionality of from 2 to 6 and a number average molecular weight of from 62 to 6000 g/mol,(ii) distilling off at least part of the water,(iii) admixing the dispersion with at least one compound (S) having at least one at least monoalkoxylated silyl group and at least one alkyl, cycloalkyl or aryl substituent, where this substituent may have groups which are reactive toward an alcohol, an amine or an isocyanate in an amount of from 0.1 to 20 μmol of (S) per m2 of surface area of (K), where steps (i) and (iii) can be carried out simultaneously or in succession in any order, (iv) optionally adjusting the pH of the silica-comprising dispersions obtained to a value of from 7 to 12 by adding a basic compound, where step (iv) can also be carried out between steps (ii) and (iii).

Disclosed and claimed herein are hybrid silica aerogels containing non-polymeric, functional organic materials covalently bonded at one or both ends to the silica network of the aerogels through a C—Si bond between a carbon atom of the organic material and a silicon atom of the aerogel network. Methods of their preparation are also disclosed.

Methods of increasing the solubility of a base in supercritical carbon dioxide include forming a complex of a Lewis acid and the base, and dissolving the complex in supercritical carbon dioxide. The Lewis acid is soluble in supercritical carbon dioxide, and the base is substantially insoluble in supercritical carbon dioxide. Methods for increasing the solubility of water in supercritical carbon dioxide include dissolving an acid or a base in supercritical carbon dioxide to form a solution and dissolving water in the solution. The acid or the base is formulated to interact with water to solubilize the water in the supercritical carbon dioxide. Some compositions include supercritical carbon dioxide, a hydrolysable metallic compound, and at least one of an acid and a base. Some compositions include an alkoxide and at least one of an acid and a base.

The invention relates to process for the treatment of a hydrophobic surface by a liquid film comprising an aqueous phase comprising the coating of said surface by the liquid whose aqueous phase comprises an effective amount of an agent of modification of the properties of surface and an active agent.

A method for producing polymer particles includes a preparation step for preparing a first oily liquid containing an oily olefin monomer, a radical polymerization initiator, and an iodine molecule, a synthesis step for obtaining a second oily liquid containing at least an iodine compound produced by a reaction between a radical generated by cleavage of the radical polymerization initiator and the iodine molecule in the first oily liquid, a suspension step for obtaining an oil droplet of the second oily liquid by suspending the second oily liquid in water, and a polymerization step for polymerizing the oily olefin monomer in the oil droplet.

The present invention relates to a method for producing particles of a compound of interest. In a method according to the invention a solution is provided of the compound of interest in a solvent. This solution is thickened or gelled and particles are formed. The invention further relates to a particle that is obtainable by the invention.

Particular aspects provide compositions comprising an electrokinetically altered oxygenated aqueous fluid, wherein the oxygen in the fluid is present in an amount of at least 25 ppm. In certain aspects, the electrokinetically altered oxygenated aqueous fluid comprises electrokinetically modified or charged oxygen species present in an amount of at least 0.5 ppm. In certain aspects the electrokinetically altered oxygenated aqueous fluid comprises solvated electrons stabilized by molecular oxygen, and wherein the solvated electrons present in an amount of at least 0.01 ppm. In certain aspects, the fluid facilitates oxidation of pyrogallol to purpurogallin in the presence of horseradish peroxidase enzyme (HRP) in an amount above that afforded by a control pressure pot generated or fine-bubble generated aqueous fluid having an equivalent dissolved oxygen level, and wherein there is no hydrogen peroxide, or less than 0.1 ppm of hydrogen peroxide present in the electrokinetic oxygen-enriched aqueous fluid.

An object of the present invention is to provide a method for producing a conductive material that allows a low electric resistance to be generated, and that is obtained by using an inexpensive and stable conductive material composition containing no adhesive. The conductive material can be provided by a producing method that includes the step of sintering a first conductive material composition that contains silver particles having an average particle diameter (median diameter) of 0.1 μm to 15 μm, and a metal oxide, so as to obtain a conductive material. The conductive material can be provided also by a method that includes the step of sintering a second conductive material composition that contains silver particles having an average particle diameter (median diameter) of 0.1 μm to 15 μm in an atmosphere of oxygen or ozone, or ambient atmosphere, at a temperature in a range of 150° C. to 320° C., so as to obtain a conductive material.

