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Electrostatic vs. electronic interactions within oxidized multinuclear Pt(bipyridine)(dithiolene) complexes

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02514H, Paper
Khalil Youssef, Antoine Vacher, Thanaphon Khrueawatthanawet, Thierry Roisnel, Frédéric Barrière, Dominique Lorcy
Multinuclear complexes involving two or three redox active Pt(dithiolene) moieties were synthesized and electronic interactions were analysed through a combination of experimental and theoretical investigations.
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Ruthenium, copper and ruthenium–copper complexes of an unsymmetrical phosphino pyridyl 1,8-naphthyridine PNNN ligand

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, 53,18037-18046
DOI: 10.1039/D4DT02755H, Paper
Jingyun Wu, Michael A. Stevens, Michael G. Gardiner, Annie L. Colebatch
A new unsymmetrical dinucleating PNNN ligand is reported, the versatility of which is demonstrated by formation of heterobimetallic, homobimetallic and monometallic complexes.
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Tunability of triplet excited states and photophysical behaviour of bis-cyclometalated iridium(III) complexes with imidazo[4,5-f][1,10]phenanthroline

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, 53,17934-17947
DOI: 10.1039/D4DT01996B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Katarzyna Choroba, Joanna Palion-Gazda, Mateusz Penkala, Patrycja Rawicka, Barbara Machura
The impact of cyclometalating ligands on the photophysical behaviour of heteroleptic Ir(III) complexes with imidazo[4,5-f][1,10]phenanthroline. [Ir(ppy)2(imphen)]+ is a 3MLLCT emitter, while [Ir(pybzth)2(imphen)]+ has a predominant 3LCN∩C character.
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An acidity-triggered aggregation nanoplatform based on degradable mesoporous organosilica nanoparticles for precise drug delivery and phototherapy of focal bacterial infection

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, 53,17893-17901
DOI: 10.1039/D4DT02111H, Paper
Yunhan Huang, Wei Guo, Xinyu Wang, Jingrui Chang, Bo Lu
An acidity-triggered aggregation antibacterial nanoplatform based on biodegradable mesoporous organic silica nanoparticles, is reported. It enables precise drug release and spatial accuracy for photodynamic therapy and photothermal therapy.
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Riding the hurdles with a winning spirit

By www.thehindu.com
Published On :: Wed, 29 Mar 2023 16:29:28 +0530

Meet Agasthi Chandrasekhar from Hyderabad, the first Indian to win a medal in the BMX National Series 2023-Series 1


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Photoelectrochemical nitrate denitrification towards acidic ammonia synthesis on copper-decorated black silicon

By pubs.rsc.org
Published On ::

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE04438J, Paper
Yuchan Li, Qi Zhang, Huan Dai, Dong He, Zunjian Ke, Xiangheng Xiao
This work highlights the exceptional performance and great potentials of a Cu nanoparticle decorated silicon nanowire arrays (Cu–Si NWs) for photoelectrocatalytic nitrate reduction to ammonia in acidic electrolyte and in realistic wastewater.
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Theoretical calculations-driven rational screening of d-block single-atom electrocatalysts based on d-p orbital hybridization for durable aqueous zinc-iodine batteries

By pubs.rsc.org
Published On ::

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04119D, Paper
Jin Yang, Yuanhong Kang, Fanxiang Meng, weiwei meng, guanhong Chen, Minghao Zhang, Zeheng Lv, Zhipeng Wen, Chengchao Li, Jinbao Zhao, Yang Yang
Aqueous Zn−iodine (Zn-I2) batteries, featuring intrinsically high-safety aqueous electrolytes and eco-friendly cathode/anode materials, however are restricted by the shuttling of polyiodide and sluggish redox kinetics of iodine redox. Although various...
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Unveiling nanoscale fluid miscible behaviors with nanofluidic slim-tube

By pubs.rsc.org
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Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE02292K, Paper
Zengding Wang, Tianjiang Zhang, Shanchao Liu, Keli Ding, Tengyu Liu, Jun Yao, Hai Sun, Yongfei Yang, Lei Zhang, Wendong Wang, Cunqi Jia, Mojdeh Delshad, Kamy Sepehrnoori, Junjie Zhong
We developed a nanofluidic method to visualize fluid miscible behaviors in nanoscale and multiscale porous media. Nano-confinement reduces MMP, while multiscale structures increase MMP, unveiling distinct miscible stages.
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Tuning the Co pre-oxidation process of Co3O4via geometrically reconstructed F–Co–O active sites for boosting acidic water oxidation

