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Drums of war, drums of development : the formation of a Pacific ruling class and industrial transformation in East and Southeast Asia, 1945-1980 / by Jim Glassman

Glassman, Jim, author




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International trade : theory & policy / Paul R. Krugman (Princeton University), Maurice Obstfeld (University of California, Berkeley), Marc J. Melitz (Harvard University)

Krugman, Paul R., author




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Employment relations : theory and practice / Mark Bray, Peter Waring, Rae Cooper, Johanna Macneil

Bray, Mark, author




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General Manager's report into developments in making enterprise agreements under the Fair Work Act 2009 (Cth) 2015-2018 / Bernadette O'Neill, General Manager

O'Neill, Bernadette, author




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General Manager's report into the operation of the provisions of the National Employment Standards relating to requests for flexible working arrangements and extensions of unpaid parental leave under s.653 of the Fair Work Act 2009 (Cth) 2015-2018 /

O'Neill, Bernadette




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Economic analysis, moral philosophy, and public policy / Daniel Hausman (University of Wisconsin, Madison), Michael McPherson (Spencer Foundation, Chicago), Debra Satz (Stanford University)

Hausman, Daniel M., 1947- author




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Global capitalism, global war, global crisis / Andreas Bieler (University of Nottingham), Adam David Morton (University of Sydney)

Bieler, Andreas, 1967- author




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Central Bank frameworks : evolution or revolution? : proceedings of a conference held in Sydney on 12-13 April 2018 / editors: John Simon, Maxwell Sutton

Central Bank Frameworks Evolution or Revolution Conference (2018 : Sydney, N.S.W.)




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The global challenge of encouraging sustainable living : opportunities, barriers, policy and practice / edited by Shane Fudge, Michael A. Peters, Steven M. Hoffman, Walter Wehrmeyer




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United Nations sustainable development goals (SDG) / The Senate Foreign Affairs, Defence and Trade References Committee

Australia. Parliament. Senate. Foreign Affairs, Defence and Trade References Committee, author, issuing body




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Capitalism : a conversation in critical theory / Nancy Fraser and Rahel Jaeggi ; edited by Brian Milstein

Fraser, Nancy, author




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You can't kill the spirit : women in a Welsh mining village / Jill Miller

Miller, Jill




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A Companion to U.S. Foreign Relations: Colonial Era to the Present


 

Covers the entire range of the history of U.S. foreign relations from the colonial period to the beginning of the 21st century.

A Companion to U.S. Foreign Relations is an authoritative guide to past and present scholarship on the history of American diplomacy and foreign relations from its seventeenth century origins to the modern day. This two-volume reference work presents a collection of historiographical essays by prominent scholars. The essays



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A Left that Dares to Speak Its Name: 34 Untimely Interventions


 

With irrepressible humor, Slavoj Žižek dissects our current political and social climate, discussing everything from Jordan Peterson and sex “unicorns” to Greta Thunberg and Chairman Mao. Taking aim at his enemies on the Left, Right, and Center, he argues that contemporary society can only be properly understood from a communist standpoint.

Why communism? The greater the triumph of global capitalism, the more its dangerous antagonisms multiply: climate



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A Left that Dares to Speak Its Name: 34 Untimely Interventions


 

With irrepressible humor, Slavoj Žižek dissects our current political and social climate, discussing everything from Jordan Peterson and sex “unicorns” to Greta Thunberg and Chairman Mao. Taking aim at his enemies on the Left, Right, and Center, he argues that contemporary society can only be properly understood from a communist standpoint.

Why communism? The greater the triumph of global capitalism, the more its dangerous antagonisms multiply: climate



Read More...




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Cascade polymerizations: recent developments in the formation of polymer repeat units by cascade reactions

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01475C, Perspective
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Gregory I. Peterson, Tae-Lim Choi
Cascade polymerizations provide new routes to unique polymer structures. In this perspective, we summarize their performance, monomer scope, and mechanisms.
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Spectroscopic investigations under whole-cell conditions provide new insight into the metal hydride chemistry of [FeFe]-hydrogenase

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00512F, Edge Article
Open Access
Lívia S. Mészáros, Pierre Ceccaldi, Marco Lorenzi, Holly J. Redman, Emanuel Pfitzner, Joachim Heberle, Moritz Senger, Sven T. Stripp, Gustav Berggren
The mechanism of hydrogen gas formation by [FeFe] hydrogenase is probed under whole cell conditions, revealing the formation of reactive metal hydride species under physiologically relevant conditions.
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Structure-mechanics statistical learning unravels the linkage between local rigidity and global flexibility in nucleic acids

