ir Iridium/palladium dual photocatalysis for oxidative decarboxylative esterification of alcohols using α-keto acids By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6367-6379DOI: 10.1039/D4QO01452A, Research ArticleSubal Mondal, Soumya Mondal, Debabrata Halder, Siba P. Midya, Ankan Paul, Pradyut GhoshHerein, we report an unprecedented oxidative decarboxylative C–O cross-coupling reaction for the esterification of feedstock α-keto carboxylic acids and alcohols under mild conditions.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ir Transition-metal-catalyzed regiodivergent sulfonylation of aziridrines for the synthesis of β-amino sulfones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6340-6346DOI: 10.1039/D4QO01376J, Research ArticleQinqiong Zeng, Yujia Gong, Xiaochun He, Xuemei Zhang, Zhong LianWe developed the first transition-metal-catalyzed, regiodivergent sulfonylation of aziridines, enabling the efficient synthesis of diverse β-amino sulfones under mild conditions with broad substrate compatibility and high regioselectivity.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ir Chiral synthetic unprecedented spiro[indoline-2,3'-thiophen]-3-ones via an organocatalytic asymmetric sulfa-Michael/aldol cascade reaction By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6426-6436DOI: 10.1039/D4QO01551G, Research ArticleMao Zhang, Xing-Hai Fei, Gui-Ping Yang, Cheng Lin, Wen-Jie Li, Ming-Liang Rao, Meng Zhou, Chong Zhao, Bin He, Yong-Long ZhaoA cinchona-derived squaramide-catalyzed asymmetric sulfa-Michael/aldol cascade reaction of 2-ylideneoxindoles with 1,4-dithiane-2,5-diol was developed to realize the chiral synthesis of spiro[indoline-2,3'-thiophen]-3-ones.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ir Well-defined chiral dinuclear copper-catalyzed tandem asymmetric propargylic amination–carboxylative cyclization sequence toward chiral 2-oxazolidinone derivatives By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6319-6326DOI: 10.1039/D4QO01368A, Research ArticleYu Lan, Peng Liu, Zekai Fang, Lili Shao, Qilong Cai, Xiaoming WangA variety of chiral 2-oxazolidinones was obtained via a dinuclear copper-catalyzed asymmetric propargylic amination–carboxylative cyclization sequence of propargylic esters with alkyl amine hydrochlorides and CO2.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ir Design, synthesis and application of bipyridine-N,N'-dioxide catalysts in asymmetric synthesis of chiral cyclopropanes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6470-6476DOI: 10.1039/D4QO01532K, Research ArticleXiaoying Cao, Xue Tian, Minmin Liu, Shi-Wu LiA novel type of highly efficient chiral C2-symmetric bipyridine-N,N'-dioxide ligands was prepared and successfully applied in the synthesis of optically pure 1,2,3-trisubstituted cyclopropanes.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ir Anomalous magnetic behaviour induced by a structural phase transition with anisotropic thermal expansion in a spirodiradical By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6495-6502DOI: 10.1039/D4QO01098A, Research Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Takuya Kanetomo, Daigo Matsunaga, Shinichi Ogawa, Masaya EnomotoA Ge-centred spirodiradical exhibited anomalous magnetic behaviour, influenced by two key structural factors: negative thermal expansion and a structural phase transition.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ir Cobalt-catalyzed enantioselective reductive addition of ketimine with cyclopropyl chloride to construct chiral amino esters bearing cyclopropyl fragments By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6311-6318DOI: 10.1039/D4QO01474J, Research ArticleJiangtao Hu, Tingting Xia, Xianqing Wu, Hongrui Feng, Jingping Qu, Yifeng ChenCo-catalyzed asymmetric reductive addition of ketimine with cyclopropyl chloride has been realized to access diverse chiral amino esters bearing cyclopropyl fragments with broad functional group tolerance and excellent enantioselectivities.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ir Recent advances in asymmetric synthesis of chiral benzoheterocycles via Earth-abundant metal catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6534-6557DOI: 10.1039/D4QO01686F, Review ArticleJinhui Cai, Wenting Zhang, Usman Muhammad, Weishuang Li, Yanjun XieThis review mainly focus on the assembly of chiral benzoheterocycles, such as dihydrobenzofurans, chromans, indolines, tetrahydroquinolines, etc., via Earth-abundant metal-catalyzed (Cu, Fe, Ni, and Ti) asymmetric synthesis in the last few decades.