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Highly homogeneous and stable single-walled carbon nanotubes dispersion modified by polyvinylpyrrolidone and alkanolamine in water

RSC Adv., 2024, 14,12947-12953
DOI: 10.1039/D4RA01614A, Paper
Open Access
Minghua Li, Shujun Yu, Xiting Fang, Zhiqiang Du, Xiaojin Ge
An easy green non-covalent surface functionalization of pristine SWCNT was carried out by using ball grinding technology, resulting in the formation of a highly homogeneous and stable PA-SWCNTs dispersion reported firstly in water.
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Development of an imidazole-based N,N-bidentate ligand for the manganese catalyzed direct coupling of nitriles with alcohols

RSC Adv., 2024, 14,12978-12982
DOI: 10.1039/D4RA00817K, Paper
Open Access
Qian Tang, Dingguo Song, Kali Zhang, Wenhao Mao, Xianghua Zhao, Ding Du, Fei Ling, Weihui Zhong
This work describes the manganese catalyzed direct coupling of nitriles with alcohols with assistance of a set of simple and new imidazole-based N,N-bidentate ligands.
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Mechanics of biomimetic free-standing lipid membranes: insights into the elasticity of complex lipid compositions

RSC Adv., 2024, 14,13044-13052
DOI: 10.1039/D4RA00738G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Alessandra Griffo, Carola Sparn, Fabio Lolicato, Friederike Nolle, Navid Khangholi, Ralf Seemann, Jean-Baptiste Fleury, Martin Brinkmann, Walter Nickel, Hendrik Hähl
In this study, we prepare pore-spanning membranes that mimic the composition of plasma membranes and perform force spectroscopy indentation measurements to unravel mechanistic insights depending on lipid composition.
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mi

ProteoMutaMetrics: machine learning approaches for solute carrier family 6 mutation pathogenicity prediction

RSC Adv., 2024, 14,13083-13094
DOI: 10.1039/D4RA00748D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jiahui Huang, Tanja Osthushenrich, Aidan MacNamara, Anders Mälarstig, Silvia Brocchetti, Samuel Bradberry, Lia Scarabottolo, Evandro Ferrada, Sergey Sosnin, Daniela Digles, Giulio Superti-Furga, Gerhard F. Ecker
Predict SLC6 mutation clinical pathogenicity by calculating the amino acid descriptors in different ranges with rationalization analysis of the prediction.
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The conjugates of 5'-deoxy-5-fluorocytidine and hydroxycinnamic acids – synthesis, anti-pancreatic cancer activity and molecular docking studies

RSC Adv., 2024, 14,13129-13141
DOI: 10.1039/D4RA01683A, Paper
Open Access
Marcin Cybulski, Magdalena Zaremba-Czogalla, Bartosz Trzaskowski, Marek Kubiszewski, Joanna Tobiasz, Anna Jaromin, Piotr Krzeczyński, Jerzy Gubernator, Olga Michalak
New conjugates 1–6 containing 5-dFCR and selected hydroxycinnamic acids were synthesized and tested in vitro against pancreatic cancer (PDAC) lines. The ADME properties and molecular docking to CES2 or human albumin were discussed.
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High performance electrochemical CO2 reduction over Pd decorated cobalt containing nitrogen doped carbon

RSC Adv., 2024, 14,13017-13026
DOI: 10.1039/D4RA01641F, Paper
Open Access
Shayan Gul, Fatima Nasim, Waheed Iqbal, Amir Waseem, Muhammad Arif Nadeem
Efficient electrocatalytic CO2 reduction reaction (eCO2RR) to various products, such as carbon monoxide (CO), is crucial for mitigating greenhouse gas emissions and enabling renewable energy storage.
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mi

Effects of external light in the magnetic field-modulated photocatalytic reactions in a microfluidic chip reactor

