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Enhanced surface reconstruction of V-Doped Ni3N driven by strong OH adsorption to boost 5-hydroxymethylfurfural electrooxidation for energy-saving H2 production

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01543F, Paper
Qi Zhou, Juan Wang, Ga Jin, Huiling Liu, Cheng Wang
Coupling biomass electrooxidation with hydrogen evolution reaction (HER) provides an alternative approach for simultaneously increasing the energy efficiency of H2 production and producing high value-added chemicals. Here, a V-doped Ni3N...
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Tua Tagovailoa on his post-interception tackle: "I wouldn't do anything differently"

Dolphins QB has no regrets about risking another concussion.




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DK Metcalf has full participation in Wednesday's practice

Seahawks coach Mike Macdonald said before practice DK Metcalf would have a limited practice Wednesday, and the receiver said he didn't know if he would return to game action this week.




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The fluorescence distinction of chiral enantiomers: a Zn coordination polymer sensor for the detection of cinchonine and cinchonidine

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC03506B, Paper
Wenping Hu, Nan Wu, Dechao Li, Yefang Yang, Shaowen Qie, Shuai Su, Ruijie Xu, Wenting Li, Ming Hu
A Zn coordination polymer was constructed to identify chiral cinchonine and cinchonidine with high sensitivity, selectivity, and reproducibility.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Pi-extended hypervalent iodine macrocycles and their supramolecular assembly with Buckminsterfullerene

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC04251D, Paper
Krishna Pandey, Samsul Arafin, Grayson Venus, Eli Jones, Yachu Du, Mina Dumre Pandey, Tahir Awais, Lichang Wang, Kyle N. Plunkett
Hypervalent iodine based macrocycles with enlarged aromatic cores can form extended supramolecular assemblies with Buckminsterfullerene.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Superconductivity above 30 K due to the introduction of oxygen element in CaFeAsF

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC03994G, Paper
Yixin Liu, Teng Wang, Zulei Xu, Da Jiang, Yi Zhao, Yanpeng Qi, Xiaoni Wang, Ming Yang, Mao Ye, Wei Peng, Gang Mu
Exploring new unconventional superconductors is of great value for both fundamental research and practical applications. It is a long-term challenge to develop and study more hole-doped superconductors in 1111 system...
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Stronger Polar Ferromagnetism and Narrower Optical Band Gaps in Two-Dimensional Hybrid Copper Perovskites Induced by Bromine-Substitution

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC03532A, Paper
Ceng Han, Jason Allan McNulty, Alasdair Bradford, Alexandra Slawin, Stephen Lee, Philip Lightfoot
Two-dimensional (2D) organic–inorganic hybrid perovskites are attracting great interest due to their structural tunability and rich functional characteristics. Here, we report a series 2D layered hybrid copper (II) halide perovskites...
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Dopant-free Tert-butyl Zn (II) Phthalocyanines: Impact of Substitution on Photo-Physical Properties in Their Role in Perovskite Solar Cells

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC04013A, Paper
Mahdi Gassara, Jose Garcés-Garcés, Luis Lezama, Javier Ortiz, Fernando Fernandez-Lazaro, Samrana Kazim, Angela Sastre-Santos, Shahzada Ahmad
We synthesized molecular hole-transporting materials (HTMs) featuring a zinc phthalocyanine (ZnPc) central core and modulated the non-perypheral position with different numbers of tert-butyl groups. The synthesized molecules were also integrated...
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Nifty prediction today – November 13, 2024: Bearish. Go short now and on a rise

Nifty 50 November futures can fall to 23,400




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Bank Nifty Prediction today – November 13, 2024: Short when the support is breached

Bank Nifty futures is now testing the support at 51,000




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A New 3D Scan, Created from 25,000 High-Resolution Images, Reveals the Remarkably Well-Preserved Wreck of Shackleton’s Endurance

Photos on this page courtesy of the Falklands Maritime Heritage  Few who hear the story of the Endurance could avoid reflecting on the aptness of the ship’s name. A year after setting out on the Imperial Trans-Antarctic Expedition in 1914, it got stuck in a mass of drifting ice off Antarctica. There it remained for ten months, […]




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A cafe in Coimbatore pays an ode to the riding community with a nutritious menu




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Two prison staff placed under suspension in Salem




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Ambulance aggregator service under consideration: Ganesh Kumar

Aimed at enhancing emergency response across Kerala




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CUSAT to host higher education conclave




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State Library Council Awards declared, M. Leelavathy wins I.V. Das award for overall contributions




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Supreme Court verdict on bulldozer demolitions: Jamiat hails verdict, victims seek compensation

It is a significant step towards safeguarding the rule of law and fundamental rights of citizens, say Jamiat leaders




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Kalpathy car fest: a spectacle of faith and tradition

Chariots of the Sree Visalakshi Sametha Viswanatha Swamy temple start moving through the streets




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Watch: Which are the smaller parties in the fray in Maharashtra? | Election Cheatsheet

We take a look at the various political alliances in the Maharashtra ahead of the Assembly elections in the State.




