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Synthesis and characterisation of light lanthanide bis-phospholyl borohydride complexes

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01241F, Paper
Jingjing Liu, Lydia E. Nodaraki, Philip J. Cobb, Marcus J. Giansiracusa, Fabrizio Ortu, Floriana Tuna, David P. Mills
Two families of lanthanide(III) phospholyl borohydride complexes are reported (carbon = grey, hydrogen = white, oxygen = red, boron = yellow, phosphorus = magenta, potassium = blue, lanthanides = teal; only BH4 hydrogens are shown for clarity).
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Conductivity and mixed conductivity of a novel dense diffusion barrier and the sensing properties of limiting current oxygen sensors

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00496K, Paper
Ke Shan, Zhong-Zhou Yi, Xi-Tao Yin, Davoud Dastan, Hamid Garmestani
First-principles calculations were used to explore the effect of various Y-doping levels on the electrical conductivity of SrTiO3.
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Highly covalent metal–ligand π bonding in chelated bis- and tris(iminoxolene) complexes of osmium and ruthenium

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01287D, Paper
Jacqueline Gianino, Seth N. Brown
Describing the π bonding in ruthenium and osmium iminoxolenes as highly covalent allows one to experimentally dissect the electron distribution in these compounds.
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Self-assembly of mixed-valent and heterometallic metallocycles: efficient catalyst for oxidation of alcohols to aldehydes with ambient air

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01340D, Communication
Ya-Liang Lai, Xue-Zhi Wang, Rui-Rong Dai, Yong-Liang Huang, Xian-Chao Zhou, Xiao-Ping Zhou, Dan Li
Two mixed-valent CuII/CuI and two heterometallic CuII/AgI metallocycles have been synthesized by the assembly of designed metalloligands and CuI/AgI ions, respectively. The CuII/CuI metallocycle can catalyze oxidation of alcohols to...
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Structural, spectroscopic and electronic properties of a family of bi-octahedral Ru25+/6+ complexes with a bridging 2,5-di(2-pyridyl)pyrrolide ligand

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01325K, Paper
Shi-Rui Kang, Qin Zi Zhou, Chang-Fang Xiong, Bin Liu, John E. McGrady, Mohammed Obies, Chao Liu, Piao He, Xiao-Yi Yi
A family of Ru2 dimers, [Ru2(μ-κ2N,N’:κ2N’,N’’-dpp)2(μ-X)(X)2]q+ (X = Cl, Br, q = 0 and X = I, q = 1) is synthesized from a [Ru2(OAc)4Cl] paddlewheel starting material. The neutral...
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The role of the excited state dynamic of the antenna ligand in the Lanthanide sensitization mechanism

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01132K, Paper
María Joaquina Beltrán Leiva, Eduardo Solis Céspedes, Dayan Paez-Hernandez
A fragmentation scheme combined with a series of theoretical approximations like TD-DFT, and multiconfigurational CASSCF/NEVPT2 methods, have been used to describe the photophysical phenomena associated with the antenna effect and...
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Probing the limits of linker substitution in aluminum MOFs through water vapor sorption studies: Mixed-MOF instead of mixed-linker CAU-23 and MIL-160 materials

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01044H, Paper
Carsten Schlüsener, Dustin Nils Jordan, Mergime Xhinovci, Tobie J. Matemb Ma Ntep, Alexa Schmitz, Beatriz Giesen, Christoph Janiak
We report the systematic study on the possibility of forming mixed-linker MOFs spanning between the aluminum metal-organic frameworks CAU-23 and MIL-160 with their 2,5-thiophenedicarboxylate (TDC) and 2,5 furandicarboxylate (FDC) linkers,...
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Luminescent organic dyes containing a phenanthro[9,10-D]imidazole core and [Ir(N^C)(N^N)]+ complexes based on the cyclometalating and diimine ligands of this type

