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Screening metal-free photocatalysts from isomorphic covalent organic frameworks for the C-3 functionalization of indoles

J. Mater. Chem. A, 2020, 8,8706-8715
DOI: 10.1039/D0TA02164D, Paper
Ziping Li, Songjie Han, Chunzhi Li, Pengpeng Shao, Hong Xia, He Li, Xiong Chen, Xiao Feng, Xiaoming Liu
An excellent framework photocatalyst was screened from a series of isomorphic COFs. The photocatalytic properties of C-3 functionalization of indoles by COF-based photocatalysts were first reported.
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An advanced three-dimensionally ordered macroporous NiCo2O4 spinel as a bifunctional electrocatalyst for rechargeable Zn–air batteries

J. Mater. Chem. A, 2020, 8,8554-8565
DOI: 10.1039/D0TA00874E, Paper
José Béjar, Lorena Álvarez-Contreras, Janet Ledesma-García, Noé Arjona, Luis Gerardo Arriaga
A rechargeable ZAB was assembled using a NiCo2O4 3DOM spinel displaying an open circuit potential of 1.44 V, a power density of 101 mW cm−2, and a high durability during charge/discharge cycling (being operated for 21 h).
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PCE11-based polymer solar cells with high efficiency over 13% achieved by room-temperature processing

J. Mater. Chem. A, 2020, 8,8661-8668
DOI: 10.1039/D0TA02271C, Paper
Jianyun Zhang, Wenrui Liu, Ming Zhang, Shengjie Xu, Feng Liu, Xiaozhang Zhu
Non-fullerene acceptors featuring excellent miscibility with temperature-dependent aggregation polymer PCE11 enable room-temperature processed polymer solar cells with high efficiency over 13%.
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Oriented bacteriorhodopsin/polyaniline hybrid bio-nanofilms as photo-assisted electrodes for high performance supercapacitors

J. Mater. Chem. A, 2020, 8,8268-8272
DOI: 10.1039/D0TA02815K, Communication
Haijuan Li, Minmin Wang, Guohua Qi, Yong Xia, Chuanping Li, Ping Wang, Mordechai Sheves, Yongdong Jin
Bacteriorhodopsin was used to improve the capacitive performance of PANI supercapacitors by its proton pumping and photoelectric function.
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Enhancing the operational stability of unencapsulated perovskite solar cells through Cu–Ag bilayer electrode incorporation

J. Mater. Chem. A, 2020, 8,8684-8691
DOI: 10.1039/D0TA01606C, Paper
Chieh-Ting Lin, Jonathan Ngiam, Bob Xu, Yu-Han Chang, Tian Du, Thomas J. Macdonald, James R. Durrant, Martyn A. McLachlan
Incorporation of bilayer electrodes (Cu:Ag) significantly reduces electrode corrosion and device degradation in perovskite solar cells operating in air. A symbiosis exists whereby Ag inhibits Cu oxidation and Cu prevents interfacial reactions between the perovskite (MAPbI3) and Ag.
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The critical effect of water content in the electrolyte on the reversible electrochemical performance of Zn–VPO4F cells

J. Mater. Chem. A, 2020, 8,8262-8267
DOI: 10.1039/D0TA01622E, Communication
Hooman Yaghoobnejad Asl, Shyam Sharma, Arumugam Manthiram
The critical role of water as a source of H+ working ions and reactive species in the Zn–VPO4F electrochemical system with an ionic liquid electrolyte.
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Anderson polyoxometalate built-in covalent organic frameworks for enhancing catalytic performances

J. Mater. Chem. A, 2020, 8,8548-8553
DOI: 10.1039/D0TA02443K, Paper
Rui Ma, Naifang Liu, Ting-Ting Lin, Tianbo Zhao, Sheng-Li Huang, Guo-Yu Yang
Anderson polyoxometalate-based covalent organic frameworks exhibited the highest catalytic activity in the photodegradation of RhB and MB, as well as 100% selective oxidation of sulfides to sulfoxides.
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Achieving ultrahigh volumetric performance of graphene composite films by an outer–inner dual space utilizing strategy

