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Pivotal role of starch in restoring the photocatalytic performance of chitosan films for eliminating water pollutants

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, 60,13364-13367
DOI: 10.1039/D4CC04759A, Communication
Aman Chauhan, Archana Negi, Kirti, Moondeep Chauhan, Ajeet Kaushik, Ganga Ram Chaudhary
The enhanced adsorption properties of chitosan films after starch impregnation combined with the excellent charge-transfer traits of the CdS@CuS catalyst restore the reduced photocatalytic activity towards ciprofloxacin degradation.
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Expedient (3+3)-annulation of carbonyl ylides with azaoxyallyl cations: formal access to oxa-benzo[c]azepin-3-ones

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Chem. Commun., 2024, 60,13368-13371
DOI: 10.1039/D4CC04946B, Communication
Kshitiz Verma, Hemanga Bhattacharyya, Sharajit Saha, Tharmalingam Punniyamurthy
Cascade C–C/C–N bond formation of carbonyl ylides with azaoxyallyl cations generated in situ using Rh-catalysis has been accomplished in the presence of a base at room temperature.
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Solution plasma synthesis of α-amino acids

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Chem. Commun., 2024, 60,13408-13411
DOI: 10.1039/D4CC04482G, Communication
Changhua Wang, Yutong Zhang, Yuanyuan Li, Yinhe Rong, Xintong Zhang
This work uses solution plasma for easier control of amino acid synthesis, successfully producing rare serine, achieving green and low-carbon synthesis from small molecules to amino acids.
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Polymeric membrane ion-selective electrode based on potential-modulated ion transfer: ultrasensitive measurement of oceanic pH

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Chem. Commun., 2024, 60,13404-13407
DOI: 10.1039/D4CC04807E, Communication
Lu Liu, Yuanxin Liu, Tianjia Jiang, Rongning Liang, Wei Qin
A simple approach to improve the precision of potentiometric sensors is proposed based on potential-modulated ion transfer without memory effects.
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Bipyridine-based conjugated microporous polymers for boosted photocatalytic U(VI) separation

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Chem. Commun., 2024, 60,13348-13351
DOI: 10.1039/D4CC04456H, Communication
Yun Xie, Zifan Li, Chenchen Liu, Qiming Song, Yunhai Liu, Zhibin Zhang, Bin Han
Incorporating bipyridine (BPY) units into conjugated microporous polymers (CMPs) boosts exciton dissociation, charge separation, and oxidation capacity, thereby exhibiting an admired U(VI) separation rate under sacrificial agent-free conditions.
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Universal synthesis of pure-phase IB-group Sn-based alloys with modulable electrocatalytic CO2 reduction products

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Published On ::

Chem. Commun., 2024, 60,13436-13439
DOI: 10.1039/D4CC05317F, Communication
Luyao Yang, Wenqing Zhang, Ximei Lv, Qianqian Zhao, Xiaojing Liu, Shulin Zhao, Yuhui Chen
A universal method for synthesizing a range of pure-phase IB-group Sn-based alloy catalysts (Cu3Sn, Ag4Sn, and AuSn) for electrochemical reduction of CO2.
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Site-specific acetyl modification of 2'-OH of RNA by an oligonucleotide acetylating reagent

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, 60,13440-13442
DOI: 10.1039/D4CC04672B, Communication
Hirotaka Murase, Mio Eto, Jeongsu Lee, Yosuke Taniguchi, Shuhei Imoto, Shigeki Sasaki
A novel oligonucleotide acetylating-reagent that induces a site-specific RNA acetylation through duplex formation has been developed.
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Constructing efficient organic solar cells by highly volatile solid additives with controlled phase morphology

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, 60,13424-13427
DOI: 10.1039/D4CC04675G, Communication
Yueheng Liu, Yetai Cheng, Shenbo Zhu, Zhengdong Wei, Chenyi Zhang, Shuyue Song, Xinyue Cui, Ya-Nan Chen, Andong Zhang, Yahui Liu, Hao Lu, Huawei Hu, Zhishan Bo
We synthesized two highly volatile and low-cost solid additives, PT and TFT.
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Ultrafine PtCo alloy nanoparticles integrated into porous N-doped nanosheets for durable oxygen reduction reaction

