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Size and orientation of polar nanoregions characterized by PDF analysis and using a statistical model in a Bi(Mg1/2Ti1/2)O3–PbTiO3 ferroelectric re-entrant relaxor

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00240G, Paper
Laijun Liu, Kaiyuan Chen, Dawei Wang, Manuel Hinterstein, Anna-Lena Hansen, Michael Knapp, Biaolin Peng, Xianran Xing, Yuanpeng Zhang, Jing Kong, Abhijit Pramanick, Mads Ry Vogel Jørgensen, Frederick Marlton
Local structure information of relaxor ferroelectrics is key to a clear understanding of their structure–property relationships. The size of polar nanoregions is determined based on the local atomic displacement and dielectric response.
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A heterostructured WO3–SnO2 nanocomposite for the efficient photocatalytic production of H2O2 under visible light

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01223B, Paper
Diya Xie, Chen Chen, Yaru Wang, Cheng Sun, Yiming Xu, Jianguo Huang
A WO3–SnO2 (WSN) nanocomposite was synthesized with unique heterostructures formed in-between the two phases, resulting in the efficient production of H2O2 under visible light due to the synergistic effect.
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Regulating Pt-Covalent Triazine Frameworks Schottky Junction by Tailor-Made Nitrogen Sites towards Efficient Photocatalysis

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00618F, Paper
Chao Li, Lijiang Guan, Jin Zhang, Cheng Cheng, Zhaoqi Guo, Zhihong Tian, Li-Ming Yang, Shangbin Jin
Covalent triazine frameworks (CTFs) of designable nitrogen-rich structures, which can form Schottky Junction with Pt nanoparticles, have been extensively studied in photocatalysis. However, how to tune the interaction inside the...
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Cationic Radical Metal–Organic Framework Enabling Low Water Evaporation Enthalpy and High Photothermal Conversion Efficiency for Solar-Driven Water Purification

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01126K, Paper
Zi-Yu Wang, Rui Wang, Hannah M Johnson, Lei Cai, An-An Zhang, Qiang Zhang, Tianfu Liu
Solar vapor generation is a promising and sustainable strategy to purify seawater and contaminated water sources. Yet, efficient integration between solar capture and desalination remains a critical challenge. In this...
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Renewable Aromatic Hydrocarbons from Waste Cooking Oil over Hierarchical Imidazole Supported Zeolite

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00416G, Paper
Bipul Sarkar, Bhanu Joshi, Omvir Singh, Ankit Agrawal, Neha Dhiman, Bhanu Prasad Vempatapu, Navin Gopinathan , Anjan Ray
Unlike coal, oil, or natural gas, waste cooking oil (WCO) acts as a renewable source of carbon. It can be converted into energy, fuels, and fine chemicals, instead of being...
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Modulation of active metal species in MOF-derived catalysts for Efficient NO reduction by CO

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01075B, Paper
Ning-Rui Zhou, Zhen Yang, Ying Tang, Ming-Qi Zhang, Yun-Peng Zha, Min-Min Liu, Feng Yu, Jiang Liu
Transition metal oxides are usually used as one of the most excellent catalysts for NO selective catalytic reduction by CO (CO-SCR), but their catalytic activity is limited by the content...
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High-performance planar Zn-ion micro-capacitors

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00300D, Paper
Open Access
Yujia Fan, Xiaopeng Liu, Nibagani Naresh, Yijia Zhu, Iman Pinnock, Tianlei Wang, Mingqing Wang, Ivan P. Parkin, Buddha Deka Boruah
Proposing a planar zinc-ion micro-capacitor, featuring battery type anode and supercapacitor type cathode to offer intermediate energy storage performance, boasting greater energy density than typical supercapacitors, superior power density compared to batteries, and minimal self-discharge rates.
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Boosting the electrocatalytic activity of single atom iron catalysts through sulfur-doping engineering for liquid and flexible rechargeable Zn–air batteries

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00524D, Paper
Tianfang Yang, Bingcheng Ge, XuPo Liu, Zunjie Zhang, Ye Chen, Yang Liu
A practical strategy is reported to design single-Fe atom decorated S/N-doped C (Fe SAs@S/N–C) catalysts with a high Fe loading of 5.45 wt%. The prepared catalysts exhibit excellent performances for liquid and all-solid-state Zn–air batteries.
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Regulating the local microenvironment on porous Cu nanosheets for enhancing electrocatalytic CO2 reduction selectivity to ethylene