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00568A, Paper
Anastasia I. Solomatina, Kirill M. Kuznetsov, Vladislav V. Gurzhiy, Vladimir V. Pavlovskiy, Vitaly V. Porsev, Robert A. Evarestov, Sergey P. Tunik
New N^N and N^C luminescent ligands with solvatochromic behavior and their iridium complexes were synthesized, characterized and investigated.
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Three diphosphates, α-Li2Na2P2O7, Li8Pb3Ba(P2O7)4 and Li7Rb(P2O7)2: influences of co-substitution on the crystal structure

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01070G, Paper
Ming Wen, Cong Hu, Hongping Wu, Zhihua Yang, Xiaohong Wu, Shilie Pan
We reported the synthesis, structure, characterization and first-principles calculations of diphosphates, α-Li2Na2P2O7, Li8Pb3Ba(P2O7)4 and Li7Rb(P2O7)2, and studied the influences of co-substitution on the crystal structure.
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Influence of magnetic dilution on relaxation processes in a solid solution comprising tetrahedral Co/ZnII complexes

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01058H, Paper
Magdalena Ceglarska, Olaf Stefańczyk, Shin-ichi Ohkoshi, Anna M. Majcher-Fitas
Dilution with diamagnetic species in a SIM solid solution leads to an increase in relaxation times at low temperatures and monotonously reduces the probability of quantum tunneling of magnetization and the direct process.
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Dehydrogenation of amines in aryl-amine functionalized pincer-like nitrogen-donor redox non-innocent ligands via ligand reduction on a Ni(II) template

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00466A, Paper
Manas Khatua, Bappaditya Goswami, Subhas Samanta
A Ni(II)-template directed dehydrogenative imine formation reaction via ligand reduction leading to the formation of new pincer-like azo imine ligands is described.
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Recent advances in coordination-driven polymeric gel materials: design and applications

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00863J, Frontier
Papri Sutar, Tapas Kumar Maji
In this article, we reviewed recent advances in coordination-driven polymeric gels and highlighted their design and applications in various fields.
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Effects of ligand substituents on the single-molecule magnetic behavior of quinonoid-bridged dicobalt compounds

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00033G, Paper
Xiao-Quan Zhu, Wen-Hai Cao, Shao-Dong Su, Xin-Tao Wu, Tian-Lu Sheng
The SMM behavior weakens until its disappearance with the substituent changing from Br, H to OMe in the quinonoid-bridged dicobalt compounds [(N4Co)2LX](ClO4)2, (X = H, Cl, Br, and OMe).
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Amorphous Ni–Fe–Se hollow nanospheres electrodeposited on nickel foam as a highly active and bifunctional catalyst for alkaline water splitting

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/C9DT04755G, Paper
Xuerui Yi, Xiaobo He, Fengxiang Yin, Biaohua Chen, Guoru Li, Huaqiang Yin
The electrodeposition of amorphous Ni–Fe–Se hollow nanospheres as a highly efficient bifunctional catalyst for the sustainable production of hydrogen.
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Selenotungstates incorporating organophosphonate ligands and metal ions: synthesis, characterization, magnetism and catalytic efficiency in Knoevenagel condensation reaction

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00444H, Paper
Jingyang Niu, Hui Kong, Peipei He, Zongfei Yang, Qiaofei Xu, Jiawei Wang, Ran Ban, Pengtao Ma, Jingping Wang
Three sandwich-type TM-containing (TM = transition metal) organophosphonate-based polyoxotungstate clusters, [TM(H2O)4(SeW6O21)2{Co(OOCCH2NCH2PO3)2}3]12– (TM = Co, Ni), have been successfully synthesized, which is the first reported TMs-containing organophosphonate-based selenotungstates. They were structurally...
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Amorphous Co-doped MoSex Effectively Enhances Photocatalysis in Visible Light

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01295E, Paper
Rui Feng, Rong Wu, Yuncheng Cao, Xiaolin Guo, Xu Ma
Molybdenum selenide has great potential for degradation of water pollutants，but its performance is limited by the active sites and recombination of photogenerated electron-hole pairs. In this study, amorphous Co-doped MoSex...
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Oxacalix[4]arene Derived Dual Sensing Fluorescence Probe for the Detection of As (V) and Cr (VI) Oxyanions in Aqueous Media

