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Structural constraint at a P–P bond: phosphinophosphination of alkenes, alkynes, and carbonyls by a concerted mechanism

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06581F, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lijun You, Daniel Roth, Lutz Greb
A structural constraint approach at a P–P bond is presented that enables the phosphinophosphination of alkynes, alkenes, and carbonyls with high regio- and diastereoselectivity. The apolar nature of the P–P bond facilitates a concerted mechanism.
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Deep Learning Enabled Ultra-high Quality NMR Chemical Shift Resolved Spectra

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC04742G, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zhengxian Yang, Weigang Cai, Wen Zhu, Xiaoxu Zheng, Xiaoqi Shi, Mengjie Qiu, Zhong Chen, Maili Liu, Yanqin Lin
High quality chemical shift resolved spectra have long been pursued in nuclear magnetic resonance (NMR). In order to obtain chemical shift information with high resolution and sensitivity, a neural network...
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Tailoring Hierarchical MnO2 Nanostructures on Self-Supporting Cathodes for High-Mass-Loading Zinc-Ion Batteries

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06182A, Edge Article
Open Access
Weijie Zheng, Zhibiao Cui, Cong Liu, Libei Yuan, Shengsong Li, Lilin Lin, Tao Meng, Liangui Yang, Yexiang Tong, Dong Shu
Aqueous zinc-ion batteries (AZIBs) with MnO2 cathodes have promising application prospects, however, their performance is hindered by their low efficiency and insufficient life. By leveraging the nanomicellar properties of cetyltrimethylammonium...
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An interactive dual energy storage mechanism boosts high-performance aqueous zinc-ion batteries

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05710D, Edge Article
Open Access
Shengen Gong, Meihua Zhu, Yan Zhou, Runan Li, Jianhua Zhang, Xiaoteng Jia, Danming Chao, Caiyun Wang
A conductive polymer cathode with high redox potential is realized by pre-doping Mn2+ into PANI, which demonstrates an interactive dual energy storage mechanism of reversible doping of multiple cations and dissolution–deposition of Mn2+.
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Morphology of Lithium Halides in Tetrahydrofuran from Molecular Dynamics with Machine Learning Potentials

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC04957H, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Marinella de Giovanetti, Sondre H. Hopen Eliasson, Sigbjørn L. Bore, Odile Eisenstein, Michele Cascella
The preferred structures of lithium halides (LiX, with X = Cl, Br, I) in organic solvents have been the subject of a wide scientific debate, and a large variety of...
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Rare-earth metal complexes bearing electrophilic and nucleophilic carbon centres and their unique reactivity patterns towards pyridine derivatives

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC04197F, Edge Article
Open Access
weikang Wu, Thayalan Rajeshkumar, Shan Zhu, Fuxiang Chai, Dongjing Hong, ZeMing Huang, Qingbing Yuan, Laurent Maron, Shaowu Wang
The rare-earth metal dialkyl complexes (κ2-L1)RE(CH2SiMe3)2(THF)2 [RE = Lu(1a), Yb(1b), Er(1c), Y(1d), Dy(1e)] (L1 = 1-(2-N-C5H10NCH2CH2)-3-(2,6-iPr2C6H3N=CH)-C8H4N) and the rare-earth metal monoalkyl complexes (κ2-L1)2RE(CH2SiMe3)(THF)n [n = 0, RE = Lu(2a), Yb(2b);...
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‘I’d like to think that one day I’ll be Chinese’

Committed Sinophile and one of the debut filmmakers at MAMI this year, Jordan Schiele is alsoan enthusiastic Mumbaikar discovers Satya Kandala




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Crushing on candy

Witness the theatrics of customised sweet-making at the city’s newest confectionery store




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Curating history through cinema

The New Medium, which debuted at MAMI, showcased a history of the moving picture and its formal innovation




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A khadi way of thinking

Fashion designer returns to her first love khadi for her new festive collection titled Vichar Vastra




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Standing apart: Shivam Pradhan




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Shape-shifting with dance

Sanjukta Sinha dwells on belonging and relationships in Kin , her new contemporary Kathak production




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A highly recommended underdog

Thrilling gameplay and beautiful visuals make Titanfall2 a worthy purchase




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History explained

In India Conquered , English historian Jon Wilson demystifies the British rule in India




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Dear Zindagi music: Déjà vu with a hint of new

Amit Trivedi returns as a composer for the new Gauri Shinde film with a bunch of feel-good tracks




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Abhishek Bachchan has ten million followers on Twitter




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Accepting queer children

A new anthology of stories, translated from Marathi, is about ordinary folks coming to terms with the queer sexuality of their children and siblings