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ir LiTMP-LiBr complex-induced lateral lithiation and cross ester condensation: direct access to isocoumarins from 2-methoxy o-toluate esters By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01678E, Research Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Mintu Rehman, Sajib Daimary, Rasajna Madhusudhana, Rajendar GoretiLiTMP-LiBr complex promotes cross-ester coupling of 2-methoxy o-toluate esters to directly yield isocoumarin is demonstrated. Method applied to many natural product precursors including synthesis of (+)- and (−)-lunatinins.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ir A two-step Kinugasa/Conia-ene-type sequential reaction for the asymmetric synthesis of 8-methylene-2,6-diazaspiro[3.4]octane-1,5-diones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01388C, Research ArticleShanyue Li, Qicai Ma, Bohua Wu, Haowen Ma, Wei Zhou, Qian CaiA two-step Kinugasa/Conia-ene-type sequential reaction is developed. The process provided a simple and efficient access to chiral 8-methylene-2,6-diazaspiro[3.4]octane-1,5-diones.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ir Catalytic asymmetric synthesis of chiral sulfilimines via S-C bond formation By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01963F, HighlightYingying Shi, Shuiyun Zheng, Jiapian Huang, Fu-Sheng He, Min Yang, Jie WuAs the aza-analogues of sulfoxides, sulfilimines bearing S(IV) stereogenic centers hold tremendous potential in synthetic chemistry and medicinal chemistry. However, the catalytic asymmetric synthesis of chiral sulfilimines are much less...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ir Iridium-catalyzed asymmetric cascade allylation/lactonization of methyl salicylates: enantioselective construction of chiral benzodioxepinones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01771D, Research ArticleBendu Pan, Yunru Wu, Yaqi Zhang, Xiaobo He, Long Jiang, Liqin QiuAn efficient asymmetric cascade allylation/lactonization of methyl salicylates is achieved. The utilization of chiral-bridged biphenyl phosphoramidite ligand resulted in good results for the construction of a wide range of chiral benzodioxepinones.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ir Metal–ligand cooperation and synergistic palladium catalysis for the dual ligand system [2,2'-bipyridin]-6(1H)–one/PCy3: milder conditions for the undirected C–H arylation of arenes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01877J, Research Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Cintya Pinilla, Mario García-Zarza, Ana C. AlbénizThe mixture of Pd(OAc)2 and two ligands segregate into distinct active species working synergistically for the C–H arylation of simple arenes.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ir Modular dehydrogenative cross-nucleophile coupling for direct construction of tetrasubstituted carbons By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01641F, Research ArticlePeng Wang, Qiang Wang, Meng Wang, Liang Wang, Lubin Xu, Xiong-Li Liu, Fangzhi Hu, Shuai-Shuai LiAn FeCl3-catalyzed cross-dehydrogenative coupling reaction for the construction of various types of C–Y (Y = C, N, O, S) bonds with air as a green oxidant.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ir Six awarded life imprisonment for trafficking Bangladeshi girls By www.thehindu.com Published On :: Thu, 07 Nov 2024 18:47:05 +0530 Full Article Telangana
ir Telangana pharmaceutical industries logged 97 major fire accidents in past decade: Fire Services Director-General Y. Nagi Reddy By www.thehindu.com Published On :: Thu, 07 Nov 2024 18:58:18 +0530 The new government would like to decentralise and set up pharma villages, in 10 clusters, Special Chief Secretary Jayesh Ranjan said Full Article Telangana
ir Traffic diversions in Rachakonda from Friday 8 a.m. for CM’s visit to Yadadri-Bhuvanagiri district By www.thehindu.com Published On :: Thu, 07 Nov 2024 23:19:05 +0530 Full Article Telangana
ir Telangana Deputy CM seeks proposals for retaining wall to prevent monsoon flooding in Madhira By www.thehindu.com Published On :: Fri, 08 Nov 2024 20:26:50 +0530 Full Article Telangana