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00452A, Paper
Shuvankar Dey, Anshu Kumar, Pradip Mondal, Krunal M. Modi, Deepak Chopra, Vinod K. Jain
An oxacalix[4]arene-Ce (III) complex viz. L-Ce(III) has been introduced for selective detection of As (V) and Cr (VI) oxyanions in aqueous medium. Binding mode of L-Ce(III) + AsO43-/ CrO42- was...
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Amide and ester derivatives of chlorido[4-carboxy-1,2-disalicylideneaminobenzene]iron(III) as necroptosis and ferroptosis inducers

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00168F, Paper
Daniel Baecker, Benjamin N. Ma, Jessica Sagasser, Lukas Schultz, Carina Hörschläger, Maria Weinreich, Lucy Steiner, Brigitte Kircher, Ronald Gust
Amide and ester derivatives of chlorido[4-carboxy-1,2-disalicylideneaminobenzene]iron(III) were synthesized and characterized as necroptosis and ferroptosis inducers using the acute myeloid leukemia cell line HL-60.
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Spin-frustration with two quasi-degenerated spin states of a copper(II) heptanuclear complex obtained from an amino acid ligand

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/C9DT04501E, Paper
Catiúcia Rodrigues Marcelino Oliveira Matos, Henrique Silva Jr, Dayenny D’Amato, Guilherme Guedes, Glaucio Braga Ferreira, Odivaldo Cambraia Alves, Filipe Barra de Almeida, Sergio Pinheiro, Acácio Souza, Flavio Garcia, Célia Machado Ronconi
The Cu(II) heptanuclear complex (Cu7atac) was synthesised using the hydrated amino acid ligand 2-(5-amino-1H-1,2,4-triazol-3-yl)acetic acid (Hatac.H2O). Single crystal X-ray diffraction analysis revealed a μ3-hydroxo bridged Cu(II) heptanuclear complex, consisting of...
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The differential magnetic relaxation behaviours of slightly distorted triangular dodecahedral dysprosium analogues in a type of cyano-bridged 3d–4f zig-zag chain compounds

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00990C, Paper
An-Qi Xue, Yang-Yu Liu, Jia-Xin Li, Yan Zhang, Yin-Shan Meng, Wen-Hua Zhu, Yi-Quan Zhang, Hao-Ling Sun, Fei Wang, Guan-Xia Qiu, Lu-Yu Liang, Xiang Wang, Song Gao
Differential magnetic properties were observed for triangular dodecahedral dysprosium analogues in a type of cyano-bridged 3d–4f zig-zag chain compound.
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Rhenium and technetium-complexed silicon rhodamines as near-infrared imaging probes for bimodal SPECT- and optical imaging

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01084G, Communication
Thines Kanagasundaram, Carsten Sven Kramer, Eszter Boros, Klaus Kopka
Radiolabelled fluorescent dyes are decisive for bimodal imaging and currently in demand for scintigraphic and optical imaging. This powerful method allows the combination of nuclear imaging (e.g. SPECT-imaging) and optical...
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A Review: Recent Advances in Preparations and Applications of Heteroatom-Doped Carbon Quantum Dots

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01004A, Perspective
Xiaoli Kou, Shicui Jiang, Soo-Jin Park, Long-Yue Meng
Carbon quantum dots (CQDs) are widely used in optoelectronic catalysis, biological imaging, and ion probes owing to their low toxicity, stable photoluminescence, and ease of chemical modification. However, the low...
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Platinum Complexes of a Boron-Rich Diphosphine Ligand

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00963F, Paper
Marcus W. Drover, Eric G Bowes, Maeve C Dufour, Lindsay Lesperance-Nantau
Herein, we describe the preparation, characterization, and reactivity of two PtIIbis-hydrocarbyl complexes containing the 1,2-bis(di(3-dicyclohexylboraneyl)propylphosphino)ethane (P2BCy4) ligand. These scaffolds are readily accessed from four-fold hydroboration of 1,2-bis(diallylphosphino)ethane PtII precursors....
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The Spirit of Sustainability: print or digital, which is “greener”?

