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A disorder-free conformation boosts phonon and charge transfer in an electron-deficient-core-based non-fullerene acceptor

J. Mater. Chem. A, 2020, 8,8566-8574
DOI: 10.1039/D0TA01260B, Paper
Chujun Zhang, Jun Yuan, Ka Lok Chiu, Hang Yin, Weifang Liu, Guanhaojie Zheng, Johnny Ka Wai Ho, Suzhen Huang, Gaoxing Yu, Feng Gao, Yingping Zou, Shu Kong So
A disorder-free molecular conformation caused by alkyl side chains facilitates electron transport, heat transfer and reduces electronic disorder.
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Achieving a 2.7 V aqueous hybrid supercapacitor by the pH-regulation of electrolyte

J. Mater. Chem. A, 2020, 8,8648-8660
DOI: 10.1039/D0TA02926B, Paper
Lijun Su, Qingnuan Zhang, Yue Wang, Jianing Meng, Yongtai Xu, Lingyang Liu, Xingbin Yan
We present an effective electrolyte pH-regulation strategy for cation-intercalated manganese oxides to extend the voltage window of aqueous supercapacitors.
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Moisture-tolerant and high-quality α-CsPbI3 films for efficient and stable perovskite solar modules

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA01968B, Paper
Ruihao Chen, Yong Hui, Binghui Wu, Yongke Wang, Xiaofeng Huang, Zhongyuan Xu, Pengpeng Ruan, Wuyong Zhang, Fangwen Cheng, Weijie Zhang, Jun Yin, Jing Li, Nanfeng Zheng
Crown ether effectively stabilizes the cubic phase of CsPbI3 to inhibit the moisture invasion and phase transformation of CsPbI3 films, producing large-area devices and improving device performance.
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Simultaneously improving the photovoltaic parameters of organic solar cells via isomerization of benzo[b]benzo[4,5]thieno[2,3-d]thiophene-based octacyclic non-fullerene acceptors

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA00451K, Paper
Zhijie Zhou, Jiamin Duan, Linglong Ye, Guo Wang, Bin Zhao, Songting Tan, Ping Shen, Hwa Sook Ryu, Han Young Woo, Yanming Sun
Three isomeric FREAs were synthesized and applied in organic solar cells. The OSC devices based on Z1-bb exhibited a PCE of 12.66%. The isomerization of a fused-ring core could be achieve high-performance OSCs with high Jsc, Voc, and FF.
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Decoupled electrolytes towards enhanced energy and high temperature performance of thermally regenerative ammonia batteries

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA03236K, Paper
Weiguang Wang, Gequn Shu, Xiuping Zhu, Hua Tian
An electrolyte decoupling strategy is proposed for ammonia batteries to restrain the self-discharge and enhance energy density as well as power generation at high temperatures.
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Inexpensive thermochemical energy storage utilising additive enhanced limestone

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA03080E, Paper
Kasper T. Møller, Ainee Ibrahim, Craig E. Buckley, Mark Paskevicius
A thermochemical energy storage capacity retention of up to 90% over 500 cycles is achieved in cheap and abundant limestone.
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An asymmetrical A–DAD–A-type acceptor simultaneously enhances voltage and current for efficient organic solar cells

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA03128C, Paper
Hanjian Lai, Hui Chen, Yulin Zhu, Lin Chen, Hsin-Hsiang Huang, Feng He
This work provides a strategy of symmetry breaking in an A–DAD–A-type acceptor with a PCE of 15.43%, which is the highest value reported to date for asymmetrical fused-ring acceptors.
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Hollow PtCu Nanoparticles Encapsulated into Carbon Shell via Mild Annealing of Metal-Organic Frameworks

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA01549K, Paper
Guanjun Chen, Huaqiang Shan, Yan Li, Hongwei Bao, Tingwei Hu, Long Zhang, Shuai Liu, Fei Ma
Alloying Pt with less expensive 3d transition metal to form bimetallic nanoparticles (NPs) has been proven to be an ideal strategy for synthesis of catalysts, especially in the field of...
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Optical in-situ monitoring during the synthesis of halide perovskite solar cells reveals formation kinetics and evolution of optoelectronic properties

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA01237H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Klara Suchan, Justus Just, Pascal Becker, Eva Lisa Unger, Thomas Unold
The formation mechanism and the evolution of optoelectronic properties during annealing of chlorine-derived methylammonium lead iodide (MAPbI3-xClx) is investigated in detail combining in-situ und ex-situ optical and structural characterization. Using...
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Three-dimensional interconnected V6O13 nest with V5+-rich state for ultrahigh Zn ion storage