By pubs.rsc.org
Published On ::

Energy Environ. Sci., 2024, 17,8820-8828
DOI: 10.1039/D4EE03982C, Paper
Yi Wang, Pu Guo, Jing Zhou, Bing Bai, Yifan Li, Mingrun Li, Pratteek Das, Xianhong Wu, Linjuan Zhang, Yi Cui, Jianping Xiao, Zhong-Shuai Wu
Optimizing the Co pre-oxidation process of Co3O4 through geometric reconstruction of F−Co−O active sites significantly enhances the performance for acidic water oxidation.
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Lakshmi Swaminathan on how legendary architect Didi Contractor imagined spaces

By www.thehindu.com
Published On :: Fri, 08 Nov 2024 09:00:00 +0530

‘Didi evocatively narrated her designs as stories as she drew. By living her ideals in day-to-day life, she introduced me to an elegantly simple lifestyle,’ says Didi’s student Lakshmi Swaminathan


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Development of an automated platform for monitoring microfluidic reactors through multi-reactor integration and online (chip-)LC/MS-detection

By pubs.rsc.org
Published On ::

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00004H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Hannes Westphal, Simon Schmidt, Sanjay Lama, Matthias Polack, Chris Weise, Toni Oestereich, Rico Warias, Tanja Gulder, Detlev Belder
Biocatalysis with packed-bed microreactors: a novel method combining microreactor technology, multi-reactor integration, and online (chip-)LC/MS analysis in a sequential automated workflow.
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A safe and new strategy for N-arylation of 2,4-thiazolidinediones via microwave irradiation using base catalyst K2CO3 in DMF

By pubs.rsc.org
Published On ::

React. Chem. Eng., 2024, 9,842-848
DOI: 10.1039/D3RE00641G, Paper
Ragini C. Patil, Nita M. Khiratkar, Sumeer Ahmed, Joazaizulfazli Jamalis, Aso Hameed Hasan, Malika Berredjem, Sarkar M. A. Kawsar, Ajmal R. Bhat
Green efforts as an alternative to existing conventional methods for providing new tools, knowledge and design of organic synthesis, will contribute to the economy and protecting the environment and health.
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Effects of Clostridium butyricum and inulin supplementation on intestinal microbial composition in high-fat diet fed mice

By pubs.rsc.org
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Food Funct., 2024, 15,10870-10884
DOI: 10.1039/D4FO02963A, Paper
Jing Liu, Suhua Zhang, Huachun Weng
Clostridium butyricum and inulin could improve dislipidemia, abnormal glucose tolerance and change intestinal microbial composition in high-fat diet (HFD) mice, increasing Parabacteroides, Bacteroides and Ruminococcaceae and regulating FGF21.
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Gastroprotective effects of Pediococcus acidilactici GKA4 and Lactobacillus brevis GKL93 against ethanol-induced gastric ulcers via regulation of the immune response and gut microbiota in mice

By pubs.rsc.org
Published On ::

Food Funct., 2024, Advance Article
DOI: 10.1039/D4FO04106B, Paper
Yun-En Huang, Sheng-Yi Chen, Tsung-Ju Li, You-Shan Tsai, Chin-Chu Chen, Gow-Chin Yen
Pediococcus acidilactici GKA4 and Lactobacillus brevis GKL93 exert gastroprotective effects against ethanol-induced gastric ulcers through multiple mechanisms.
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Characterisation and quantification of phenolic, anthocyanidin and terpene species in plant foods and plant food-based complementary products with antioxidant and neuroprotective properties

By pubs.rsc.org
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Food Funct., 2024, Advance Article
DOI: 10.1039/D4FO02942A, Paper
Naomi May, Jiahua Shi, Helen Clunas, Julianna Lys de Sousa Alves Neri, Celine Kelso, Jody Morgan, Yinghua Yu, Karen Charlton, Katrina Weston-Green
Phytochemicals, including phenolic compounds and terpenes, are of interest for the treatment and prevention of conditions with oxidative stress, inflammatory and neurodegenerative pathologies.
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Alleviating effect of whey protein supplementation on oxidative stress in hypothyroidism

By pubs.rsc.org
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Food Funct., 2024, 15,11158-11168
DOI: 10.1039/D4FO03186E, Paper
Ann Liya Sajan, Jenat Pazheparambil Jerom, Bhagyasree Rajasekharan Nair, Devanandana Dileep Kumar Sajitha, Reshma Soman, Ajmal Jalal, Raveendran Harikumaran Nair
Supplementation with whey protein is effective for treating hypothyroidism-associated oxidative stress by enhancing the antioxidant system, reducing lipid peroxidation and maintaining cellular ionic balance.
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Avoiding digital arrest

