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Measuring Up: Equity Lessons from Australia’s Early Childhood Development Census

Australia is the only country in the world that regularly collects comprehensive information about the holistic development of every child entering its schools. This information, gathered through the Australian Early Development Census (AEDC), guides national and state policy and informs program development. Over the past 12 years, AEDC data have shown progress in reaching the most vulnerable children. The AEDC, along with population-based measurement more broadly, is useful for the United States because it can inform current discussions of equity in access to early childhood services.




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Testing New Earnings Rules for Social Security Disability Insurance: Findings from the Benefit Offset National Demonstration

The current earnings rules for Social Security Disability Insurance (DI) specify that, after using available work incentives, DI beneficiaries are not owed a DI benefit check if they earn more than a certain threshold. The Benefit Offset National Demonstration (BOND) tested a design intended to encourage DI beneficiaries to work by replacing the so-called cash cliff with a ramp—a $1 reduction in benefits for every $2 of additional earnings. BOND simultaneously tested the new rules with two groups: a nationally representative sample of DI beneficiaries and a group of recruited and informed volunteers—those thought to be most likely to earn more than the earnings threshold. Results from the five-year evaluation of BOND are now available for both groups.




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Nothing About Us Without Us: How the Need for Cultural Responsiveness is Changing Research

There is increased awareness and urgency within the research community to ensure that evaluation and assessment practices are sensitive to the cultures of people who are most impacted by those practices. Driven by changing demographics and the increasing complexity of problems that researchers and communities seek to address, new efforts are underway to develop research practices that better account for the unique perspectives and needs of the communities being studied. But there is hardly consensus on what culturally responsive research actually means or, more broadly, what implications such approaches could have on evidence-based policies and programs.




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New Evidence of the ACA’s Effect on People with Disabilities: Health Insurance, Employment, and Benefits

The Patient Protection and Affordable Care Act (ACA) of 2010 changed several aspects of the law concerning access to health insurance that were particularly salient for people with disabilities. These changes included removing limits on preexisting conditions, extending parent’s health insurance coverage of young adults until the age of 26, expanding Medicaid to more adults with low incomes, and making it easier to obtain affordable coverage outside the traditional employer-sponsored benefit system.




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Improving Transition Outcomes for Youth SSI Recipients: Early Findings from the PROMISE Evaluation




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Webinar: Strengthening Principal Preparation Through On-the-Job Training

A key challenge for policymakers is creating a pipeline of principals who are prepared to serve as instructional leaders. Districts often use the assistant principal position as a training ground for new principals. Yet little is known about how to design and implement on-the-job training opportunities that prepare assistant principals to serve as principals.




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REL Webinar: Using Teacher Feedback in School Leader Evaluations

The goal of the webinar is to expand local and state leaders’ knowledge of teacher survey instruments to enhance the evaluation of school leaders.




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Understanding the Power of Long-Term Impact Evaluations

International development programs are designed to make lasting and positive improvements in the health, education, and income of disadvantaged people around the world.




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A Framework for Educational Equity and Culturally Responsive Pedagogy

This webinar defined educational inequity and discussed its implications. It included a brief introduction to culturally responsive pedagogy and what broader systemic changes may be necessary to implement equity and culturally responsive pedagogy.




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Seeing Is Believing: Visualizing Data for Evidence-Based Policymaking

While many industries have increasingly turned to data science to make informed business decisions, social service organizations and government agencies have been slower to fully embrace the potential of current and emerging data science methods. The challenges are real.




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Research and Practice in Culturally Responsive Pedagogy and How to Sustain Systemic Changes

This webinar explored research on culturally responsive pedagogy and what is known about its effectiveness.




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Implementing District and School Policies and Practices to Support Culturally Responsive Pedagogy

This webinar explored how a school and district have approached the challenge of implementing culturally responsive practice. It elaborated on programs, policies, and practices that were implemented to support efforts to achieve equity and use culturally responsive pedagogy.




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Developing Culturally Responsive Educators in Pre-Service Programs

This webinar explored how best to prepare educators to implement culturally responsive pedagogy, including and exploration of how programs train future teachers and school administrators and what changes programs may need to consider to effectively prepare these educators.




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SSI Youth Solutions Project: Informational Webinar for Applicants on the Call for Policy Proposals

Mathematica is seeking innovative ideas on how to help youth who receive Supplemental Security Income (SSI) improve their employment outcomes as they transition to adulthood.




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Health Affairs Briefing on the Affordable Care Act Turns 10

The March 2020 issue of Health Affairs, “The Affordable Care Act Turns 10,” offers must-read analyses of the ACA.




