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Regioselective Molybdenum-catalyzed allylic substitution of tertiary allylic electrophiles: methodology development and applications

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01763A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Muhammad Salman, Yaoyao Xu, Shahid Khan, Junjie Zhang, Ajmal Khan
The first molybdenum-catalyzed allylic sulfonylation of tertiary allylic electrophile is described. The method utilizes a readily accesable catalyst (Mo(CO)6/2,2'-bipyridine, both are commercially available) and represent the first example of the...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Vibrational characterization of a diiron bridging hydride complex – a model for hydrogen catalysis

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01290D, Edge Article
Open Access
Leland Bruce Gee, Vladimir Pelmenschikov, Hongxin Wang, Nakul Mishra, Yu-Chiao Liu, Yoshitaka Yoda, Kenji TAMASAKU, Ming-Hsi Chiang, Stephen P Cramer
A diiron complex containing a bridging hydride and a protonated terminal thiolate of the form [(μ,κ2-bdtH)(μ-PPh2)(μ-H)Fe2(CO)5]+ has been investigated through 57Fe nuclear resonance vibrational spectroscopy (NRVS) and interpreted using density...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Sequential C–O decarboxylative vinylation/C–H arylation of cyclic oxalates via a nickel-catalyzed multicomponent radical cascade

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01471K, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Huan Li, Lei Guo, Xiaoliang Feng, Liping Huo, Shengqing Zhu, Lingling Chu
A selective, sequential C–O decarboxylative vinylation/C–H arylation of cyclic alcohol derivatives enabled by visible-light photoredox/nickel dual catalysis has been described.
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Cancer cell discrimination and dynamic viability monitoring through wash-free bioimaging using AIEgens

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01213K, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ruoyao Zhang, Guangle Niu, Qing Lu, Xiaolin Huang, Joe H. C. Chau, Ryan T. K. Kwok, Xiaoqiang Yu, Min-Hui Li, Jacky W. Y. Lam, Ben Zhong Tang
We present a series of AIEgens for cancer cell discrimination and dynamic viability monitoring.
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Near-infrared light-activated membrane fusion for cancer cell therapeutic applications

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC00863J, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Fujian Huang, Ruilin Duan, Zhixin Zhou, Margarita Vázquez-González, fan xia, Itamar Willner
The spatiotemporal stimulation of liposome-liposome or liposome-membrane fusion processes attracts growing interest as a means to mimic cell-cell interactions in nature and for using these processes for biomedical applications. We...
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Observations of tetrel bonding between sp3–carbon and THF

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01559H, Edge Article
Open Access
Victoria V. L. Heywood, T. P. J. Alford, Julius J.J. Roeleveld, Siebe S. J. Lekanne-Deprez, Abraham A. Verhoofstad, Jarl Ivar van der Vlugt, Melanie Schnell, Sérgio R Domingos, Anthony P. Davis, Tiddo Jonathan Mooibroek
We report the direct observation of tetrel bonding interactions between sp3-carbons of the supramolecular synthon 3,3-dimethyl-tetracyanocyclopropane (1) and tetrahydrofuran in the gas and crystalline phase. The intermolecular contact is established...
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N2Phos – an easily made, highly effective ligand designed for ppm level Pd-catalyzed Suzuki–Miyaura cross couplings in water

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00968G, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Nnamdi Akporji, Ruchita R. Thakore, Margery Cortes-Clerget, Joel Andersen, Evan Landstrom, Donald H. Aue, Fabrice Gallou, Bruce H. Lipshutz
A new, biaryl phosphine-containing ligand, N2Phos, forms a 1 : 1 complex with Pd resulting in an active catalyst at the ppm level for Suzuki–Miyaura couplings in water, enabled by an aqueous micellar medium. Notably, aryl chlorides are shown to be amenable substrates.
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Electrochemical Radical Reactions of Alkyl Iodides: A Highly Efficient, Clean, Green Alternative to Tin Reagents

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01694B, Edge Article
Open Access
diyuan Li, Tsz-Kan Ma, Reuben J Scott, Jonathan David Wilden
An electrochemical ‘redox-relay’ system has been developed which allows the generation of C-centered radicals. Intermolecular ‘tin-like’ radical reactions can subsequently be conducted under the most benign of conditions. The yields...
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Many electronics shops defy DM’s order in Patna

A day after the state home department issued an order allowing certain categories of shops to reopen, some electronics, electrical and vehicle spare parts shops reopened in the city on Thursday.




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Wife dead, man held on dowry charges in Patna

A 30-year-old man was arrested in Patna after his wife was found dead at their home in Shivpuri under Shastri Nagar police station area on Thursday. The couple, Manish Kumar and Anita Devi, were marred in 2017.




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Delhi: 2nd 'shramik spl train' leaves for Bihar

The workers were ferried to the New Delhi Railway station mostly in Delhi Transport Corporation (DTC) buses, and in some cases in police vans from shelters homes run by the city government.




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Lockdown helps Bihar cops trace ‘missing’ persons

The lockdown has its other advantages than containing Covid-19 spread. It has helped police trace persons going missing from home. Some of the cases are related to persons with learning difficulties, who could not have got traced easily in normal situation.




