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Selective syntheses of homoleptic Ir(III) complexes bearing di-CF3-functionalized benzoimidazol-2-ylidenes for generation of blue phosphorescence

Inorg. Chem. Front., 2024, 11,2413-2426
DOI: 10.1039/D4QI00454J, Research Article
Open Access
Jie Yan, Yi Pan, I-Che Peng, Wen-Yi Hung, Bingjie Hu, Guowei Ni, Shek-Man Yiu, Yun Chi, Kai Chung Lau
Di-CF3-functionalized benzo[d]imidazol-3-ium pro-chelates were employed in the selective syntheses of fac-coordinated Ir(III) carbene emitters for efficient blue electroluminescence and hyperphosphorescence.
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Ultrathin 2D–2D NiFe LDH/MOF heterojunction nanosheets: an efficient oxygen evolution reaction catalyst for water oxidation

Inorg. Chem. Front., 2024, 11,2489-2497
DOI: 10.1039/D4QI00090K, Research Article
Haoran Yin, Shibiao Su, Di Yao, Lixia Wang, Xinqiang Liu, Tayirjan Taylor Isimjan, Xiulin Yang, Dandan Cai
An ultrathin NiFe LDH/MOF catalyst is grown on carbon paper by an in situ self-dissociation–assembly strategy. Studies reveal that the strong electronic interaction between Fe and Ni species with rich active sites results in good OER and OWS performance.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Electrochemical conversion of 5-hydroxymethylfurfural over CuNi bimetallic catalysts: the synergistic effect of interfacial active sites

Inorg. Chem. Front., 2024, 11,2479-2488
DOI: 10.1039/D4QI00145A, Research Article
Yiwei Zhao, Chao Zhang, Shuangxi Xing, Zuhang Jin, Tingting Xiao
ECO of HMF to FDCA and ECR to BHMF with high yield have been studied on CuNi-based bimetallic catalysts. The presence of the Cu–O–Ni interfacial area was beneficial for promoting the catalytic performance in ECO.
The content of this RSS Feed (c) The Royal Society of Chemistry




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CDs "inserted" abundant FeB based electrode via "local photothermal effect" strategy toward efficient overall seawater splitting

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00415A, Research Article
Shiheng Liang, Liugang Wu, Yiming Wang, Yuqi Shao, Hongyuan Song, Ziliang Chen, Weiju Hao
Construction of high-efficiency, long-stable catalytic electrodes for hydrogen by seawater splitting is a huge challenge in the field of green hydrogen. Herein, a matrix-type titanium dioxide nanorod (Ti/TiO2) is constructed...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Disruption of lipid metabolism to induce ferroptosis using multifunctional fibrate-Pt(IV) prodrugs for cancer treatment

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00386A, Research Article
Peng Sun, Jia-Qian Wang, Qiang Xie, Xuan-Lin Ren, Xin Qiao, Jing-Yuan Xu
Two multifunctional fibrate-Pt(IV) prodrugs, 1 and 3, bearing lipid-modulating agents, exhibited impressive anticancer activity by triggering ferroptosis and apoptosis.
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Enhanced photocatalytic CO2 reduction by controlled oxygen vacancy generation and co-constructed heterojunction strategy for Pd/CeO2

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00581C, Research Article
Fanlin Kong, Xiaoyan Lu, Jing Xie, Zhenjiang Lu, Jindou Hu, Yali Cao
Rational control of Vo concentration and the construction of a heterojunction strategy enable Pd/CeO2-Vo(r) to exhibit excellent photocatalytic CO2RR activity. The presence of COOHcreates favorable conditions for CO formation and desorption.
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An unprecedented {Y2 ⊂ Y10} type disk-like Y12 nanocluster featuring electroluminescence property in OLED device

