io Extraction empire : undermining the systems, states, & scales of Canada's global resource empire / edited by Pierre Bélanger By prospero.murdoch.edu.au Published On :: Full Article
io A Companion to U.S. Foreign Relations: Colonial Era to the Present By www.wiley.com Published On :: 2020-03-24T04:00:00Z Covers the entire range of the history of U.S. foreign relations from the colonial period to the beginning of the 21st century.A Companion to U.S. Foreign Relations is an authoritative guide to past and present scholarship on the history of American diplomacy and foreign relations from its seventeenth century origins to the modern day. This two-volume reference work presents a collection of historiographical essays by prominent scholars. The essays Read More... Full Article
io Social Movements: An Introduction, 3rd Edition By www.wiley.com Published On :: 2020-04-06T04:00:00Z A new, fully-revised and updated edition of the leading introduction to social movements and collective action –covers a broad range of approaches in the social sciences.Now in its third edition, Social Movements is the market-leading introductory text on collective action in contemporary society. The text draws from theory-driven, systematic empirical research from across the social sciences to address central questions and concepts in the field. Read More... Full Article
io Resident Foreigners: A Philosophy of Migration By www.wiley.com Published On :: 2020-04-13T04:00:00Z From the shores of Europe to the Mexican-US border, mass migration is one of the most pressing issues we face today. Yet at the same time, calls to defend national sovereignty are becoming ever more vitriolic, with those fleeing war, persecution, and famine vilified as a threat to our security as well as our social and economic order. In this book, written amidst the dark resurgence of appeals to defend ‘blood and soil’, Donatella Di Cesare challenges Read More... Full Article
io Resident Foreigners: A Philosophy of Migration By www.wiley.com Published On :: 2020-04-13T04:00:00Z From the shores of Europe to the Mexican-US border, mass migration is one of the most pressing issues we face today. Yet at the same time, calls to defend national sovereignty are becoming ever more vitriolic, with those fleeing war, persecution, and famine vilified as a threat to our security as well as our social and economic order. In this book, written amidst the dark resurgence of appeals to defend ‘blood and soil’, Donatella Di Cesare challenges Read More... Full Article
io Political Geography: A Critical Introduction By www.wiley.com Published On :: 2020-04-27T04:00:00Z Brings political geography to life—explores key concepts, critical debates, and contemporary research in the field. Political geography is the study of how power struggles both shape and are shaped by the places in which they occur—the spatial nature of political power. PoliticalGeography: A Critical Introduction helps students understand how power is related to space, place, and territory, illustrating how everyday life and the world of global conflict Read More... Full Article
io A Left that Dares to Speak Its Name: 34 Untimely Interventions By www.wiley.com Published On :: 2020-04-27T04:00:00Z With irrepressible humor, Slavoj Žižek dissects our current political and social climate, discussing everything from Jordan Peterson and sex “unicorns” to Greta Thunberg and Chairman Mao. Taking aim at his enemies on the Left, Right, and Center, he argues that contemporary society can only be properly understood from a communist standpoint.Why communism? The greater the triumph of global capitalism, the more its dangerous antagonisms multiply: climate Read More... Full Article
io A Left that Dares to Speak Its Name: 34 Untimely Interventions By www.wiley.com Published On :: 2020-04-27T04:00:00Z With irrepressible humor, Slavoj Žižek dissects our current political and social climate, discussing everything from Jordan Peterson and sex “unicorns” to Greta Thunberg and Chairman Mao. Taking aim at his enemies on the Left, Right, and Center, he argues that contemporary society can only be properly understood from a communist standpoint.Why communism? The greater the triumph of global capitalism, the more its dangerous antagonisms multiply: climate Read More... Full Article
