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Organohypervalent heterocycles

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D2CS01055K, Review Article
Ravi Kumar, Toshifumi Dohi, Viktor V. Zhdankin
This review summarizes structural and synthetic aspects of heterocyclic molecules incorporating an atom of a hypervalent main-group element. The higher thermal stability of hypervalent heterocycles, as compared to their acyclic analogs, adds special feature to their chemistry.
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Targeted protein degradation directly engaging lysosomes or proteasomes

Chem. Soc. Rev., 2024, 53,3253-3272
DOI: 10.1039/D3CS00344B, Tutorial Review
Open Access
Jiseong Kim, Insuk Byun, Do Young Kim, Hyunhi Joh, Hak Joong Kim, Min Jae Lee
This review delineates emerging technologies for targeted protein degradation that directly involve lysosomes or proteasomes. It explores their unique features, advantages, and limitations, offering perspectives on future therapeutic applications.
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Unlocking the potential of metal ligand cooperation for enantioselective transformations

Chem. Soc. Rev., 2024, 53,3216-3223
DOI: 10.1039/D3CS00998J, Viewpoint
Open Access
Tizian-Frank Ramspoth, Johanan Kootstra, Syuzanna R. Harutyunyan
Metal–ligand cooperation, (MLC) is a versatile catalysis concept. Herein, we discuss the historical context, mechanisms, and applications, suggesting exploring MLC for enantioselective transformations beyond (de)hydrogenative processes.
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Recent advances in super-resolution optical imaging based on aggregation-induced emission

Chem. Soc. Rev., 2024, 53,3350-3383
DOI: 10.1039/D3CS00698K, Review Article
Feng-Yu Zhu, Li-Jun Mei, Rui Tian, Chong Li, Ya-Long Wang, Shi-Li Xiang, Ming-Qiang Zhu, Ben Zhong Tang
From aggregation-induced emission to super-resolution imaging: the significance of reversible dynamic interaction.
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Organoboron-mediated polymerizations

Chem. Soc. Rev., 2024, 53,3384-3456
DOI: 10.1039/D3CS00115F, Review Article
Yao-Yao Zhang, Guan-Wen Yang, Chenjie Lu, Xiao-Feng Zhu, Yuhui Wang, Guang-Peng Wu
This review provides a comprehensive summary of organoboron-mediated free radical polymerization, Lewis pair polymerization, ionic polymerization, and polyhomologation, laying the groundwork for further establishment of polymerization methods.
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Thermally activated structural phase transitions and processes in metal–organic frameworks

Chem. Soc. Rev., 2024, 53,3606-3629
DOI: 10.1039/D3CS01105D, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Celia Castillo-Blas, Ashleigh M. Chester, David A. Keen, Thomas D. Bennett
The structural knowledge of metal–organic frameworks is crucial for understanding and developing new efficient materials for industrial implementation.
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Low oxidation state and hydrido group 2 complexes: synthesis and applications in the activation of gaseous substrates

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D4CS00097H, Review Article
Matthew J. Evans, Cameron Jones
This review summarises advances in the chemistry of low-oxidation state and hydrido group 2 metal complexes, focussing on their use for the reductive activation of feed-stock gaseous small molecules, and their subsequent transformation into value added products.
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Visible photons as ideal reagents for the activation of coloured organic compounds

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS01129A, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lorenzo Di Terlizzi, Luca Nicchio, Stefano Protti, Maurizio Fagnoni
In search for the perfect wave(length). This review is dedicated to recent efforts in the development of visible light driven photochemical strategies occurring in coloured organic compounds.
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Construction of olefinic coordination polymer single crystal platforms: precise organic synthesis, in situ exploration of reaction mechanisms and beyond

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS01050C, Review Article
Qiaoqiao Zhang, Yong Wang, Pierre Braunstein, Jian-Ping Lang
Olefinic coordination polymers were used as universal single crystal platforms for precise organic synthesis, in situ mechanism exploration and photochemical applications.
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Bridging the gap between academic research and industrial development in advanced all-solid-state lithium–sulfur batteries

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS00439B, Review Article
Jieun Lee, Chen Zhao, Changhong Wang, Anna Chen, Xueliang Sun, Khalil Amine, Gui-Liang Xu
This review builds upon the fundamentals and substantial progress achieved, aiming to inspire the battery community to advance all-solid-state lithium–sulfur batteries toward practical applications and accelerate the industrialization process.
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Peptide hydrogen-bonded organic frameworks