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00635F, Research Article
Lin-Ping Shi, Wen-Liang Li, Pu-Yue Wang, Xiaoming Wu, Zhao-Quan Yao, Jiong-Peng Zhao, Fuchen Liu
Although great efforts have been made in exploring the exquisite rare-earth (RE) clusters, the design and construction of planar RE-clusters with disk-like geometrical features are still scarce. Herein, a novel...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Yolk-Shell type Carbon-Silica Nanoarchitecture Dispersed and Stabilized Ru Nanoparticles for Enhanced Hydrogenation of Aromatic Compounds

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00553H, Research Article
Lu Yan, Yue Shen, Zidan Zou, Xiao Zhang, Zhixin Yu, Guozhong Wang, Chun Chen
Hydrogenation of aromatic rings can be used not only for synthesis fine chemicals, but also for hydrogen storage and transportation using organic hydride. In this paper, yolk-shell structural SiO2@Ru@NC catalyst,...
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Unleashing the power of directed electron transfer: unraveling the potential of {PV4}2 in heterogeneous photocatalysis

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00606B, Research Article
Xin Su, Yuzan He, Kunhong Li, Miao Wang, Wei Tang, Shihao Zhang, Pengtao Ma, Jingyang Niu, Jingping Wang
{PV4}2 unleash the power of directed electron transfer in heterogeneous photocatalysis reduction.
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Solar heating catalytic formic acid dehydrogenation by graphene-porous foam-supported tungsten nitride nanoparticles

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00590B, Research Article
Jiarong Chang, Tianhua Hao, Cuncai Lv, Maoyu Xu, Deyi Zhang, Linjie Gao, Shangbo Ning, Yaguang Li, Jinhua Ye
WN/Gr PF exhibits significant solar heating catalytic formic acid dehydrogenation and the rate exceeds those of other reported photocatalysts.
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Tuning lithium–yttrium chloride local structure through coordination control and mixing during synthesis

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00559G, Research Article
Open Access
Teerth Brahmbhatt, Cheng Li, Mounesha N. Garaga, Wan-Yu Tsai, Steve G. Greenbaum, Jagjit Nanda, Robert L. Sacci
Synthesis of Li3YCl6 is facilitated by the addition of NH4Cl. Synthesis method affects local ordering and Li+ dynamics as determined by neutron diffraction, impedance and NMR spectroscopy.
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ICRIER study explores untapped potential of India’s turmeric sector

Offers roadmap as the country dominates the global market with 70% market share




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AgCare Tech launches digital marketplace for agri inputs

‘Golden Farms’ is designed to digitise the agricultural input supply chain




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Crude oil futures rebound after Tuesday’s fall

Uncertainties over the developments in West Asia helped boost the price of the commodity




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Zinc futures may bounce off ₹275

Traders can buy on a dip and look for a target of ₹290 




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SEBI panel mulls new category of commodity funds

MF investment in ETCDs is estimated to be under ₹10,000 crore




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Row over ISMA’s suggestion to regulate khandsari units

Opposing curbs, traditional sweeteners body BHAKTI says Centre should not be swayed by false narratives




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MCX launches cottonseed wash oil futures contract

It will offer a robust price risk management solutions for the cottonseed oil industry




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MCX to launch monthly gold option contract

MCX reduces gold option expiry to monthly, improving liquidity and attracting more participants, benefiting jewellers and increasing revenue




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Global steel demand to drop a tad in 2024, rebound in 2025: worldsteel

Ongoing weakness in housing construction, driven by tight financing conditions and high costs, cited as reason for the fall in demand




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SEA survey estimates 27% increase in Gujarat groundnut production this season

Good rains this year and the increase in acreage might help Gujarat achieve a record groundnut production of 42.19 lakh tonnes this year, surpassing the previous record of 38.55 lakh tonnes set in 2021-22




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Crude check: Outlook is uncertain

Traders can stay out for now




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Nickel prices likely to be under pressure on market surplus

Analysts peg its average price for 2024 at around $17,000/tonne




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Storage in key Indian reservoirs unchanged for 3rd week in a row