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, 60,13432-13435
DOI: 10.1039/D4CC04661G, Communication
Baoliang Chen, Lei Zhao, Zhaozhao Zhu, Pei Xiong, Zhao Li, Jun Song Chen, Lanlan Li, Rui Wu
The PtCo–CoNC–P catalyst, featuring sub-3 nm small-size PtCo alloy nanoparticles integrated into a porous nitrogen-doped nanosheet, exhibits exceptional durability after 30 000 cycles of accelerated durability tests.
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Ultra-high Li+ transfer efficiency of in situ grown membrane for high-performance batteries

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Published On ::

Chem. Commun., 2024, 60,13412-13415
DOI: 10.1039/D4CC04546G, Communication
Jian Wang, Kang Ma, Yanbo Zhang, Jiawei Chen, Xin Song, Jianmin Zhang
Lewis acid effect of in situ grown nano-Al2O3 promotes lithium salt dissociation to improve Li+ transport efficiency.
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Functional metal–organic frameworks derived electrode materials for electrochemical energy storage: a review

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, 60,13292-13313
DOI: 10.1039/D4CC04086D, Highlight
Basree, Arif Ali, Khusboo Kumari, Musheer Ahmad, Ganesh Chandra Nayak
Pristine MOFs and their derivatives have been proven for supercapacitor as well as energy storage due to their versatile features like huge specific surface area, high porosity, redox active metal centre, high thermal stability, and so on.
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Solid-state synthesis of ligand-assisted lead halide nanoclusters

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Published On ::

Chem. Commun., 2024, 60,13396-13399
DOI: 10.1039/D4CC04623D, Communication
David C. Zeitz, Kai-Chun Chou, Jin Z. Zhang
A solid-state synthesis of blue-emitting lead halide nanoclusters has been demonstrated for the first time.
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Atomistic insight into the promising thermoelectric performance of the copper-based ternary phosphide CaCuP

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, 60,13400-13403
DOI: 10.1039/D4CC04660A, Communication
Un-Gi Jong, Chol Ryu, Ji-Min Hwang, Su-Hyang Kim, Il-Gwang Ju, Chol-Jun Yu
We provide a valuable atomistic insight into the thermoelectric properties of hexagonal CaCuP, revealing that nano-structuring can double the thermoelectric figure of merit by further reducing lattice thermal conductivity.
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Enhancing the performance of ionic conductivity for solid-state electrolytes: an effective strategy of injecting lithium ions within anionic metal–organic frameworks

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, 60,13416-13419
DOI: 10.1039/D4CC04515G, Communication
Lu Shi, Xin Wang, Zhiliang Liu
An ionotropic MOF (Li+[Cu-BTC]) with lithium ions in the pores of the lattice was synthesized, which displays outstanding lithium ionic conducting properties over a wide temperature range.
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On site portable detection of gaseous I2 using green and pollution-free electrochemical methods

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05418K, Communication
Xiao-Lan Yang, Qiu-Hong Zhu, Guo-Hao Zhang, Shuang-Long Wang, Lijian Ma, Song Qin, Guo-Hong Tao, Ling He
A poly(ionic liquid) (PIL) probe material that is rich in I2 interaction sites was developed, and a green and pollution-free electrochemical method was used to detect gaseous I2 using PIL-based film sensors.
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Bioinspired hydrogels: polymeric designs towards artificial photosynthesis

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Chem. Commun., 2024, 60,13314-13324
DOI: 10.1039/D4CC04033C, Feature Article
Open Access
Reina Hagiwara, Ryo Yoshida, Kosuke Okeyoshi
This Feature Article outlines the design of polymer networks for water splitting induced by visible light to develop artificial chloroplasts. The network serves as a mediator for photoinduced electron transfer among precisely organised molecules.
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Catalytically transforming legacy phthalate esters from plastic waste into benzoic acid and benzoate plasticizers

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05158K, Communication
Open Access
Simon Windels, Dirk E. De Vos
Upcycling of plastic-waste derived phthalate plasticizers into benzoic acid via a one-pot hydrolysis–decarboxylation process using Cu2O and H-beta 75 in water.
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Investigations of the interactions between ZnO nanorods and H2 with 17O NMR spectroscopy

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Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05371K, Communication
Benteng Song, Fang Wang, Qin Zhu, Ling-Hai Xie, Luming Peng
Schematic diagram for the interaction of H2 with ZnO nanorods under different conditions.
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Intramolecular cyclization of N-aryl amides for the synthesis of 3-amino oxindoles

