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un Advances, opportunities, and challenges in methods for interrogating the structure activity relationships of natural products By pubs.rsc.org Published On :: Nat. Prod. Rep., 2024, 41,1543-1578DOI: 10.1039/D4NP00009A, Review Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Christine Mae F. Ancajas, Abiodun S. Oyedele, Caitlin M. Butt, Allison S. WalkerThis review highlights methods for studying structure activity relationships of natural products and proposes that these methods are complementary and could be used to build an iterative computational-experimental workflow.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
un The dichapetalins and dichapetalin-type compounds: structural diversity, bioactivity, and future research perspectives By pubs.rsc.org Published On :: Nat. Prod. Rep., 2024, 41,1579-1603DOI: 10.1039/D3NP00039G, Review ArticleIvan Addae-Mensah, Godwin Akpeko Dziwornu, Mary Anti Chama, Dorcas Osei-SafoThis review discusses the structural diversity of the dichapetalins and related compounds from the genera Dichapetalum and Phyllanthus, their manifestation in the diversity of their biological activities, and areas of potential future research.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
un Volatile organic compounds (VOCs) in terrestrial extreme environments: implications for life detection beyond Earth By pubs.rsc.org Published On :: Nat. Prod. Rep., 2024, Advance ArticleDOI: 10.1039/D4NP00037D, Review Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Claire A. Batty, Victoria K. Pearson, Karen Olsson-Francis, Geraint MorganThis review highlights how discovering and analysing VOCs in extreme environments on Earth can help identify biosignatures and unravel complex patterns in metabolic data that could help identify life on other planetary bodies.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
un Small animals with unique chemistry – the natural product chemistry of Collembola By pubs.rsc.org Published On :: Nat. Prod. Rep., 2024, Advance ArticleDOI: 10.1039/D4NP00049H, Highlight Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Anton Möllerke, Stefan SchulzThe secondary metabolites of springtails (Collembola) include defensive compounds, cuticular lipids, and semiochemicals, many of which are not known from other natural sources. The springtail chemistry differs largely from that of insects.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
un Carbon dots induce abundant oxygen vacancies in CeVO4 for promoting photocatalytic selective hydrogenation of functionalized nitroarenes By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2128-2135DOI: 10.1039/D4QI00002A, Research ArticleErnan Pang, Shijia Li, Jie Wu, Qing Chang, Ning Li, Jinlong Yang, Shengliang HuCarbon dots create the appropriate oxygen vacancies (OVs) in CeVO4 for the chemoselective hydrogenation of functionalized nitroarenes under light irradiation.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
un Gelation-induced controlled synthesis of TiO2 with tunable phase transition for efficient photocatalytic hydrogen evolution By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2178-2186DOI: 10.1039/D4QI00193A, Research ArticleWenwei Lei, Ying Wang, Hongji Wang, Norihiro Suzuki, Chiaki Terashima, Akira FujishimaA facile gelation-assisted coordination self-assembly method for mediated fabrication of TiO2 photocatalysts with controlled phase structures and morphologies is presented, showing excellent photocatalytic hydrogen production performance.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
un Electron-deficient Co modulated by the construction of heterojunctions Co@NC boosts the electroreduction of nitrate to ammonia By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2144-2151DOI: 10.1039/D4QI00110A, Research ArticleBo Zhang, Fengshou Yu, Yaohua Hong, Yuzhuo Zhou, Yaheng Wang, Shaobo Zhang, Lu-Hua ZhangFormation of electron-deficient Co by the construction of heterojunctions to promote the electroreduction of nitrate to ammonia.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
un Structural isomerism-tuned magnetisation relaxation dynamics in lanthanide coordination complexes By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2116-2127DOI: 10.1039/D4QI00161C, Research ArticleSteen H. Hansen, Christian D. Buch, Stergios PiligkosControl of the composition of molecular magnetic materials by chemical modification leads to tuning of their magnetization dynamics. We show that two structural isomers display such differences with respect to each other and to their parent complex.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
un Combination of dimensional reduction and active site addition strategies for preparing unique {RE9}-cluster-based MOFs: efficient CO2 fixation and Knoevenagel condensation By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2071-2080DOI: 10.1039/D3QI02527F, Research ArticleYing Zhao, Dan Wu, Yidan Qiao, Guo-Ping Yang, Lu-Fang Ma, Yao-Yu WangA series of 2D {RE9}-cluster-based rare-earth MOFs were built by dimensional reduction and active site addition strategies. They exhibit excellent catalytic activity in CO2 fixation and Knoevenagel condensation under mild conditions.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