RSC Adv., 2024, 14,13053-13061
DOI: 10.1039/D4RA00415A, Paper
Open Access
Hung Ji Huang, Yen Han Wang, Xuan-Yu Shih, Sy-Hann Chen, Hai-Pang Chiang, Yuan-Fong Chou Chau, Jeffrey Chi-Sheng Wu
Mutual enhancement of plasmonic photocatalytic reaction by both magnetic field and plasmonic enhancement was presented through Au–TiO2 nanoparticles.
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Regioselective C(sp2)–H halogenation of pyrazolo[1,5-a]pyrimidines facilitated by hypervalent iodine(III) under aqueous and ambient conditions

RSC Adv., 2024, 14,13095-13099
DOI: 10.1039/D4RA02090A, Paper
Open Access
Abhinay S. Chillal, Rajesh T. Bhawale, Umesh A. Kshirsagar
An efficient and mild approach has been developed for the regio-selective direct C3 halogenation of pyrazolo[1,5-a]pyrimidines employing readily available potassium halide salts and a hypervalent iodine(III) reagent at ambient temperature.
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Grind, shine and detect: mechanochemical synthesis of AIE-active polyaromatic amide and its application as molecular receptor of monovalent anions or nucleotides

RSC Adv., 2024, 14,13227-13236
DOI: 10.1039/D4RA02129K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jakub S. Cyniak, Artur Kasprzak
The mechanochemical synthesis of AIE-active amide, as well as the application of the title compound as molecular receptor of monovalent anions and nucleotides, are described.
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Quinazolines and thiazolidine-2,4-dions as SARS-CoV-2 inhibitors: repurposing, in silico molecular docking and dynamics simulation

RSC Adv., 2024, 14,13237-13250
DOI: 10.1039/D4RA02029D, Paper
Open Access
Sanadelaslam S. A. El-Hddad, Mohamed H. Sobhy, Ahmed El-morsy, Nabil A. Shoman, Khaled El-Adl
This paper presents an extensive analysis of COVID-19 with a specific focus on VEGFR-2 inhibitors as potential treatments.
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Dispersive micro solid phase extraction of glibenclamide from plasma, urine, and wastewater using a magnetic molecularly imprinted polymer followed by its determination by a high-performance liquid chromatography-photodiode array detector

RSC Adv., 2024, 14,13168-13179
DOI: 10.1039/D4RA00452C, Paper
Open Access
Najmeh Sabbaghi, Shayessteh Dadfarnia, Ali Mohammad Haji Shabani, Majid Farsadrooh
The present study describes the development of a simple and selective analytical method for dispersive micro solid phase extraction and determination of glibenclamide (GLB) using magnetic molecularly imprinted polymer (MMIP) as a sorbent.
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1D hollow tubular/2D nanosheet hybrid dimensional porous carbon prepared by one-step carbonization using natural minerals as templates for supercapacitors

RSC Adv., 2024, 14,13190-13199
DOI: 10.1039/D4RA01873G, Paper
Open Access
Fangfang Liu, Chao Zhang, Weiwei Huang, Lei Chen, Yuanshuang Wang, Jinan Niu, Xiuyun Chuan
1D hollow tubular/2D nanosheet hybrid dimensional porous carbon was synthesized through one-step carbonization using 1D fibrous brucite and 2D layered magnesium carbonate hydroxide as templates.
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A multi-channel microfluidic platform based on human flavin-containing monooxygenase 3 for personalised medicine

RSC Adv., 2024, 14,13209-13217
DOI: 10.1039/D4RA01516A, Paper
Open Access
Melissa De Angelis, Silvia Schobesberger, Florian Selinger, Viktor Laurin Sedlmayr, Martin Frauenlob, Orsola Corcione, Shiman Dong, Gianfranco Gilardi, Peter Ertl, Sheila J. Sadeghi
A microfluidic platform with immobilized human flavin-containing monooxygenase for high-throughput screening of drugs with relevance to personalised medicine.
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Bishydrazone ligand and its Zn-complex: synthesis, characterization and estimation of scalability inhibition mitigation effectiveness for API 5L X70 carbon steel in 3.5% NaCl solutions