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01198H, Paper
Dan Wang, Qingqing Song, Kaibin Li, Yuwei Zhou, Junjun Mao, Chenchen Zhang, Yang Lou, Chengsi Pan, Jiawei Zhang, Yongfa Zhu, Ying Zhang
Local microenvironments of the ECO2RR play an important role in tuning the adsorption energy of crucial intermediates, which helps enhance ECO2RR selectivity.
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Boosting reaction kinetics of polycrystalline phase Fe7S8/FeS2 heterostructures encapsulated in hollow carbon nanofiber for superior fast sodium storage

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01241K, Paper
Hui Cai, Fei Wang, Huiyan Feng, Zhendong Liu, Chengzhi Zhang, Anbang Lu, Xi Zhao, Qiuhong Lu, Quanbing Liu, Jun Tan
Metal sulfides have been regarded as highly competitive anode materials for fast sodium storage due to the excellent redox reversibility and comparatively great electron properties. Nevertheless, metal sulfides suffer from...
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Bio-inspired design of a self-supported bismuth microforest for high performance sodium storage

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00950A, Paper
Jia Bai, Yan Liu, Ben Pu, Qi Tang, Yongbin Wang, Ruihan Yuan, Jin Cui, Yi Yang, Xiaojia Zheng, Bin Zhou, Weiqing Yang
A self-supported bismuth microforest anode material, prepared by a simple, efficient and scalable in situ galvanic replacement approach, exhibits high performance for sodium-ion batteries.
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Tuning the ion conductivity of Zr-based metal organic framework ionogels by linker functionalization

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D3TA06986A, Paper
Open Access
Antonija Ferbezar, Roman Zettl, Katharina Hogrefe, Harald Fitzek, Bernhard Gadermaier, Martin Wilkening, Ilie Hanzu
Solid-state ion conductors have improved significantly in the past decade. Envisioned applications range from metal anode batteries and fuel cells to sensors and medical technologies. The choice of solid electrolytes...
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In situ construction of a double perovskite heterostructure with exsolved FeNi3 alloy nanoparticles for CO2 electrolysis in solid oxide electrolysis cells

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA07820E, Paper
Xiaoyu Wang, Haibo Hu, Caiyue Xie, Yifei Wang, Haowei Li, Xifeng Ding
FeNi3 nanoparticles anchored on the (PrBa)0.95Fe1.6Ni0.4O6−δ double perovskite enhance the electrochemical performance and durability in direct CO2 electrolysis.
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Multifunctional buried interface modification for efficient and stable SnO2-based perovskite solar cells

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00108G, Paper
Rui Wu, Junhua Meng, Yiming Shi, Zhengchang Xia, Chunxia Yan, Lisheng Zhang, Wenkang Liu, Jinliang Zhao, JinXiang Deng, Xing Wang Zhang
Buried interface modification with multiple roles is key to boost the performance of perovskite solar cells (PSCs). Herein, a multifunctional passivator, N-(2-hydroxyethyl) ethylene diamine triacetic acid trisodium salt (HEDTA-3Na), is...
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An electrically conducting 3D coronene-based metal–organic framework

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA07120K, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Marina I. Schönherr, Patricia I. Scheurle, Laura Frey, Marta Martínez-Abadía, Markus Döblinger, Andre Mähringer, Dominik Fehn, Lena Gerhards, Irina Santourian, Alfred Schirmacher, Tatjana Quast, Gunther Wittstock, Thomas Bein, Karsten Meyer, Aurelio Mateo-Alonso, Dana D. Medina
A novel electrically conducting cubic mesoporous metal–organic framework (MOF), consisting of hexahydroxy-cata-hexabenzocoronene (c-HBC) and FeIII ions is presented.
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Efficient photocatalytic hydrogen evolution based on Z-scheme 2D OV-LaVO4/Mo-doped SV-ZnIn2S4 heterojunctions

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00754A, Paper
Wei Guan, Lin Zhang, Peng Wang, Ying Wang, Haoyu Wang, Xingchen Dong, Liyan Yu, Zhixing Gan, Lifeng Dong, Lina Sui
The purposeful design and construction of two-dimensional (2D) semiconductor heterojunctions offers a promising avenue for achieving efficient photocatalytic activity. However, the challenge of enabling efficient charge migration at the interface...
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Oxygen insertion at the cage center: an unconventional tuning strategy for enhancing the photocatalytic performance of atomically precise copper cluster cocatalysts