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I never do anything that I don’t enjoy: Ruskin Bond

The celebrated author chats about his latest work, how everything inspires him and why his books always have such a visual element to them




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This struggle is real

In Andheri, eight performers play up-and-coming actors reflecting the ruthlessness of getting into Hindi cinema




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Why this balanced advantage fund is a useful addition amidst rough markets

ICICI Prudential Balanced Advantage juggles stocks, bonds and derivatives smartly for optimal returns




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Share Market Highlights 18 April 2024: Sensex falls 330 pts, Nifty at 22,000; media, metal stocks shine, FMCG, healthcare drag

Sensex, Nifty updates on 18th April 2024: Equity benchmarks BSE Sensex and NSE Nifty extended losses on Thursday. As per provisional figures, BSE Sensex fell 332.23 pts or 0.46 per cent to trade at 72,611.45 as of 3.35 pm and Nifty 50 declined 103.70 pts or 0.47 per cent to trade at 22,044.20., Bharti Airtel, Power Grid Corp, M&M, BPCL, and Tata Steel were the top gainers, while Nestle, Apollo Hospitals, Axis Bank, HCL Technologies, and ONGC were the major laggards. The stocks that hit a 52-week high on the NSE include AAA Tech (19.33 per cent), Just Dial (12.95 per cent), Indo Tech (10 per cent) and Hi-Tech Gear (10 per cent).




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Why this conservative hybrid fund makes sense amidst market volatility

Aditya Birla Sun Life Regular Savings has been a consistent outperformer while keeping risks at bay




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In debt funds, the focus is on high-quality credit strategies: Rahul Goswami, CIO-India Fixed Income, Franklin Templeton Mutual Fund

Rahul Goswami, CIO &MD - India Fixed Income, Franklin Templeton Asset Management, on what investors can expect on the debt side from the AMC and on his rate cut expectations




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Why this equity savings fund is well-suited for volatile markets

HDFC Equity Savings fund delivers robust risk-adjusted returns by juggling stocks, bonds and derivatives




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Markets correlate with economic performance, not political dispensation: Ashish Somaiyaa, CEO, WhiteOak Capital AMC

Ashish Somaiyaa, CEO, WhiteOak Capital AMC, on the impact of elections on the market and more




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Why this dividend yield fund may suit investors seeking lower volatility

Since its inception in December 2020, HDFC Dividend Yield fund has outperformed the broader markets convincingly




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Why this consumption thematic fund is an attractive investment now

Nippon India Consumption fund has been a consistent outperformer across market cycles




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Why this consistent ultra short-term fund is a worthy debt investment

ICICI Prudential Ultra Short-Term fund can make the most of persistently high short-term interest rates




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Why this fund is a good option for investors wanting to play the consumption theme

Performance, portfolio composition and downside protection are three reasons that work for Mirae Asset Great Consumer Fund




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At ₹40,608 crore, MFs asset and equity inflows hit a new high in June

Industry AUM crosses ₹60 lakh-crore on new fund offers, mark-to-market gain




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SBI Contra fund: Why this long-term outperformer is a worthy investment

A multi-cap and contrarian approach helps the fund figure among the best across equity categories




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Snatching value back from a fire

When you suddenly cannot afford to continue paying the premiums on a life policy, you may still be able to protect value. A new measure from IRDAI helps you in this quest 




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Why this value fund may be a good investment for the long term

Nippon India Value has consistently outperformed its benchmark and delivered optimal risk-adjusted returns




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This new passive fund tracks the tourism theme: Should you invest?

Kotak Nifty India Tourism Index fund will invest in airlines, airport operators, hotels, restaurants and travel portals




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Why this focused fund can be a worthy investment in heated markets

Mahindra Manulife Focused fund is large-cap heavy and takes moderate risks in its portfolio




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This value fund has just completed 20 years: Should you invest?

As benchmarks rise and broader markets correct, a portfolio anchored in strong value-based stock-selection criteria may work well for investors




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Amid volatile markets, this dividend yield fund is a smart investment

With geopolitical tensions, US elections and crude prices weighing on sentiments, it may be a good time to take the safer option of dividend yield investing




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Why this large cap fund is a suitable investment in current volatile market

Canara Robeco Blue Chip Equity has consistently beaten the benchmark and delivered above-average performance




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Why investing in this large-cap fund can be rewarding in choppy markets

Kotak Bluechip is a steady outperformer and suits investors, with a medium risk appetite, saving for long-term goals




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Demographic dividend to demographic disaster

Raising the retirement age seems to be an invitation for demographic disaster.