A manufacturing method of a glass substrate for a magnetic disk is provided whereby nano pits and/or nano scratches cannot be easily produced in polishing a principal face of a glass substrate using a slurry containing zirconium oxide as an abrasive. The manufacturing method of a glass substrate for a magnetic disk includes, for instance, a polishing step of polishing a principal face of a glass substrate using a slurry containing, as an abrasive, zirconium oxide abrasive grains having monoclinic crystalline structures (M) and tetragonal crystalline structures (T).

Described is a method to prepare wet foams exhibiting long-term stability wherein colloidal particles are used to stabilize the gas-liquid interface, said particles being initially inherently partially lyophobic particles or partially lyophobized particles having mean particle sizes from 1 nm to 20 μm. In one aspect, the partially lyophobized particles are prepared in-situ by treating initially hydrophilic particles with amphiphilic molecules of specific solubility in the liquid phase of the suspension.

The disclosure relates to methods of making polymer particles, said methods including the steps of: making an aqueous gel reaction mixture; forming an emulsion having dispersed aqueous phase micelles of gel reaction mixture in a continuous phase; adding an initiator oil comprising at least one polymerization initiator to the continuous phase; and performing a polymerization reaction in the micelles. Further, the initiator oil is present in a volume % relative to a volume of the aqueous gel reaction mixture of between about 1 vol % to about 20 vol %. The disclosure also relates to methods of making nucleic acid polymer particles having the same method steps and wherein the aqueous gel reaction mixture includes a nucleic acid fragment, such as a primer.

A method of making cerium-containing metal oxide nanoparticles in non-polar solvent eliminates the need for solvent shifting steps. The direct synthesis method involves: (a) forming a reaction mixture of a source of cerous ion and a carboxylic acid, and optionally, a hydrocarbon solvent; and optionally further comprises a non-cerous metal ion; (b) heating the reaction mixture to oxidize cerous ion to ceric ion; and (c) recovering a nanoparticle of either cerium oxide or a mixed metal oxide comprising cerium. The cerium-containing oxide nanoparticles thus obtained have cubic fluorite crystal structure and a geometric diameter in the range of about 1 nanometer to about 20 nanometers. Dispersions of cerium-containing oxide nanoparticles prepared by this method can be used as a component of a fuel or lubricant additive.

Process for preparing a dispersion comprising silicon dioxide particles and cationizing agents, by dispersing 50 to 75 parts by weight of water, 25 to 50 parts by weight of silicon dioxide particles having a BET surface area of 30 to 500 m2/g and 100 to 300 μg of cationizing agent per square meter of the BET surface area of the silicon dioxide particles, wherein the cationizing agent is obtainable by reacting at least one haloalkyl-functional alkoxysilane, hydrolysis products, condensation products and/or mixtures thereof with at least one aminoalcohol and water; and optionally removing the resulting hydrolysis alcohol from the reaction mixture. Also the process for preparing the dispersion, wherein the cationizing agent comprises one or more quaternary, aminoalcohol-functional, organosilicon compounds of formula III and/or condensation products thereof, wherein Ru and Rv are independently C2-4 alkyl group, m is 2-5 and n is 2-5.

The present invention provides a method of testing the integrity of a microporous membrane using a colloid solution containing metal particles or metal compound particles that can accurately determine the integrity of a virus removal membrane formed of hydrophilized synthetic polymer that has been subjected to protein solution filtration, and to provide a method of producing the colloid solution. The colloid solution comprises a solvent and metal particles dispersed in the solvent, and the solvent comprises components (A) and (B), (A) and (C), or (A), (B), and (C), wherein the component (A) is an anionic polymer having a sulfonic acid group, the component (B) is at least one nonionic surfactant selected from the group consisting of a nonionic surfactant having a polycyclic structure in a hydrophobic moiety and a polyoxyethylene sorbitan fatty acid ester, and the component (C) is a water-soluble polymer having a pyrrolidone group.

According to the present invention, a metal nanoparticle dispersion suitable to multiple layered coating by jetting in the form of fine droplets is prepared by dispersing metal nanoparticles having an average particle size of 1 to 100 nm in a dispersion solvent having a boiling point of 80° C. or higher in such a manner that the volume percentage of the dispersion solvent is selected in the range of 55 to 80% by volume and the fluid viscosity (20° C.) of the dispersion is chosen in the range of 2 mPa·s to 30 mPa·s, and then when the dispersion is discharged in the form of fine droplets by inkjet method or the like, the dispersion is concentrated by evaporation of the dispersion solvent in the droplets in the course of flight, coming to be a viscous dispersion which can be applicable to multi-layered coating.