RSC Adv., 2024, 14,13258-13276
DOI: 10.1039/D4RA00404C, Paper
Open Access
Ola. A. El-Gammal, Dina A. Saad, Marwa N. El-Nahass, Kamal Shalabi, Yasser M. Abdallah
Zn-complex: characterization and estimation of scalability inhibition mitigation effectiveness for API 5L X70 carbon steel in 3.5% NaCl solutions.
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On the use of modelling antagonistic enzymes to aid in temporal programming of pH and PVA–borate gelation

Mol. Syst. Des. Eng., 2024, 9,372-381
DOI: 10.1039/D3ME00138E, Paper
Open Access
Nadeem Bashir, Anna S. Leathard, Madeline McHugh, Imogen Hoffman, Fahima Shaon, Jorge A. Belgodere, Annette F. Taylor, John A. Pojman
A model was developed to help predict how enzymes can be used to temporally control the gelation of polyvinyl alcohol (PVA) with borate.
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mi

Designing biphenanthridine-based singlet fission materials using computational chemistry

Mol. Syst. Des. Eng., 2024, 9,423-435
DOI: 10.1039/D3ME00181D, Paper
Keighlynn A. Veilleux, Georg Schreckenbach, David E. Herbert
A systematic search for novel singlet fission materials based on the recently synthesized 6,6'-biphenanthridine (biphe) framework is reported, utilizing a straightforward computational approach.
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mi

Engineering the interaction of short antimicrobial peptides with bacterial barriers

Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00021H, Minireview
Open Access
Costanza Montis, Elisa Marelli, Francesco Valle, Francesca Baldelli Bombelli, Claudia Pigliacelli
Designing short antimicrobial peptides and tuning their interaction with bacterial barriers.
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A fruitful time for migrant labourers

The apple season in Himachal Pradesh spells good earnings for workers from India and Nepal




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Farming smart foods




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Where technology yields not microchips but sun-dried chips

The Women’s Technology Park in Salem is turning rural women into entrepreneurs, through sustainable schemes




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Busy hands help fight the pandemic

SHGs and prisoners in Himachal Pradesh are stitching masks/PPEs, and making sanitisers




mi

Not a day’s medicine missed

How Project Ahana reached out to the HIV-positive community during the lockdown




mi

The sky’s the limit, for ASMAN

How this Alliance saves mothers and newborns by timely use of technology




mi

MGNREGA: A welcome salve in pandemic times

In Himachal Pradesh, the scheme comes as a breather to those who lost their jobs




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Pedagogy despite the pandemic

How children without access to online education in Jharkhand and Bihar villages get their lessons




mi

Elon Musk And Vivek Ramaswamy To Head New 'Department Of Government Efficiency' Under Trump Administration

The two will head the newly formed Department of Government Efficiency in the upcoming Trump administration, set to begin in January 2025.  




mi

Emerging trends in the chemistry of polymeric resists for extreme ultraviolet lithography

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00957F, Review Article
Jie Cen, Zhengyu Deng, Shiyong Liu
Patterning materials have advanced significantly to achieve high-resolution fabrication of integrated circuits for extreme ultraviolet (EUV) lithography. Emerging trends in the chemistry of polymeric resists for EUV lithography are summarized.
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Self-healable, reprocessable and anti-flammable eugenol-derived covalent adaptable thermosets based on dynamic covalent boronic esters and thiol–ene click chemistry

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00684D, Paper
Haoxin Niu, Yu Li, Ping Zhang, Wenwen Guo, Xin Wang, Yuan Hu
Self-healable and reprocessable eugenol-derived covalent adaptable thermosets were fabricated via dynamic covalent boronic esters and thiol–ene click chemistry.
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mi