By www.thehindubusinessline.com
Published On :: Thu, 07 Nov 2024 20:34:40 +0530

Stay informed, don’t share personal information


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Nilakanta Sastri’s take on Dravidian-Aryan divide and the claims on the Indus Valley Civilisation

By www.thehindu.com
Published On :: Tue, 12 Nov 2024 22:51:49 +0530

In his lectures at Patna University in 1964, Sastri quotes J. Burrow, Professor of Oxford University, who had suggested that “Vedic speech was influenced not by the Dravidian languages of history as we know them, but by an earlier form, a sort of proto-Dravidian, which has long preceded them as well as Aryan advent into India”


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Ultrasmall RuO2/CoFe2O4 nanoparticles with robust interfacial interactions for the enhanced acidic oxygen evolution reaction

By pubs.rsc.org
Published On ::

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00719K, Paper
Open Access
Ming Wei, Liuhua Mu, Zhiwei Liu, Feng Gao, Guangjian Song, Qiankang Si, Mao Zhang, Fangfang Dai, Min Zhang, Rui Ding, Li Yang, Zhonggui Gao, Sanzhao Song
Ultrasmall RuO2/CoFe2O4 nanoparticles with strong interfacial interactions exhibit enhanced oxygen evolution reaction (OER) performance, driven by efficient charge transfer between RuO2 and CoFe2O4.
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New insights into influences of initial oxidization states on dynamic reconstruction of Cu catalysts and C–C coupling in CO2 reduction

By pubs.rsc.org
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Catal. Sci. Technol., 2024, 14,6224-6232
DOI: 10.1039/D4CY00781F, Paper
Chen Qin, Xuheng Li, Haoyang Li, Ting Wang, Xue Zhang, Yuyao Wang, Fuping Pan, Kai-Jie Chen
The spontaneous oxidization/reduction of the Cu surface occurs during CO2 reduction, resulting in the dynamic evolution of i-CuOx species. The in situ formed i-CuOx plays decisive roles in promoting C–C coupling.
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A metal-free route to substituted imidazolidines via ring-opening cyclization (ROC) of activated aziridines with N-benzylanilines: DA-COP catalyzed photo-oxidative C–H activation

By pubs.rsc.org
Published On ::

Catal. Sci. Technol., 2024, 14,6411-6419
DOI: 10.1039/D4CY00808A, Paper
Manish Kumar, Bharat Singh, Sugandha Singh, Indresh Verma, Kamal K. Kar, Manas K. Ghorai
A metal-free, conjugated organic polymer (TPA-PQ)-catalyzed intramolecular C–H functionalization strategy for the synthesis of imidazolidines in the presence of light and O2 is reported.
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Experimental and DFT study of the MoO2@Fe2O3 catalyst for overall water splitting in acidic and alkaline electrolytes

By pubs.rsc.org
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00779D, Paper
Suchitra N. Sapakal, Arvind Singh, Ayesha Khan, Mayur Gaikwad, Jin H. Kim, Anamika Kadam
HER: overpotential for HER, OER: overpotential for OER; Rs: solution resistance, Rct: charge transfer resistance. The comparison of various parameters of the MoO2@Fe2O3 electrode in KOH and H2SO4 electrolytes.
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Effects of zeolite porosity and acidity on catalytic conversion of carbohydrates to bio-based chemicals: a review

By pubs.rsc.org
Published On ::

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01070A, Review Article
Deyu Chu, Jinjing Ma, Qishun Liu, Jie Fu, Heng Yin
Optimizing the production process of high value-added chemicals derived from renewable biomass holds immense promise for clean energy utilization and environmental sustainability.
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Synergistic promotion of oxygen vacancy and Lewis acidity of Nb2O5 on the preferential hydroxymethyl hydrogenolysis of 5-hydroxymethylfurfural catalyzed by single atom Pt

By pubs.rsc.org
Published On ::

Catal. Sci. Technol., 2024, 14,6550-6560
DOI: 10.1039/D4CY00559G, Paper
Ting-Hao Liu, Shuai Fu, Jin-Tao Gou, Yin-Sheng Zhang, Chang-Wei Hu, Hua-Qing Yang
Over Pt1/Nb2O5, oxygen vacancy increases the catalytic activity, while the strong Lewis acidity of Nb2O5 selectively promotes the hydrogenolysis of the –CH2OH group rather than the hydrogenation of the –CHO group.
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Boron–pyridine nitrogen cooperative catalytic conversion of carbon dioxide and epoxides to cyclic carbonates