Provided is an oil-in-water silicone emulsion composition that has a low silicone oligomer content, and that can form, even without the use of an organotin compound as a curing catalyst, a cured film that exhibits satisfactory strength and satisfactory adherence to a substrate, through the removal of water fraction. An oil-in-water silicone emulsion composition comprising (A) 100 mass parts of a polyorganosiloxane that contains in each molecule at least two groups selected from the group consisting of a silicon-bonded hydroxyl group, alkoxy group, and alkoxyalkoxy group, (B) 0.1 to 200 mass parts of a colloidal silica, (C) 0.1 to 100 mass parts of an aminoxy group-containing organosilicon compound that has in each molecule an average of two silicon-bonded aminoxy groups, (D) 1 to 100 mass parts of an ionic emulsifying agent, (E) 0.1 to 50 mass parts of a non-ionic emulsifying agent, and (F) 10 to 500 mass parts of water.

A computing section is provided with a plurality of computing units and correlatively stores entries of configuration information that describes configurations of the plurality of computing units with physical configuration numbers that represent the entries of configuration information and executes a computation in a configuration corresponding to a designated physical configuration number. A status management section designates a physical configuration number corresponding to a status to which the computing section needs to advance the next time for the computing section and outputs the status to which the computing section needs to advance the next time as a logical status number that uniquely identifies the status to which the computing section needs to advance the next time in an object code. A determination section determines whether or not the computing section has stored an entry of configuration information corresponding to the status to which the computing section needs to advance the next time based on the logical status number that is output from the status management section. A rewriting section correlatively stores the entry of the configuration information and a physical configuration number corresponding to the entry of the configuration information in the computing section when the determination section determines that the computing section has not stored the entry of configuration information corresponding to the status to which the computing section needs to advance the next time.

A statue management section of a control section is provided with a corresponding real number storage section that stores a real number converted from a logical number by a configuration number converting section. When the corresponding real number storage section has stored configuration information with a real number of the next transition state, the state management section directly supplies the real number to the configuration information storage section in the next or later processing cycle.

A method and circuit arrangement utilize a low latency variable transfer network between the register files of multiple processing cores in a multi-core processor chip to support fine grained parallelism of virtual threads across multiple hardware threads. The communication of a variable over the variable transfer network may be initiated by a move from a local register in a register file of a source processing core to a variable register that is allocated to a destination hardware thread in a destination processing core, so that the destination hardware thread can then move the variable from the variable register to a local register in the destination processing core.

Embodiments provide methods, apparatus, systems, and computer readable media associated with predicting predicates and branch targets during execution of programs using combined branch target and predicate predictions. The predictions may be made using one or more prediction control flow graphs which represent predicates in instruction blocks and branches between blocks in a program. The prediction control flow graphs may be structured as trees such that each node in the graphs is associated with a predicate instruction, and each leaf associated with a branch target which jumps to another block. During execution of a block, a prediction generator may take a control point history and generate a prediction. Following the path suggested by the prediction through the tree, both predicate values and branch targets may be predicted. Other embodiments may be described and claimed.

The disclosure provides a method for passing a parameter between processors. The method comprises the following steps: in a source program of a slave processor, directly introducing a static configuration parameter to be passed; obtaining a relative address of the static configuration parameter when converting the source program of the slave processor into a target program of the slave processor; and configuring directly, by a master processor, a parameter value of the static configuration parameter in the target program of the slave processor according to the obtained relative address of the static configuration parameter. The disclosure also provides a system for passing a parameter between processors. The system has no need to use external hardware such as a dual-port Random Access Memory (RAM) and a register, thus, the requirement of parameter transmission on the external hardware is reduced, and further the area and static power consumption of a chip are reduced. The disclosure reduces the cycle delay of the slave processor in accessing the dual-port RAM and the register, thereby effectively reducing the dynamic power consumption of the chip, improving the processing capability of the slave processor and enhancing the effective performance of the slave processor.

A processor determines whether a first program is under execution when a second program is executed, and changes a setting of a memory management unit based on access prohibition information so that a fault occurs when the second program makes an access to a memory when the first program is under execution. Then, the processor determines whether an access from the second program to a memory area used by the first program is permitted based on memory restriction information when the fault occurs while the first program and the second program are under execution, and changes the setting of the memory management unit so that the fault does not occur when the access to the memory area is permitted.