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05259E, Communication
Haitao Yang, Yu Pan, Yijing Tian, Kaili Yu, Yifeng Bai, Yonggang Jiang, Hongbin Zhang, Guogang Deng, Xiaodong Yang
A mild and efficient strategy to synthesize pharmaceutically important 3-amino oxindoles from readily available N-aryl amides has been developed.
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An effective orange-red solution-processed circularly polarized organic light-emitting diode

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04938A, Communication
Junqing Wang, Xiaoyi Lai, Yongzhi Zhou, Lei Hua, Weiguo Zhu, Pengfei Duan, Yafei Wang
Two orange-red emission circularly polarized thermally activated delayed fluorescence emitters (R)-ad-PXZ/(S)-ad-PXZ were synthesized. The solution processable device exhibits the maximum external quantum efficiency of 9.0% and gEL value of 10−3.
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A MOF-derived CuO/TiO2 photocatalyst for methanol production from CO2 reduction in an AI-assisted continuous flow reactor

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05008H, Communication
Bhavya Jaksani, Ruchi Chauhan, Switi Dattatraya Kshirsagar, Abhilash Rana, Ujjwal Pal, Ajay K. Singh
An AI-assisted continuous flow reactor for CO2 reduction to methanol using a MOF-derived CuO/TiO2 photocatalyst.
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Origin of anisotropic thermal transport in CsPbBr3

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05037A, Communication
Open Access
Wilarachchige D. C. B. Gunatilleke, Oluwagbemiga P. Ojo, George S. Nolas
We reveal the specific structural and bonding features that result in anisotropic thermal transport for CsPbBr3 by directional single-crystal measurements and elucidate the bases for the low Debye temperature and speed of sound.
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Synthesis of substituent-free dioxadiaza[8]circulene to investigate intermolecular interactions and photophysical properties

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05539J, Communication
Aoi Nakagawa, Wataru Ota, Takumi Ehara, Yusuke Matsuo, Kiyoshi Miyata, Ken Onda, Tohru Sato, Shu Seki, Takayuki Tanaka
Substituent-free dioxadiaza[8]circulene has been synthesized and its dense packing structure and optical properties were analyzed in detail.
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Rapid identification of P–C bonds in phosphorus–carbon anode materials

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC03317E, Communication
Yadong Ye, Qiang Xiao, Huanyu Xie, Hongchang Jin, Hengxing Ji
This work presents a simple, rapid, and convenient spectroscopic analysis method for characterizing the bonding state in phosphorus-carbon composites.
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Polarizable AMOEBA force field predicts thin and dense hydration layer around monosaccharides.

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04415K, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Luke A Newman, Mackenzie G Patton, Breyanna A Rodriguez, Ethan W Sumner, Valerie Vaissier Welborn
Polarizable force fields crucially enhance the modeling of macromolecules in polar media. Here, we present new parameters to model six common monosaccharides with the polarizable AMOEBA force field. These parameters...
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Rapid and sensitive detection of vanillylmandelic acid based on a luminescent fourteen-metal Tb(III) planar nanocluster

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC03667K, Communication
Yanheng Meng, Shiqing Wang, Xiaoli Lv, Xianfeng Huang, Wei-Bing Zhang, Xiaojun Wu, Desmond Schipper, Xiaoping Yang
A 14-metal Tb(III) nanocluster with four CO32- anions as templates was constructed for the quantitative and qualitative detection of vanillylmandelic acid (VMA) with high sensitivity and selectivity. The luminescence response...
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Palladium catalyzed C(sp3)-H alkylation of 8-methylquinolines with aziridines: access to functionalized γ-quinolinylpropylamines

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05275G, Communication
Anita Sahoo, Tripti Paul, Shubhajit Basak, Tharmalingam Punniyamurthy
Palladium-catalyzed directed site-selective C(sp3)-H alkylation of 8-methylquinolines has been accomplished using aziridine as an alkylating source via a sequential C-H and C-N bond activation. Site selectivity, funtional group tolerance and...
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Metal-free photocatalysts with charge-transfer excited states enable visible light-driven atom transfer radical polymerization