Synthesis of Asymmetric Imine Polymers for Highly Selective Sorting of Semiconducting Single-Walled Carbon Nanotubes by Two in One Strategy

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00607K, Paper
Ying Zhang, Yu Li, Yuchi Wan, Jun-Hao Wang, Yunzhen Chang, Sheng Zhu, Lan Bai, Yu Cao, Xuelei Liang, Gaoyi Han
By two in one strategy, we get three polymers of fluorene derivative with asymmetric structure functionalized with two types of arenes with different orientation and electronic properties. The polymers are...
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mi

Long afterglow epoxidized soybean oil polymer composites with reversible dynamic cross-linking for intelligent coating

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00857J, Paper
Jiaman Hu, Zihao Wang, Minglin Yang, Chuansong Yu, Siyu Li, Yinggang Miao, Xiangqian Quan, Jize Liu, Shiyang Shao
High-performance coatings with advanced functions such as long afterglow luminescence and self-healing have attracted great interest around the world, however, the integration of these desired multifunctions in a single composite...
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mi

An efficient and economical degradation strategy for epoxy thermoset based on low cost transesterification catalyst

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY01137F, Paper
Zhijun Yang, Shuhan Zhang, Huan Liang, Enjian He, Yixuan Wang, Ting Lei, Zhicheng Wu, Qiulin Chen, Fusheng Zhou, Yen Wei, Yan Ji
Epoxy thermoset materials are widely used in the field of electrical engineering, including gas-insulated enclosed switches and drytype transformers. It is a challenge to degrade and recycle traditional epoxy thermoset,...
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A novel amine-first strategy suitable for preparing both functional and engineering bio-polyamides: furfurylamine as the sole furan source for bisfuranic diamine/diacid monomers

Polym. Chem., 2024, 15,4433-4446
DOI: 10.1039/D4PY00567H, Paper
Hong-Hui Shu, Yun Liu, Sheng-Li Han, Xiu-Qin Fang, Chang Wang, Cheng-Mei Liu
Biomass-based polyamides (bioPAs) are renewable materials that are viable alternatives to petroleum-based polyamides in the engineering field.
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Star Copolymers with Tunable Clusteroluminescence

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY01198H, Communication
Zixuan Zhou, Xiang Chen, Yang Wang, Ting Li, Xuhui Zhang, Bihua Xia, Shibo Wang, Weifu Dong, Jinliang Qiao
Clusteroluminescence (CL) has recently drawn more attention due to its unique photophysical behaviors that differ from traditional conjugated luminogens. However, the design of red emission from such systems is still...
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Reversible aminolysis: a new concept for postpolymerization modification

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00827H, Communication
Koki Kasai, Hideki Amii, Ryohei Kakuchi
Efficient yet reversible aminolysis postpolymerization modification reactions.
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Mesomorphic and photochromic luminescent behaviour of side-chain liquid crystalline polymers containing di-substituted cyanostilbene groups with the different number of alkyl tail chain

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00889H, Paper
Juan Luo, Juan Wang, Junde Zhang, Huizi Cao, Xiaofang Chen
In this work, side-chain luminescent liquid crystalline polymers (SCLLCPs) that contain di-substituted cyanostilbene (CS) groups with the different substituted number of terminal alkyl chain, which are PNB-Z-4, PNB-Z-34, and PNB-Z-345,...
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Reducing Agent Triggered Templated Synthesis of Dynamic Covalent Poly(disulfide)s Nanonetwork: Remarkable Tuning in Noncovalent Encapsulation Stabilities and Cargo Release

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY01109K, Paper
Arun Mondal, S. K. Sujauddin, Dhiman Mondal, Soumya Kolay, Shuvajyoti Sarkar, Mijanur Rahaman Molla
Here, we demonstrated a new methodology for the templated synthesis of cross-linked poly(disulfide)s based dynamic covalent nanonetwork as highly stable potential delivery vehicle in the field of chemotherapeutic applications. The...
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Axial-phenyl Constrained Bis(imino)acenaphthene-Nickel Precatalysts Enhancing Ethylene Polymerization