un Reasonable regulation of flexible sulfur-based bifunctional catalytic electrodes for efficient seawater splitting By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2152-2163DOI: 10.1039/D3QI02575F, Research ArticleFengjing Lei, Xunwei Ma, Xinyun Shao, Ziyan Fang, Yuqin Wang, Weiju HaoAn iron-regulated three-dimensional nano-conical, economical, and flexible Fe-NiS@HA electrode exhibiting high intrinsic activity is prepared by gentle one-step electroless plating for efficient, durable hydrogen production in alkaline seawater.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
un Tailoring two magic number Au13 nanoclusters with N-containing diphosphine ligands: a classical icosahedral core vs. an unprecedented UFO- shaped core By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00334A, Research ArticleJing Liu, Jia-Chuan Liu, Hai-Ling Wang, Pei-Yu Liao, Jian-Hua Jia, Ming-Liang TongTwo magic number Au13 nanoclusters were tailored using two N-containing multidentate phosphine ligands with a classical icosahedral core and an unprecedented “UFO”-shaped polyhedral core, respectively.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
un Modulating Mn self-reduction and multimodal luminescence in CaSb2O6 through La3+ doping for quadruple-mode dynamic anti-counterfeiting and optical temperature sensing applications By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00493K, Research ArticleFenzhong Long, Lu Xie, Jiawei Fu, Kaian Shan, Huihui Fei, Xinmin ZhangThe co-doping La3+strategy was employed to modulate Mn self-reduction and multimodal luminescence in CaS2O6:Mn. CaS2O6:Mn has potential application in optical anti-counterfeiting and high-sensitivity temperature sensing applications.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
un An unusual reaction in nitromethane solution: use of the Cp*Rh moiety to form Prussian blue analogues By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00343H, Research ArticleHuirong Ma, Liangchen Liu, Yuluan Liao, Huatian Shi, Po Sun, Weibin YuThe direct decomposition of nitromethane into nitrile compounds is a significant challenge due to the occurrence of severe side-reactions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
un Yellow-Emissive Organic Copper(I) Halide Single Crystals with [Cu4I4] Cubane Unit as Efficient X-ray Scintillators By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QI00500G, Research ArticleQingzheng Kong, Xiaomei Jiang, Ying Sun, Jianguo Zhu, Xutang TaoRecently, low-dimensional copper(I)-based halide is considered as a potential substitute for lead-based counterpart due to its environmental friendliness, facile preparation and superior luminescence performances. In particular, as a representative of...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
un Hysteretic magnetism–dielectricity switching in 2D Hofmann type spin-crossover compounds By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D3QI02660D, Research ArticleNian-Tao Yao, Meng-Jia Shang, Han-Han Lu, Qiang Liu, Wen Wen, Shi-Hui Zhang, Liang Zhao, Hiroki Oshio, Yin-Shan Meng, Tao LiuTwo 2D Hofmann type compounds {Fe(3,4-bpt)2[M(CN)4]} were synthesized. They showed reversible switching in magnetism, dielectricity, and thermochromism actuated by the spin transition of Fe(II).To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
un Solvent-modulated assembly of peptide and cerium functionalized gigantic {Mo120Ce6}2 dimers for high-efficiency photocatalytic oxidation By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2355-2364DOI: 10.1039/D4QI00339J, Research ArticleDexiang Zhou, Bingbing Li, Qixin Zhao, Xinyu Tang, Tingya Lan, Heyang Su, Guoping Yang, Weimin XuanTwo gigantic peptide and cerium functionalized {Mo120Ce6}2 dimers have been constructed via a solvent-modulated assembly and applied for effective photocatalytic aerobic oxidation of sulfides to sulfoxides.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
un Understanding the synthesis mechanism, chemical structures and optical properties of aromatic carbon nitride By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2346-2354DOI: 10.1039/D4QI00355A, Research ArticleYunhu Wang, Fangxu Dai, Yafei Tao, Kai Zhang, Bingjie Li, Mingming Zhang, Kang Liu, Jixiang Xu, Lei Wang, Jun XingThe chemical structures and optical properties of aromatic carbon nitride and intermediates have been systematically studied; hereby the detailed synthesis mechanism of aromatic carbon nitride is explicitly proposed.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
un Boosting structural variety and catalytic activity of porphyrinic metal–organic frameworks by harnessing bifunctional ligands By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2281-2289DOI: 10.1039/D4QI00314D, Research ArticleWei Wu, Xiu-Liang Lv, Tao He, Guang-Rui Si, Hongliang Huang, Lin-Hua Xie, Yabo Xie, Jian-Rong LiHigh catalytic performance of porphyrin-based MOFs has been achieved by introducing multiple functionality into their ligands and modulating their conformation.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
un Achieving a near-unity photoluminescence quantum yield and high stability of CsPbI3 nanoplatelets by hydroiodic acid-assisted ligand treatment By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2392-2401DOI: 10.1039/D4QI00168K, Research ArticleZongnan Li, Yusheng Song, Sheng Cao, Ke Xing, Zhentao Du, Bingsuo Zou, Jialong ZhaoWe demonstrate a near-unity photoluminescence quantum yield and high stability of CsPbI3 nanoplatelets achieved through a hydroiodic acid-assisted ligand treatment strategy, showcasing their application in perovskite LEDs.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