io Transferring Axial Molecular Chirality Through a Sequence of On-Surface Reactions By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01653E, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Néstor Merino-Díez, Mohammed S. G. Mohammed, Jesus Castro, Luciano Colazzo, Alejandro Berdonces-Layunta, James Lawrence, Jose Ignacio Pascual, Dimas G. de Oteyza, Diego PeñaFine management of chiral processes on solid surfaces has progressed over the years, yet still faces the need for the controlled and selective production of advanced chiral materials. Here, we...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Cascade polymerizations: recent developments in the formation of polymer repeat units by cascade reactions By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01475C, Perspective Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Gregory I. Peterson, Tae-Lim ChoiCascade polymerizations provide new routes to unique polymer structures. In this perspective, we summarize their performance, monomer scope, and mechanisms.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Copper-catalysed photoinduced decarboxylative alkynylation: a combined experimental and computational study By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC02213F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yu Mao, Wenxuan Zhao, Shuo Lu, Lei Yu, Yi Wang, Yong Liang, Shengyang Ni, Yi PanRedox-active esters (RAEs) as alkyl radical precursors have demonstrated great advantages for Cu-catalysed C–C bond formation.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Spectroscopic investigations under whole-cell conditions provide new insight into the metal hydride chemistry of [FeFe]-hydrogenase By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00512F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lívia S. Mészáros, Pierre Ceccaldi, Marco Lorenzi, Holly J. Redman, Emanuel Pfitzner, Joachim Heberle, Moritz Senger, Sven T. Stripp, Gustav BerggrenThe mechanism of hydrogen gas formation by [FeFe] hydrogenase is probed under whole cell conditions, revealing the formation of reactive metal hydride species under physiologically relevant conditions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Evolutionary chemical space exploration for functional materials: computational organic semiconductor discovery By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00554A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Chi Y. Cheng, Josh E. Campbell, Graeme M. DayEvolutionary optimisation and crystal structure prediction are used to explore chemical space for molecular organic semiconductors.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Palladium-catalysed 5-endo-trig allylic (hetero)arylation By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01932A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Bara Singh, Siddheshwar K. Bankar, Ketan Kumar, S. S. V. RamasastryA palladium-catalysed intramolecular allylic (hetero)arylation strategy for the synthesis of fused cyclopentenes incorporated with all-carbon quaternary and spiro centres is described.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Allylic C(sp3)–H alkylation via synergistic organo- and photoredox catalyzed radical addition to imines By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00819B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jiaqi Jia, Rajesh Kancherla, Magnus Rueping, Long HuangA new catalytic method for the direct alkylation of allylic C(sp3)–H bonds from unactivated alkenes via synergistic organo- and photoredox catalysis is described.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Transformation from helical to layered supramolecular organization of asymmetric perylene diimides via multiple intermolecular hydrogen bonding By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01911A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Mengmeng Li, Wojciech Zajaczkowski, Gangamallaiah Velpula, Daniel Jänsch, Robert Graf, Tomasz Marszalek, Sapun H. Parekh, Yulian Zagranyarski, Kunal Mali, Manfred Wagner, Steven De Feyter, Chen Li, Klaus Müllen, Wojciech PisulaThe solid-state supramolecular organization of asymmetric perylene diimide is transformed from helical to layered self-assembly after thermal annealing.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Ultrafast Amidation of Esters using Lithium Amides under Aerobic Ambient Temperature Conditions in Sustainable Solvents By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01349H, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Michael Fairley, Leonie Bole, Florian Mulks, Laura Main, Alan Kennedy, Charles T. O'Hara, Joaquín García-Álvarez, Eva HeviaLithium amides constitute one of the most commonly used class of reagents in synthetic chemisty. However, despite many applications, their use is handicapped by their requirements of low temperatures, in...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Programmable synthesis of multiply arylated cubanes through C–H metalation and arylation By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01909G, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Ryo Okude, Genki Mori, Akiko Yagi, Kenichiro ItamiCubane has attracted attention due to its unique 3D structure. Herein, we report the programmable synthesis of multiply arylated cubanes. The developed reaction allows the late-stage and regioselective installation of aryl groups.