ir Guru Nanak’s 555th birth anniversary celebrations to begin in Hyderabad on November 11 By www.thehindu.com Published On :: Sun, 10 Nov 2024 19:48:15 +0530 Full Article Telangana
ir Lorry ferrying EV cars to Hyderabad catches fire By www.thehindu.com Published On :: Sun, 10 Nov 2024 22:51:21 +0530 Full Article Telangana
ir Hyderabad-based Raghu Vamsi Group acquires British precision machining firm PMC Group By www.thehindu.com Published On :: Mon, 11 Nov 2024 14:55:02 +0530 The Hyderabad-based MSME, Raghu Vamsi Group, has completed the acquisition of British precision machining firm PMC GGroup, that traces its roots to over 100 years Full Article Hyderabad
ir Fire engulfs two scrap godowns By www.thehindu.com Published On :: Mon, 11 Nov 2024 18:49:32 +0530 Full Article Telangana
ir SRIRAM’s IAS launches coaching centre in Hyderabad By www.thehindu.com Published On :: Mon, 11 Nov 2024 20:49:07 +0530 Full Article Telangana
ir Telangana to repair 9,000 km of roads using advanced technology: Minister Komatireddy By www.thehindu.com Published On :: Tue, 12 Nov 2024 00:43:54 +0530 Full Article Telangana
ir Three schoolgirls in Telangana tribal school hospitalised after suspected food poisoning, one critical By www.thehindu.com Published On :: Tue, 12 Nov 2024 19:20:20 +0530 The girls, aged between 13 and 16, suffered acute gastroenteritis, dehydration, and kidney-related complications Full Article Telangana
ir IND vs NZ third Test: India shoots itself in the foot after dominating most of the day By www.thehindu.com Published On :: Fri, 01 Nov 2024 19:20:07 +0530 A combination of reckless batting and decision-making undoes all the good work done by Jadeja and Washington in restricting New Zealand to a modest 235 Full Article Cricket
ir IND vs NZ third Test: Ravindra Jadeja rues worst fears having come true By www.thehindu.com Published On :: Fri, 01 Nov 2024 19:40:26 +0530 In India’s last series loss at home prior to this, Jadeja – a rookie – had featured in a solitary Test. Full Article Cricket
ir Virat Kohli drops hints of completing 20 years with RCB By www.thehindu.com Published On :: Sat, 02 Nov 2024 15:52:51 +0530 Virat Kohli has been playing for RCB ever since IPL's inception in 2008 and is the leading run-scorer in the competition, amassing over 8,000 runs Full Article Cricket
ir IND vs NZ third Test Day 2: Chase won't be easy, we have to bat really well, says Ravichandran Ashwin By www.thehindu.com Published On :: Sat, 02 Nov 2024 18:03:18 +0530 What surprised Ashwin is the nature of low bounce, not exactly synonymous with red soil Mumbai surfaces which helps the ball to fly. Full Article Cricket
ir IND vs NZ third Test: India takes a narrow lead, with the Test poised on a knife’s edge By www.thehindu.com Published On :: Sat, 02 Nov 2024 19:19:18 +0530 Pant leads the way with an entertaining knock, while Gill is unlucky to miss his hundred; Azaz once again excels with a five-for to keep the Kiwis in the hunt on a turning track turning hostile for the batters with every passing hour Full Article Cricket
ir IND vs NZ third Test: Don’t know how the Pant decision was overturned, says Rohit Sharma By www.thehindu.com Published On :: Sun, 03 Nov 2024 23:02:41 +0530 New Zealand captain Tom Latham stated his troupe was confident it had heard two sounds. Full Article Cricket
ir Wriddhiman Saha announces retirement from cricket after this year's Ranji Trophy By www.thehindu.com Published On :: Mon, 04 Nov 2024 11:03:14 +0530 Veteran cricketer Wriddhiman Saha announces retirement, last season in Ranji Trophy, ending a cherished journey in cricket Full Article Cricket
ir Wriddhiman Saha to retire after this season Ranji Trophy By www.thehindu.com Published On :: Mon, 04 Nov 2024 17:38:48 +0530 Full Article Cricket
ir Can skipper Rohit find inspiration to ‘pull’ his side out of the numbing depths? By www.thehindu.com Published On :: Tue, 05 Nov 2024 00:32:21 +0530 India has been in similar situations in the past and found a way to bounce back in style. Nothing will motivate the skipper more than the prospect of a statement-making performance down under, especially with qualification for the final of the World Test Championship now hanging by a slender thread Full Article Cricket