By pubs.rsc.org
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Catal. Sci. Technol., 2024, 14,6692-6700
DOI: 10.1039/D4CY01052C, Paper
Yu-Hui Luo, Sheng Tao, Fei Chen, Zhi-Hong Du, Hao Zhang, Min Li, Ning Liu
A type of N-heterocyclic carbene (NHC)-diboron adduct in combination with tetrabutylammonium iodide (TBAI) was used as a catalyst for the synthesis of cyclic carbonates from CO2 with epoxides.
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Unspecific peroxygenase immobilization in 3D-printed microfluidics: towards tailor-made screening platforms

By pubs.rsc.org
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Catal. Sci. Technol., 2024, 14,6496-6502
DOI: 10.1039/D4CY00869C, Communication
Elena Gkantzou, Theofilia Koulopoulou, Hannah Brass, David Schönauer, Anton Glieder, Selin Kara
In the context of empowering biocatalysis, an easy-to-develop, reproducible, and easy-to-scale biocatalytic system is demonstrated as a microfluidic screening platform.
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Preceramic polymer hybridized phenolic aerogels and the derived ZrC/SiC/C ceramic aerogels with ultrafine nanocrystallines

By pubs.rsc.org
Published On ::

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03470H, Paper
Ding Nie, Hangyu Zhong, Hongli Hu, Zhenhua Luo, Boxing Zhang
Phenolic and carbon aerogels have important applications for thermal insulation and ablative resistance materials in aerospace areas. However, their antioxidant ability in long-term and high-temperature aerobic environments is facing serious...
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N-Halaminated spermidine-containing polymeric coating enables titanium to achieve dual functions of antibacterial and osseointegration

By pubs.rsc.org
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Biomater. Sci., 2024, Advance Article
DOI: 10.1039/D4BM00061G, Paper
Hang Ren, Peng Wang, Hanwen Huang, Junshen Huang, Yuheng Lu, Yanfeng Wu, Zhongyu Xie, Youchen Tang, Zhaopeng Cai, Huiyong Shen
Modified Ti with a porous N-halaminated spermidine-containing polymeric coating is constructed, and it has both excellent antibacterial and osteogenic abilities to enhance osseointegration, making it potentially applicable in orthopedics.
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Correction: Clodronate-nintedanib-loaded exosome–liposome hybridization enhances the liver fibrosis therapy by inhibiting Kupffer cell activity

By pubs.rsc.org
Published On ::

Biomater. Sci., 2024, Advance Article
DOI: 10.1039/D4BM90028F, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Keqin Ji, Mingrui Fan, Dong Huang, Lingna Sun, Bingqin Li, Ruoting Xu, Jiajing Zhang, Xuan Shao, Yanzuo Chen
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Aca Sports Counselling in Hyderabad integrates sports and academics, providing personalised guidance to athletes

By www.thehindu.com
Published On :: Wed, 27 Mar 2024 15:25:38 +0530

Padmavathi Devarakonda’s Aca Sports Counselling in Hyderabad blends the spirit of sports with academic guidance to help aspiring athletes achieve their dreams


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Fibreglass sculpture of Rani Gaidinliu ready for installation at TFFM in Tajangi

By www.thehindu.com
Published On :: Fri, 08 Nov 2024 08:40:04 +0530


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Nvidia to take Intel's spot on Dow Jones Industrial Average

By www.thehindu.com
Published On :: Sat, 02 Nov 2024 09:57:26 +0530

This development comes a day after Intel expressed optimism about the future of its PC and server businesses, projecting current-quarter revenue above estimates but warning that it had “a lot of work to do”


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Facebook, Nvidia ask U.S. Supreme Court to spare them from securities fraud suits

By www.thehindu.com
Published On :: Tue, 05 Nov 2024 09:20:57 +0530

The U.S. Supreme Court is set to consider bids by two tech giants - Meta's Facebook and Nvidia - to fend off federal securities fraud lawsuits in separate cases


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Nvidia surpasses Apple as world's biggest company

By www.thehindu.com
Published On :: Wed, 06 Nov 2024 08:27:16 +0530

Chip-making giant Nvidia surpassed Apple on Tuesday to become the highest valued company in the world


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Nvidia surpasses $3.6 trillion market value after Trump win

By www.thehindu.com
Published On :: Fri, 08 Nov 2024 08:26:40 +0530

Shares of Nvidia rallied to a record high on Thursday, making the chipmaker the first company in history to surpass a stock market value of $3.6 trillion as Wall Street extended a rally sparked by Donald Trump's return