Chem. Soc. Rev., 2024, 53,3640-3655
DOI: 10.1039/D3CS00648D, Tutorial Review
Open Access
Thangavel Vijayakanth, Sneha Dasgupta, Pragati Ganatra, Sigal Rencus-Lazar, Aamod V. Desai, Shyamapada Nandi, Rahul Jain, Santu Bera, Andy I. Nguyen, Ehud Gazit, Rajkumar Misra
This tutorial review discusses the design principles, implications, and future challenges associated with peptide-based hydrogen-bonded porous frameworks (P-HPFs).
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Gaurav Gill finishes Day 1 of Otago Rally in top-three

Gaurav Gill and his New-Zealand-based co-driver Jared Hudson were third on the timesheets, a little over 30 seconds behind overall leader Jack Hawkeswood and 11 seconds adrift of second-placed Robbie Stokes




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Jagan declared the winner after dead-heat in Pro-Stock 165cc Open




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F1: Lando Norris takes Hungary pole in McLaren front row lockout

Lando Norris leads Oscar Piastri in McLaren qualifying one-two; Verstappen comes third




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Formula 4 race: organisers expect event to boost Chennai’s economy

A report on the economic impact of the race on the city will be submitted after a month, says Abhinandan B., co-founder, Racing Promotions Private Limited; the aim is to put Chennai on a global map, and boost its profileJ. Meghanatha Reddy, Member Secretary, SDAT




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Singapore GP: Norris puts McLaren on top in, Russell crashes

Verstappen, 59 points ahead of closest rival Norris with seven rounds remaining, was 1.294 seconds off the pace with team mate Sergio Perez eighth at the winding Marina Bay street circuit




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Lando Norris cruises to victory at Singapore Grand Prix to cut Max Verstappen's F1 lead

Verstappen came in second for Red Bull after a race that was largely uneventful after he held off Lewis Hamilton into the first corner at the start




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Sreejesh to retire after Paris Olympic Games




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Paris Olympics: Harmanpreet's late strike hands India 1-1 draw against Argentina

Lucas Martinez gave Argentina the lead in the 22nd minute before Harmanpreet converted India's 10th and last penalty corner to pick up a crucial point from the game.




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India vs Great Britain Olympics quarterfinal: Everyone gathered around and worked on the tactics, says Craig Fulton

“Sreejesh is a legend, he is one of the best we have. He is saving us from day one. But when you ask him, he will say it was a team effort, so team first, then individuals,” said Harmanpreet.




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Sreejesh urges India to fight for bronze against Spain after semifinal loss to Germany in Paris Olympics

Sreejesh, who would play his last international match in the third place encounter against Spain on Thursday (August 8), said winning a medal should be the team’s priority




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Asian Champions Trophy semifinal: In-form India clear favourites against Korea

It has been a commanding performance from the Indians as they excelled in every department — be it forwardline, midfield or defence.




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Title holders India to open women's ACT campaign against Malaysia

India won the tournament in 2016 in Singapore before reclaiming the title in Ranchi last year




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Shrachi Rarh Bengal Tigers to have Aussie coaches




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India eyes Paris revenge against Germany in Test series as international hockey returns to Delhi

For the last 10 years, the capital's Major Dhyan Chand National Stadium, once considered the spiritual home of the game, has not hosted any international match.




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Karnataka defeats Chandigarh, makes the last-eight stage




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Carpathian Brigade

Our newest supplement for Panzer Grenadier is ready right now! Carpathian Brigade has eleven new scenarios (not 10 -- it goes to 11!) based on the historical battles of the Polish Carpathian Brigade in North Africa. You can buy it in a print edition for $9.99, or download it right away for just $5.99.




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Yoga a compulsory subject in Central schools




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When empty chairs became teachers in Telengana

Telangana villagers garland empty chairs to protest lack of staff in schools.