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Nitric oxide monooxygenation (NOM) reaction of cobalt-nitrosyl {Co(NO)}8 to CoII-nitrito {CoII(NO2−)}: base induced hydrogen gas (H2) evolution By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01572E, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sandip Das, Kulbir, Somnath Ghosh, Subash Chandra Sahoo, Pankaj KumarBase-induced hydrogen (H2) gas evolution in the nitric oxide monoxygenation reaction.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Introduction of a 7-aza-6-MeO-indoline auxiliary in Lewis-acid/photoredox cooperative catalysis: highly enantioselective aminomethylation of α,β-unsaturated amides By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01890B, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Santosh K. Pagire, Naoya Kumagai, Masakatsu ShibasakiAn efficient cooperative chiral Lewis acid and photoredox catalytic system towards the highly enantioselective radical conjugate addition of α-amino radicals to α,β-unsaturated amides is developed with the implementation of unique auxiliaries.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Water-induced formation of an alkali-ion dimer in cryptomelane nanorods By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01517B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Shaobo Cheng, Vidushi Sharma, Altug S. Poyraz, Lijun Wu, Xing Li, Amy C. Marschilok, Esther S. Takeuchi, Kenneth J. Takeuchi, Marivi Fernández-Serra, Yimei ZhuWater displaces potassium ions and initiates the formation of a homonuclear dimer ion (K2+) in the tunnels of hollandite.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Dynamic reaction-induced phase separation in tunable, adaptive covalent networks By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00605J, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Katie M. Herbert, Patrick T. Getty, Neil D. Dolinski, Jerald E. Hertzog, Derek de Jong, James H. Lettow, Joy Romulus, Jonathan W. Onorato, Elizabeth M. Foster, Stuart J. RowanDynamic covalent networks comprised of tunable thia-Michael bonds result in phase separated networks with tailorable mechanical and adaptive properties.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Metal-metal cooperative bond activation by heterobimetallic alkyl, aryl, and acetylide PtII/CuI complexes By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC00646G, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Shubham Deolka, Orestes Rivada, Sandra L. Aristizábal, Robert R. Fayzullin, Shrinwantu Pal, Kyoko Nozaki, Eugene Khaskin, Julia R KhusnutdinovaWe report selective formation of heterobimetallic PtII/CuI complexes that demonstrate how facile bond activation processes can be achieved by altering reactivity of common organoplatinum compounds through their interaction with another...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Molecular recognition of pyrazine N,N'-dioxide using aryl extended calix[4]pyrroles By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01496F, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Chenxing Guo, Hu Wang, Vincent M. Lynch, Xiaofan Ji, Zachariah A. Page, Jonathan L. SesslerThe molecular recognition of pyrazine N,N'-dioxide by aryl extended 'two-walled' calix[4]pyrrole-based receptors is seen to stabilise two different binding modes in the solid state.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Efficient alkene hydrosilation with bis(8-quinolyl)phosphine (NPN) nickel catalysts. The dominant role of silyl-over hydrido-nickel catalytic intermediates By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00997K, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jian Yang, Verònica Postils, Michael I. Lipschutz, Meg Fasulo, Christophe Raynaud, Eric Clot, Odile Eisenstein, T. Don TilleyA cationic nickel complex of the bis(8-quinolyl)(3,5-di-tert-butylphenoxy)phosphine (NPN) ligand, [(NPN)NiCl]+, is a precursor to efficient catalysts for the hydrosilation of alkenes with hydrosilanes under mild conditions and low catalyst loadings.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Triblock polyester thermoplastic elastomers with semi-aromatic polymer end blocks by ring-opening copolymerization By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00463D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Georgina L. Gregory, Gregory S. Sulley, Leticia Peña Carrodeguas, Thomas T. D. Chen, Alba Santmarti, Nicholas J. Terrill, Koon-Yang Lee, Charlotte K. WilliamsA new series of block polyester thermoplastic elastomers are prepared by a one-pot procedure; they show properties competitive or better than conventional materials and can be fully degraded after use.