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[ASAP] Exploring Homogeneous Conditions for Mild Buchwald–Hartwig Amination in Batch and Flow

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00018




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[ASAP] Safety Case Study. Intrinsic Instability of Concentrated Solutions of Alcoholic Hydrogen Chloride: Potential Hazards Associated with Methanol

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00034




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[ASAP] Process Development and Large-Scale Synthesis of BTK Inhibitor BIIB068

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00087




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[ASAP] <italic toggle="yes">N</italic>-Acyl-5,5-Dimethylhydantoins: Mild Acyl-Transfer Reagents for the Synthesis of Ketones Using Pd–PEPPSI or Pd/Phosphine Catalysts

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00054




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[ASAP] Bromine–Lithium Exchange on a <italic toggle="yes">gem</italic>-Dibromoalkene, Part 2: Comparative Performance of Flow Micromixers

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00203




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[ASAP] Continuous Process for Preparing the Difluoromethylating Reagent [(DMPU)<sub>2</sub>Zn(CF<sub>2</sub>H)<sub>2</sub>] and Improved Synthesis of the ICHF<sub>2</sub> Precursor

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00089




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[ASAP] Development and Production of an Enantioselective Tetrahydroisoquinoline Synthesis Enabled by Continuous Cryogenic Lithium–Halogen Exchange

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00141




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[ASAP] Correction to “Application of Crabtree/Pfaltz-type Iridium Complexes for the Catalyzed Asymmetric Hydrogenation of an Agrochemical Building Block”

Organic Process Research & Development
DOI: 10.1021/acs.oprd.0c00206




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[ASAP] Catalyst-Free Cyclization- and Curtius Rearrangement-Induced Functional Group Transformation: An Improved Synthetic Strategy of First-in-Class ATX Inhibitor Ziritaxestat (GLPG-1690)

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00511




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Enhancing aqueous pollutants photodegradation via Fermi level matched Z-scheme BiOI/Pt/g-C3N4 photocatalyst: unobstructed photogenerated charge behavior and degradation pathway exploration

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00429D, Paper
Jingjing Jiang, Yueyu Song, Xingyue Wang, Tianren Li, Mingyu Li, Yanhong Lin, Tengfeng Xie, Shuangshi Dong
Z-scheme photocatalytic system was widely requisited to solve water pollution problem. However, the degradation mechanism for pollutants with Z-scheme photocatalyst has been ambiguous. In this work, an efficient all solid-state...
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Synergetic effect of Lewis acid and base in modified Sn-β on the direct conversion of levoglucosan to lactic acid

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00089B, Paper
Wenda Hu, Zixin Chi, Yan Wan, Shuai Wang, Jingdong Lin, Shaolong Wan, Yong Wang
The synergetic effect of Lewis acid and base in modified Sn-β boosts the yield of lactic acid produced from levoglucosan.
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Oxidation of lignocellulosic platform molecules to value-added chemicals using heterogeneous catalytic technologies

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00240B, Minireview
Pedro L. Arias, Juan A. Cecilia, Iñaki Gandarias, José Iglesias, Manuel López Granados, Rafael Mariscal, Gabriel Morales, Ramón Moreno-Tost, Pedro Maireles-Torres
This minireview gives an overview about heterogeneous catalytic technologies for the oxidation of key platform molecules (glucose, 5-hydroxymethylfurfural, furfural and levulinic acid) into valuable chemicals.
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Hydrodeoxygenation of anisole to benzene over an Fe2P catalyst by a direct deoxygenation pathway

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00046A, Paper
Shuyuan Wang, Dan Xu, Yunlei Chen, Song Zhou, Di Zhu, Xiaodong Wen, Yong Yang, Yongwang Li
Fe2P catalyst was highly selective for the cleavage of C–O bond of anisole via direct deoxygenation pathway.
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Metal free alkene hydrogenation by B-doped graphitic carbon nitride

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00488J, Paper
Ashima Dogra, Ilaria Barlocco, Amritpal Singh, Ferenc Somodi, Alberto Villa, Neeraj Gupta
Metal free hydrogenation of styrene under mild conditions employing boron-doped carbon nitride catalysts is reported.
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Water-soluble NHC-stabilized platinum nanoparticles as recoverable catalysts for hydrogenation in water

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00481B, Paper
Andrea M. Ruiz-Varilla, Edwin A. Baquero, Bruno Chaudret, Ernesto de Jesús, Camino Gonzalez-Arellano, Juan C. Flores
Aromatic compounds have been hydrogenated in water using recoverable catalysts based on water-soluble platinum nanoparticles capped with NHC ligands.
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Recent advances and prospects of inkjet printing in heterogeneous catalysis