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04470C, Communication
Yuchen Huang, Yangxin Liu, Yingde Yan, Yanjun Gong, Yifan Zhang, Yanke Che, Jincai Zhao
Photoredox-catalyzed atom transfer radical polymerization (O-ATRP) offers powerful tools for the precise control of polymer synthesis. Metal-free photocatalysts are particularly desirable due to their high level of control in O-ATRP...
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Ceria-based supported metal catalysts for the low-temperature water-gas shift reaction

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04072D, Feature Article
Xin-Pu Fu, hui zhao, Chun-Jiang Jia
Water-gas shift (WGS) reaction is a crucial step for the industrial production of hydrogen or upgrading hydrogen generated from fossil or biomass sources by removing the residual CO. However, current...
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Base-Promoted Cascade 5-exo-dig Annulation/Carboxylation of o-(1-Alkynyl)benzenesulfonamides with CO2: Divergent Synthesis of Mono- or Gem-dicarboxylic Esters

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05239K, Communication
Yang Yao, Junxue Bai, Peidong Cheng, Han Yang, Jianwei Sun, Song Sun
A base-promoted cascade 5-exo-dig cyclization/carboxylation of o-alkynylsulfamides with CO2 has been accomplished, furnishing a variety of benzosultams-containing acrylates in good yields by using CO2 as the carboxylic source. Notably, in...
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Machine Learning Directed Discovery and Optimisation of a Platinum-Catalysed Amide Reduction

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05273K, Communication
Open Access
Eleonora Casillo, Benon Maliszewski, Cesar Blanco, Thomas Scattolin, Catherine Cazin, Steven P Nolan
The discovery and optimisation of reaction conditions leading to the reduction of amides, a fundamental large-scale industrial reaction, is achieved using a machine learning (ML) platform and a platinum catalyst....
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Sandwich structured Fe3O4@C@MoSe2 architecture for efficient lithium-ion storage

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04631E, Communication
Linan Yang, Chengjie Zhang, Liuyang Cao, Rong Xu, Hongbo Li, Zhanjun Yang, Juan Li
A unique sandwich structure Fe3O4@C@MoSe2 architecture is proposed for high-performance lithium storage. Carbon shell as the connection of in/external structures can not only improve the overall conductivity, but also alleviate...
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Tuneable Sulfonated Hypercrosslinked Polymers for Selective Esterification: Insights into Performance and Stability

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05208K, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Paul Schweng, Dorian Guerin-Faucheur, Freddy Kleitz, Robert Thomas Woodward
We report sulfonated hypercrosslinked polymers (SHCPs) as heterogeneous catalysts for the selective esterification of hexanoic acid with benzyl alcohol. The SHCPs demonstrate tuneable catalytic activity and selectivity, outperforming conventional acid...
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Axial oxygen-bridged FeN4O/NC produced by ultrafast joule heating for efficient oxygen reduction reaction

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05604C, Communication
Feng Liu, Xinyu Guo, Yan Zhong, Shaqi Fu, Jingsha Li, Chunmei Zhang, Heng Zhang, Fenghui Ye, Shuai Yuan, Chuangang Hu, Chunxian Guo
Herein, we report an atomically dispersed Fe-N-C catalyst with axial oxygen ligands (FeN4O/NC) firstly synthesized by ultrafast joule heating. The formation of oxygen species between FeN4 and graphene, which offers...
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Synthesis of Aryl Fluorocyclopropanes from Aryl Fluorodiazirines and Alkenes in Continuous Flow

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC01881H, Communication
Hoang-Minh To, Shima Mirakhorli, Thierry Ollevier
Photochemically induced generation of aryl fluorocarbene from arylfluorodiazirines and their subsequent [2 + 1] cycloaddition with alkenes was developed in continuous flow. The in situ generated electrophilic aryl fluorocarbene reacted...
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Copper nanoclusters: emerging photoredox catalysts for organic bond formations

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04774E, Feature Article
Open Access
Arunachalam Sagadevan, Kathiravan Murugesan, Osman M. Bakr, Magnus Rueping
In this feature article, we provide an overview of the photocatalytic capabilities of copper-based nanoclusters for organic bond-forming reactions.
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A liquid-infiltrated Al2O3 framework electrolyte enables aqueous zinc batteries