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00480D, Edge Article
Open Access
Yi-Tsao Chen, Haw Yang, Jhih-Wei Chu
The mechanical properties of nucleic acids underlie biological processes ranging from genome packaging to gene expression. We devise structural mechanics statistical learning method to reveal their molecular origin in terms of chemical interactions.
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When Hollow Multi-Shelled Structures (HoMSs) Meet Metal-Organic Frameworks (MOFs)

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01284J, Perspective
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zumin Wang, Nailiang Yang, Dan Wang
Hollow multishelled structures (HoMSs) have distinguished advantages, such as large effective surface area, short mass transport route, and high loading capacity, but the fabrication of HoMS was a big challenge....
The content of this RSS Feed (c) The Royal Society of Chemistry




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Transformation from helical to layered supramolecular organization of asymmetric perylene diimides via multiple intermolecular hydrogen bonding

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01911A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Mengmeng Li, Wojciech Zajaczkowski, Gangamallaiah Velpula, Daniel Jänsch, Robert Graf, Tomasz Marszalek, Sapun H. Parekh, Yulian Zagranyarski, Kunal Mali, Manfred Wagner, Steven De Feyter, Chen Li, Klaus Müllen, Wojciech Pisula
The solid-state supramolecular organization of asymmetric perylene diimide is transformed from helical to layered self-assembly after thermal annealing.
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Covalent Organic Frameworks as Microreactors: Confinement-enhanced Electrochemiluminescence

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01817A, Edge Article
Open Access
Wei-Jia Zeng, Kun Wang, Wenbin Liang, Yaqin Chai, Ruo Yuan, Ying Zhuo
Herein, the electrochemiluminescence (ECL) microreactors with enhanced intensity and extreme stability were firstly established by the assembly of tris(2,2’-bipyridyl) ruthenium (II) (Ru(bpy)32+) onto the covalent organic frameworks (COFs) where a...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Crystallographic facet selective HER catalysis: exemplified in FeP and NiP2 single crystals

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00676A, Edge Article
Open Access
Bryan Owens-Baird, Juliana P. S. Sousa, Yasmine Ziouani, Dmitri Y. Petrovykh, Nikolai A. Zarkevich, Duane D. Johnson, Yury V. Kolen'ko, Kirill Kovnir
The effect of the crystal structure of ordered transition-metal phosphide catalysts on the hydrogen-evolution reaction is investigated using single crystals of iron-phosphide (FeP) and monoclinic nickel-diphosphide (m-NiP2).
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Introduction of a 7-aza-6-MeO-indoline auxiliary in Lewis-acid/photoredox cooperative catalysis: highly enantioselective aminomethylation of α,β-unsaturated amides

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01890B, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Santosh K. Pagire, Naoya Kumagai, Masakatsu Shibasaki
An efficient cooperative chiral Lewis acid and photoredox catalytic system towards the highly enantioselective radical conjugate addition of α-amino radicals to α,β-unsaturated amides is developed with the implementation of unique auxiliaries.
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Water-induced formation of an alkali-ion dimer in cryptomelane nanorods

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01517B, Edge Article
Open Access
Shaobo Cheng, Vidushi Sharma, Altug S. Poyraz, Lijun Wu, Xing Li, Amy C. Marschilok, Esther S. Takeuchi, Kenneth J. Takeuchi, Marivi Fernández-Serra, Yimei Zhu
Water displaces potassium ions and initiates the formation of a homonuclear dimer ion (K2+) in the tunnels of hollandite.
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Structure of Copper sites in Zeolites Examined by Fourier and Wavelet Transform Analysis of EXAFS

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01472A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Vitaly L. Sushkevich, Olga V. Safonova, Dennis Palagin, Mark A Newton, Jeroen van Bokhoven
Copper-exchanged zeolites are a class of redox-active materials that find application in the selective catalytic reduction of exhaust gases of diesel vehicles, and, more recently, the selective oxidation of methane...
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Efficient alkene hydrosilation with bis(8-quinolyl)phosphine (NPN) nickel catalysts. The dominant role of silyl-over hydrido-nickel catalytic intermediates