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Humidity controls supramolecular self-assembly

By cen.acs.org
Published On :: 01 Jun 2018 00:29:53 +0000

Trace water that gets into organic solvents can participate actively when molecules start to self-assemble


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Fish struggle to smell in acidic oceans

By cen.acs.org
Published On :: 25 Jul 2018 18:39:06 +0000

Rising CO2 levels could stop fish finding food and detecting predators


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XUV700 is a powerhouse hiding under a gentle beast

By www.rediff.com
Published On :: Sat, 21 Aug 2021 09:48:39 +0530

Is the XUV700 just a facelifted XUV500 or is it a completely new breed in the vast range of SUVs available today? Rajesh Karkera takes the latest offering from the Mahindra stable for a spin to find out.


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Pix: The stunning Jeep Meridian is here!

By www.rediff.com
Published On :: Tue, 03 May 2022 15:33:43 +0530

Jeep India, a part of automotive group Stellantis, on Tuesday announced the opening of bookings for its upcoming SUV Meridian, the production of which has also commenced from its joint venture manufacturing facility at Ranjangaon, Maharashtra.Customers can book the Meridian either at Jeep India dealership network or through the company's website with a down payment of Rs 50,000.Deliveries of the vehicle will start in June, it said in a statement.


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Jeep's comeback vehicle Meridian lacks the bite

By www.rediff.com
Published On :: Wed, 29 Jun 2022 09:30:00 +0530

The Meridian feels comfortable and upright with the quality of gadgetry, interiors and plastics expected from an international brand car.However, it lacks the overall premium-ness that may come with a top-end Japanese car or even a mid-range German car, says Pavan Lall.


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Solid phase peptide synthesis using side-chain unprotected arginine and histidine with Oxyma Pure/TBEC in green solvents

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,10929-10939
DOI: 10.1039/D4GC03209H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tommaso Fantoni, Andrea Orlandin, Ilaria Di Stefano, Marco Macis, Alessandra Tolomelli, Antonio Ricci, Walter Cabri, Lucia Ferrazzano
Oxyma Pure/TBEC coupling protocol in green solid phase peptide synthesis (GSPPS) eliminates protective groups on Arg and His, enhancing atom economy and reducing impurities during cleavage. The technology was extended to side-chain-free Tyr and Trp.
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Green synthesis of N-sulfonyl amidine using a CuI-incorporated CoFe2O4 nano-catalyst in aqueous medium

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04033C, Paper
Samrat Charaimuria, Prodeep Phukan
A magnetically separable nanocatalyst has been developed by the incorporation of CuI on the functionalized surface of cobalt ferrite nanoparticles for the synthesis of N-sulfonyl amidines in aqueous medium at ambient temperature.
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Photocatalytic acylation of lysine screened using a microfluidic-based chemical robotic system

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,11238-11248
DOI: 10.1039/D4GC03562C, Paper
Zhanfeng Hou, Chuan Wan, Heming Jiang, Yuena Wang, Yun Xing, Jinpeng Wang, Zhihong Liu, Xiaochun Guo, Yuhao An, Wei Han, Rui Wang, Xinhao Zhang, Feng Yin, Zigang Li
In our work, we contribute to the photoredox catalytic lysine acylation in proteins and peptides. The optimal reaction conditions were obtained using a high-throughput microfluidic-based chemical robotic system and GPR model.
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High-efficient green catalytic conversion for waste CS2 by non-noble metal cage-based MOFs: An access to high-valued thiazolidine-2-thione

By pubs.rsc.org
Published On ::

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04541F, Paper
Wenyu Ding, Xinyu Tang, Sheng Jin, Zhao Li, Dongwei Xu, Xiaomin Kang, Zhiliang Liu
Green and effective disposal of Carbon disulfide (CS2) waste into high-valued chemicals under mild conditions is meaningful and challenging. Herein, a novel 3D cluster-based metal-organic framework (MOF) {(Me2NH2)2[Co3(µ3-O)(XN)(BDC)3]∙4DMF∙5MeOH}n (compound 1)...
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Khot ridicules Sharad Pawar’s face, Ajit Pawar objects

By indianexpress.com
Published On :: Wed, 06 Nov 2024 21:57:44 +0000


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Superstar Vijay is taking on Dravidian parties. But how different is his TVK from them?

By indianexpress.com
Published On :: Mon, 28 Oct 2024 12:23:30 +0000


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