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA03165H, Paper
Pingge He, Jiaohao Liu, Xudong Zhao, Zhenping Ding, Peng Gao, Li-Zhen Fan
Aqueous zinc ion batteries (ZIBs) have attracted intensive attention due to their low cost, environmental friendliness and high safety. However, exploring suitable cathode materials and deep understanding of their energy...
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Hydrogen generation from toxic formaldehyde catalyzed by low-cost Pd–Sn alloys driven by visible light

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA02833A, Paper
Hongxia Liu, Meng Wang, Jiantai Ma, Gongxuan Lu
New high active low-cost Pd-Sn alloy catalyst for hydrogen evolution from toxic formaldehyde driven by visible light was developed via alloying of Pd with abundance element Sn.
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The rational and effective design of nonfullerene acceptors guided by a semi-empirical model for an organic solar cell with an efficiency over 15%

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA03087B, Paper
Xin Ke, Lingxian Meng, Xiangjian Wan, Mingpeng Li, Yanna Sun, Ziqi Guo, Simin Wu, Hongtao Zhang, Chenxi Li, Yongsheng Chen
Guided by a semi-empirical model, two small-molecule acceptors were rationally designed and an impressive PCE of 15.05% was achieved.
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Highly efficient and durable aqueous electrocatalytic reduction of CO2 to HCOOH with a novel bismuth–MOF: experimental and DFT studies

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA00384K, Paper
Xurui Zhang, Yanxing Zhang, Qingqing Li, Xiaodong Zhou, Qingyu Li, Jin Yi, Yuyu Liu, Jiujun Zhang
Electrochemical reduction of carbon dioxide (ERCO2) to low-carbon fuel and useful chemicals, which can simultaneously store renewable energy and recover CO2 in a green manner, has proven to be a viable energy storage and conversion strategy.
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A Cu2B2 monolayer with planar hypercoordinate motifs: an efficient catalyst for CO electroreduction to ethanol

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA02471F, Paper
Jingjing Jia, Haijun Zhang, Zhongxu Wang, Jingxiang Zhao, Zhen Zhou
By means of first-principles computations, we identified that metallic Cu2B2 monolayer with planar heptacoordinate motifs could effectively reduce CO to ethanol through the “carbene” mechanism with a low limiting potential and a small barrier for C–C coupling.
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Semiconducting polymer contributes favorably to the Seebeck coefficient in multi-component, high-performance n-type thermoelectric nanocomposites

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA02388D, Paper
Junhui Tang, Ruisi Chen, Lidong Chen, Guillermo C. Bazan, Ziqi Liang
n-Type Co NWs/N2200 TENCs yield a high S, mainly from the semiconducting polymer, yet σ is limited by poor connectivity between inorganic and organic domains. By adding flexible n-doped SWCNTs to yield more conductive paths, σ and mechanical bendability are greatly enhanced.
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Rational design of high nitrogen-doped and core–shell/mesoporous carbon nanospheres with high rate capability and cycling longevity for pseudocapacitive sodium storage

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA03229H, Paper
Jiayi Mao, Dechao Niu, Nan Jiang, Guangyu Jiang, Meiwan Chen, Yongsheng Li, Jianlin Shi
A facile soft-template strategy is developed to construct high-nitrogen-doped and core–shell/mesoporous carbon nanospheres for high-rate and long-term stable sodium-ion batteries.
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Smart Porous Wood Supported Flower-like NiS/Ni Conjuction with Vitrimer Co-effect as Multifunctional Material with Reshaping, Shape-memory and Self-healing for High-Performance Supercapacitors, Catalysts and Sensors

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA03664A, Paper
Chuanyin Xiong, Bingbing Li, Heguang Liu, Wei Zhao, Chao Duan, Haiwei Wu, Yong Ni
Wood-based materials are attracting more and more attention for applications in energy storage, due to their environment friendly and numerous channels structure. However, the poor conductivity and flexibility of wood...
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A novel integrated Cr(VI) adsorption–photoreduction system using MOF@polymer composite beads

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA01046D, Paper
Bardiya Valizadeh, Tu N. Nguyen, Stavroula Kampouri, Daniel T. Sun, Mounir D. Mensi, Kyriakos Stylianou, Berend Smit, Wendy L. Queen
Herein, a novel integrated adsorption–photoreduction system, which captures highly mobile and toxic hexavalent chromium (Cr(VI)) from real-world water samples and reduces it to less mobile and benign Cr(III) species, was designed.
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Power and carbon monoxide co-production by a proton-conducting solid oxide fuel cell with La0.6Sr0.2Cr0.85Ni0.15O3−δ for on-cell dry reforming of CH4 by CO2