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Q-CCIIT: Measuring the Quality of Caregiver–Child Interactions: Free Webinar for Early Childhood Professionals

Mathematica will launch a groundbreaking new quality measurement observation tool, now available to the early childhood community (including program administrators, professional development providers, researchers, and others) during a webinar.




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A fentanyl vaccine constructed upon opsonizing antibodies specific for the Galα1-3Gal epitope

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02107E, Communication
Jiaxing Wang, Beverly A Ellis, Bin Zhou, Lisa M. Eubanks, Steven Blake, Kim D Janda
A double conjugation strategy was implemented to produce an anti-fentanyl vaccine, which was predicated upon preformed-antibody-assisted antigen presentation. The new vaccine was found to reduce the psychoactive effects of fentanyl...
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Simultaneous co-assembly of fenofibrate and ketoprofen peptide for the dual-targeted treatment of nonalcoholic fatty liver disease (NAFLD)

Chem. Commun., 2020, 56,4922-4925
DOI: 10.1039/D0CC00513D, Communication
Zhongyan Wang, Chuanrui Ma, Yuna Shang, Lijun Yang, Jing Zhang, Cuihong Yang, Chunhua Ren, Jinjian Liu, Guanwei Fan, Jianfeng Liu
An ingenious co-assembled nanosystem based on fenofibrate and ketoprofen peptide for the dual-targeted treatment of NAFLD by reducing hepatic lipid accumulation and inflammatory responses.
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Photochemical α-carboxyalkylation of tryptophols and tryptamines via C–H functionalization

Chem. Commun., 2020, 56,4930-4933
DOI: 10.1039/D0CC00847H, Communication
Zhiqiang Pan, Yuchang Liu, Fengchi Hu, Qinglong Liu, Wenbin Shang, Chengfeng Xia
A process for the α-carboxyalkylation of tryptophols and tryptamines by the functionalization of C–H bonds under visible light irradiation has been developed.
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Noncovalent structural locking of thermoresponsive polyion complex micelles, nanowires, and vesicles via polymerization-induced electrostatic self-assembly using an arginine-like monomer

Chem. Commun., 2020, 56,4954-4957
DOI: 10.1039/D0CC00427H, Communication
Qingqing Zhao, Qizhou Liu, Chao Li, Lei Cao, Lei Ma, Xiyu Wang, Yuanli Cai
The noncovalent locking of nanostructured thermoresponsive polyion complexes can be achieved via polymerization-induced electrostatic self-assembly (PIESA) using an arginine-like cationic monomer.
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Graphene-modulated assembly of zinc phthalocyanine on BiVO4 nanosheets for efficient visible-light catalytic conversion of CO2

Chem. Commun., 2020, 56,4926-4929
DOI: 10.1039/D0CC01518K, Communication
Ji Bian, Jiannan Feng, Ziqing Zhang, Jiawen Sun, Mingna Chu, Ling Sun, Xin Li, Dongyan Tang, Liqiang Jing
Graphene-modulated ZnPc/BiVO4 Z-scheme heterojunctions for efficient visible-light catalytic CO2 conversion are achieved by increasing the optimized amount of highly dispersed ZnPc.
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Synthesis of chiral α-substituted α-amino acid and amine derivatives through Ni-catalyzed asymmetric hydrogenation

Chem. Commun., 2020, 56,4934-4937
DOI: 10.1039/D0CC01220C, Communication
Gongyi Liu, Xianghe Zhang, Heng Wang, Hengjiang Cong, Xumu Zhang, Xiu-Qin Dong
Efficient Ni-catalyzed asymmetric hydrogenation of cyclic N-sulfonyl ketimino esters and ketimines was successfully developed to prepare a series of chiral α-monosubstituted α-amino acid derivatives and amine derivatives with excellent results.
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Nonlinear organic–inorganic halide hybrids containing unprecedented linear [MIX2]− coordination units and quasi-two-dimensional lone pairs

Chem. Commun., 2020, 56,4894-4897
DOI: 10.1039/D0CC01532F, Communication
Qi Wu, Xian Liu, Yeshuang Du, Chunlin Teng, Fei Liang
A first example of monovalent-metal-based hybrid halides [N(CH3)4]MCl2 (M = Ga+, In+) with zero-dimensional configuration containing unprecedented linear [GaCl2]/[InCl2] units have been designed and synthesized.
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Structural elucidation of the degradation mechanism of nickel-rich layered cathodes during high-voltage cycling