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00997K, Edge Article
Open Access
Jian Yang, Verònica Postils, Michael I. Lipschutz, Meg Fasulo, Christophe Raynaud, Eric Clot, Odile Eisenstein, T. Don Tilley
A cationic nickel complex of the bis(8-quinolyl)(3,5-di-tert-butylphenoxy)phosphine (NPN) ligand, [(NPN)NiCl]+, is a precursor to efficient catalysts for the hydrosilation of alkenes with hydrosilanes under mild conditions and low catalyst loadings.
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Triblock polyester thermoplastic elastomers with semi-aromatic polymer end blocks by ring-opening copolymerization

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00463D, Edge Article
Open Access
Georgina L. Gregory, Gregory S. Sulley, Leticia Peña Carrodeguas, Thomas T. D. Chen, Alba Santmarti, Nicholas J. Terrill, Koon-Yang Lee, Charlotte K. Williams
A new series of block polyester thermoplastic elastomers are prepared by a one-pot procedure; they show properties competitive or better than conventional materials and can be fully degraded after use.
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Protease-Responsive Mass Barcoded Nanotranslaters for Simultaneously Quantifying the Intracellular Activity of Cascaded Caspases in Apoptosis Pathways

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01534B, Edge Article
Open Access
Hongmei Xu, Xiaodan Huang, Zhenzhen Zhang, xuemeng zhang, Qianhao Min, Jun-Jie Zhu
Quantitatively delineating the activation network of multiple proteases that participate in cellular processes is highly essential to understanding physiological and pathological states of cells. In this study, protease-responsive mass barcoded...
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Nickel catalysis enables convergent paired electrolysis for direct arylation of benzylic C–H bonds

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01445A, Edge Article
Open Access
Lei Zhang, Xile Hu
A direct arylation of benzylic C–H bonds is achieved by integrating Ni-catalyzed benzyl–aryl coupling into convergent paired electrolysis.
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Regioselective B(3,4)–H Arylation of o-Carboranes by Weak Amide Coordination at Room Temperature

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01515F, Edge Article
Open Access
Yu-Feng Liang, Long Yang, Becky Bongsuiru Jei, Rositha Kuniyil, Lutz Ackermann
Palladium-catalyzed regioselective di- or mono-arylation of o-carboranes was achieved by weakly coordinating amides at room temperature. Thereby, a series of B(3,4)-diarylated and B(3)-monoarylated o-carboranes anchored with valuable functional groups were...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Rapidly Self-deoxygenating Controlled Radical Polymerization in water via in-situ Disproportionation of Cu(I)

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01512A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
David Haddleton, Evelina Liarou, Yisong Han, Marc Walker, Ana Sanchez
The first rapidly self-deoxygenating Cu-RDRP in aqueous media is investigated. The disproportionation of Cu(I)/Me6Tren in water towards Cu(II) and highly reactive Cu(0) leads to O2-free reaction environments within the first...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Biofunctional Janus Particles Promote Phagocytosis of Tumor Cells by Macrophages

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01146K, Edge Article
Open Access
Ya-Ru Zhang, Jia-Qi Luo, Jia-Xian Li, Qiu-Yue Huang, Xiao-Xiao Shi, Yong-Cong Huang, Kam W Leong, Weiling He, Jinzhi Du
Herein, a versatile strategy for the construction of biofunctional Janus particles (JPs) through the combination of Pickering emulsion and copper-free click chemistry is developed for the study of particle-mediated cell-cell interactions. A...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Structural trends in the dehydrogenation selectivity of palladium alloys

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00875C, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Stephen C. Purdy, Ranga Rohit Seemakurthi, Garrett M. Mitchell, Mark Davidson, Brooke A. Lauderback, Siddharth Deshpande, Zhenwei Wu, Evan C. Wegener, Jeffrey Greeley, Jeffrey T. Miller
Alloying is well-known to improve the dehydrogenation selectivity of pure metals, but there remains considerable debate about the structural and electronic features of alloy surfaces that give rise to this behavior.
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Recent developments in nickel-catalyzed intermolecular dicarbofunctionalization of alkenes

Chem. Sci., 2020, 11,4287-4296
DOI: 10.1039/C9SC06006E, Minireview
Open Access
Joseph Derosa, Omar Apolinar, Taeho Kang, Van T. Tran, Keary M. Engle
Nickel-catalyzed three-component alkene difunctionalization has rapidly emerged as a powerful tool for forging multiple C–C bonds in a single step.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Exploiting single-electron transfer in Lewis pairs for catalytic bond-forming reactions