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA03458D, Paper
Tong Wei, Peng Qiu, Lichao Jia, Yuan Tan, Xin Yang, Shichen Sun, Fanglin Chen, Jian Li
Highly efficient on-cell dry reforming of CH4 for power and CO co-production by H-SOFCs is achieved with an engineered LSCN@Ni layer.
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Ultrahigh Photothermal Temperature in Graphene/Conducting Polymer System Enables Contact Thermochemical Reaction

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA03347B, Paper
Yuqiao Chai, Hui Ma, Xinlei Ma, Xinyue Zhang, Yonglin He, Yapei Wang, Qianqian Jiang, Xusheng Wang, Junhui Ji, Mianqi Xue
Photothermal conversion in near-infrared (NIR) wavelengths, which converts light energy into heat energy, has caused great concern and been developing rapidly in recent years for its wide applications in health...
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Hydrophilic ultrafiltration membranes with surface-bound eosin Y for an integrated synthesis-separation system of aqueous RAFT photopolymerization

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA03112G, Paper
Yujie Zhao, Senlin Shao, Jiangbin Xia, Ya Huang, Yu Chi Zhang, Xue Li, Tao Cai
The photocatalyst-based ultrafiltration membrane fitted integrated synthesis–separation system holds the promises to bridge the gap between the precision of PET-RAFT polymerization and the efficiency of membrane separation process.
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Exceeding the Volcano Relationship in Oxygen Reduction/Evolution Reactions using Single-atom-based Catalysts with Dual-active-sites

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA01399D, Communication
Xiyu Li, Sai Duan, Edward Sharman, Yuan Zhao, Li Yang, Zhiwen Zhuo, Peng Cui, Jun Jiang, Yi Luo
Finding cost-effective catalysts to drive oxygen reduction/evolution reactions (ORR/OER) is a highly attractive goal. Most catalysts follow a volcano relationship of performance, making it difficult to search thoroughly enough among...
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Organic Solar Cells Based on Small Molecule Donor and Polymer Acceptor Operating at 150 °C

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA02865G, Paper
Junhui Miao, Bin Meng, Zicheng Ding, Jun Liu, Lixiang Wang
Inorganic or organic solar cells always operate at temperature lower than 100 °C and are not suitable for operating at high temperature. In this work, using blends of small molecular...
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Bimetallic-MOF Catalyst for Efficient CO2 Photoreduction from Simulated Flue Gas to Value-added Formate

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA00205D, Paper
Shao-hong Guo, Xiang-Juan Qi, Hui-Min Zhou, Jie Zhou, Xiao-Hui Wang, Man Dong, Xue Zhao, Chun-Yi Sun, Xinlong Wang, Zhong-Min Su
Direct CO2 conversion from flue gas into high-value products is of great significance not only in relieving environmental burden but alleviating energy crisis by a low-cost and saving-energy avenue, yet...
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TONIGHT: "Fearless" with Alice McDermott

I“Fearless: A Tribute to Irish American Women,” features novelist Alice McDermott in conversation with Pennsylvania Rep. Mary Gay Scanlon and CBS News’ Margaret Brennan.

McDermott’s critically acclaimed eighth novel, “The Ninth Hour,” set in Irish Brooklyn, was a finalist for the 2017 National Book Critics Circle Award and the 2017 Kirkus Prize for Fiction. Time magazine, The Wall Street Journal, NPR and others named the novel among the top works of fiction in 2017. McDermott is known for her portrayals of Irish American family life.

Scanlon is an education and human rights advocate representing Pennsylvania’s 5th District. She was first sworn in as a member of Congress on Nov. 13, 2018. Brennan is moderator of CBS News’ “Face the Nation” and the network’s senior foreign affairs correspondent based in Washington. All three women will discuss their Irish backgrounds and family stories.

Watch TONIGHT Thursday, Feb. 6 at 7pm ET on the Library's YouTube channel.

 




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WordPress Breadcrumbs: How to Use This Function?

Unfortunely, WordPress doesn’t have a default function to display a breadcrumb. We’ll see how to create this navigation technique, and display it on our posts, pages and categories archives. Breadcrumb…What’s that?!? Wikipedia says: Breadcrumbs or breadcrumb trail are a navigation technique used in user interfaces. Its purpose is to give users a way to keep …

WordPress Breadcrumbs: How to Use This Function? Read More »




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PHP cURL Examples: 10 Awesome Things to Do With cURL

cURL, and its PHP extension libcURL, are tools which can be used to simulate a web browser. In fact, it can for example, submit forms. In this article, I'm going to show you 10 incredible things that you can do using PHP and cURL.