By www.berkshirepublishing.com
Published On :: Thu, 12 Dec 2019 17:04:40 +0000

When we published the Encyclopedia of Sustainability in 2012, a librarian wrote, “That goes against the spirit of sustainability.” I got a similar response this week, so I want to explain why we publish in print and online, and why online is not “green.” An ebook probably kills more trees through deforestation than an equivalent print book,

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First Look at the T S Eliot – Emily Hale Letters (podcast)

By www.berkshirepublishing.com
Published On :: Wed, 15 Jan 2020 00:36:24 +0000

In what one scholar called “the literary event of the decade,” on 2 January 2020, Princeton University Library opened up more than 1,100 letters that the Nobel-Prize-winning poet T.S. Eliot wrote over the course of three decades to an American speech professor and amateur actress named Emily Hale. The day became even more

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Gastrodiplomacy in China; T S Eliot’s Love Letters

By www.berkshirepublishing.com
Published On :: Fri, 21 Feb 2020 10:04:19 +0000

Chinese food, anyone? I'll be co-presenting a program about gastrodiplomacy at Schwarzman College in Beijing next month, and I am looking for stories to share, from history as well as personal experience. Schwarzman College 苏世民书院 is a residential college at Tsinghua University. Schwarzman scholarships are modeled on the Rhodes Scholarships at Oxford. The one-year MA

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  • Seeing the World
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T.S. Eliot “Got Cheese” Campaign Announced

By www.berkshirepublishing.com
Published On :: Wed, 01 Apr 2020 08:54:50 +0000

Great Barrington, MA - COVID-19 has delayed the launch of a record-setting marketing deal expected to boost international appreciation of English and European cheeses. The image and words of the Nobel Prize winning poet T S Eliot, as well as characters from the musical Cats, will be used to promote cheese and cheese products throughout the world.

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The Origins of Berkshire Publishing’s Chinese Name, 宝库山

By www.berkshirepublishing.com
Published On :: Wed, 29 Apr 2020 15:33:04 +0000

When I meet someone Chinese, in Beijing or New York or London, they often exclaim over our name. Publishers tell me how exactly right its meaning - “treasure mountain library” - is, especially for a press known for encyclopedias on global topics. I explain that 宝库山 was carefully crafted by a group of friends who

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Karen’s Letter: The Libraries We Love

By www.berkshirepublishing.com
Published On :: Thu, 30 Apr 2020 16:21:54 +0000

Last month I wrote about third places ("What is a “third place,” and do you have one?"). Along with some great stories about your favorite third places, I received a few emails blasting me for not mentioning libraries. That was a shock, since Berkshire Publishing has close ties to libraries: we’ve written and published about

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Selma and the Liuzzo murder trials: the first modern civil rights convictions / by James P. Turner

By library.mit.edu
Published On :: Sun, 21 Jul 2019 09:24:23 EDT

Dewey Library - KF224.K7 T87 2018


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The World Bank policy for projects on international waterways: an historical and legal analysis / Salman M.A. Salman

By library.mit.edu
Published On :: Sun, 28 Jul 2019 10:20:39 EDT

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Real estate finance in a nutshell / Vada Waters Lindsey, Associate Professor of Law, Marquette University Law School

By library.mit.edu
Published On :: Sun, 28 Jul 2019 10:20:39 EDT

Rotch Library - KF695.Z9 L56 2018


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Many nations under many gods: public land management and American Indian sacred sites / Todd Allin Morman

By library.mit.edu
Published On :: Sun, 28 Jul 2019 10:20:39 EDT

Rotch Library - KF5605.M67 2018


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Implementing environmental constitutionalism: current global challenges / edited by Erin Daly, James R. May

By library.mit.edu
Published On :: Sun, 28 Jul 2019 10:20:39 EDT

Rotch Library - K3585.I596 2018


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Decarcerating America: from mass punishment to public health / edited by Ernest Drucker