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/C9TA13585E, Paper
Cong Huang, Qunli Tang, Qiushui Feng, Yanhua Li, Yali Xu, Yan Zhang, Aiping Hu, Shiying Zhang, Weina Deng, Xiaohua Chen
An outer–inner dual space utilizing strategy is reported for the fabrication of an ultrahigh volumetric performance polydopamine-coated dopamine/reduced graphene oxide composite film.
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Evidence of phase coexistence in hydrothermally synthesized K0.5Na0.5NbO3 nanofibers

J. Mater. Chem. A, 2020, 8,8731-8739
DOI: 10.1039/C9TA14153G, Paper
Mohammad B. Ghasemian, Aditya Rawal, Zahra Shahrbabaki, Qi Zhang, Teng Lu, Yun Liu, Danyang Wang
The 2D 23Na 3QMAS NMR analyses provide new insights into the crystalline structure of K0.5Na0.5NbO3 nanostructures on the microscopic scale, which are critical to understand the functional properties of these nano-materials.
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Synthesis of metal-free lightweight materials with sequence-encoded properties

J. Mater. Chem. A, 2020, 8,8752-8760
DOI: 10.1039/D0TA03162C, Paper
Adi Azoulay, Jesús Barrio, Jonathan Tzadikov, Michael Volokh, Josep Albero, Christel Gervais, Pilar Amo-Ochoa, Hermenegildo García, Félix Zamora, Menny Shalom
A general synthesis of phosphorus–nitrogen–carbon materials with highly tunable elemental composition and spatial organization as well as structural, electronic, and thermal stability properties is reported.
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Understanding the mechanism of byproduct formation with in operando synchrotron techniques and its effects on the electrochemical performance of VO2(B) nanoflakes in aqueous rechargeable zinc batteries

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA00858C, Paper
Qiang Pang, Hainan Zhao, Ruqian Lian, Qiang Fu, Yingjin Wei, Angelina Sarapulova, Junqi Sun, Chunzhong Wang, Gang Chen, Helmut Ehrenberg
The byproduct protects the vanadium-based positive electrode of ARZBs and facilitates Zn2+ insertion into the electrode.
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Quasi-quantum dot-induced stabilization of α-CsPbI3 perovskite for high-efficiency solar cells

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA02807J, Paper
Cheng Liu, Yi Yang, Xin Liu, Yong Ding, Zulqarnain Arain, Xinye Li, Yuanlong Li, Zian Zhou, Songyuan Dai, Mohammad Khaja Nazeeruddin
Quasi-quantum dots α-CsPbI3 films are in situ prepared by using a new ligand with ultralow contents. By increasing the film hydrophobicity and surface Gibbs energy, the device with efficiency of 13.5% keeps stable under ambient condition for 30 days.
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Decoupled electrolytes towards enhanced energy and high temperature performance of thermally regenerative ammonia batteries

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA03236K, Paper
Weiguang Wang, Gequn Shu, Xiuping Zhu, Hua Tian
An electrolyte decoupling strategy is proposed for ammonia batteries to restrain the self-discharge and enhance energy density as well as power generation at high temperatures.
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Inexpensive thermochemical energy storage utilising additive enhanced limestone

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA03080E, Paper
Kasper T. Møller, Ainee Ibrahim, Craig E. Buckley, Mark Paskevicius
A thermochemical energy storage capacity retention of up to 90% over 500 cycles is achieved in cheap and abundant limestone.
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An asymmetrical A–DAD–A-type acceptor simultaneously enhances voltage and current for efficient organic solar cells

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA03128C, Paper
Hanjian Lai, Hui Chen, Yulin Zhu, Lin Chen, Hsin-Hsiang Huang, Feng He
This work provides a strategy of symmetry breaking in an A–DAD–A-type acceptor with a PCE of 15.43%, which is the highest value reported to date for asymmetrical fused-ring acceptors.
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Co-gel strategy for preparing hierarchically porous silica/polyimide nanocomposite aerogel with thermal insulation and flame retardancy

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/C9TA13011J, Paper
Xinhai Zhang, Xingxing Ni, Chenxi Li, Bo You, Gang Sun
Co-gel strategy for preparing hierarchically porous silica/polyimide aerogel with low density, high specific modulus, hydrophobicity, flame retardancy, and thermal insulation.
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Hollow PtCu Nanoparticles Encapsulated into Carbon Shell via Mild Annealing of Metal-Organic Frameworks