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00040J, Minireview
Open Access
Hesam Maleki, Volfango Bertola
This review provides an insight into inkjet printing technology in the context of heterogeneous catalysis.
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Deactivation and regeneration of carbon supported Pt and Ru catalysts in aqueous phase hydrogenation of 2-pentanone

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00163E, Paper
Jiajie Huo, Hien N. Pham, Yan Cheng, Hsi-Hsin Lin, Luke T. Roling, Abhaya K. Datye, Brent H. Shanks
Aqueous phase conversion of biomass-derived molecules requires development of catalysts and operating strategies that create viable operation for extended performance as necessitated for industrial applications.
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Development of an engineered thermostable amine dehydrogenase for the synthesis of structurally diverse chiral amines

Catal. Sci. Technol., 2020, 10,2353-2358
DOI: 10.1039/D0CY00071J, Paper
Lei Liu, Dong-Hao Wang, Fei-Fei Chen, Zhi-Jun Zhang, Qi Chen, Jian-He Xu, Zhi-Long Wang, Gao-Wei Zheng
Structurally diverse chiral amines and amino alcohols were synthesized using an engineered thermostable amine dehydrogenase, demonstrating its extensive synthesis potential.
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Pd–Au bimetallic catalysts supported on ZnO for selective 1,3-butadiene hydrogenation

Catal. Sci. Technol., 2020, 10,2503-2512
DOI: 10.1039/C9CY02395J, Paper
Open Access
Belén Bachiller-Baeza, Ana Iglesias-Juez, Giovanni Agostini, Eva Castillejos-López
The effect of the ZnO morphology on the properties of Pd–Au bimetallic catalysts has been discussed.
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Path of electron transfer created in S-doped NH2-UiO-66 bridged ZnIn2S4/MoS2 nanosheet heterostructure for boosting photocatalytic hydrogen evolution

Catal. Sci. Technol., 2020, 10,2531-2539
DOI: 10.1039/D0CY00127A, Paper
Qi Ran, Zebin Yu, Ronghua Jiang, Lun Qian, Yanping Hou, Fei Yang, Fengyuan Li, Mingjie Li, Qianqian Sun, Heqing Zhang
This work introduces the synthesis of ZnIn2S4/NH2-UiO-66/MoS2 sheet heterostructure photocatalysts and their application to photocatalytic hydrogen evolution.
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Direct synthesis of hydrogen peroxide without the use of acids or halide promoters in dissolution

Catal. Sci. Technol., 2020, 10,2333-2336
DOI: 10.1039/D0CY00416B, Communication
Open Access
G. Blanco-Brieva, F. Desmedt, P. Miquel, J. M. Campos-Martin, J. L. G. Fierro
We show the first catalyst family able to produce hydrogen peroxide at concentrations higher than 5 wt% in the absence of any promoter or stabilizing agent in dissolution.
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Highly-efficient Ru/Al–SBA-15 catalysts with strong Lewis acid sites for the water-assisted hydrogenation of p-phthalic acid

Catal. Sci. Technol., 2020, 10,2443-2451
DOI: 10.1039/D0CY00047G, Paper
Cong Mao, Jingwei Zheng, Babasaheb M. Matsagar, Ranjith Kumar Kankala, Tansir Ahamad, Yucheng Yang, Kevin C.-W. Wu, Xueqin Zhang
A Ru/Al–SBA-15 catalyst with excess Lewis acid sites displayed excellent efficiency (100%), high cis-isomer selectivity (84%), and exceptional stability towards hydrogenation of p-phthalic acid in water.
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Adjustable anchoring of Ni/Co cations by oxygen-containing functional groups on functionalized graphite paper and accelerated mass/electron transfer for overall water splitting

Catal. Sci. Technol., 2020, 10,2627-2643
DOI: 10.1039/D0CY00181C, Paper
Yiyi Huang, Lei Sun, Zebin Yu, Ronghua Jiang, Jun Huang, Yanping Hou, Fei Yang, Boge Zhang, Runzhi Zhang, Yalan Zhang
NCS–NCO/FGP0.44 with a cellular network of porous nanosheets and close-contact heterointerface reveals accelerated interfacial mass/electron transportation for overall water splitting.
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Mechanistic insights into photocatalysis and over two days of stable H2 generation in electrocatalysis by a molecular cobalt catalyst immobilized on TiO2