Chem. Commun., 2020, 56,4886-4889
DOI: 10.1039/D0CC00327A, Communication
Open Access
Jing Lai, Jun Zhang, Zuowei Li, Yao Xiao, Weibo Hua, Zhenguo Wu, Yanxiao Chen, Yanjun Zhong, Wei Xiang, Xiaodong Guo
A splitting of two O3 phases, rather than the often observed O1 phases in the conventional LiCoO2 electrode, was discovered in the LiNi0.85Co0.10Mn0.05O2 at high-voltage region (>4.6 V) by in situ high-resolution synchrotron radiation diffraction.
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Fe3Pt intermetallic nanoparticles anchored on N-doped mesoporous carbon for the highly efficient oxygen reduction reaction

Chem. Commun., 2020, 56,4898-4901
DOI: 10.1039/D0CC00895H, Communication
Danke Chen, Zhuoyi Li, Yu Zhou, Xu Ma, Hanqing Lin, Wen Ying, Xinsheng Peng
N-Doped mesoporous carbon catalysts dispersed with Fe3Pt intermetallic nanoparticles, exhibiting excellent ORR performance, were synthesised by direct pyrolysis of Pt–Fe co-functionalized ZIF-8.
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A heteroleptic diradical Cr(III) complex with extended spin delocalization and large intramolecular magnetic exchange

Chem. Commun., 2020, 56,4906-4909
DOI: 10.1039/D0CC00548G, Communication
Xiaozhou Ma, Elizaveta A. Suturina, Mathieu Rouzières, Fabrice Wilhelm, Andrei Rogalev, Rodolphe Clérac, Pierre Dechambenoit
Ligand-based successive reductions in a heteroleptic Cr(III) complex give rise to intended extremely strong metal–radical magnetic interactions.
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A dual-round signal amplification strategy for colorimetric/photoacoustic/fluorescence triple read-out detection of prostate specific antigen

Chem. Commun., 2020, 56,4942-4945
DOI: 10.1039/D0CC01086C, Communication
Chao Jiang, Yan Huang, Ting He, Peng Huang, Jing Lin
A colorimetric/fluorescence/photoacoustic triple read-out detection of prostate specific antigen (PSA) was developed by using a silica coated Au@Ag core–shell nanorod (denoted Au@Ag@SiO2) based enzyme-linked immunosorbent assay (ELISA) system.
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The design of hypercrosslinked polymers from benzyl ether self-condensing compounds and external crosslinkers

Chem. Commun., 2020, 56,4938-4941
DOI: 10.1039/D0CC01002B, Communication
Robert T. Woodward
Hypercrosslinked polymers were produced via the self-condensation of benzyl ether compounds, providing a one-component route to highly porous networks and significant reductions in catalyst waste compared to conventional routes.
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Atomically thin TiO2 nanosheets synthesized using liquid metal chemistry

Chem. Commun., 2020, 56,4914-4917
DOI: 10.1039/D0CC01456G, Communication
Turki Alkathiri, Nripen Dhar, Azmira Jannat, Nitu Syed, Md Mohiuddin, Manal M. Y. A. Alsaif, Robi S. Datta, Kibret A. Messalea, Bao Yue Zhang, Muhammad Waqas Khan, Aaron Elbourne, Naresh Pillai, Jian Zhen Ou, Ali Zavabeti, Torben Daeneke
The library of two-dimensional materials is limited since many transition metal compounds are not stratified and can thus not be easily isolated as nanosheets. Liquid metal-based synthesis provides a new approach to overcome this limitation.
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A highly active Rh1/CeO2 single-atom catalyst for low-temperature CO oxidation

Chem. Commun., 2020, 56,4870-4873
DOI: 10.1039/D0CC00230E, Communication
Bing Han, Tianbo Li, Junying Zhang, Chaobin Zeng, Hiroaki Matsumoto, Yang Su, Botao Qiao, Tao Zhang
Rh1/CeO2 SAC is highly active for CO oxidation, which exhibits a high TOF of 0.41 s−1via the Mars–van Krevelen mechanism.
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New insight derived from a two-compartment cell: electrochemical behavior of FeF3 positive electrode

Chem. Commun., 2020, 56,4878-4881
DOI: 10.1039/D0CC01162B, Communication
Kazuki Yoshii, Noboru Taguchi, Takeshi Miyazaki, Masahiro Shikano, Hikari Sakaebe
A designed two-compartment cell revealed the degradation mechanism and an essentially effective additive for the FeF3 composite electrode.
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Conformational control of N-methyl-N,N'-diacylhydrazines by noncovalent carbon bonding in solution