Augmented processor hardware contains a microcode interpreter. When encrypted microcode is included in a message from a service, the microcode may be passed to the microcode interpreter. Based on decryption and execution of the microcode taking place at the processor hardware, extended functionality may be realized.

A multi-threaded in-order superscalar processor 2 includes an issue stage 12 including issue circuitry 22, 24 for selecting instructions to be issued to execution units 14, 16 in dependence upon a currently selected issue policy. A plurality of different issue policies are provided by associated different policy circuitry 28, 30, 32 and a selection between which of these instances of the policy circuitry 28, 30, 32 is active is made by policy selecting circuitry 34 in dependence upon detected dynamic behavior of the processor 2.

A microprocessor having performs an architectural instruction that instructs it to perform an operation on first and second source operands to generate a result and to write the result to a destination register only if its architectural condition flags satisfy a condition specified in the architectural instruction. A hardware instruction translator translates the instruction into first and second microinstructions. To execute the first microinstruction, an execution pipeline performs the operation on the source operands to generate the result. To execute the second microinstruction, it writes the destination register with the result generated by the first microinstruction if the architectural condition flags satisfy the condition, and writes the destination register with the current value of the destination register if the architectural condition flags do not satisfy the condition.

A hypervisor and one or more guest operating systems resident in a data processing system and hosted by the hypervisor are configured to selectively enable or disable branch prediction logic through separate hypervisor-mode and guest-mode instructions. By doing so, different branch prediction strategies may be employed for different operating systems and user applications hosted thereby to provide finer grained optimization of the branch prediction logic for different operating scenarios.

A computing method includes accepting a definition of a computing task, which includes multiple Processing Elements (PEs) having execution dependencies. The computing task is compiled for concurrent execution on a multiprocessor device, by arranging the PEs in a series of two or more invocations of the multiprocessor device, including assigning the PEs to the invocations depending on the execution dependencies. The multiprocessor device is invoked to run software code that executes the series of the invocations, so as to produce a result of the computing task.

A data accessing method, and a storage system and a controller using the same are provided. The data accessing method is suitable for a flash memory storage system having a data perturbation module. The data accessing method includes receiving a read command from a host and obtaining a logical block to be read and a page to be read from the read command. The data accessing method also includes determining whether a physical block in a data area corresponding to the logical block to be read is a new block and transmitting a predetermined data to the host when the physical block corresponding to the logical block to be read is a new block. Thereby, the host is prevented from reading garbled code from the flash memory storage system having the data perturbation module.

A method of monitoring thread execution within a multicore processor architecture which comprises a plurality of interconnected processor elements for processing the threads, the method comprising receiving a plurality of thread parameter indicators of one or more parameters relating to the function and/or identity and/or execution location of a thread or threads, comparing at least one of the thread parameter indicators with a first plurality of predefined criteria each representative of an indicator of interest, and generating an output consequential upon thread parameter indicators which have been identified to be of interest as a result of the said comparison.

A system and method is disclosed for communicating with sensors/loggers in integrated radio frequency identification (RFID) tags. An RFID reader uses a Communicate With Data Logger Command to communicate with a data logger in an RFID tag. The RFID reader performs data access processes using an Index Register and a Data Register of the RFID tag. The RFID reader selects one of (1) Index Read access (2) Index Write access (3) Data Write access (4) Data Read access with parity and (5) Data Read access with cyclic redundancy check (CRC). The RFID tag performs the requested data access and then performs an error detection process.

A microprocessor capable of running both x86 instruction set architecture (ISA) machine language programs and Advanced RISC Machines (ARM) ISA machine language programs. The microprocessor includes a mode indicator that indicates whether the microprocessor is currently fetching instructions of an x86 ISA or ARM ISA machine language program. The microprocessor also includes a plurality of model-specific registers (MSRs) that control aspects of the operation of the microprocessor. When the mode indicator indicates the microprocessor is currently fetching x86 ISA machine language program instructions, each of the plurality of MSRs is accessible via an x86 ISA RDMSR/WRMSR instruction that specifies an address of the MSR. When the mode indicator indicates the microprocessor is currently fetching ARM ISA machine language program instructions, each of the plurality of MSRs is accessible via an ARM ISA MRRC/MCRR instruction that specifies the address of the MSR.

A method includes, in a processor, loading/moving a first portion of bits of a source into a first portion of a destination register and duplicate that first portion of bits in a subsequent portion of the destination register.