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Stereo-controlled anti-hydromagnesiation of aryl alkynes by magnesium hydrides By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01773F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Bin Wang, Derek Yiren Ong, Yihang Li, Jia Hao Pang, Kohei Watanabe, Ryo TAKITA, Shunsuke ChibaA concise protocol for anti-hydromagnesiation of aryl alkynes was established using 1:1 molar combination of sodium hydride (NaH) and magnesium iodide (MgI2) without the aid of any transition metal catalysts....The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Ring-Fused Cyclobutanes via Cycloisomerization of Alkylidenecyclopropane Acylsilanes By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC02224A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Erick M Carreira, Sarah S Eichenberger, Moritz Hönig, Matthieu JR Richter, Renana Gershoni-PoranneA novel Lewis acid-catalyzed cycloisomerization of alkylidenecyclopropane acylsilanes is disclosed. The readily available starting materials participate in tandem Prins addition/ring expansion/1,2-silyl shift to grant access to bicyclo[4.2.0]octanes and bicyclo[3.2.0]heptanes, which...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Structure and redox tuning of gas adsorption properties in calixarene-supported Fe(II)-based porous cages By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01833C, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Meaghan Deegan, Tonia Ahmed, Glenn Yap, Eric D BlochWe describe the synthesis of Fe(II)-based octahedral coordination cages supported by calixarene capping ligands. The most porous of these molecular cages has an argon accessible BET surface area of 898...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Nickel catalysis enables convergent paired electrolysis for direct arylation of benzylic C–H bonds By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01445A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lei Zhang, Xile HuA direct arylation of benzylic C–H bonds is achieved by integrating Ni-catalyzed benzyl–aryl coupling into convergent paired electrolysis.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Pore engineering of ultrathin covalent organic framework membranes for organic solvent nanofiltration and molecular sieving By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01679A, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Digambar B. Shinde, Li Cao, A. D. Dinga Wonanke, Xiang Li, Sushil Kumar, Xiaowei Liu, Mohamed N. Hedhili, Abdul-Hamid Emwas, Matthew Addicoat, Kuo-Wei Huang, Zhiping LaiPore surface engineering of ultrathin COF membranes by introducing different lengths of alkyl chains into the skeleton, which allows us to precisely control the pore size of COF membranes for OSN applications and molecular sieving.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Speciation of Be2+ in acidic liquid ammonia and formation of tetra- and octanuclear beryllium amido clusters By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01112F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Matthias Müller, Antti J Karttunen, Magnus Richard BuchnerThe hexa-μ2-amido-tetraammine-tetraberyllium compounds [Be4(NH2)6(NH3)4]X2 (X = Cl, Br, I, CN, SCN, N3) have been prepared from beryllium metal and NH4X or [Be(NH3)4]X2 in liquid ammonia at ambient temperature. The obtained...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Regioselective B(3,4)–H Arylation of o-Carboranes by Weak Amide Coordination at Room Temperature By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01515F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yu-Feng Liang, Long Yang, Becky Bongsuiru Jei, Rositha Kuniyil, Lutz AckermannPalladium-catalyzed regioselective di- or mono-arylation of o-carboranes was achieved by weakly coordinating amides at room temperature. Thereby, a series of B(3,4)-diarylated and B(3)-monoarylated o-carboranes anchored with valuable functional groups were...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Rapidly Self-deoxygenating Controlled Radical Polymerization in water via in-situ Disproportionation of Cu(I) By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01512A, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.David Haddleton, Evelina Liarou, Yisong Han, Marc Walker, Ana SanchezThe first rapidly self-deoxygenating Cu-RDRP in aqueous media is investigated. The disproportionation of Cu(I)/Me6Tren in water towards Cu(II) and highly reactive Cu(0) leads to O2-free reaction environments within the first...