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Magnesium(II) complexes supported by indole- and pyrrole-containing Schiff-base ligands: syntheses, structures, and applications as precatalysts in the hydroboration of nitriles and alkynes

New J. Chem., 2024, 48,7125-7133
DOI: 10.1039/D4NJ00492B, Paper
Mengxiang Wu, Ling Chen, Xiaohan Yang, Yahong Li
Five magnesium compounds were synthesized. They are active precatalysts for the hydroboration of nitriles and alkynes. The catalytic reactions feature mild reaction conditions, excellent functional group tolerance, and high yields.
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Effects of silylene ligands on the catalytic activity of [PSiP] pincer cobalt(II) chloride for N2 silylation

New J. Chem., 2024, 48,7334-7339
DOI: 10.1039/D4NJ00883A, Paper
Min Zhang, Yanhong Dong, Qingshuang Li, Xiaoyan Li, Hongjian Sun
Three silyl [PSiP] pincer cobalt(II) chlorides [(2-Ph2PC6H4)2MeSiCo(Cl)(PMe3)] (1), [(2-iPr2PC6H4)2MeSiCo(Cl)(PMe3)] (2) and [(2-Ph2PC6H4)2MeSiCo(Cl)(LSi:)] (LSi: = {PhC(NtBu)2}SiCl) (3) were used as catalysts for dinitrogen silylation was studied.
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Mechanochemical synthesis of biphenyl-derived organic fluorescent materials via solvent-free and ligand-free oxidative homocoupling reactions

New J. Chem., 2024, 48,7356-7361
DOI: 10.1039/D4NJ00886C, Paper
Zefeng Li, Caihang Zhang, Yingxuan Zheng, Ping Deng, Yan Yu
The palladium-catalyzed solvent-free and ligand-free oxidative homocoupling reactions of aryl boronic acids via ball-milling are developed to synthesize a series of biphenyl-derived organic fluorescent materials.
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Investigating drug abuse in hair samples using the electrospun PEDOT–CNT nanostructure along with EA-IT-SPME

New J. Chem., 2024, 48,7277-7286
DOI: 10.1039/D4NJ00023D, Paper
Negar Sabahi Moosavi, Yadollah Yamini, Payam Osooli
Electrospinning, a simple and low-cost method, is one of the best ways to produce nanoscale porous adsorbents.
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Rhodium-catalysed homo-coupling of terminal alkynes: divergent synthesis of bioactive 1,3-diynes and conjugated enediynes

New J. Chem., 2024, 48,7517-7523
DOI: 10.1039/D4NJ00366G, Paper
Yijie Xiao, Lijie Lv, Nanxuan Luo, Peirui Zhao, Yao Chen, Zhangshun Luo, Houhua Yin, Yi He, Shenyou Nie
C(sp)–C(sp) cross-coupling of terminal alkynes represents a robust tool for building biologically active 1,3-diynes although confronted with huge challenges regarding selectivity control.
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Hydrogen-bonded organic frameworks with extended conjugate systems for boosted photocatalytic degradation

New J. Chem., 2024, 48,7213-7224
DOI: 10.1039/D4NJ00610K, Paper
Xiaojuan Bai, YiLin Xin, Tianqi Jia, Linlong Guo, Wei Song, Derek Hao
A schematic mechanism of the photocatalytic degradation process of SMX by solvothermal synthesis of hydrogen-bonded organic framework materials.
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Oxazoline amino acid bioconjugates: one-pot synthesis and analysis of supramolecular interactions

New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00995A, Paper
Marija Bakija, Berislav Perić, Srećko I. Kirin
Oxazoline amino acid bioconjugates were synthesized; the relative stability of a supramolecular dimer of a tris-derivative was investigated using mean absolute error values (MAE), derived from 1H NMR experiments and DFT calculations.
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Theoretical investigation of the effect of radical substituents on the open-shell character of polycyclic aromatic hydrocarbons

New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00555D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tomohito Shinozuka, Daiki Shimizu, Kenji Matsuda
Radical substituents was found to significantly alter the open-shell character y of PAHs compared to non-radical substituents.
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Influence of the secondary ligand, phenanthroline, on the antioxidant and pro-oxidant and cytotoxic effects of the oxidovanadium(IV)/naringin complex

New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00655K, Paper
Andrés G. Restrepo, Angel L. Huamani, Alexandra Velásquez Bravo, Pablo J. González, Luciana G. Naso, Evelina G. Ferrer, Patricia A. M. Williams
Replacement of phen in [VO(Narg)2] induces greater π electronic delocalization, thus improving antioxidant action. However, due to its lipophilic character, cellular uptake of V is increased, leading to enhanced pro-oxidant and anticancer effects.
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Sugar and spice and all things nice

Whether it’s food, décor or crafts, the second edition of The Gourmet Bazaar has a great range of stuff on offer




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Bengaluru’s weekend art scene




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Bengaluru, this weekend




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Music, dance, food and Bengaluru




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Events in Bengaluru




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Bengaluru and its art scene




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Mentalist Suhani Shah is all set to mesmerise Bangaloreans

Suhani Shah, said to be India’s first female mentalist, will be performing in Bengaluru this weekend as part of her silver jubilee celebrations in the field of magic




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Bengaluru’s weekend art scene




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Music, dance, food and art in Bengaluru




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What’s on in Bengaluru this weekend




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The weekend art scene in Bengaluru




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Remo Fernandes’ second fado is a love song for Portugal’s Alentejo

‘Fado da Terra Lenta’ has contemporary orchestration with instruments and choral voices not used in the old fado form



  • Life & Style

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Évents in Bengaluru




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English dystopian thriller ‘Edgar and Annabel’ comes to Chennai

British playwright Sam Holcroft’s Edgar and Annabel, a dystopian story of dissenters fighting against the establishment, comes to Chennai, directed by Sunandha Raghunathan




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Events in and around Bengaluru: Radha Thomas Quartet, Nirali’s ‘Hanchike 2022’, and more




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Bengaluru’s Christmas treats




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Bengaluru’s New year offerings




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Bengaluru’s weekend events




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New Year, new you: 10 clubs in Bengaluru you can join in 2023

From books to board games, we offer you a variety of activities you can get into at the beginning of the year




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Presenting Bengaluru’s weekend activities




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Weekend events in Bengaluru




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Bengaluru’s V-Day offers




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Weekend with food, music and more in Bengaluru




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An architect and a student are beautifying public spaces in Bengaluru

After painting the walls of a 100-year-old school building, and a hospital, Namitha B Ramaiah and Siddharth Kaul are looking to up the interest quotient of public spaces in Bengaluru




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Arts, music, food and more in Bengaluru




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Weekend events in Bengaluru




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An all-woman night walk takes over one of Bengaluru’s oldest lanes

The women-led tour through the lanes of Chickpet not just showcased the neighbourhood’s distinctive nightlife, but also aimed to create more safe spaces for women to walk at night, and reclaim the streets




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Bengaluru, this weekend




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Weekend events in Bengaluru