io

J-dimer emission in interwoven metal–organic frameworks

Chem. Sci., 2020, 11,4391-4396
DOI: 10.1039/D0SC00876A, Edge Article
Open Access
Wesley J. Newsome, Arnab Chakraborty, Richard T. Ly, Gavin S. Pour, David C. Fairchild, Amanda J. Morris, Fernando J. Uribe-Romo
J-dimer emission is an emergent property that occurs when pairs of ground-state fluorophores associate within multivariate MOFs producing tunable red shifted emission.
The content of this RSS Feed (c) The Royal Society of Chemistry




io

Biocatalytic reversible control of the stiffness of DNA-modified responsive hydrogels: applications in shape-memory, self-healing and autonomous controlled release of insulin

Chem. Sci., 2020, 11,4516-4524
DOI: 10.1039/D0SC01319F, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Chen Wang, Amit Fischer, Avner Ehrlich, Yaakov Nahmias, Itamar Willner
Biocatalytic control over the stiffness of pH-responsive hydrogels is applied to develop shape-memory, self-healing and controlled release matrices.
The content of this RSS Feed (c) The Royal Society of Chemistry




io

Metal-free carbon monoxide-releasing micelles undergo tandem photochemical reactions for cutaneous wound healing

Chem. Sci., 2020, 11,4499-4507
DOI: 10.1039/D0SC00135J, Edge Article
Open Access
Jian Cheng, Bin Zheng, Sheng Cheng, Guoying Zhang, Jinming Hu
Metal-free carbon monoxide-releasing polymers (CORPs) are synthesized via a direct polymerization approach, exhibiting not only improved stability but also accelerated wound healing performance as compared to CORM-3.
The content of this RSS Feed (c) The Royal Society of Chemistry




io

Correction: Metal complexes as a promising source for new antibiotics

Chem. Sci., 2020, 11,4531-4531
DOI: 10.1039/D0SC90075C, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Angelo Frei, Johannes Zuegg, Alysha G. Elliott, Murray Baker, Stefan Braese, Christopher Brown, Feng Chen, Christopher G. Dowson, Gilles Dujardin, Nicole Jung, A. Paden King, Ahmed M. Mansour, Massimiliano Massi, John Moat, Heba A. Mohamed, Anna K. Renfrew, Peter J. Rutledge, Peter J. Sadler, Matthew H. Todd, Charlotte E. Willans, Justin J. Wilson, Matthew A. Cooper, Mark A. T. Blaskovich
The content of this RSS Feed (c) The Royal Society of Chemistry




io

Mapping the multi-step mechanism of a photoredox catalyzed atom-transfer radical polymerization reaction by direct observation of the reactive intermediates

Chem. Sci., 2020, 11,4475-4481
DOI: 10.1039/D0SC01194K, Edge Article
Open Access
Luke Lewis-Borrell, Mahima Sneha, Aditi Bhattacherjee, Ian P. Clark, Andrew J. Orr-Ewing
Short-lived intermediates are tracked in real-time by transient absorption spectroscopy during a multi-step photoredox catalysed polymerization reaction.
The content of this RSS Feed (c) The Royal Society of Chemistry




io

Designing naphthopyran mechanophores with tunable mechanochromic behavior

Chem. Sci., 2020, 11,4525-4530
DOI: 10.1039/D0SC01359E, Edge Article
Open Access
Brooke A. Versaw, Molly E. McFadden, Corey C. Husic, Maxwell J. Robb
Structure–activity relationships for strategic substitution of the naphthopyran mechanophore scaffold enable polymeric materials with tunable mechanochromic behavior.
The content of this RSS Feed (c) The Royal Society of Chemistry




io

Multifunctional streptavidin–biotin conjugates with precise stoichiometries

Chem. Sci., 2020, 11,4422-4429
DOI: 10.1039/D0SC01589J, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Dongdong Xu, Seraphine V. Wegner
Multifunctional streptavidin-biotin conjugates with defined stoichiometry and number of open binding pockets provide molecularly precise alternatives to the statistical mixture of products that typically forms.
The content of this RSS Feed (c) The Royal Society of Chemistry




io

Small-molecule fluorescent probes for imaging gaseous signaling molecules: current progress and future implications