Chem. Sci., 2020, 11,4305-4311
DOI: 10.1039/D0SC01159B, Edge Article
Open Access
Yoshitaka Aramaki, Naoki Imaizumi, Mao Hotta, Jun Kumagai, Takashi Ooi
Radical–ion pair generation from common Lewis pairs and its application to catalytic carbon–carbon bond formation.
The content of this RSS Feed (c) The Royal Society of Chemistry




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General and selective synthesis of primary amines using Ni-based homogeneous catalysts

Chem. Sci., 2020, 11,4332-4339
DOI: 10.1039/D0SC01084G, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Kathiravan Murugesan, Zhihong Wei, Vishwas G. Chandrashekhar, Haijun Jiao, Matthias Beller, Rajenahally V. Jagadeesh
A Ni-triphos based homogeneous catalyst enabled the synthesis of all kinds of primary amines by reductive amination of carbonyl compounds with ammonia and hydrogenation of nitroarenes.
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A pH ratiometrically responsive surface enhanced resonance Raman scattering probe for tumor acidic margin delineation and image-guided surgery

Chem. Sci., 2020, 11,4397-4402
DOI: 10.1039/D0SC00844C, Edge Article
Open Access
Wenjia Duan, Qi Yue, Ying Liu, Yunfei Zhang, Qinghua Guo, Cong Wang, Shujie Yin, Dandan Fan, Wenjing Xu, Jiexian Zhuang, Jiachao Gong, Xinwei Li, Ruimin Huang, Liang Chen, Silvio Aime, Zhongliang Wang, Jianfeng Feng, Ying Mao, Xiao-Yong Zhang, Cong Li
A novel pH ratiometrically responsive surface-enhanced resonance Raman scattering (SERRS) probe was developed for tumor acidic margin delineation and image-guided surgery.
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Intramolecular Csp3–H/C–C bond amination of alkyl azides for the selective synthesis of cyclic imines and tertiary amines

Chem. Sci., 2020, 11,4482-4487
DOI: 10.1039/C9SC05522C, Edge Article
Open Access
Xiaojin Wen, Xinyao Li, Xiao Luo, Weijin Wang, Song Song, Ning Jiao
A novel intramolecular cyclization of alkyl azides for the synthesis of cyclic imines and tertiary amines has been developed. The aliphatic C–H or C–C bond was selectively cleaved with the efficient formation of two C–N single bonds or a CN double bond.
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Self-assembly of reversed bilayer vesicles through pnictogen bonding: water-stable supramolecular nanocontainers for organic solvents

Chem. Sci., 2020, 11,4374-4380
DOI: 10.1039/D0SC00206B, Edge Article
Open Access
Shiva Moaven, Brandon T. Watson, Shelby B. Thompson, Veronica J. Lyons, Daniel K. Unruh, Dominick J. Casadonte, Dimitri Pappas, Anthony F. Cozzolino
A new air and moisture stable antimony thiolate compound has been prepared that spontaneously forms stable hollow vesicles.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Biocatalytic reversible control of the stiffness of DNA-modified responsive hydrogels: applications in shape-memory, self-healing and autonomous controlled release of insulin

Chem. Sci., 2020, 11,4516-4524
DOI: 10.1039/D0SC01319F, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Chen Wang, Amit Fischer, Avner Ehrlich, Yaakov Nahmias, Itamar Willner
Biocatalytic control over the stiffness of pH-responsive hydrogels is applied to develop shape-memory, self-healing and controlled release matrices.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Metal-free carbon monoxide-releasing micelles undergo tandem photochemical reactions for cutaneous wound healing

Chem. Sci., 2020, 11,4499-4507
DOI: 10.1039/D0SC00135J, Edge Article
Open Access
Jian Cheng, Bin Zheng, Sheng Cheng, Guoying Zhang, Jinming Hu
Metal-free carbon monoxide-releasing polymers (CORPs) are synthesized via a direct polymerization approach, exhibiting not only improved stability but also accelerated wound healing performance as compared to CORM-3.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Chemical control of competing electron transfer pathways in iron tetracyano-polypyridyl photosensitizers