Chem. Commun., 2020, 56,4874-4877
DOI: 10.1039/D0CC00943A, Communication
Jugal Kishore Rai Deka, Biswajit Sahariah, Kalpita Baruah, Arun Kumar Bar, Bani Kanta Sarma
Unusual N(amide)⋯C–X noncovalent carbon bonding interactions stabilize the transcis (tc) amide bond rotamers of N-methyl-N,N'-diacylhydrazines over the expected transtrans (tt) rotamers in solution.
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Beyond temperature: controlling collagen fibrillogenesis under physiological conditions via interaction with cucurbit[7]uril

Chem. Commun., 2020, 56,4946-4949
DOI: 10.1039/D0CC01444C, Communication
Qiuping Xie, Delong Hou, Jinming Chang, Zhou Xu, Qi Zeng, Zhonghui Wang, Yi Chen
A supramolecular strategy as efficient as temperature that enabled facile control over collagen fibrillogenesis under physiological conditions was reported.
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Temperature-driven n–p conduction type switching without structural transition in a Cu-rich chalcogenide, NaCu5S3

Chem. Commun., 2020, 56,4882-4885
DOI: 10.1039/D0CC01429J, Communication
Shangqing Qu, Yonggang Wang, Yu Xiao, Yujie Yuan, Shengyi Li, Jikun Chen, Lidong Zhao, Zhiguo Xia, Jing Zhao
We report for the first time the discovery of reversible n–p conduction type switching in a chalcogenide, NaCu5S3, without structural transition.
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Pd-Promoted cross coupling of iodobenzene with vinylgold via an unprecedented phenyl transmetalation from Pd to Au

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02645J, Communication
Jiwei Wang, Licheng Zhan, Gendi Wang, Yin Wei, Min Shi, Jun Zhang
Oxidative addition of Pd/Au vinylene species with iodobenzene reveals the effect of a strong metallophilic Pd⋯Au interaction on phenyl transmetalation from PdIV to AuI, which allows subsequent reductive elimination of LAuI at Pd and Au.
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Chemically synthesized circular RNAs with phosphoramidate linkages enable rolling circle translation

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02140G, Communication
Kosuke Nakamoto, Naoko Abe, Genichiro Tsuji, Yasuaki Kimura, Fumiaki Tomoike, Yoshihiro Shimizu, Hiroshi Abe
Circular RNA without a stop codon enables rolling circle translation. we carried out one-pot chemical synthesis of circular RNA from RNA fragments. The synthesized circular RNAs acted as translation templates, despite the presence of unnatural phosphoramidate linkages.
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A convenient reagent for the conversion of aldoximes into nitriles and isonitriles

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC00188K, Communication
Wei Zhang, Jin-Hong Lin, Pengfei Zhang, Ji-Chang Xiao
Described herein is the convenient transformation of aldoximes into nitriles or isonitriles by slightly modifying reaction conditions.
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Construction of Nanocage-Structured Heterogeneous Binary Metal Sulfides via Step-by-Step Confined Growth for Boosted Lithium Storage Properties

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00962H, Communication
Rongfang Zhao, Yue Han, Wenlong Li, Jinhua Li, Ming Chen, Lingxin Chen
Nanocage-structured materials-heterogeneous binary metal sulfides (MoS2 and Co9S8) in carbon nanocages (Co9S8/MoS2@CNCs) via step-by-step confined growth display superior Li-storage performance, profiting from the synergistic effect of bimetallic sulfides, high filling...
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Ultrasensitive DNA Electrochemical Biosensor Based on MnTBAP Biomimetic Catalyzed AGET ATRP Signal Amplification Reaction

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02176H, Communication
Haobo Sun, Yunliang Qiu, Yajie Lu, Jinming Kong, Xueji Zhang
In this paper, an ultrasensitive, highly selective and green electrochemical biosensor for quantifying DNA sequences (aM DNA) based on MnTBAP catalyst for AGET ATRP reaction is proposed. For the first...
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Surfactant-free synthesis of ultralong silver nanowires for endurable transparent conducting electrodes

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01915A, Communication
Sian-Hong Tseng, Lian-Ming Lyu, Kai-Yuan Hsiao, Wan-Hua Ho, Ming-Yen Lu
The present study employed the surfactant-free growth of ultralong (~50 μm) silver nanowires (AgNWs) with high aspect ratio (up to 500) by galvanic replacement. AgNW conducting film were fabricated as...
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A DNA logic gate with dual-anchored proximity aptamers for accurate identification of circulating tumor cells

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00564A, Communication
Tianshu Chen, Xin Fu, Qianqian Zhang, Dongsheng Mao, Yuchen Song, Chang Feng, Xiaoli Zhu
We have designed a DNA logic gate that can integrate multiple biomarkers recognition with signal amplification to perform accurate and and sensitive analysis of circulating tumor cells (CTCs). It also...
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Intra-mitochondrial self-assembly to overcome the intracellular enzymatic degradation of L-peptides