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01482F, Perspective
Open Access
Mingwang Yang, Jiangli Fan, Jianjun Du, Xiaojun Peng
This perspective article aims to introduce the design principles and recognition strategies of small-molecule fluorescent probes which are applied for the detection of gas signaling molecules including NO, CO and H2S in biological systems.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




io

Redox deracemization of β,γ-alkynyl α-amino esters

Chem. Sci., 2020, 11,4444-4449
DOI: 10.1039/D0SC00944J, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lu Zhang, Rongxiu Zhu, Aili Feng, Changyin Zhao, Lei Chen, Guidong Feng, Lei Liu
A one-pot deracemization of β,γ-alkynyl α-amino esters consisting of an aerobic oxidation and chiral phosphoric acid-catalyzed asymmetric transfer hydrogenation has been described.
The content of this RSS Feed (c) The Royal Society of Chemistry




io

Functional group interaction profiles: a general treatment of solvent effects on non-covalent interactions

Chem. Sci., 2020, 11,4456-4466
DOI: 10.1039/D0SC01288B, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Mark D. Driver, Mark J. Williamson, Joanne L. Cook, Christopher A. Hunter
Functional group interaction profiles are a quantitative tool for predicting the effect of solvent on the free energy changes associated with non-covalent interactions.
The content of this RSS Feed (c) The Royal Society of Chemistry




io

Enantioselective total synthesis of (−)-myrifabral A and B

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01141J, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tyler J. Fulton, Anthony Y. Chen, Michael D. Bartberger, Brian M. Stoltz
A catalytic enantioselective approach to the Myrioneuron alkaloids (−)-myrifabral A and (−)-myrifabral B is described.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




io

Selective electrochemical reduction of carbon dioxide to ethanol via a relay catalytic platform

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01133A, Edge Article
Open Access
Juan Du, Shaopeng Li, Shulin Liu, Yu Xin, Bingfeng Chen, Huizhen Liu, Buxing Han
The relay catalytic platform is very efficient and selective for CO2 electroreduction to ethanol.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




io

Geometric landscapes for material discovery within energy–structure–function maps

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00049C, Edge Article
Open Access
Seyed Mohamad Moosavi, Henglu Xu, Linjiang Chen, Andrew I. Cooper, Berend Smit
We introduce a representation for the geometric features of the pores of porous molecular crystals. This representation provides a good basis for supervised (predict adsorption properties) and unsupervised (polymorph classification) tasks.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




io

Ultraviolet photochemistry of ethane: implications for the atmospheric chemistry of the gas giants

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01746A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yao Chang, Jiayue Yang, Zhichao Chen, Zhiguo Zhang, Yong Yu, Qingming Li, Zhigang He, Weiqing Zhang, Guorong Wu, Rebecca A. Ingle, Matthew Bain, Michael N. R. Ashfold, Kaijun Yuan, Xueming Yang, Christopher S. Hansen
The vacuum ultraviolet photodissociation dynamics of ethane provide clues for modelling the atmospheric chemistry of the gas giants.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




io

Determination of protein-ligand binding modes using fast multi-dimensional NMR with hyperpolarization

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC00266F, Edge Article
Open Access
Yunyi Wang, Jihyun Kim, Christian Hilty
Elucidation of small molecule-protein interactions provides essential information for understanding biological processes such as cellular signaling, as well as for rational drug development. Here, multi-dimensional NMR with sensitivity enhancement by...
The content of this RSS Feed (c) The Royal Society of Chemistry




io

Enlightening advances in polymer bioconjugate chemistry: light-based techniques for grafting to and from biomacromolecules

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01544J, Perspective
Open Access
Rebecca A. Olson, Angie B. Korpusik, Brent S. Sumerlin
Light-driven synthetic techniques have revolutionized polymer–biomacromolecule conjugation. This Perspective discusses the benefits of photochemistry for polymer–protein ligation and considerations when designing a new light-driven conjugation approach.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




io

Quinone Methide Dimers Lacking Labile Hydrogen Atoms Are Surprisingly Excellent Radical-Trapping Antioxidants

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC02020F, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Derek A. Pratt, Mark A R Raycroft, Jean-Philippe R Chauvin, Matthew Galliher, Kevin Romero, Corey Stephenson
Hydrogen atom transfer (HAT) is the mechanism by which the vast majority of radical-trapping antioxidants (RTAs), such as hindered phenols, inhibit autoxidation. As such, at least one weak O–H bond...
The content of this RSS Feed (c) The Royal Society of Chemistry




io

Correction: Enantioselective synthesis of isochromans and tetrahydroisoquinolines by C–H insertion of donor/donor carbenes