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Biofunctional Janus Particles Promote Phagocytosis of Tumor Cells by Macrophages By feeds.rsc.org Published On :: Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC01146K, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ya-Ru Zhang, Jia-Qi Luo, Jia-Xian Li, Qiu-Yue Huang, Xiao-Xiao Shi, Yong-Cong Huang, Kam W Leong, Weiling He, Jinzhi DuHerein, a versatile strategy for the construction of biofunctional Janus particles (JPs) through the combination of Pickering emulsion and copper-free click chemistry is developed for the study of particle-mediated cell-cell interactions. A...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Structural trends in the dehydrogenation selectivity of palladium alloys By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC00875C, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Stephen C. Purdy, Ranga Rohit Seemakurthi, Garrett M. Mitchell, Mark Davidson, Brooke A. Lauderback, Siddharth Deshpande, Zhenwei Wu, Evan C. Wegener, Jeffrey Greeley, Jeffrey T. MillerAlloying is well-known to improve the dehydrogenation selectivity of pure metals, but there remains considerable debate about the structural and electronic features of alloy surfaces that give rise to this behavior.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Evolution of pure hydrocarbon hosts: simpler structure, higher performance and universal application in RGB phosphorescent organic light-emitting diodes By feeds.rsc.org Published On :: Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC01238F, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Qiang Wang, Fabien Lucas, Cassandre Quinton, Yang-Kun Qu, Joëlle Rault-Berthelot, Olivier Jeannin, Sheng-Yi Yang, Fan-Cheng Kong, Sarvendra Kumar, Liang-Sheng Liao, Cyril Poriel, Zuo-Quan JiangIn this work, we propose pure hydrocarbon materials as universal hosts for high-efficiency red, green and blue phosphorescent organic light-emitting diodes.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Recent developments in nickel-catalyzed intermolecular dicarbofunctionalization of alkenes By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4287-4296DOI: 10.1039/C9SC06006E, Minireview Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Joseph Derosa, Omar Apolinar, Taeho Kang, Van T. Tran, Keary M. EngleNickel-catalyzed three-component alkene difunctionalization has rapidly emerged as a powerful tool for forging multiple C–C bonds in a single step.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Redox-responsive supramolecular polymeric networks having double-threaded inclusion complexes By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4322-4331DOI: 10.1039/C9SC05589D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Hikaru Aramoto, Motofumi Osaki, Subaru Konishi, Chiharu Ueda, Yuichiro Kobayashi, Yoshinori Takashima, Akira Harada, Hiroyasu YamaguchiA hydrogel actuator with a 1:2 host–guest complex controlled by redox stimuli has been developed to realize faster and larger deformation.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Exploiting single-electron transfer in Lewis pairs for catalytic bond-forming reactions By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4305-4311DOI: 10.1039/D0SC01159B, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yoshitaka Aramaki, Naoki Imaizumi, Mao Hotta, Jun Kumagai, Takashi OoiRadical–ion pair generation from common Lewis pairs and its application to catalytic carbon–carbon bond formation.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io SAXS studies of the thermally-induced fusion of diblock copolymer spheres: formation of hybrid nanoparticles of intermediate size and shape By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4312-4321DOI: 10.1039/D0SC00569J, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.E. J. Cornel, P. S. O'Hora, T. Smith, D. J. Growney, O. O. Mykhaylyk, S. P. ArmesDilute dispersions of poly(lauryl methacrylate)-poly(benzyl methacrylate) diblock copolymer spheres of differing mean diameter are mixed and thermally annealed at 150 °C to produce either spherical or non-spherical nanoparticles of intermediate size.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io An RGB-emitting molecular cocktail for the detection of bacterial fingerprints By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4403-4409DOI: 10.1039/D0SC01704C, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sheng Hong, Di-Wei Zheng, Qiu-Ling Zhang, Wei-Wei Deng, Wen-Fang Song, Si-Xue Cheng, Zhi-Jun Sun, Xian-Zheng ZhangA technique named the Microcolor system was developed to detect microbes and diagnose diseases based on changes in microbiota signatures.