Chem. Sci., 2020, 11,4360-4373
DOI: 10.1039/C9SC06272F, Edge Article
Open Access
Kristjan Kunnus, Lin Li, Charles J. Titus, Sang Jun Lee, Marco E. Reinhard, Sergey Koroidov, Kasper S. Kjær, Kiryong Hong, Kathryn Ledbetter, William B. Doriese, Galen C. O'Neil, Daniel S. Swetz, Joel N. Ullom, Dale Li, Kent Irwin, Dennis Nordlund, Amy A. Cordones, Kelly J. Gaffney
Photoinduced intramolecular electron transfer in Fe tetracyano-polypyridyl complexes was investigated with static and time-resolved UV-visible absorption and resonant inelastic X-ray scattering which revealed a competition of two relaxation pathways.
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Self-enhanced multicolor electrochemiluminescence by competitive electron-transfer processes

Chem. Sci., 2020, 11,4508-4515
DOI: 10.1039/D0SC00853B, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Silvia Voci, Romain Duwald, Stéphane Grass, David J. Hayne, Laurent Bouffier, Paul S. Francis, Jérôme Lacour, Neso Sojic
Controlling electrochemiluminescence (ECL) color(s) is crucial for many applications ranging from multiplexed bioassays to ECL microscopy.
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A highly stable RNA aptamer probe for the retinoblastoma protein in live cells

Chem. Sci., 2020, 11,4467-4474
DOI: 10.1039/D0SC01613F, Edge Article
Open Access
Thao T. Le, Andreas Bruckbauer, Bogachan Tahirbegi, Alastair J. Magness, Liming Ying, Andrew D. Ellington, Anthony E. G. Cass
An RNA G-quadruplex aptamer, specific for the human retinoblastoma protein (RB) and highly stable inside cells, is selected and its application to live cell probing of the protein illustrated.
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Enantioselective total synthesis of (−)-myrifabral A and B

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01141J, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tyler J. Fulton, Anthony Y. Chen, Michael D. Bartberger, Brian M. Stoltz
A catalytic enantioselective approach to the Myrioneuron alkaloids (−)-myrifabral A and (−)-myrifabral B is described.
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Synthesis and properties of hypervalent electron-rich pentacoordinate nitrogen compounds

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00002G, Edge Article
Open Access
Chenting Yan, Masato Takeshita, Jun-ya Nakatsuji, Akihiro Kurosaki, Kaoko Sato, Rong Shang, Masaaki Nakamoto, Yohsuke Yamamoto, Yohei Adachi, Ko Furukawa, Ryohei Kishi, Masayoshi Nakano
Structural characterization of hypervalent electron-rich pentacoordinate nitrogen species has long been a synthetic challenge. Here we report the first nitrogen cationic radical (11-N-5) species featuring a weak hypervalent 3c-5e interaction.
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Selective electrochemical reduction of carbon dioxide to ethanol via a relay catalytic platform

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01133A, Edge Article
Open Access
Juan Du, Shaopeng Li, Shulin Liu, Yu Xin, Bingfeng Chen, Huizhen Liu, Buxing Han
The relay catalytic platform is very efficient and selective for CO2 electroreduction to ethanol.
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Quinone Methide Dimers Lacking Labile Hydrogen Atoms Are Surprisingly Excellent Radical-Trapping Antioxidants

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC02020F, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Derek A. Pratt, Mark A R Raycroft, Jean-Philippe R Chauvin, Matthew Galliher, Kevin Romero, Corey Stephenson
Hydrogen atom transfer (HAT) is the mechanism by which the vast majority of radical-trapping antioxidants (RTAs), such as hindered phenols, inhibit autoxidation. As such, at least one weak O–H bond...
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Correction: Enantioselective synthesis of isochromans and tetrahydroisoquinolines by C–H insertion of donor/donor carbenes

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC90081H, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Leslie A. Nickerson, Benjamin D. Bergstrom, Mingchun Gao, Yuan-Shin Shiue, Croix J. Laconsay, Matthew R. Culberson, Walker A. Knauss, James C. Fettinger, Dean J. Tantillo, Jared T. Shaw
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Synthesis of unstrained Criegee intermediates: inverse α-effect and other protective stereoelectronic forces can stop Baeyer-Villiger rearrangement of γ-hydroperoxy-γ-peroxylactones

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01025A, Edge Article
Open Access
Vera A. Vil', Yana Barsegyan, Leah Kuhn, Maria V. Ekimova, Egor A. Semenov, Alexander Korlyukov, Alexander Olegovich Terent'ev, Igor Alabugin
How far can we push the limits in removing stereoelectronic protection from an unstable intermediate? We address this question by exploring the interplay between the primary and secondary stereoelectronic effects...
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