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PM Modi a 'demanding' boss, have to be 'fully prepared' to hold discussions with him: EAM Jaishankar




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Justice Sanjiv Khanna sworn in as 51st Chief Justice of India




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Chinmaya Mission takes up growing challenges of mental health




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'Namo buddhaya': Kiren Rijiju expresses gratitude on visit to Buddha memorial in Maharashtra's Nashik




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Mass Historia Reviewed by Monsters & Critics

Book Review: Mass Historia
Fiction Book Reviews

Emmy award winning comedy writer Chris Regan has turned his considerable talents to past events and come out with a winner in this uproarious look at 365 days in history. Embellishing facts with liberal doses of light humor, history has never been more entertaining as demonstrated by the January 4 entry celebrating Utah’s statehood that explains how Utah became the forty-fifth state which coincidentally, was the average number of wives enjoyed by most Utah men at the time. Then learn about the army suppression of an uprising of a hoard of Donnie Osmond groupies and the five top Mormon fun facts.

Even better, on June 24, 1997 the U.S. Air Force released their final report on the Roswell incident, a 231-page tome that would prove to be light reading for those who can polish off 251 pages of a Dune novel while awaiting a Star Trek rerun. Or how about the November 15, 1887 entry highlighting the birth of Georgia O’Keeffe with the notation, “After being born, the baby looks up at where she came from, and gets her first-and last-idea for a painting.”

Chock full of fun “facts”, sidebars and irreverently captioned pictures, this is not history as we learned it in school, thank goodness! Regan’s view of history is smart, pointed, frequently not PC but always entertaining. Think History Channel crossed with equal portions South Park and Robot Chicken and you get the general idea.

http://www.monstersandcritics.com/books/fiction/reviews/article_1441330.php/Book_Review_Mass_Historia




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President Obama Reviewed by Philadephia Inquirer

The Philadelphia Inquirer’s review of President Obama Election 2008: A Collection of Newspaper Front Pages Selected by the Poynter Institute on Sunday (1/19/09) includes the following:

Everyone should probably grab one as a momento, but for sheer fun, the best of the commemoratives is President Obama/Election 2008: A Collection of Newspaper Front Pages from the Poynter Institute (Andrews McMeel). It gathers dull headlines (“Historic Victory”), witty ones (the Tulsa World’s, “Yes He Did”), and lovingly local riffs (The Jakarta Post’s “Barry’s Done It!”).


President Obama
(ISBN-13: 978-0-7407-8480-4)




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Towards real-time myocardial infarction diagnosis: a convergence of machine learning and ion-exchange membrane technologies leveraging miRNA signatures

Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00640B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xiang Ren, Ruyu Zhou, George Ronan, S. Gulberk Ozcebe, Jiaying Ji, Satyajyoti Senapati, Keith L. March, Eileen Handberg, David Anderson, Carl J. Pepine, Hsueh-Chia Chang, Fang Liu, Pinar Zorlutuna
Rapid diagnosis of acute myocardial infarction (AMI) is crucial for optimal patient management.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Microfluidic antisolvent crystallization for chiral symmetry breaking

Lab Chip, 2024, 24,5055-5064
DOI: 10.1039/D4LC00658E, Paper
Jiye Jang, Gerard Coquerel, Tae Seok Seo, Woo-Sik Kim, Bum Jun Park
Microfluidic antisolvent crystallization was used to study the effect of solution volume on chiral symmetry breaking (CSB) in NaClO3 crystals. 100% CSB occurs below a critical emulsion volume due to rapid molecule depletion and suppressed nucleation.
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Exploring cancer-associated fibroblast-induced resistance to tyrosine kinase inhibitors in hepatoma cells using a liver-on-a-chip model

Lab Chip, 2024, 24,5043-5054
DOI: 10.1039/D4LC00624K, Paper
Madhu Shree Poddar, Yu-De Chu, Gaurav Pendharkar, Cheng-Hsien Liu, Chau-Ting Yeh
3D liver-on-a-chip reveals AHSG and CLEC3B to mediate cancer-associated fibroblast-induced resistance to TKIs in hepatoma cells.
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Rapid low-cost assembly of modular microvessel-on-a-chip with benchtop xurography

Lab Chip, 2024, 24,5065-5076
DOI: 10.1039/D4LC00565A, Paper
Open Access
Shashwat S. Agarwal, Marcos Cortes-Medina, Jacob C. Holter, Alex Avendano, Joseph W. Tinapple, Joseph M. Barlage, Miles M. Menyhert, Lotanna M. Onua, Jonathan W. Song
Our study is a novel implementation of xurography for multi-layer microfluidic device fabrication. We demonstrate the versatility of this approach by presenting several modular 3D vessel-matrix arrangements.
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