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A.P. has second thoughts on dropping Telangana lessons




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Long gap a setback for students




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Not declaring deletions on Mahatma Gandhi, RSS in textbooks an ‘oversight’, says NCERT head

The issue is being blown out of proportion, says D.P. Saklani, reacting to the controversy over the removal of sentences on Gandhiji and the RSS; Congress president Kharge says the BJP cannot erase history, no matter how hard it tries




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Astronomy for curious kids : an illustrated introduction to the Solar System, our galaxy, space travel--and more! / [Giles Sparrow ; illustrated by Nik Neves]

Sparrow, Giles, 1970- author




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The leaf detective : how Margaret Lowman uncovered secrets in the rainforest / Heather Lang ; illustrated by Jana Christy

Lang, Heather, 1966- author




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This book is full of holes : from underground to outer space and everywhere in between / written by Nora Nickum ; illustrated by Robert Meganck

Nickum, Nora, author




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Dogtown / Katherine Applegate and Gennifer Choldenko ; with illustrations by Wallace West

Applegate, Katherine, author




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If I see you again tomorrow / Robbie Couch

Couch, Robbie, author




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Reaching Valhalla : tales and sagas from Norse mythology / written and illustrated by Zachary Hamby

Hamby, Zachary, author, illustrator




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Poe : stories and poems / a graphic novel adaptation by Gareth Hinds

Hinds, Gareth, 1971- author, illustrator




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Abracadabra, it's spring! / by Anne Sibley O'Brien ; illustrated by Susan Gal

O'Brien, Anne Sibley, author




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Negative cat / Sophie Blackall

Blackall, Sophie, author, illustrator




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La neige / écrit par Michael Kusugak ; illustré par Bill Helin

Kusugak, Michael, author




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Fireside Ventures aims to birth Indian mega-brands

Why VC firm Fireside Ventures believes it can build multimillion-dollar consumer brands in India without burning capital




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Hovering fighters birthed in Bengaluru

Start-up Zulu Defence manufactures drones geared for deployment in warfare




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It’s a lonely battle for brand aggregators 

Why e-commerce roll-up — banding together smaller online brands for growth — didn’t find strength in numbers 




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Outer-surface adduct formation and selective separation of cis-type gallated and cis-type non-gallated catechins using cucurbit[7]uril

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05035E, Communication
Open Access
Hiroyuki Tsutsumi, An Miura, Asuka Hanada, Rino Sonoda, Rie Nakashima, Tomonori Ohata, Hirohito Ikeda
The selective separation of cis-type gallated and non-gallated catechins in solution was achieved by utilizing the formation of outer-surface adducts between cis-type catechins and cucurbit[7]uril.
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Direct π-extension of a Conjugated Carbon Nanohoop Using a Zipper Method

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04976D, Communication
kang Wei, Zaitian Cheng, Xingyu Zhang, Qiang Huang, Pingwu Du
The π-extension of carbon nanorings towards ultrashort carbon nanotubes (CNTs) is a great challenge for synthetic chemists. Herein, we report the synthesis, characterization, and properties of a nanographene-embedded carbon nanoring...
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Varied CO2 photoreduction activity over UiO-66-NH2 with different aggregation morphology

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04919E, Communication
Shuran Zhang, Yan-Hong Zou, Hai-Ning Wang, Guangjuan Xu, Wei Xie, Na Xu, Yanhong Xu, Yaqian Lan
UiO-66-NH2 with different aggregation morphology are prepared to verify the morphology of photocatalysts could influence the charge transfer. Among them, UiO-66-NH2 with the poor aggregation exhibits superior performances over CO2...
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Bidirectional strain release in a thermosalient organic salt crystal induced by anisotropic thermal expansion and phase transformation

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04764H, Communication
Priyasha Harsha, Dinabandhu Das
Two-way release of strain followed by jumping in an organic salt crystal can be attributed to the anisotropic thermal expansion by heating and phase transformation followed by shear deformation of the crystals by cooling.
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Hydrazone-linked Covalent Organic Frameworks for Fluorescence Detection of Hg2+

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05468G, Communication
Xuefeng Wang, Zhaowei Yang, Lingsuo Meng, Xuehui Li, Hongtao Wei, Jing Ning, Shitao Wang, Dapeng Cao, Long Hao
A hydrazone-linked COF (DvDf-C3XJ-COF) with hydrogen-bond reinforcement and abundant coordination sites was synthesized, exhibiting strong fluorescence and high sensitivity/selectivity for Hg²⁺ detection, with a detection limit of 1.65 × 10⁻⁶...
The content of this RSS Feed (c) The Royal Society of Chemistry