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA07218E, Paper
Yun-Dong Cao, Di Yin, Ming-Liang Wang, Hong Liu, Yi Feng, Lin-Lin Fan, Cai-Li Lv, Guang-Gang Gao
This work not only confirms the long-standing prediction that the Cu8 center can accommodate an oxygen atom but also demonstrates a novel central atom regulation strategy to obtain highly active copper clusters as photocatalysts.
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Closed pore structure engineering from ultra-micropores with the assistance of polypropylene for boosted sodium ion storage

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01375A, Paper
Xue Li, Ning Sun, Shaohong Zhang, Razium Ali Soomro, Bin Xu
Closed pore architectures with exceptional Na-storage performance have been successfully fabricated from ultra-micropores with the assistance of polypropylene.
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Highly stable photovoltaic effects in A2+–Zr4+ (A = Ca, Sr, Ba) co-doped BiFeO3 films with self-polarization

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00649F, Paper
Lei Shi, Wenyue Zhao, Zhao Wang, Wenjing Hua, Xiaoxia Yang, Weidong Fei, Yu Zhao
The photovoltaic responses and temperature stabilities of A2+–Zr4+ (A = Ca, Sr, Ba) composite doped BiFeO3 films with self-polarization were enhanced in the R to MA phase transition.
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Data-driven discovery of carbonyl organic electrode molecules: machine learning and experiment

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00136B, Paper
Jiayi Du, Jun Guo, Qiqi Sun, Wei Liu, Tong Liu, Gang Huang, Xinbo Zhang
In this work, a universal strategy for the identification of high-performance OEMs for LIBs has been illustrated. The predicted molecule, naphthalene-1,4,5,8-tetraone, exhibits excellent electrochemical performance in terms of capacity and lifetime.
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NiFeCo–OH/NiTe nanoarrays with amorphous/crystalline interfaces for highly efficient oxygen evolution reaction

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00772G, Paper
Jing Liu, Da Liu, Xiaoxiao Yan, Peifang Guo, Hongbin Xu, Peng Chen, Renbing Wu
One-dimensional heterostructured NiFeCo–OH/NiTe nanorod arrays with amorphous/crystalline interfaces have been rationally synthesized, exhibiting an excellent OER electrocatalytic performance.
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Lightweight, elastic and conductive pure PEDOT:PSS foam for dual-mode sensing

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01631A, Paper
Haibin Li, Rubai Luo, Jingbo Hu, Shisheng Zhou, Xing Zhou, Bin Du
Pure PEDOT:PSS foam with a multi-scale porous structure and dual-mode sensing characteristics.
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In situ analysis of the oxygen evolution reaction on the CuO film in alkaline solution by surface interrogation scanning electrochemical microscopy: investigating active sites (CuIII) and kinetics

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00628C, Paper
Seokjun Han, Jinoh Yoo, Won Tae Choi
Surface interrogation scanning electrochemical microscopy was employed to assess the electrocatalytic activity of CuO films for the oxygen evolution reaction in an alkaline solution.
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Configuration-entropy effects on BiFeO3–BaTiO3 relaxor ferroelectric ceramics for high-density energy storage

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00921E, Paper
Open Access
Rhys Montecillo, Cheng-Sao Chen, Kuei-Chih Feng, R. R. Chien, Pin-Yi Chen, Chi-Shun Tu
A high-configuration entropy results in the formation of grain boundaries and nanoclusters, which act as barriers for enhancing breakdown strength and energy-storage capability.
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Enhancing CO2 gasification-reforming of municipal solid waste with Ni/CeO2 and Ni/ZrO2 catalysts

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00665H, Paper
Shiyu Zhang, Yibing Peng, Mengna Wu, Qinghai Li, Yanguo Zhang, Hui Zhou
CO2 gasification-reforming facilitates CO2 utilization and yields CO-rich syngas for municipal waste management. Catalysts are essential for enhancing syngas production via catalytic tar reforming.
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Cubic-to-hexagonal Structural Phase Transition in Metal Halide Compounds: A DFT Study

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D3TA06604E, Paper
Iván Ornelas-Cruz, Ramiro M. dos Santos, José E. González, Matheus Paes Lima, Juarez L. F. Da Silva
Phase transitions into photo-inactive structural phases have impacted the use of metal halide perovskites as photovoltaic materials. However, the chemical composition has been found to mitigate this issue. This study...
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Highly Boosted Energy Storage Performance of Few-Layered MoS2 Utilized by Improved Electrode Fabrication: Experimental and Theoretical Studies