ir Ranji Trophy | Birla’s six-for puts Chandigarh in driving seat against Delhi By www.thehindu.com Published On :: Fri, 08 Nov 2024 19:57:46 +0530 The host ends day three at 46 for no loss after dismissing the visitor for 250 in its second innings and needs 157 more runs to clinch an outright victory Full Article Cricket
ir “Indians find Ireland ideal” By www.thehindu.com Published On :: Sun, 11 Oct 2015 17:00:32 +0530 Full Article Careers
ir The ABC of first impressions By www.thehindu.com Published On :: Sun, 25 Oct 2015 17:00:48 +0530 Just out of college and looking for a job? Some tips on professional etiquette. Full Article Careers
ir Free coaching classes for TNPSC job aspirants By www.thehindu.com Published On :: Tue, 08 Dec 2015 10:54:23 +0530 Full Article Coimbatore
ir Civil services aspirants at sea By www.thehindu.com Published On :: Fri, 11 Dec 2015 00:00:00 +0530 Full Article Tamil Nadu
ir Tirumurai as explained by Periyava By www.thehindu.com Published On :: Thu, 19 May 2016 16:09:34 +0530 Full Article Faith
ir The songster’s journey to Tiruvaiyaru By www.thehindu.com Published On :: Thu, 02 Jun 2016 17:18:29 +0530 Jagdish Koppa’s book on Bangalore Nagarathnamma is a detailed account of the musician and also the life of devadasis in South India Full Article Friday Review
ir In the name of Kabir By www.thehindu.com Published On :: Thu, 16 Jun 2016 15:30:12 +0530 Bhoomija’s evening of Kabir songs, Shabad Dhun Laagi was poignant Full Article Friday Review
ir The spirit of Bengal By www.thehindu.com Published On :: Thu, 16 Jun 2016 16:14:06 +0530 Probal Ray Choudhury, professor of culture education, on the tradition of Durga Puja. Full Article History & Culture
ir Tiruppugazh scholar’s new book By www.thehindu.com Published On :: Thu, 23 Jun 2016 17:30:19 +0530 Full Article History & Culture
ir Regulating temple affairs By www.thehindu.com Published On :: Thu, 21 Jul 2016 16:13:09 +0530 Full Article History & Culture
ir The cheetah that loved Hyderabadi biryani By www.thehindu.com Published On :: Sat, 01 Oct 2022 20:01:04 +0530 Nobility showed off their pet cheetahs and posed for photographs before and after hunts; for the British, they defined India’s exotic wildlife Full Article Hyderabad
ir The Complete to Planning Your Estate in Virginia: A Step-by-Step Plan to Protect Your Assets, Limit Your Taxes, and Ensure Your Wishes are Fulfilled for Virginia Residents By atlanticpub.wordpress.com Published On :: Tue, 31 Jul 2012 19:40:29 +0000 What happens to your estate after you are gone is very much within your control. Estate planning is not only for the wealthy; it is for everyone. It is simply the process of deciding where your assets are to be distributed after your death. For those people who wish to preserve their assets for designated […] Full Article Publisher
ir The Sex Drive Solution for Women: Dr. Jen’s Power Plan to Fire Up Your Libido By atlanticpub.wordpress.com Published On :: Tue, 31 Jul 2012 19:52:42 +0000 Dr. Jen doesn’t only talk about weight management, renewed energy and sexual vitality for women over 40 – she is a living, breathing example that all of that and more are possible. The Sex Drive Solution is a wealth of information not only from an expert doctor, but a woman, a wife, a mother who […] Full Article Publisher
ir Graphene-supported organoiridium clusters catalyze N-alkylation of amines via hydrogen borrowing reaction By pubs.rsc.org Published On :: RSC Adv., 2024, 14,35163-35171DOI: 10.1039/D4RA06595F, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Tsun-Ren Chen, Siang-Yu Chiu, Wen-Jen Lee, Yi-Siou Tsai, Yu-Sheng HuangGraphene-supported organic iridium clusters (GSOIC) exhibit excellent N-alkylation on various substrates under green processes.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ir Synthesis and antibiotic potential of myxocoumarin-inspired chromene dione analogs By pubs.rsc.org Published On :: RSC Adv., 2024, 14,35215-35219DOI: 10.1039/D4RA05941G, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Antonia Behnsen, Gesa Hertrampf, Sandra Vojnović, Jasmina Nikodinović-Runić, Tobias A. M. GulderThe myxocoumarins are natural products with strong antibiotic activity. We herein explored structural simplification of the myxocoumarins while aiming to retain their antibacterial properties. This led to the discovery of potent myxochromene diones.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article