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC90081H, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Leslie A. Nickerson, Benjamin D. Bergstrom, Mingchun Gao, Yuan-Shin Shiue, Croix J. Laconsay, Matthew R. Culberson, Walker A. Knauss, James C. Fettinger, Dean J. Tantillo, Jared T. Shaw
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




io

Regioselective Molybdenum-catalyzed allylic substitution of tertiary allylic electrophiles: methodology development and applications

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01763A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Muhammad Salman, Yaoyao Xu, Shahid Khan, Junjie Zhang, Ajmal Khan
The first molybdenum-catalyzed allylic sulfonylation of tertiary allylic electrophile is described. The method utilizes a readily accesable catalyst (Mo(CO)6/2,2'-bipyridine, both are commercially available) and represent the first example of the...
The content of this RSS Feed (c) The Royal Society of Chemistry




io

Vibrational characterization of a diiron bridging hydride complex – a model for hydrogen catalysis

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01290D, Edge Article
Open Access
Leland Bruce Gee, Vladimir Pelmenschikov, Hongxin Wang, Nakul Mishra, Yu-Chiao Liu, Yoshitaka Yoda, Kenji TAMASAKU, Ming-Hsi Chiang, Stephen P Cramer
A diiron complex containing a bridging hydride and a protonated terminal thiolate of the form [(μ,κ2-bdtH)(μ-PPh2)(μ-H)Fe2(CO)5]+ has been investigated through 57Fe nuclear resonance vibrational spectroscopy (NRVS) and interpreted using density...
The content of this RSS Feed (c) The Royal Society of Chemistry




io

Direct and quantitative monitoring of catalytic organic reactions under heterogeneous conditions using direct analysis in real time mass spectrometry

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00021C, Edge Article
Open Access
Koichiro Masuda, Shū Kobayashi
A direct and quantitative method for monitoring heterogeneous organic reactions has been developed by using direct analysis in real time mass spectrometry (DART-MS) with an isotope-labeled reaction product as an internal standard.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




io

Sequential C–O decarboxylative vinylation/C–H arylation of cyclic oxalates via a nickel-catalyzed multicomponent radical cascade

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01471K, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Huan Li, Lei Guo, Xiaoliang Feng, Liping Huo, Shengqing Zhu, Lingling Chu
A selective, sequential C–O decarboxylative vinylation/C–H arylation of cyclic alcohol derivatives enabled by visible-light photoredox/nickel dual catalysis has been described.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




io

Cancer cell discrimination and dynamic viability monitoring through wash-free bioimaging using AIEgens

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01213K, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ruoyao Zhang, Guangle Niu, Qing Lu, Xiaolin Huang, Joe H. C. Chau, Ryan T. K. Kwok, Xiaoqiang Yu, Min-Hui Li, Jacky W. Y. Lam, Ben Zhong Tang
We present a series of AIEgens for cancer cell discrimination and dynamic viability monitoring.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




io

Near-infrared light-activated membrane fusion for cancer cell therapeutic applications

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC00863J, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Fujian Huang, Ruilin Duan, Zhixin Zhou, Margarita Vázquez-González, fan xia, Itamar Willner
The spatiotemporal stimulation of liposome-liposome or liposome-membrane fusion processes attracts growing interest as a means to mimic cell-cell interactions in nature and for using these processes for biomedical applications. We...
The content of this RSS Feed (c) The Royal Society of Chemistry




io

Observations of tetrel bonding between sp3–carbon and THF

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01559H, Edge Article
Open Access
Victoria V. L. Heywood, T. P. J. Alford, Julius J.J. Roeleveld, Siebe S. J. Lekanne-Deprez, Abraham A. Verhoofstad, Jarl Ivar van der Vlugt, Melanie Schnell, Sérgio R Domingos, Anthony P. Davis, Tiddo Jonathan Mooibroek
We report the direct observation of tetrel bonding interactions between sp3-carbons of the supramolecular synthon 3,3-dimethyl-tetracyanocyclopropane (1) and tetrahydrofuran in the gas and crystalline phase. The intermolecular contact is established...
The content of this RSS Feed (c) The Royal Society of Chemistry




io

The Endeavor of Vibration-Induced Emission (VIE) for Dynamic Emissions

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01591A, Perspective
Open Access
Zhiyun Zhang, Guangchen Sun, Wei Chen, Jianhua Su, He Tian
Organic chromophores with large Stokes shifts and dual emissions are fascinating because of their fundamental and application interests. Vibration-induced emission (VIE) refers to a tunable multiple fluorescence exhibited by saddle-shaped...
The content of this RSS Feed (c) The Royal Society of Chemistry




io

Enhancing catalytic alkane hydroxylation by tuning the outer coordination sphere in a heme-containing metal–organic framework