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04928D, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Rongyu Deng, Yi Yuan, Zixuan Li, Feixiang Wu, Alex W Robertson
Aqueous zinc-ion battery anodes face the twin challenges of dendrite growth and severe side reactions. Here a liquid-infiltrated Al2O3 framework electrolyte (LIAFE) is developed to address these issues and enables...
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Nickel-catalyzed stereospecific reductive cross-coupling of vinyl chlorosilanes with axially chiral biaryl electrophiles

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04293J, Communication
Tiantian Yin, Shiyuan Sui, Shuqi Li, Junbiao Chang, Dachang Bai
Nickel-catalyzed stereospecific reductive cross-coupling of vinyl chlorosilanes with chiral biaryl electrophiles for the synthesis of axially chiral organosilanes.
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Laccase-catalyzed tyrosine click reaction with 1-methyl-4-arylurazole: rapid labeling on protein surfaces

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC03802A, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Keita Nakane, Chizu Fujimura, Shogo Miyano, Zhengyi Liu, Tatsuya Niwa, Hafumi Nishi, Tetsuya Kadonosono, Hideki Taguchi, Shusuke Tomoshige, Minoru Ishikawa, Shinichi Sato
Our study shows efficient tyrosine labeling using 1-methyl-4-arylurazole (MAUra) with laccase under mild conditions. This method achieves a high efficiency (kcat/Km = 7.88 × 104 M−1 s−1), selectively targeting exposed tyrosine sites on proteins.
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Iron-catalysed intramolecular C(sp3)–H amination of alkyl azides

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04169K, Feature Article
Open Access
Kai Wu, Chi-Ming Che
This review summarizes recent major advances in iron-catalysed C–H aminations of alkyl azides through iron–alkylnitrene/alkylimido intermediates to access various N-heterocycles.
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Positional effects of electron-donating and withdrawing groups on the photophysical properties of single benzene fluorophores

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04451G, Communication
Dopil Kim, Jun Yeong Kim, Haein Kim, Eunjin Jeong, Minhyuk Lee, Dongwook Kim, JunWoo Kim, Myung Hwan Park, Min Kim
We investigated how the positional arrangement of electron-donating (amino) and electron-withdrawing (ester) groups in single benzene-based fluorophores influences their emission properties. By synthesizing 26 regioisomeric fluorophores, we achieved wavelength modulation...
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Sustainable Production of Aromatic Chemicals from Lignin using Enzymes and Engineered Microbes

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Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05064A, Feature Article
Open Access
Timothy D.H. Bugg, Victoria Sodré
Lignin is an aromatic biopolymer found in plant cell walls, that is the must abundant source of renewable aromatic carbon in the biosphere. Hence there is considerable interest in the...
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For the love of legiyam

By www.thehindu.com
Published On :: Fri, 28 Oct 2016 16:49:22 +0530

SRINIVASA RAMANUJAM queues up to find out what goes into this Deepavali preparation at the iconic Dabba Chetty Shop in Mylapore


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Fragrance of composite culture

By www.thehindu.com
Published On :: Mon, 31 Oct 2016 15:34:20 +0530

Atiya Zaidi brings the flavours of the Doab to the city and leaves RAHUL VERMA licking his fingers


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The wonders of veganism

By www.thehindu.com
Published On :: Tue, 01 Nov 2016 15:27:50 +0530

The latest trend in the food space is going off milk and meat. Read on and find out where Bengaluru stands on this


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Feeling peckish?

By www.thehindu.com
Published On :: Thu, 03 Nov 2016 16:39:46 +0530

Head to the Bird on Tree and choose from a variety of cuisines


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A garden, some magic and food memories

By www.thehindu.com
Published On :: Thu, 03 Nov 2016 17:47:46 +0530

The leisurely ambience of Soul Garden Bistro and 196* Below Dessert Lab offers you a chance to sit back and relax


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Hot from the oven

By www.thehindu.com
Published On :: Thu, 10 Nov 2016 14:46:07 +0530

Prasobhithan S. of Bread Fort Bakery at Chakka on why his homemade bakes sell like hot cakes


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In the creative universe of Raghu Rai

By www.thehindu.com
Published On :: Thu, 10 Nov 2016 16:51:14 +0530

The internationally-acclaimed photographer tells us how he enjoys his work and food


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‘Our food is about love’

By www.thehindu.com
Published On :: Fri, 11 Nov 2016 14:02:14 +0530

Osama Jalali says plating and presentation were not the focus of traditional Indian cuisine


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