Catal. Sci. Technol., 2020, 10,2549-2560
DOI: 10.1039/D0CY00330A, Paper
Open Access
Nicola Weder, Benjamin Probst, Laurent Sévery, Ricardo J. Fernández-Terán, Jan Beckord, Olivier Blacque, S. David Tilley, Peter Hamm, Jürg Osterwalder, Roger Alberto
Molecular and heterogeneous water reduction combined: Over 2 days of electrocatalysis of a cobalt polypyridyl catalyst immobilized on TiO2.
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Enhanced oxygen evolution catalysis by aluminium-doped cobalt phosphide through in situ surface area increase

Catal. Sci. Technol., 2020, 10,2398-2406
DOI: 10.1039/D0CY00123F, Paper
Timothy E. Rosser, Juliana P. S. Sousa, Yasmine Ziouani, Oleksandr Bondarchuk, Dmitri Y. Petrovykh, Xian-Kui Wei, Jo J. L. Humphrey, Marc Heggen, Yury V. Kolen'ko, Andrew J. Wain
Al-doping of cobalt phosphide oxygen evolution catalysts results in enhanced performance which, based on in situ and operando analysis, is shown to result from a surface area increase associated with modified oxidation behaviour.
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Enhancing hydrogen evolution reaction through modulating electronic structure of self-supported NiFe LDH

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00315H, Paper
Xiao-Peng Li, Wen-Kai Han, Kang Xiao, Ting Ouyang, Nan Li, Feng Peng, Zhao-Qing Liu
NiFe-layered double hydroxide (NiFe LDH), as an efficient oxygen evolution reaction (OER) electrocatalyst, has emerged as a promising electrocatalyst for catalyzing overall water splitting in alkaline electrolyte.
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Optimized preparation and regeneration of MFI type base catalysts for D-glucose isomerization in water

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00188K, Paper
Margarida M. Antunes, Auguste Fernandes, Diogo Falcão, Martyn Pillinger, Filipa Ribeiro, Anabela A. Valente
Eco-friendly solid bases possessing hierarchical MFI structure for D-glucose isomerization to D-fructose. Optimizing catalyst synthesis and composition for enhanced stability.
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Development of BiOI as an effective photocatalyst for oxygen evolution reaction under simulated solar irradiation

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00266F, Paper
Tzu-Hsin Chen, Masaaki Yoshida, Shun Tsunekawa, Jia-Hao Wu, Kun-Yi Andrew Lin, Chechia Hu
In this study, crystalline BiOI powders were prepared for photocatalytic O2 evolution in the presence of NaIO3 as the electron mediator.
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An in situ grown lanthanum sulfide/molybdenum sulfide hybrid catalyst for electrochemical hydrogen evolution

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00425A, Paper
Xinran Ding, Tao Yang, Wenxian Wei, Yihui Wang, Kai Xu, Zizheng Zhu, Hong Zhao, Tingting Yu, Dongen Zhang
An La2S3–MoS2 catalyst with expanded interlayer spacing and engineered nano-interfaces was facilely synthesized, demonstrating enhanced catalytic activity for electrochemical hydrogen evolution.
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Carbon nanotube/PTFE as a hybrid platform for lipase B from Candida antarctica in transformation of α-angelica lactone into alkyl levulinates

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00545B, Paper
Anna Szelwicka, Anna Kolanowska, Piotr Latos, Sebastian Jurczyk, Slawomir Boncel, Anna Chrobok
A highly active biocatalyst based on a hybrid platform was designed for the conversion of α-angelica lactone to alkyl levulinates.
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Heterogeneous iron-containing nanocatalysts – promising systems for selective hydrogenation and hydrogenolysis

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00086H, Minireview
Anastasiya A. Shesterkina, Leonid M. Kustov, Anna A. Strekalova, Vladimir B. Kazansky
Bimetallic catalytic systems Fe–Me (Pt, Pd, Cu) demonstrate synergy in the activity/selectivity pattern in reactions involving hydrogen: selective hydrogenation of CC bonds, NO2 and carbonyl groups and hydrogenolysis of C–O bonds.
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Regulation of rutile/anatase TiO2 heterophase interface by Ni12P5 to improve photocatalytic hydrogen evolution