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA01549K, Paper
Guanjun Chen, Huaqiang Shan, Yan Li, Hongwei Bao, Tingwei Hu, Long Zhang, Shuai Liu, Fei Ma
Alloying Pt with less expensive 3d transition metal to form bimetallic nanoparticles (NPs) has been proven to be an ideal strategy for synthesis of catalysts, especially in the field of...
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Synchronous surface and bulk composition management for red-shifted light absorption and suppressed interfacial recombination in perovskite solar cells

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA02449J, Paper
Jun-Xing Zhong, Jin-Feng Liao, Yong Jiang, Lianzhou Wang, Dai-Bin Kuang, Wu-Qiang Wu
Perovskite solar cells with a reverse vertical gradient distribution of α/δ-FAPbI3 achieved a record efficiency of up to 21.9% owing to synergistic advantages of expanded photon harvesting and robust surface defect passivation.
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The rational and effective design of nonfullerene acceptors guided by a semi-empirical model for an organic solar cell with an efficiency over 15%

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA03087B, Paper
Xin Ke, Lingxian Meng, Xiangjian Wan, Mingpeng Li, Yanna Sun, Ziqi Guo, Simin Wu, Hongtao Zhang, Chenxi Li, Yongsheng Chen
Guided by a semi-empirical model, two small-molecule acceptors were rationally designed and an impressive PCE of 15.05% was achieved.
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Semiconducting polymer contributes favorably to the Seebeck coefficient in multi-component, high-performance n-type thermoelectric nanocomposites

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA02388D, Paper
Junhui Tang, Ruisi Chen, Lidong Chen, Guillermo C. Bazan, Ziqi Liang
n-Type Co NWs/N2200 TENCs yield a high S, mainly from the semiconducting polymer, yet σ is limited by poor connectivity between inorganic and organic domains. By adding flexible n-doped SWCNTs to yield more conductive paths, σ and mechanical bendability are greatly enhanced.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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High Performance Potassium-Sulfur Batteries and Its Reaction Mechanism

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA03602A, Paper
Xinxin Zhao, Youran Hong, Mingren Cheng, Shiwen Wang, Lei zheng, Jiangwei Wang, Yunhua Xu
Benefiting from the high natural abundance and high theoretical specific capacities of potassium and sulfur, potassium-sulfur (K-S) battery is deemed as a promising energy storage system for large-scale energy storage...
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Smart Porous Wood Supported Flower-like NiS/Ni Conjuction with Vitrimer Co-effect as Multifunctional Material with Reshaping, Shape-memory and Self-healing for High-Performance Supercapacitors, Catalysts and Sensors

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA03664A, Paper
Chuanyin Xiong, Bingbing Li, Heguang Liu, Wei Zhao, Chao Duan, Haiwei Wu, Yong Ni
Wood-based materials are attracting more and more attention for applications in energy storage, due to their environment friendly and numerous channels structure. However, the poor conductivity and flexibility of wood...
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Highly efficient removal of uranium from highly acidic media achieved on a phosphine oxide and amino functionalized superparamagnetic composite polymer adsorbent

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA01633K, Paper
Shiao Zhang, Dingzhong Yuan, Qinghua Zhang, Yun Wang, Yan Liu, Jizhou Zhao, Bibo Chen
It is very necessary to develop the magnetic adsorbents for the efficient extraction of uranium from highly acidic media. In this work, a novel magnetic adsorbent Fe3O4/P (DMAA-DMP) functionalized with...
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Surface-Functionalized Palladium Catalysts for Electrochemical CO2 Reduction

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA03427D, Paper
Rong Xia, Sheng Zhang, Xinbin Ma, Feng Jiao
Rational design and synthesis of efficient catalysts for electrochemical CO2 reduction is a critical step towards practical CO2 electrolyzer systems. In this work, we report a strategy to tune the...
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Rational Design of Well-Dispersed Ultrafine CoS2 Nanocrystals in Micro-Mesoporous Carbon Spheres with Synergistic Effect for High-Performance Lithium-Sulfur Batteries