By library.mit.edu
Published On :: Sun, 28 Jul 2019 10:20:39 EDT

Dewey Library - KF9730.D43 2018


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Contempt: a memoir of the Clinton investigation / Ken Starr

By library.mit.edu
Published On :: Sun, 28 Jul 2019 10:20:39 EDT

Dewey Library - KF5076.C57 S72 2018


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Practitioner's guide to project-based vouchers: a successor to the Beginner's guide / Sarah Molseed and Julie S. McGovern

By library.mit.edu
Published On :: Sun, 28 Jul 2019 10:20:39 EDT

Rotch Library - KF5735.M654 2018


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Religious exemptions / edited by Kevin Vallier and Michael Weber

By library.mit.edu
Published On :: Sun, 28 Jul 2019 10:20:39 EDT

Dewey Library - K3258.R453 2018


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Networked press freedom: creating infrastructures for a public right to hear / Mike Ananny

By library.mit.edu
Published On :: Sun, 28 Jul 2019 10:20:39 EDT

Dewey Library - K3255.A958 2018


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Armed conflict and forcible displacement: individual rights under international law / edited by Elena Katselli Proukaki

By library.mit.edu
Published On :: Sun, 4 Aug 2019 10:22:43 EDT

Dewey Library - KZ6530.A75 2018


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Silenced victims of wartime sexual violence / Olivera Simić

By library.mit.edu
Published On :: Sun, 11 Aug 2019 10:25:18 EDT

Dewey Library - KZ7162.S56 2018


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Regulatory counter-terrorism: a critical appraisal of proactive global governance / Nathanael Tilahun Ali

By library.mit.edu
Published On :: Sun, 11 Aug 2019 10:25:18 EDT

Dewey Library - KZ7220.A9565 2018


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Transactional intellectual property: from startups to public companies / Richard S. Gruner, professor of law, John Marshall Law School), Shubha Ghosh (Crandall Melvin Professor of Law, director, Technology Commercialization Law Program & Syracuse Inte

By library.mit.edu
Published On :: Sun, 11 Aug 2019 10:25:18 EDT

Dewey Library - KF2980.G78 2018


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Protecting patron privacy: a LITA guide / edited by Bobbi Newman, Bonnie Tijerina

By library.mit.edu
Published On :: Sun, 11 Aug 2019 10:25:18 EDT

Hayden Library - KF4315.P76 2017


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Land use planning and development regulation law / Julian Conrad Juergensmeyer (professor and Ben F. Johnson Jr. Chair in Law, Georgia State University College of Law, adjunct professor in city and regional planning, Georgia Institute of Technology), Tho

By library.mit.edu
Published On :: Sun, 11 Aug 2019 10:25:18 EDT

Rotch Library - KF5698.J84 2018


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Killing with prejudice: institutionalized racism in American capital punishment / R. J. Maratea

By library.mit.edu
Published On :: Sun, 11 Aug 2019 10:25:18 EDT

Dewey Library - KF9227.C2 M37 2019


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The U.S. Supreme Court and racial minorities: two centuries of judicial review on trial / Leslie F. Goldstein, Judge Hugh M. Moris Professor Emerita, University of Delaware, USA

By library.mit.edu
Published On :: Sun, 11 Aug 2019 10:25:18 EDT

Dewey Library - KF8742.G65 2017


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The grey zone: civilian protection between human rights and the laws of war / edited by Mark Lattimer and Philippe Sands

By library.mit.edu
Published On :: Sun, 11 Aug 2019 10:25:18 EDT

Dewey Library - KZ6515.G74 2018


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Military professionalism and humanitarian law: the struggle to reduce the hazards of war / Yishai Beer

By library.mit.edu
Published On :: Sun, 11 Aug 2019 10:25:18 EDT

Dewey Library - KZ6396.B44 2018


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Secrecy, privacy and accountability: challenges for social research / Mike Sheaff

By library.mit.edu
Published On :: Sun, 18 Aug 2019 10:23:08 EDT

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