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY01110D, Paper
Quanchao Wang, Qiuyue Zhang, Yizhou Wang, Song Zou, Yanping Ma, Tongling Liang, Wen Hua Sun
To enhance the performance of the bis(imino)acenaphthene-nickel precatalyst, the axial phenyl group is introduced on the acenaphthenyl backbone forming five analogues, bis(aryl)imino-5-phenylacenaphthene nickel bromides (aryl: 2,6-dimethylphenyl, Ni1; 2,6-diethylphenyl, Ni2; 2,6-diisopropylphenyl,...
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Single-ion quasi-solid-state electrolytes based on sulfonimide-functionalized covalent organic framework

Polym. Chem., 2024, 15,4529-4541
DOI: 10.1039/D4PY00352G, Paper
Haomin Wu, Wencan Ma, Xin Huang, Yifeng Cai, Junheng Li, Qiaobo Liao, Kai Xi, Qiuhong Zhang, Xudong Jia
The COF based SIQSSEs with a high ionic conductivity of 4.3 × 10−4 S cm−1, a high LTN of 0.90. A high initial capacity (150.3 mA h g−1), high retention (99% after 100 cycles), good cycling stability and rate performance in Li/LFP battery test.
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Catalytic copolymerization of carbon dioxide and cyclohexene oxide by a trinuclear cyclohexane-bridged tetradentate Schiff base chromium complex

Polym. Chem., 2024, 15,4519-4528
DOI: 10.1039/D4PY00956H, Paper
Jie Huang, Boxiong Shen
The development of catalytic systems is a central area of research in carbon dioxide (CO2) and epoxy copolymerization.
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Interpretable machining learning assisted insights into bifunctional squaramide catalyzed ring-opening polymerization of lactide

Polym. Chem., 2024, 15,4562-4569
DOI: 10.1039/D4PY00866A, Paper
Shaoju Cao, Mengting Hong, Junyuan Hu, Zhenjiang Li, Jin Huang, Kai Guo
A bifunctional squaramide catalyst with tunable activity enables the controlled ring-opening polymerization of lactide. Combining bench experiments and interpretable machine learning offer insights into catalyst structures, promoting catalyst design.
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Polymer chemistry informed neural networks (PCINNs) for data-driven modelling of polymerization processes

Polym. Chem., 2024, 15,4580-4590
DOI: 10.1039/D4PY00995A, Paper
Nicholas Ballard, Jon Larrañaga, Kiarash Farajzadehahary, José M. Asua
A method for training neural networks to predict the outcome of polymerization processes is described that incorporates fundamental chemical knowledge. This permits generation of data-driven predictive models with limited datasets.
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Composition-dependent emission colors for biomass-based main-chain luminescent liquid crystalline copolyesters with excellent tensile properties

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00946K, Paper
Wei Wang, Jing Wang, Wenting Li, Guangjian Liao, Yuan Qiu, Guochuan Yin, Yonggui Liao, Xiaolin Xie
The emission colors of high-performance MCLCPs with biomass-based bifuran and AIE-active cyanostilbene units can be tuned by the composition from blue to cyan, and then to green. Upon UV exposure, the thin film can undergo an emission color change.
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Structure, humidity adaptivity, and elasticity of hydrogen-bonded complexes formed by self-assembly of a triblock copolymer and a homopolymer

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00959B, Paper
Weijie Wang, Hanxin Jian, Hao Huang, Fengfeng Feng, Qingye Meng, Yuli Li, Gang Chen, Shuguang Yang
The tri-block copolymer polystyrene-b-poly(ethylene oxide)-b-polystyrene (SES) and the homopolymer poly(acrylic acid) (PAA) were applied to fabricate elastomers with multi-hierarchical architectures.
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Dibenzobarrelene-Derived Pd-NHCs: Efficient Precatalysts for the Suzuki-Miyaura Polycondensations of Dichloroarenes Monomers