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA02692A, Paper
Zhanshuang Jin, Ming Zhao, Tianning Lin, Bingqiu Liu, Qi Zhang, Lingyu Zhang, Lihua Chen, Lu Li, Zhong-Min Su, Chungang Wang
The physical confinement and chemical catalysis of lithium polysulfides (LiPSs) are effective ways to improve the performance of lithium-sulfur (Li-S) batteries. How to effectively combine physical confinement and chemical catalysis...
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Plasmon-Enhanced Electrocatalytic Oxygen Reduction in Alkaline Media on Gold Nanohole Electrodes

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/C9TA14174J, Paper
Nait Saada Tamazouzt, Anderson da Silva, Palaniappan Subramanian, Liuqing Pang, Noual Adnane, Bahram Djafari-Rouhani, Vladyslav Mishyn, Dalila Meziane, Sorin Melinte, Georgiana Sandu, Franck Dumeignil, Sebastien Paul, Robert Wojcieszak, Rabah Boukherroub, Sabine Szunerits
Plasmon-driven chemical transformation has become a promising approach for enhancing sluggish electrocatalytic reactions. Herein, an alternative enhancement strategy employing plasmon-induced hot electrons is developed to be competitive with oxygen reduction...
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Aliovalent Fluorine Doping and Anodization-Induced Amorphization Enable Bifunctional Catalysts for Efficient Water Splitting

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA00876A, Paper
Chenglin Zhong, Zhen Han, Tongtong Wang, Qin-chao Wang, Zihan Shen, Qingwen Zhou, Jiaao Wang, Shuo Zhang, Xin Jin, Shengwen Li, Peng Wang, Daqiang Gao, Yong-Ning Zhou, Huigang Zhang
High-efficiency non-precious electrocatalysts are urgently demanded in hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). Transition metal oxides catalysts have shown high activity for the OER in alkaline medium,...
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Dihydrazone-based Dynamic Covalent Epoxy Networks with High Creep Resistance, Controlled Degradability, and Intrinsic Antibacteria from Bioresources

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA01419B, Paper
Xiwei Xu, Songqi Ma, Sheng Wang, Jiahui Wu, Qiong Li, na lu, yanlin liu, Jintao Yang, Jie Feng, Jin Zhu
Covalent adaptable networks (CANs) provide a promising approach to the recycle issue of thermosets due to their dynamic cross-linked networks. However, CANs are susceptible to creep at relatively low temperatures,...
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Now Available: Concerts from the Library of Congress

 

You can get tickets for any 2020 event that is part of Concerts from the Library of Congress.

PLEASE NOTE: All films, talks and pre-concert events this year are general admission with no ticket required, unless otherwise indicated. You can still register for reminders and updates about those events, but seating will be first-come, first-served.

Click here for more information.

Request ADA accommodations five business days in advance at (202) 707-6362 or ADA@loc.gov.




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Upcoming Events: Library Announces Annual Cherry Blossom Festival Events

 

The Library of Congress announces two cultural events during the 2020 National Cherry Blossom Festival, an annual commemoration of Japan’s 1912 gift to the U.S. of 3,020 cherry trees. An artwork display and book launch for “Cherry Blossoms: Sakura Collections from the Library of Congress” will kick off the Library’s celebration on Thursday, April 9. The gift book visualizes the fascinating history of cherry blossoms through original works of art from the Library of Congress collections.

Click here for more information.

Request ADA accommodations five business days in advance at (202) 707-6362 or ADA@loc.gov.




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Live! At the Library Event Series Launched

The Library of Congress is extending its public hours on Thursday evenings and will feature regular live programming for visitors as part of a new initiative, Live! At the Library, beginning April 2 to showcase the broad range of literature, poetry, art, music, digital collections and other holdings at the national library.

The Library’s Thomas Jefferson Building and all exhibitions at the Library – currently featuring the long fight for women’s voting rights and Rosa Parks’ groundbreaking role in civil rights – will be open for extended hours on Thursday evenings from 5 to 8 p.m. every week. Exhibitions and programs will remain free and open to everyone. The Main Reading Room will be open for research during this time, and visitors and researchers will have the opportunity to register for reader cards. Other selected reading rooms may also be open on Thursday nights as a part of evening programming.

Click here for more information.

Request ADA accommodations five business days in advance at (202) 707-6362 or ADA@loc.gov.