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00634C, Paper
Qiu Chengwei, Jinjin Lin, Jinni Shen, Dan Liu, Zizhong Zhang, Huaxiang Lin, Xuxu wang
Anatase/rutile TiO2 heterophase junction composite has been documented to have much higher photocatalytic activity than single phase TiO2 (nude anatase or nude rutile) for various chemical reactions including the hydrogen...
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Photocatalytic hydrogen evolution over nickel cobalt bimetallic phosphate anchored graphitic carbon nitrides by regulation of d-band electronic structure

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00556H, Paper
Yuanzheng Zhang, Yunrong Dai, Lifeng Yin, Huihui Li, Xiang Chen, Bin Chen
Non-precious metal co-catalysts with high activity and stability are extremely desirable for economically viable photocatalytic molecular hydrogen (H2) evolution. Herein, nickel cobalt phosphate (NiCo-Pi) was introduced into graphitic carbon nitride...
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Surface reconstruction and effect of Ni-modification in the selective hydrogenation of 1,3-butadiene over Mo2C-based catalysts

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00402B, Paper
Qiuchen Yang, Rui Qiu, Xixi Ma, Ruijun Hou, Kening Sun
In the current study, Mo2C, NiMo2C, H-Mo2C and H-NiMo2C were synthesized to understand the effects of Ni modification and synthesis route. The catalysts were characterized by XRD, N2-physisorption, SEM, TEM,...
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Facile synthesis of oxygen-deficient nano-TiO2 coordinated by acetate ligands for enhanced visible-light photocatalytic performance

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00592D, Paper
Shaohua Pang, Yunfei Lu, Lin Cheng, Juming Liu, Huiyan Ma, Jucai Yang, Qiancheng Zhang
To date, various methods have been adopted to enhance the visible-light photocatalytic activity of nano-TiO2. However, a more facile and moderate method is still highly desirable. In this work, a...
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Importance of the decoration in shaped cobalt nanoparticles in the acceptor-less secondary alcohol dehydrogenation

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00390E, Paper
Kamila Kaźmierczak, Raj Kumar Ramamoorthy, Arthur Moisset, Guillaume Viau, Arnaud Viola, Marion Giraud, Jennifer Peron, Lorette Sicard, Jean-Yves Piquemal, Michèle Besson, Noémie Perret, Carine Michel
Ligands matter for shaped decorated Co nanoparticles, at the frontier between homogeneous and heterogeneous catalysis.
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Semi-rational hinge engineering: modulating the conformational transformation of glutamate dehydrogenase for enhanced reductive amination activity towards non-natural substrates

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/C9CY02576F, Paper
Xinjian Yin, Yayun Liu, Lijun Meng, Haisheng Zhou, Jianping Wu, Lirong Yang
The hinge region was identified to be a promising hotspot for activity engineering of GluDHs, providing a potent alternative for developing high-performance biocatalysts toward valuable optically pure L-amino acid production.
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Phosphorus-Doped Inverse Opal g-C3N4 for Efficient and Selective CO Generation from Photocatalytic Reduction of CO2

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00457J, Paper
xiaoyue huang, Wenyi Gu, Songchang Hu, Yan Hu, Liang Zhou, Juying Lei, Lingzhi Wang, Yongdi Liu, Jinlong Zhang
In this work, inverse opal (IO) structure construction and phosphorus doping were combined to modify carbon nitride (g-C3N4) for photocatalytic reduction of CO2. The inverse opal structure was fabricated by...
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Bifunctional rhenium-copper nanostructures for intensified and stable ethanol synthesis via hydrogenation of dimethyl oxalate

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00579G, Communication
Zhongnan Du, Meng Chen, Xuepeng Wang, Xingkun Chen, Xiaolin Mou, Yuan Tan, Wenshao Yang, Chuanqi Huang, Hejun Zhu, Ronghe Lin, Yunjie Ding
Decorating small copper nanoparticles with isolated and/or clusted oxophilic rhenium species enables the first low-copper catalytic technology for intensified and stable ethanol production under mild conditions in dimethyl oxalate hydrogenation....
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Ligand photodissociation in Ru(II)–1,4,7-triazacyclononane complexes enhances water oxidation and enables electrochemical generation of surface active species

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/C9CY02575H, Paper
Hussein A. Younus, Nazir Ahmad, Ibrahim Yildiz, Serge Zhuiykov, Shiguo Zhang, Francis Verpoort
Ligand transformations involved in metal complexes during water oxidation (WO), such as ligand decomposition, partial oxidation, or complete dissociation have been reported, however, ligand photodissociation has not been reported yet.
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Impact of edge structures on interfacial interactions and efficient visible-light photocatalytic activity of metal–semiconductor hybrid 2D materials