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Bihar man held, stolen gold biscuits seized

Police arrested one Mohan Kumar (30) from Shivaji Nagar Bagicha under the Digha police station area in Patna on Friday and recovered stolen gold biscuits, jewellery and cash worth around Rs 20 lakh from his possession.




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Is it possible to enter an IPO bid below floor price?

Floor price is the minimum price at which bids can be made for offer.




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Japan IPO cancellations hit record this month on coronavirus

Investors who had planned to buy new offerings might opt for existing start-up shares instead.




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Half of FY20 IPOs hold head above water in this selloff, some remain multibaggers

Out of the 15 stocks that got listed in FY 2019-20, seven are still trading above issue prices.




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Parent perceptions of their school council / Leonie M. Southwell

Southwell, Leonie, M., author




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Photosensitive students and digital media : a survey of educators regarding knowledge and self efficacy / Janene Sproul

Sproul, Janene, author




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The value of international education to Australia / prepared by Deloitte Access Economics

Deloitte Access Economics




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Handbook of research on teaching / edited by Drew H. Gitomer and Courtney A. Bell




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The silent university : towards a transversal pedagogy / edited by Florian Malzacher, Ahmet Ögüt, Pelin Tan




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Observation [videorecording] : the developing child / Magna Systems, Inc. ; program producers, Shanta and Milan Herzog ; design and script, Janet Gonzalez-Mena ; editor, Susan Jenkins




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The inside story [videorecording] : developing children's understanding about their bodies




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Wondrous words : writers and writing in the elementary classroom / Katie Wood Ray

Ray, Katie Wood, 1964- author




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Professional development, instructional intelligence and teacher emotions : a mixed methods study of a four-year systemic change initiative / by Rebecca Ann Saunders

Saunders, Rebecca Ann, author




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International handbook of research on conceptual change / edited by Stella Vosniadou




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Alternatives to privatizing public education and curriculum : Festschrift in honor of Dale D. Johnson / by Daniel Ness & Stephen J. Farenga




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Situation models and children's reading comprehension : what role does visual imagery play? / by Maroulia Katsipis

Katsipis, Maroulia, author




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The skillful teacher : on technique, trust, and responsiveness in the classroom / Stephen D. Brookfield

Brookfield, Stephen, author




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Transforming schools : creativity, critical reflection, communication, collaboration / Miranda Jefferson and Michael Anderson

Jefferson, Miranda




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Research methods for pedagogy / Melanie Nind, Alicia Curtin and Kathy Hall

Nind, Melanie, author




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Literacy for the 21st century : a balanced approach / Gail Tompkins, Rod Campbell, David Green and Carol Smith

Tompkins, Gail E., author




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Loose parts : inspiring play in young children / Lisa Daly and Miriam Beloglovsky ; photography by Jenna Daly

Daly, Lisa




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Evolving entrepreneurial education : innovation in the Babson classroom / edited by Victoria L. Crittenden, Kathryn Esper, Nathaniel Karst, Rosa Siegers, Babson College, USA




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Peer-group mentoring for teacher development / edited by Hannu Heikkinen, Hannu Jokinen and Päivi Tynjälä




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Still learning to think thinking to learn : within the Australian curriculum : planning with a thinking focus / Michael Pohl

Pohl, Michael, author




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Teaching thinking skills in the primary years : a whole school approach / by Michael Pohl

Pohl, Michael




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Naming silenced lives : personal narratives and processes of educational change / [edited by] Daniel McLaughlin and William G. Tierney




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Study skills connected : using technology to support your studies / Stella Cottrell and Neil Morris

Cottrell, Stella, author




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Creating wonder : using natural and recycled materials / Jenny Aitken, Jan Hunt, Elizabeth Roy & Bess Sajfar

Aitken, Jenny, author




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You're telling the story : how to develop useful assessments for learning in early childhood / Janet Moles

Moles, Janet




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Case studies in multiliteracies and inclusive pedagogy : facilitating meaningful literacy learning / Rachel Drewry

Drewry, Rachel, author




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The new meaning of educational change / Michael Fullan

Fullan, Michael, author




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Comparative and international education : an introduction to theory, method, and practice / David Phillips and Michele Schweisfurth

Phillips, David, 1944 December 15- author




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Teaching in inclusive school environments / Roselyn Dixon, Stuart Woodcock, Kathleen Tanner, Leanne Woodley, Amanda Webster

Dixon, Roselyn M




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What is it about Tribes? : the research-based components of the developmental process of Tribes Learning Communities / Bonnie Benard (WestEd)

Benard, Bonnie, author




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Diversity, inclusion and engagement / edited by Mervyn Hyde, Lorelei Carpenter, Shelley Dole




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Developing the curriculum / Peter F. Oliva, William R. Gordon, II

Oliva, Peter F, author




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Developing the curriculum : improved outcomes through systems approaches / William R. Gordon II, Ed.D. (Chief Operations Officer, Retired, Florida virtual School, Orlando, Florida), Rosemarye T. Taylor, Ph.D. (Professor, Educational Leadership, University

Gordon, William, II, author




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Higher education research methodology : a step-by-step guide to the research process / Ben Kei Daniel and Tony Harland

Daniel, Ben Kei, 1971- author