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Upcoming Events: Earth and Space Science Talks

This month, the Library of Congress will kick off the annual Earth and Space Science lecture series. The series is presented in partnership with the NASA Goddard Space Flight Center and the Science, Technology and Business Division at the Library.

Click here for more information.

Request ADA accommodations five business days in advance at (202) 707-6362 or ADA@loc.gov.




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NEWS: Library of Congress Cancels Events Until May 11

The Library of Congress announced today that all public events at the Library are canceled until May 11 to reduce the risk of transmitting COVID-19 coronavirus. Whenever possible, the Library will reschedule the public programs that have been canceled. We will also provide regular public updates on the operating status of Library facilities. Library of Congress buildings and facilities remain closed to the public until Wednesday, April 1, 2020 at 8 a.m.

Click here for more information.




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UPDATE: Library Cancels Public Events Until July 1

The Library of Congress announced today that it will cancel all scheduled public events at the Library until July 1 as part of its ongoing efforts to reduce the risk of transmitting COVID-19 coronavirus. Whenever possible, the Library will reschedule the public programs that have been canceled. We will also provide regular public updates on the operating status of Library facilities.

Click here for more information.




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WordPress Breadcrumbs: How to Use This Function?

Unfortunely, WordPress doesn’t have a default function to display a breadcrumb. We’ll see how to create this navigation technique, and display it on our posts, pages and categories archives. Breadcrumb…What’s that?!? Wikipedia says: Breadcrumbs or breadcrumb trail are a navigation technique used in user interfaces. Its purpose is to give users a way to keep …

WordPress Breadcrumbs: How to Use This Function? Read More »




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Advanced CSS Tricks and Techniques

As time goes by, CSS is becoming more and more powerful and nowadays it offers lots of possibilities to create visually stunning websites. This article is a compilation of fresh, advanced CSS tips and techniques to master your web design and front-end web development skills. Each technique features sample code snippet, demo, and explanations. Warning: …

Advanced CSS Tricks and Techniques Read More »




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Assam keen to woo MNCs looking to move out of China

Multinational companies looking to move out of China should consider Assam, with its abundant natural resources, strategic location and robust industrial infrastructure, as their destination for setting up production facilities in India, state Industries Minister Chandra Mohan Patowary said on Wednesday.




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CVC Capital set to buy into Cancer chain HCG, to be co-promoter

Singapore's Temasek holds a 9.4% stake in the widely held company, while Indgrowth Capital owns 1.2%. Public shareholding is 76.1%, as per latest regulatory disclosures.




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CSIR submits 53 genome sequences of coronavirus to global body; to share 450 more by May 15

CSIR's Institute of Genomics and Integrative Biology (IGIB), Delhi, Centre for Cellular and Molecular Biology (CCMB), Hyderabad and Institute of Microbial Technology, Chandigarh are currently sequencing the genomes of the novel coronavirus, he said. Other CSIR institutes are also expected to join the process.




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Zydus Cadila launches generic prostate cancer drug at nearly 70% less price in India

"Our aim is to make a preferred choice of therapy like Obynx available and more accessible to people suffering from cancer. Bridging these unmet gaps comes from our patient-first approach," Zydus Cadila MD Sharvil Patel told .




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Harpsichord sonatas / Vincent Persichetti

MEDIA PhonCD P431 hpsmu




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Into the silence / Nicholas DiEugenio, Mimi Solomon

MEDIA PhonCD D5678 int




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Violin concerto: Grand duo / Lou Harrison

MEDIA PhonCD H248.2 insmu c




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Viola concertos / Amanda Harberg, Max Wolpert

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Monológos: música mexicana de concierto para violonchelo solo / Gustavo Martín, violonchelo

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Concerti per violino: "La boemia" / Vivaldi

MEDIA PhonCD V836 covb h




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Renaissance polyphony of Portugal for Our Lady of Fatima / St. John Cantius Choir of St. Cecilia, Fr. Scott A. Haynes

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Overture to Candide: Fancy free ; Anniversaries for orchestra ; Overture to Wonderful town / Bernstein

MEDIA PhonCD B458 insmu




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Concerti per archi.: e concerti per viola d'amore / Vivaldi

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There is no other / Rhiannon Giddens ; with Francesco Turrisi

MEDIA PhonCD F G3701.C6.G533