A processor receives an instruction operation (OP) code from a verification system. The instruction OP code includes instruction bits and forced event bits. The processor identifies a forced event based upon the forced event bits, which is unrelated to an instruction that corresponds to the instruction bits. In turn, the processor executes the forced event.

In an example embodiment, there is described herein an apparatus comprising an interface for communicating with a plurality of digital signal processors and logic operable to send and receive data via the interface. The logic is configured to determine a first set of digital signal processors to be maintained in a ready state, a second set of digital signal processors to be maintained in a first energy saving state, and a third set of digital signal processors to be maintained in a second energy saving state.

A method is disclosed which may include analyzing communication requests in a business process between a client and a server offering a service application to be tested. The method may further include identifying a call to a web service in the analyzed communication. The method may also include determining a location of a Web Service Description Language (WSDL) file relating to the web service on a remote server and downloading the WSDL file from the determined location. A computer readable medium having stored thereon instructions for performing the method and a computer system are also disclosed.

A method of applying formal verification methodologies to event processing applications is provided herein. The method includes the following stages: representing an event processing application as an event processing network, being a graph with event processing agents as nodes; generating a finite state machine based on the event processing network, wherein the finite state machine is an over-approximation of the event processing application; expressing stateful rules and policies that are associated with the event processing application using temporal logic, to yield a temporal representation of the event processing application; combining the temporal representation and the finite state machine into a model; generating a statement associated with a user-selected verification-related property of the event processing application, wherein the statement is generated using the temporal representation; and applying the statement to the model, to yield an indication for: (i) a correctness of the statement or (ii) a counter example, respectively.

Graphical programming or modeling environments in which a coding standard can be applied to graphical programs or models are disclosed. The present invention provides mechanisms for applying the coding standard to graphical programs/models in the graphical programming/modeling environments. The mechanisms may detect violations of the coding standard in the graphical model and report such violations to the users. The mechanisms may automatically correct the graphical model to remove the violations from the graphical model. The mechanisms may also automatically avoid the violations in the simulation and/or code generation of the graphical model.

The disclosure generally describes computer-implemented methods, software, and systems for creating and using two-tier mobile applications. A computer-implemented method includes identifying at least a portion of a database to be associated with a mobile application, retrieving a set of metadata associated with the at least a portion of the identified database, automatically generating a set of mobile application source code for directly accessing the at least a portion of the database based on the set of retrieved metadata, and compiling the set of mobile application source code into a distributable mobile application, the distributable mobile application configured to directly access the identified database associated with the mobile application. In some instances, the identifying, retrieving, generating, and compiling operations are performed at design time, while at runtime, the mobile application is executable by a mobile device and, during runtime execution, can request database-related information directly from the identified database.

Methods, devices, and systems for management of a cloud computing environment for use by a software application. The cloud computing environment may be an N-tier environment. Multiple cloud providers may be used to provide the cloud computing environment.

The present invention provides a method, a system and a computer program product for defining a version identifier of a service component. The method includes determining various specification levels corresponding to the service component. Thereafter, the determined specification levels are integrated according to a predefined hierarchy to obtain the version identifier of the service component. The present invention also enables the identification of the service components. The service components are identified from one or more service components on the basis of one or more user requirements.

A deployment system provides the ability to deploy a multi-node distributed application, such as a cloud computing platform application that has a plurality of interconnected nodes performing specialized jobs. The deployment system includes a release management system that builds and manages versioned releases of application services and/or software modules that are executed by the plurality of nodes of the cloud computing platform application. The release management system utilizes specification files to define a jobs and application packages and configurations needed to perform the jobs. The jobs and application packages are assembled into a self-contained release bundle that may be provided to the deployment system. The deployment system unwraps the release bundle and provides each job to deployment agents executing on VMs. The deployment agents apply the jobs to their respective VM (e.g., launching applications), thereby deploying the cloud computing platform application.

A system and method for efficient compilation and invocation of function type calls in a virtual machine (VM), or other runtime environment, and particularly for use in a system that includes a Java Virtual Machine (JVM). In accordance with an embodiment, the system comprises a virtual machine for executing a software application; a memory space for the application byte code comprising callsites generated using a function type carrier; a bytecode to machine code compiler which performs MethodHandle invocation optimizations; a memory space for the compiled machine code; and a memory space for storing software objects as part of the software application. The system enables carrying the function type from the original MethodHandle to a callsite in the generated bytecode, including maintaining generics information for a function type acquired from a target function, and generating a callsite based on the generics information for the function object invocation.