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY01026D, Paper
Yuman Guo, Hao Wu, Meng-Jiao Zhang, Feng-Shou Liu
The Pd-catalyzed Suzuki-Miyaura polycondensations (SMPs) has emerged as a powerful method for synthesizing conjugated polymers (CPs). While numerous reports have utilized dibromoarene and diiodoarene derivatives as monomers, research on the...
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ROS/pH dual-responsive quercetin-loaded guanosine borate supramolecular hydrogel enema in dextran sulfate sodium-induced colitis in mice

J. Mater. Chem. B, 2024, 12,10861-10876
DOI: 10.1039/D4TB01659A, Paper
Luqing Zhao, Dan Dou, Di Zhang, Xin Deng, Ning Ding, Yun Ma, Xingyu Ji, Shengsheng Zhang, Chao Li
GBQ hydrogel enema for treating DSS-induced colitis in mice.
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mi

Development of substrate-independent heparin coating to mitigate surface-induced thrombogenesis: efficacy and mechanism

J. Mater. Chem. B, 2024, 12,10994-11011
DOI: 10.1039/D4TB01779J, Paper
Shengjun Cheng, Haifeng Ji, Tao Xu, Xianda Liu, Lin Xu, Weifeng Zhao, Changsheng Zhao
A facile and substrate independent heparin-based coating was developed in this study. And the associated anticoagulant mechanism of this coating was clarified.
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Mercaptoimidazole-capped gold nanoparticles as a potent agent against plant pathogenic fungi

J. Mater. Chem. B, 2024, 12,10949-10961
DOI: 10.1039/D4TB01032A, Paper
Open Access
Tang Xu, Wenshuai Hao, Ran Du, Dai Dai, Cuixia Wang, Suhua Li, Carol Sze Ki Lin, Ruitao Cha, Jianbin Yan, Chong Li
The first evidence that MI-Au NPs prevent plants from fungal infection is presented.
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High-temperature emulsification coupled with low-temperature gelation for fabrication of agarose microsphere implants with well-controlled size for skin tissue enhancement

J. Mater. Chem. B, 2024, 12,10983-10993
DOI: 10.1039/D4TB01564A, Paper
Qi Wang, Huiyu Yan, Ying Guo, Bei Tian, Jianxi Xiao
Agarose offers self-gelation, biodegradability, and biocompatibility. We have developed a high-temperature emulsification followed by low-temperature gelation method to create agarose microsphere implants for skin tissue augmentation.
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An in situ-activated and chemi-excited photooxygenation system based on G-poly(thioacetal) for Aβ1–42 aggregates

J. Mater. Chem. B, 2024, 12,10850-10860
DOI: 10.1039/D4TB01147C, Communication
Shasha Liu, Yanping Li, Jinrong Yang, Lei Zhang, Jinwu Yan
BD-6-QM/NPs are chemically activated by H2O2 to produce 1O2, inhibit Aβ1–42 aggregation, promote BV2 phagocytosis of Aβ1–42, and alleviate Aβ1–42-induced neurotoxicity.
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Mitigating intubation stress, mucosa injury, and inflammatory response in nasogastric tube intubation via suppression of the NF-κB signaling pathway by engineering a hydration lubrication coating

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01171F, Paper
Xi Liao, Meng-Han Bai, Yu-Wei Liu, Yu-Qing Wei, Jun-Yang Wang, Zhi-Guo Wang, Rui Hong, Ju-Xiang Gou, Jia-Zhuang Xu, Zhong-Ming Li, Ka Li
The hydrated micelle coating, composed of hyaluronic acid and Pluronic, demonstrated superior hydrophilicity and aqueous lubricity to effectively alleviate mucosal lesions and inflammation caused by NGT insertion.
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