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01796E, Edge Article
Open Access
David Zhi Hong Zee, T. David Harris
Catalytic heme active sites of enzymes are sequestered by the protein superstructure and are regulated by precisely defined outer coordination spheres. Here, we emulate both of these protective functions in...
The content of this RSS Feed (c) The Royal Society of Chemistry




io

Electrochemical Radical Reactions of Alkyl Iodides: A Highly Efficient, Clean, Green Alternative to Tin Reagents

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01694B, Edge Article
Open Access
diyuan Li, Tsz-Kan Ma, Reuben J Scott, Jonathan David Wilden
An electrochemical ‘redox-relay’ system has been developed which allows the generation of C-centered radicals. Intermolecular ‘tin-like’ radical reactions can subsequently be conducted under the most benign of conditions. The yields...
The content of this RSS Feed (c) The Royal Society of Chemistry




io

YES Bank okays board reconstitution; Prashant Kumar to be new MD & CEO

The other board members will be Sunil Mehta, former non-executive chairman of Punjab National Bank, as the non executive chairman of YES Bank




io

Now, write letters & send cards to Covid warriors

Writing letters may have become a passé, but thanks to the initiative of Patna postal division, many city residents are now thanking corona warriors by sending them personal handwritten letters or greeting cards.




io

Japan IPO cancellations hit record this month on coronavirus

Investors who had planned to buy new offerings might opt for existing start-up shares instead.




io

Applied learning design in an online teacher-education course / Jillian J. Downing

Downing, Jillian J., author




io

Parent perceptions of their school council / Leonie M. Southwell

Southwell, Leonie, M., author




io

International guide to student achievement / edited by John Hattie, Eric M. Anderman




io

National Strategy for International Education 2025 / Australian Government

Australia, author, issuing body




io

Interim report : first steps for improving educational opportunities for Aboriginal and Torres Strait Islander students / House of Representatives Standing Committee on Indigenous Affairs

Australia. Parliament. House of Representatives. Standing Committee on Indigenous Affairs, author, issuing body




io

Educating for sustainability / Energy Action Australia

Energy Action Australia




io

Reflective teaching in higher education / Paul Ashwin and [and 10 others]

Ashwin, Paul, 1970-




io

Researching higher education : international perspectives on theory, policy and practice / edited by Jennifer M. Case and Jeroen Huisman




io

The Humboldtian tradition : origins and legacies / edited by Peter Josephson, Thomas Karlsohn, Johan Östling




io

The value of international education to Australia / prepared by Deloitte Access Economics

Deloitte Access Economics




io

Understanding the University : institution, idea, possibilities / Ronald Barnett

Barnett, Ronald, 1947- author




io

Teaching and learning for the twenty-first century : educational goals, policies, and curricula from six nations / Fernando M. Reimers, Connie K. Chung, editors




io

Observation [videorecording] : the developing child / Magna Systems, Inc. ; program producers, Shanta and Milan Herzog ; design and script, Janet Gonzalez-Mena ; editor, Susan Jenkins




io

Professional development, instructional intelligence and teacher emotions : a mixed methods study of a four-year systemic change initiative / by Rebecca Ann Saunders

Saunders, Rebecca Ann, author




io

Corporate humanities in higher education : moving beyond the neoliberal academy / Jeffrey R. Di Leo

Di Leo, Jeffrey R., author




io

International handbook of research on conceptual change / edited by Stella Vosniadou




io

Alternatives to privatizing public education and curriculum : Festschrift in honor of Dale D. Johnson / by Daniel Ness & Stephen J. Farenga




io

The abandoned generation : democracy beyond the culture of fear / Henry A. Giroux

Giroux, Henry A




io

America's education deficit and the war on youth / by Henry A. Giroux

Giroux, Henry A