They are higher than normal, filled to 87 per cent of the 180.852 BCM capacity




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Communities lead

The theme on World AIDS Day (December 1) is ‘Let Communities Lead’




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Mountain rides, mindfulness and insightful reading

Start your day with InsuranceDekho CTO Ish Babbar’s morning mindfulness routine: deep breathing, stretching, running & more




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Nutrition, hydration & neighbourhood runs

Marathoner shares 20-year fitness regime of cardio, strength, and stability, prioritising training and recovery for marathon success




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Immunisation turns 50

The Expanded Programme on Immunization (EPI) — an initiative of the World Health Organization (1974) turns 50 this year




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Counting calories, steps and taking off-road rides

Varun Madan, Founder and CEO, Salad Days, on food, fitness, travel and much more.




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Union Budget: Hopeful of an investment blueprint for healthcare

India’s healthcare sector needs government-private sector partnerships, funding for screening and diagnostics and lower taxes to enhance services




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Funding healthcare: Stable investment in a volatile market

Investors are increasingly focusing on India’s healthcare sector for stable returns, with promising growth and investment opportunities




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Morning run, nutritious meals and unwinding

Prioritise mornings with running, balanced diet, revitalizing workouts and meditation for mental health, says Nishant Pitti, CEO and Co-Founder, EaseMyTrip




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Private capital, a catalyst to Universal Health Coverage

India is committed to achieving Universal Health Coverage (UHC) for all by 2030. For India to achieve thisUHC, it is essential that both private enterprises and the government come together.




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Cricket, cooking and the classics to unwind

Director and CEO of Sahyadri Hospitals on finding joy in cricket, cooking, gym, and movies for relaxation and wellness




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PLI, plugging chinks in the country’s manufacturing armour for drugs and devices

 Call for simplification of licencing regimes gets louder even as benefits become tangible 




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Tennis, yoga and unwinding with a book

Ritesh Kumar’s daily routine includes yoga, a plant-based diet, contemplation, tennis, and unwinding with a good book.




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Mountain hikes, for fitness and zen

Uma R Krishnan, MD, Optum India, on her exercise routine, favourite cuisines and tips to manage stress




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Runing, cycling & a ‘colourful’ meal

Maya Nair, Executive Director of Elixir Consulting, on her fitness regimen, diet and love for table tennis




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Data integrity alarm sounded for CROs, the backbone to pharma industry

USFDA cautions CROs; says such incidents “undermine the reputation of generic industry”




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Reviewing TRIPS, an opportunity for evidence-based policies

Colombia calls for review of TRIPS Agreement implementation, highlighting need for evidence-based IP law and policy




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Lung cancer, in need of local research

Lung cancer in India presents unique challenges, with different patterns, genetics, and treatment options compared to the western world.




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Centre launches mobile app for grievance redressal of rice millers

Move to enchance transparency, accountability




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NSRCEL launches second cohort of Circular Economy programme

Pernod Ricard India Foundation to offer continued support




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Maharashtra cashew board plans to expand area under the crop, promote organic farming

Plans promoting the State’s produce as unique brand, says director Patil




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Storage in India’s key reservoirs unchanged for 4th week in a row

The 155 major reservoirs were filled to 87 per cent of capacity; level in 4 States below normal




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Blue Pearl, a new fish farmer producer company launched in Kodungallur

Highlighting the rapid growth of the fisheries sector, the Minister said the Centre has outlined several schemes dedicated to strengthening the fisheries sector




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Mandi prices indicate higher production in soyabean, groundnut

Production of rice, maize, bajra, ragi may be around last year’s levels




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Marut Dronetech raises $6.2 mn from Lok Capital in Series A funding

Funds to be deployed on developing advanced agri drones, expanding channel partner network and service centres




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Fertiliser shortage hits Kerala’s pineapple farming community 




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Government re-starts sales of rice, atta under ‘Bharat’ brand, raises prices

After flagging off the mobile vans of these cooperatives, carrying the items, Joshi said that the intervention would continue till the allocated stock gets exhausted