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01713G, Paper
Zeyad M. Abdulhamid, Abhishek C. Lokhande, Adewale Hammed Pasanaje, Daniel S Choi, Nirpendra Singh, Kyriaki Polychronopoulou, Dalaver H. Anjum
Few-layer two-dimensional (2D) molybdenum disulfide (MoS2) has great potential in designing high-performance supercapacitors due to its high theoretical specific capacity, tunable bandgap, and fascinating 2D layered structure. However, the lack...
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Enhanced Hydrogen Production by Assisted Biomass Gasification Using Lithium Manganate as Bifunctional Material

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00224E, Paper
Open Access
Carlos Hernández-Fontes, Nan Wang, Nayeli Gómez-Garduño, Heriberto Pfeiffer
The rising energy demand, among other economic and technological factors, increases the greenhouse gas emissions. Therefore, it is crucial to develop technologies to produce clean energy, such as hydrogen (H2)...
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Amphipathic Emulsion Binder for Enhanced Performance of Lithium-Sulfur Batteries

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01037J, Paper
Yuan He, Xulong Jing, Tianxing Lai, Dong Jiang, Chao Wan, Pavel S Postnikov, Olga Guselnikova, Lixin Xu, Xiaojun He, Yusuke Yamauchi , Biyu Jin
The application of polyvinylidene fluoride (PVDF) binder in lithium-sulfur batteries faces challenges due to inadequate adhesion, undesirable conductivities, limited lithium polysulfides absorbability, and its dependence on the use of toxic...
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Molecular-polaron-coupling-enhanced photocatalytic CO2 reduction on copper phthalocyanine/NiMgFe layered double hydroxide nanocomposites

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA07538A, Paper
Yuexian Li, Wenli Su, Xiaoyan Wang, Jun Lu, Wenkai Zhang, Shuo Wei
We built CuPcS/NiMgFe-LDHs composites and probed the unique photogenerated-carrier transfer mechanism. A series of long-range Forster energy transfers prolonged the lifetime of photogenerated carriers to match the timescale of surface reaction.
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Constructing vacancy-rich metal phosphates by the spatial effect of ionic oligomers for enhanced OER activity

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01706D, Paper
Yida Zhao, Xinyu He, Xiaoming Ma, Zhengxi Guo, Menghui Qi, Zhaoming Liu, Ruikang Tang
By rationally selecting ionic oligomers as building blocks, sub-nano-sized gaps can be constructed in the solid structure of catalysts. This can overcome the inherent limitations associated with vacancy formation of the traditional nucleation pathway.
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Harvesting solar energy with a Ni-MOF-based evaporator for efficient solar thermal storage and steam generation

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00203B, Paper
You Xu, Zhengyun Wang, Xianbao Wang, Zhenzhen Guo, Muhammad Sultan Irshad, Naila Arshad, Jiang Gong, Hongfang Liu, Guangfang Li
A hybrid solar evaporator comprising a Ni-based metal–organic framework material and a phase change material composite was fabricated for high performance solar-thermal energy storage and continuous solar vapor generation.
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Efficient first principles based modeling via machine learning: from simple representations to high entropy materials

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00982G, Paper
Kangming Li, Kamal Choudhary, Brian DeCost, Michael Greenwood, Jason Hattrick-Simpers
Generalization performance of machine learning models: (upper panel) generalization from small ordered to large disordered structures (SQS); (lower panel) generalization from low-order to high-order systems.
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Machine Learning Enabled Exploration of Multicomponent Metal Oxides for Catalyzing Oxygen Reduction in Alkaline Media

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01884B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xue Jia, Hao Li
Low-cost metal oxides have emerged as promising candidates used as electrocatalysts for oxygen reduction reaction (ORR) due to their remarkable stability under oxidizing conditions, particularly in alkaline media. Recent studies...
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Insight into piezoelectricity modulation mechanism of ZnO doped with Y ions