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Redox-inactive ions control the redox-activity of molecular vanadium oxides By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4450-4455DOI: 10.1039/D0SC01401J, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Simon Greiner, Benjamin Schwarz, Mark Ringenberg, Maximilian Dürr, Ivana Ivanovic-Burmazovic, Maximilian Fichtner, Montaha Anjass, Carsten StrebThe enhanced redox-activity of a molecular vanadium oxide cluster upon functionalization with redox-inert Ca2+ ions is reported together with initial insights into its performance as a lithium ion battery cathode.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io A pH ratiometrically responsive surface enhanced resonance Raman scattering probe for tumor acidic margin delineation and image-guided surgery By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4397-4402DOI: 10.1039/D0SC00844C, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Wenjia Duan, Qi Yue, Ying Liu, Yunfei Zhang, Qinghua Guo, Cong Wang, Shujie Yin, Dandan Fan, Wenjing Xu, Jiexian Zhuang, Jiachao Gong, Xinwei Li, Ruimin Huang, Liang Chen, Silvio Aime, Zhongliang Wang, Jianfeng Feng, Ying Mao, Xiao-Yong Zhang, Cong LiA novel pH ratiometrically responsive surface-enhanced resonance Raman scattering (SERRS) probe was developed for tumor acidic margin delineation and image-guided surgery.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io What is the role of acid–acid interactions in asymmetric phosphoric acid organocatalysis? A detailed mechanistic study using interlocked and non-interlocked catalysts By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4381-4390DOI: 10.1039/D0SC01026J, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Dennis Jansen, Johannes Gramüller, Felix Niemeyer, Torsten Schaller, Matthias C. Letzel, Stefan Grimme, Hui Zhu, Ruth M. Gschwind, Jochen NiemeyerSupramolecular acid–acid interactions lead to competing monomeric and dimeric pathways in phosphoric acid catalysis – so that stereoselectivities depend on catalyst concentration.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Ortho C–H arylation of arenes at room temperature using visible light ruthenium C–H activation By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4439-4443DOI: 10.1039/D0SC01289K, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Arunachalam Sagadevan, Anastasios Charitou, Fen Wang, Maria Ivanova, Martin Vuagnat, Michael F. GreaneyA ruthenium-catalyzed ortho C–H arylation process is described using visible light.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Intramolecular Csp3–H/C–C bond amination of alkyl azides for the selective synthesis of cyclic imines and tertiary amines By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4482-4487DOI: 10.1039/C9SC05522C, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xiaojin Wen, Xinyao Li, Xiao Luo, Weijin Wang, Song Song, Ning JiaoA novel intramolecular cyclization of alkyl azides for the synthesis of cyclic imines and tertiary amines has been developed. The aliphatic C–H or C–C bond was selectively cleaved with the efficient formation of two C–N single bonds or a CN double bond.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Chemical synthesis and immunological evaluation of new generation multivalent anticancer vaccines based on a Tn antigen analogue By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4488-4498DOI: 10.1039/D0SC00544D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Carlo Pifferi, Ane Ruiz-de-Angulo, David Goyard, Claire Tiertant, Nagore Sacristán, Diego Barriales, Nathalie Berthet, Juan Anguita, Olivier Renaudet, Alberto Fernández-TejadaA fully-synthetic anticancer vaccine candidate incorporating an hexadecavalent Tn antigen analogue display via oxime linkages induced tumor-specific IgG antibodies and cellular immune responses in mice coadministered with QS-21 as an adjuvant.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io Hydrogen peroxide reduction on single platinum nanoparticles By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4416-4421DOI: 10.1039/D0SC00379D, Edge Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xin Chang, Christopher Batchelor-McAuley, Richard G. ComptonAt the single platinum nanoparticle scale the hydrogen peroxide reduction reaction is a surface limited process.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
io The structures of ordered defects in thiocyanate analogues of Prussian Blue By feeds.rsc.org Published On :: Chem. Sci., 2020, 11,4430-4438DOI: 10.1039/D0SC01246G, Edge Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Matthew J. Cliffe, Evan N. Keyzer, Andrew D. Bond, Maxwell A. Astle, Clare P. GreyWe report the structures of six new divalent transition metal hexathiocyanatobismuthate Prussian Blue analogues frameworks, which contain complex ordered defect structures.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