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Additional stop for four trains at Vaikom




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Four awards for Senior Chamber Palakkad legion




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Omar seeks compensation from Centre over losses due to Indus Water Treaty

Jammu and Kashmir Chief Minister’s remarks that the IWT hinders J&K’s power capacity spark row; the focus should be the return of power projects from National Hydroelectric Power Corporation, says former Chief Minister Mehbooba Mufti




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BJP accuses Congress of releasing election manifesto during “silence” period in Jharkhand

Mr. Patra claimed that the Congress wanted to give 4% reservation to the Muslim organisations and contractors in public tenders




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BJP’s win in recent polls is expression of people’s faith in govt. policies: Haryana Governor




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ED arrests four, including two Bangladeshi nationals, in human trafficking case




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Nirmal Municipality junior assistant in ACB net




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Amaran collection in TN crosses ₹100 crore within two weeks; global collection ₹250 crore

Global collection of Amaran in the first 11 days was ₹248 crore, which was far less than the Vijay starrer The GOAT that had a whopping collection of ₹397 crore but ahead of Rajinikanth’s Vettaiyan at ₹225 crore, according to data




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AP CM Naidu halts uranium exploration in Kappatralla forest as locals protest

The YSR Congress Party Government led by Y S Jagan Mohan Reddy has given stage - I approvals for conducting explorations in the region to assess the availability of uranium




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Global fossil emissions to reach record high in 2024; India's share to rise by 4.6%: Report

According to a UN report released last month, India's greenhouse gas emissions surged by 6.1 per cent in 2023, contributing to 8 per cent of the global total




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Indian households accumulated USD 9.7 trillion in wealth over last ten years: Morgan Stanley




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India IT spending to reach USD 160 billion in 2025 fueled by application and infrastructure software market growth: Gartner




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Vegetable prices sky-rocket in October, food inflation at 10.87%, CPI at 6.21 %




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India's index of industrial production shows 3.1 per cent growth in September 2024




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FSSAI discusses various sets of compliances with e-commerce food operators




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LTIMindtree expands footprint in US with new innovation facility




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Russia discusses cooperation in pulses trade with India




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Coal import for blending purposes in power generation declines by 8.5% during April-Sept 2024




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India could save 91,000 crore rupees on import bill through biofuel blending: Hardeep Singh Puri




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Photocatalytic 1,3-Oxyheteroarylation of Aryl Cyclopropanes with Azine N-oxides

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06723A, Edge Article
Open Access
Doyoung Kim, Hyewon Ju, Wooseok Lee, Sungwoo Hong
Cyclopropanes, valuable C3 building blocks in organic synthesis, possess high strain energy and inherent stability. We present an efficient, environmentally benign 1,3-oxyheteroarylation of aryl cyclopropanes using azine N-oxides as bifunctional...
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A multifunctional “three-in-one” fluorescent theranostic system for hepatic ischemia–reperfusion injury

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC04962D, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jihong Liu, Dongni Yin, Wen Zhang, Xin Wang, Tony D. James, Ping Li, Bo Tang
A single-component multifunctional fluorescent theranostic system (MB-Gly) for use during hepatic ischemia-reperfusion injury (HIRI) has been developed.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Phase transition induced hydrogen activation for enhanced furfural reductive amination over CoCu bimetallic catalyst

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05885B, Edge Article
Open Access
Yilin Wei, Zixu Ma, Beibei Liu, Jialin Yang, Dan Wu, Yongsheng Zhang, Yuexing Zhang, Charles Chunbao Xu, Renfeng Nie
The synthesis of primary amines from renewable biomass and its derivatives through reductive amination has garnered significant attention. How to construct efficient non-noble-metal catalysts that enable low-temperature catalysis still remains...
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Gaining the Molecular Design Principles for Efficient Diarylethene Photoacid and Photohydride Generators Based on Photochemical Reaction Mechanism

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06202G, Edge Article
Open Access
Yifan Su, Dexin Zheng, Lingfeng Ge, Le Yu, David Lee Phillips, Jiani Ma, Yu Fang
Abstract: Photoacid generators (PAGs) and photohydride generators (PHGs) are specific photolabile protecting groups that release acid and hydride, respectively. Over the past decade, great efforts have been devoted to developing...
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Synthesis of highly condensed phospholes by Lewis acid-assisted dehydrogenative Mallory reaction under visible light irradiation

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05657D, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ikki Kamiyoshi, Yuki Kojima, Shibo Xu, Kosuke Yasui, Yuji Nishii, Koji Hirano
A photo-promoted oxidative cyclization, that is, Mallory reaction of 2,3-diarylbenzophopholes has been developed. With an assistance of Bi(OTf)3 Lewis acid, the reaction proceeds smoothly under visible light irradiation even without...
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'PM Modi's govt gives highest priority to over 35 mn Indian diaspora', says EAM Jaishankar on website launch for Pravasi Bharatiya Divas




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Providing better healthcare biggest priority: PM Modi ahead of Darbhanga AIIMS inauguration




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India's CO2 emissions account 8pc of global total, to rise by 4.6pc in 2024: Report




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Assam: Army celebrates 'National Education Day' with students in Tinsukia




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UP: Devotees celebrate 'Tulsi Vivah' at Balua Ghat in Prayagraj, marking sacred union of Lord Vishnu, Vrinda




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There will be census in country but not based on caste: Union Minister Shobha Karandlaje




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Union Education Minister Dharmendra Pradhan urges states to support exam reforms for zero-error entrance test