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Useful SQL Queries To Clean Up Your WordPress Database

After years of usage, your WordPress database can contain weird characters, be filled with data you don’t need anymore, and so on. In this article, you will learn about SQL queries to clean up your WordPress database. Two things to note: First, any of these queries should be preceded by a backup of your whole …

Useful SQL Queries To Clean Up Your WordPress Database Read More »




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CodeIgniter Tutorial: Learn to Master CodeIgniter

CodeIgniter is an open source rapid development web application framework, for use in building dynamic web sites with PHP. In today's article, I have compiled 10 very useful tutorials to learn to do almost everything with this powerful PHP framework.




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Best WooCommerce Code Snippets: Add to Cart Link & More

Since over 5 years, WooCommerce is recognized as the most powerful and easy to use e-commerce plugin for WordPress. In this article, I have compiled my all time favorite hacks and code snippets to extend WooCommerce possibilities.




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10+ Best Online Code Editors

As a developer, your main tool is obviously the one that allows you to turn your ideas into code: A text editor. As time goes by, more online text editors are created that can help you code from any computer with Internet access. In this article, let’s take a look at 10+ useful online code …

10+ Best Online Code Editors Read More »




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Janaushadhi Kendras accepting orders on WhatsApp, e-mail to facilitate access to medicines: Government

"It is heartening to note that many PMBJKs are using modern communication tools including social media platforms like Whatsapp to provide better services in effecting faster delivery of essential medicines to the needy," Minister of Chemicals and Fertilizers DV Sadananda Gowda said.




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India to send nearly 1,000 tonnes of paracetamol raw material to Europe

The Indian government in March put a hold on exports of several drugs including paracetamol to secure supplies for its people after the coronavirus outbreak disrupted the industry's supply chain globally. COVID-19 is the respiratory disease caused by the novel coronavirus.




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Assam keen to woo MNCs looking to move out of China

Multinational companies looking to move out of China should consider Assam, with its abundant natural resources, strategic location and robust industrial infrastructure, as their destination for setting up production facilities in India, state Industries Minister Chandra Mohan Patowary said on Wednesday.




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CVC Capital set to buy into Cancer chain HCG, to be co-promoter

Singapore's Temasek holds a 9.4% stake in the widely held company, while Indgrowth Capital owns 1.2%. Public shareholding is 76.1%, as per latest regulatory disclosures.




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CSIR submits 53 genome sequences of coronavirus to global body; to share 450 more by May 15

CSIR's Institute of Genomics and Integrative Biology (IGIB), Delhi, Centre for Cellular and Molecular Biology (CCMB), Hyderabad and Institute of Microbial Technology, Chandigarh are currently sequencing the genomes of the novel coronavirus, he said. Other CSIR institutes are also expected to join the process.




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Bilateral deals might not be equitable for Covid-19: MPP executive director Charles Gore

The Medicines Patent Pool is a United Nations-backed public health organisation that helps middle- and low-income countries get access to critical drugs. MPP executive director Charles Gore told ET’s Divya Rajagopal about the organisation’s plan to ensure equitable access of Covid-19 drugs and vaccines.




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Gilead under gun to mass-produce virus drug or risk exclusivity

All of that could add up to market wins if remdesivir lives up to expectations and Gilead can ramp up to sufficiently respond to Covid-driven demand. But if it can’t, Gilead could be “very vulnerable” to the federal government using its powers to compel the licensure of remdesivir patents, Roth said.




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Chinese drugmaker in talks to test virus vaccine globally

With China having largely curbed its growth of new infections, its drugmakers will need to seek international cooperation to test their vaccine candidates in other countries — a task that may be complicated by tensions between China and some nations, especially the US, over how and where the virus originated.




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Into the silence / Nicholas DiEugenio, Mimi Solomon

MEDIA PhonCD D5678 int




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Violin concerto: Grand duo / Lou Harrison

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The Andrée expedition: From the diary of Virginia Woolf / Dominick Argento

MEDIA PhonCD Ar37 song




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Viola concertos / Amanda Harberg, Max Wolpert

MEDIA PhonCD D486 vio




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'From noon to starry night' / Baker

MEDIA PhonCD B171 insmu




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Complete works for violin and for viola / Salvatore Sciarrino

MEDIA PhonCD Sci12 insmu a




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Monológos: música mexicana de concierto para violonchelo solo / Gustavo Martín, violonchelo

MEDIA PhonCD M3631 mon




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Overture to Candide: Fancy free ; Anniversaries for orchestra ; Overture to Wonderful town / Bernstein

MEDIA PhonCD B458 insmu




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Cat o' nine tails: The dead man ; Memento mori ; Kol nidre / John Zorn

MEDIA PhonCD Z77 quasmu




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Petite fleur: the music of Sidney Bechet / David Liebman ; John Stowell

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Double concertos: Brahms, Rihm, Harbison / Mira Wang, Jan Vogler, Royal Scottish National Orchestra, Peter Oundjian

MEDIA PhonCD W18412 dou