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02029J, Communication
M. T. Jeena, Seokyoung Lee, Ayan Kumar Barui, Seongeon Jin, Yuri Cho, Suk-Won Hwang, Sehoon Kim, Ja-Hyoung Ryu
The design of peptide-based therapeutics is generally based on the replacement of L-amino acids with D-isomers to obtain improved therapeutic efficiency.
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A three-dimensional BODIPY–iron(III) compound with improved H2O2-response for NIR-II photoacoustic imaging guided chemodynamic/photothermal therapy

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01164A, Communication
Changjin Ou, Yewei Zhang, Wei Ge, Liping Zhong, Yong Huang, Weili Si, Wenjun Wang, Yongxiang Zhao, Xiaochen Dong
3D boron dipyrromethene (BODIPY)–Fe(III) coordination polymer nanoparticles with NIR-II absorption were developed as photothermal and chemodynamic agent to effectively kill cancer cells.
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Inter-chain double-site synergistic photocatalytic hydrogen evolution in robust cuprous coordination polymers

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01785J, Communication
Ying Zang, Jiangwei Zhang, Rui Wang, Zhao-Di Wang, Yandi Zhu, Xiaoyan Ren, Shunfang Li, Xi-Yan Dong, Shuang-Quan Zang
We evaluate photocatalytic H2 generation of three Cu-based coordination polymers, a record-high rate of 57.64 mmol g−1 h−1 for Cu–MIM, and reveal that the excellent performances are due to the synergies of the inter-chain double-site Cu atoms.
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Deep imaging for visualizing nitric oxide in lipid droplets: discovering the relationship between nitric oxide and resistance to cancer chemotherapy drugs

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01856B, Communication
Miantai Ye, Wei Hu, Meng He, Chenchen Li, Shuyang Zhai, Zhihong Liu, Yanying Wang, Huijuan Zhang, Chunya Li
A near-infrared two-photon fluorescent probe for selective detection and deep-depth imaging of NO helps to discover the relationship between NO and resistance to antitumor drugs.
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Harnessing chemical exchange: 19F magnetic resonance OFF/ON zinc sensing with a Tm(III) complex

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01876G, Communication
Meng Yu, Da Xie, Rahul T. Kadakia, Weiran Wang, Emily L. Que
A Tm(III) complex displays an “off–on” 19F NMR/MRI response to Zn(II) upon tuning the chemical exchange rate.
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An ultrasensitive electrochemical biosensor for Pseudomonas aeruginosa assay based on a rolling circle amplification-assisted multipedal DNA walker

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01619E, Communication
Huang Zhou, Shaoyun Duan, Ji Huang, Fengjiao He
An ultrasensitive electrochemical biosensor was developed based on RCA and multipedal DNA walking strategy for the assay of 16S rRNA gene, and it has great application potential in food safety, environmental monitoring, and disease diagnosis.
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Smart azobenzene-containing tubular polymersomes: fabrication and multiple morphological tuning

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01934H, Communication
Lishan Li, Songbo Cui, An Hu, Wei Zhang, Yiwen Li, Nianchen Zhou, Zhengbiao Zhang, Xiulin Zhu
Several kinds of novel azobenzene-containing tubular polymersomes were fabricated via self-assembly, and their shape could be tuned precisely by changing the chemical structure, self-assembly condition and external stimuli.
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A highly active and robust iron quinquepyridine complex for photocatalytic CO2 reduction in aqueous acetonitrile solution

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01930E, Communication
Yanfei Qin, Lingjing Chen, Gui Chen, Zhenguo Guo, Lei Wang, Hongbo Fan, Marc Robert, Tai-Chu Lau
[Fe(qnpy)(H2O)2]2+ is a highly efficient and robust catalyst for visible-light-driven reduction of CO2 to CO, with a TON for CO of up to 14 095 and selectivity of 98% using Ru(phen)3Cl2 as photosensitizer and BIH as sacrificial reductant.
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3D spongy nanofiber structure Fe–NC catalysts built by a graphene regulated electrospinning method

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01517B, Communication
Weiyuan Ding, Hongquan Yu, Yu Tang, Zhuxin Li, Bijiao Liu, Dechong Liu, Yuyu Wang, Shu hong Liu, Hong Zhao, Daniel Mandler
A Fe–NC catalyst containing carbon nanotubes, mesopores and macropores with a measurable 3D framework structure was prepared by electrospinning.
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