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01317D, Paper
Zihan Wang, Yue Sun, Shenglong Wang, Da Xiong, Guo Tian, Longchao Huang, Boling Lan, Long Jin, Weiqing Yang, Weili Deng
ZnO is a performance-rich material due to its unique coupling of piezoelectricity and semiconductor properties. However, the intrinsic piezoelectric screening effect of ZnO weakens the electromechanical conversion efficiency and greatly...
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Highly selective and high-performance sulfonated poly(ether ether ketone)-based hybrid membrane enabled by complexed UiO-66-NH2 and sulfonated graphitic carbon nitride for vanadium flow battery

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00988F, Paper
Caiyuan Zhao, Haixia Wang, Lang Li, Liping Liu, Xinrui Cui, Haifeng Shi
A series of sulfonated poly(ether ether ketone) (SPEEK) hybrid membranes (SPEEK/NF) with a constant 1 wt% complexed nanofillers (NF) comprising of UiO-66-NH2 and sulfonated graphitic carbon nitride (s-g-C3N4) are prepared...
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Broncos open WR Josh Reynolds' 21-day practice window

The Broncos designated wide receiver Josh Reynolds for return from injured reserve, the team announced Wednesday.




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DK Metcalf has full participation in Wednesday's practice

Seahawks coach Mike Macdonald said before practice DK Metcalf would have a limited practice Wednesday, and the receiver said he didn't know if he would return to game action this week.




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Plasticity tunable artificial synapses based on organic electrochemical transistors with aqueous electrolytes

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC03569K, Paper
Ruhua Wu, Miao Xie, Yuhua Cheng, Dan Zhao, Liang-Wen Feng, Jianhua Chen, Wei Huang
By regulating ion transporting kinetics and ion diffusion distances in organic mixed ionic–electronic conductor channels, highly tunable short- and long-term plasticity are obtained in vOECTs with aqueous electrolytes.
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Stronger Polar Ferromagnetism and Narrower Optical Band Gaps in Two-Dimensional Hybrid Copper Perovskites Induced by Bromine-Substitution

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC03532A, Paper
Ceng Han, Jason Allan McNulty, Alasdair Bradford, Alexandra Slawin, Stephen Lee, Philip Lightfoot
Two-dimensional (2D) organic–inorganic hybrid perovskites are attracting great interest due to their structural tunability and rich functional characteristics. Here, we report a series 2D layered hybrid copper (II) halide perovskites...
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Dopant-free Tert-butyl Zn (II) Phthalocyanines: Impact of Substitution on Photo-Physical Properties in Their Role in Perovskite Solar Cells

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC04013A, Paper
Mahdi Gassara, Jose Garcés-Garcés, Luis Lezama, Javier Ortiz, Fernando Fernandez-Lazaro, Samrana Kazim, Angela Sastre-Santos, Shahzada Ahmad
We synthesized molecular hole-transporting materials (HTMs) featuring a zinc phthalocyanine (ZnPc) central core and modulated the non-perypheral position with different numbers of tert-butyl groups. The synthesized molecules were also integrated...
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Giant Magnetocaloric Effect in Fe doped Rare earth Orthochromite GdCr0.5Fe0.5O3

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC03873H, Paper
Abinash Prusty, Sudipta Mahana, B. Sheetal Priyadarshini, Andrei Gloskovskii, Dinesh Topwal, Unnikrishnan Manju
In this manuscript we present the magnetic and magnetocaloric property investigations of Fe doped orthochromite system GdCr0.5Fe0.5O3, along with the structural, electronic and thermal properties. Manifestations of orbital mediated electron-phonon...
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Nifty prediction today – November 13, 2024: Bearish. Go short now and on a rise

Nifty 50 November futures can fall to 23,400




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Bank Nifty Prediction today – November 13, 2024: Short when the support is breached

Bank Nifty futures is now testing the support at 51,000




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Beneficiaries receive ₹22.15 lakh in loans from TAMCO for minority welfare




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Coimbatore District Police arrest two men for robbing Kerala jeweller of ₹54 lakh




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Ambulance aggregator service under consideration: Ganesh Kumar

Aimed at enhancing emergency response across Kerala




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Supreme Court verdict on bulldozer demolitions: Jamiat hails verdict, victims seek compensation

It is a significant step towards safeguarding the rule of law and fundamental rights of citizens, say Jamiat leaders




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Watch: Which are the smaller parties in the fray in Maharashtra? | Election Cheatsheet

We take a look at the various political alliances in the Maharashtra ahead of the Assembly elections in the State.




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Food prices rising due to failed policies of Modi govt., says Congress

Tomatoes, onions, and potatoes disappearing from common man’s plate, says Jairam Ramesh