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00420K, Paper
Open Access
Deobrat Singh, Pritam Kumar Panda, Nabil Khossossi, Yogendra Kumar Mishra, Abdelmajid Ainane, Rajeev Ahuja
The present work systematically investigates the structural, electronic, and optical properties of MoS2/Si2BN heterostructures based on first-principles calculations.
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Homogeneous vs. Heterogeneous: Mechanistic Insights into Iron Group Metal-Catalyzed Reductions from Poisoning Experiments

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00644K, Minireview
Axel Jacobi von Wangelin, Sebastian Sandl, Dominik Gärtner
Iron group metal catalysts constitute a promising alternative to well-established noble metal catalysts in reduction reactions. However, the development of effective 3d metal catalysts has largely been hampered by their...
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Heterogenization for polyoxometalates as solid catalysts in aerobic oxidation of glycerol

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00403K, Paper
Meilin Tao, yue li, Yiming Li, Xueyan Zhang, Yurii Geletii, Xiaohong Wang, Craig L Hill
A series of heterogeneous catalysts based on phosphomolybdic salts with different Lewis metals in counter or substituent places LnPMo12O40 (L = Al3+, Fe3+, Cr3+, Ti4+, Zr4+ and Zn2+, abbreviated as...
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Photocatalytic asymmetric epoxidation of trans-stilbene with manganese–porphyrin/graphene-oxide nanocomposite and molecular oxygen: axial ligand effect

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00441C, Paper
Elahe Ahadi, Hassan Hosseini-Monfared, Alex Spieß, Christoph Janiak
An efficient, visible light-driven manganese–porphyrin photocatalyst was developed for the asymmetric epoxidation of trans-stilbene by molecular oxygen under mild conditions.
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Does the structure of CuZn hydroxycarbonate precursors affect the intrinsic hydrogenolysis activity of CuZn catalysts?

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00143K, Paper
Violetta Pospelova, Jaroslav Aubrecht, Kateřina Pacultová, Miloslav Lhotka, Oleg Kikhtyanin, David Kubička
A comparative study of the properties and activity of catalysts derived from single-phase CuZn precursors to elucidate the effect of the precursor structure on the catalyst activity in DMA hydrogenolysis and to examine replacement of CuCr catalysts.
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Facet-Dependent Activity of Hematite Nanocrystals toward Oxygen Evolution Reaction

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00655F, Paper
Toshihiro Takashima, Shota Hemmi, Qingyu Liu, Hiroshi Irie
Electrocatalytic activity of hematite exposed with different facets toward the oxygen evolution reaction (OER) was investigated. Hematite nanoparticles with pseudo cubic, hexagonal bipyramid, and plate morphologies were prepared, which predominantly...
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Synthesis of FeCo-N@N-doped carbon oxygen reduction catalysts via microwave-assisted ammoxidation

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00376J, Paper
Hung-Chih Kuo, Shou-Heng Liu, Yan-Gu Lin, Chao-Lung Chiang, Dan CW Tsang
A core-shell structured FeCo-N@N-doped carbon derived from biomass wastes (sugarcane and palm kernel shell) is facilely prepared by hydrothermal carbonization and NH3 microwave ammoxidation method. The fabricated carbons are thoroughly...
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Change SASS variable depending of subdomain

Hi,

I have a WordPress multi site (site.com / subdomain1.site.com / subdomain2.site.com), and I want to change the primary color depending of the subdomain.
I have assigned a class to the body depending of the subdomain.

I tried this :
.subdomain-1
$primary : #5E1B3C
.subdomain-2
$primary: #BE0050

But it doesn’t work. Have you got an idea of how to do this ?

Thank you !




ge

Reply To: [Solved] Background Image Not Showing

Hey guys,

Having the same issue.

Wondering if someone can confirm this,

my filepath

file:///Users/asaule/Dropbox/html5theme_1/assets/css/images/banner.jpg

HTML code;

CSS code;

#banner {

background-image: url(/images/banner.jpg);
background-attachment: fixed;
background-position: center;
/* border-top: solid 1px #005782; */
box-shadow: inset 0px 1px 5px 0px #3e484f;
padding: 35px 0 35px 0;
display: block;

}

Please let me know if you have any tips




ge

Reliance General Insurance scraps IPO plan; withdraws draft offer documents

Markets regulator Sebi had received draft red herring prospectus for the proposed IPO on February 8