an

[ASAP] Transformation of a Norbornadiene Unit to Ethylenylcyclopentene Requiring Cooperation between Boron and Rhodium Centers

Organometallics
DOI: 10.1021/acs.organomet.0c00155




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[ASAP] NHC-Palladium(II) Mononuclear and Binuclear Complexes Containing Phenylene-Bridged Bis(thione) Ligands: Synthesis, Characterization, and Catalytic Activities

Organometallics
DOI: 10.1021/acs.organomet.0c00091




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[ASAP] C–F Bond Activation of a Perfluorinated Ligand Leading to Nucleophilic Fluorination of an Organic Electrophile

Organometallics
DOI: 10.1021/acs.organomet.0c00176




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[ASAP] Spatial Recognition Within Terpenes: Redox and H-bond Promoted Linkage Isomerizations and the Selective Binding of Complex Alkenes

Organometallics
DOI: 10.1021/acs.organomet.0c00151




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[ASAP] Linkage Isomerism in Dinuclear Al and Ga Organometallic Complexes: Structural and Reactivity Consequences

Organometallics
DOI: 10.1021/acs.organomet.0c00096




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[ASAP] Effect of the Lead(II) Bond Angle on the Reactivity of Diaminoplumbylenes toward Ammonia: From Inertness to Immediate Ammonolysis

Organometallics
DOI: 10.1021/acs.organomet.0c00196




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[ASAP] Sila-Peterson Reaction of Cyclic Silanides

Organometallics
DOI: 10.1021/acs.organomet.0c00106




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[ASAP] Improving Redox Reversibility and Intermetallic Coupling of Co(III) Alkynyls through Tuning of Frontier Orbitals

Organometallics
DOI: 10.1021/acs.organomet.0c00183




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[ASAP] A Stiboranyl Platinum Triflate Complex as an Electrophilic Catalyst

Organometallics
DOI: 10.1021/acs.organomet.0c00193




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[ASAP] Synthesis and Characterization of an Oxo-Centered Homotrimetallic Uranium(IV)–Cyclobutadienyl Dianion Complex

Organometallics
DOI: 10.1021/acs.organomet.0c00104




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[ASAP] Development of Quinoline-Derived Chiral Diaminocarbene Ligands and Their Transition Metal Complexes: Synthesis, Structural Characterization, and Catalytic Properties

Organometallics
DOI: 10.1021/acs.organomet.0c00141




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[ASAP] Ga(N,P) Growth on Si and Decomposition Studies of the N–P Precursor Di-<italic toggle="yes">tert</italic>-butylaminophosphane (DTBAP)

Organometallics
DOI: 10.1021/acs.organomet.0c00078




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[ASAP] Reactivity of [Ce(NR<sub>2</sub>)<sub>3</sub>] (R = SiMe<sub>3</sub>) with Prospective Carbon Atom Transfer Reagents

Organometallics
DOI: 10.1021/acs.organomet.0c00186




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[ASAP] Radical Capture at Nickel(II) Complexes: C–C, C–N, and C–O Bond Formation

Organometallics
DOI: 10.1021/acs.organomet.0c00021




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[ASAP] Reactivity of Amidinatosilylenes and Amidinatogermylenes with [PtMe<sub>2</sub>(?<sup>4</sup>-cod)]: <italic toggle="yes">cis</italic>- versus <italic toggle="yes">trans</italic>-[

Organometallics
DOI: 10.1021/acs.organomet.0c00188




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[ASAP] Synthesis and Characterization of Tungsten Alkylidene and Alkylidyne Complexes Featuring a New Carbazole-Based Rigid Trianionic ONO<sup>3–</sup> Pincer-Type Ligand

Organometallics
DOI: 10.1021/acs.organomet.0c00150




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[ASAP] <italic toggle="yes">O</italic>-Carboranylene versus Phenylene Backbones in Cyclization Reactions of 1,2 Diketones with Hydrosilanes

Organometallics
DOI: 10.1021/acs.organomet.0c00208




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[ASAP] Use of Ligand Steric Properties to Control the Thermodynamics and Kinetics of Oxidative Addition and Reductive Elimination with Pincer-Ligated Rh Complexes

Organometallics
DOI: 10.1021/acs.organomet.0c00122




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[ASAP] Sesquicarbene Complexes: Bonding at the Interface Between M–C Single Bonds and M-C Double Bonds

Organometallics
DOI: 10.1021/acs.organomet.0c00102




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[ASAP] Synthesis, Structures, and Electronic Properties of O- and S-Heterocyclic Carbene Complexes of Iridium, Copper, Silver, and Gold

Organometallics
DOI: 10.1021/acs.organomet.0c00066




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Annual Awards Special

It’s the end of year Back to Front Show awards special. An opinonated, and occasionally tongue in cheek, look back over the last year in which we celebrate the events, the trends, the people, the apps, the podcasts, the magazines and the books that have made 2013 a great year. We also have details of our first ever guest co-host who will be joining Keir in December!

Award Categories

Winners will be linked up in a few weeks time *

  • Conference/event of the year
  • Side project of the year
  • Podcast of the year
  • Magazine of the year
  • Book of the year
  • “Blogger who you wished blogged more” of the year
  • Hipster Web Site of the year (AKA the moustache wax award for web ingenuity)
  • Dog related tech product of the year
  • Team of the year
  • Man of the year
  • Woman of the year
  • Trend of the year
  • “And finally…” of the year

* We really want you to listen to find out!




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Transitioning

Just when you thought you could delete us from your podcatcher we are back and with a distinct lack of excuses for our absence. This week we discuss our new weekly formats and chat extensively about “transitioning”.

Over the last few months both of us have found our main focuses shifting and as a result the way we present ourselves online has changed, or had to change, too. We revisit our discussion on “flowery Twitter bios” and look at ways in which our friends, colleagues and heroes represent themselves online – through the blog posts they write, links they curate and share and other output including podcasts and videos. We touch on expectations, schedules and much more in our first episode back behind the Yeti’s.

We’d love to hear about your experiences of transitioning. Get in touch on Twitter and Facebook.





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Kieran&#8217;s Big Red Button

It’s hard to believe it’s only been one week, no really, since our last confession. Where does the time go?

In this episode we catch up on what’s happened in our lives in the last seven days, discuss the latest goings on at Medium, ponder why the Guardian doesn’t write listicles and end on probably the best API in the world!




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Kieran's Tiny House Dream

Tap tap, is this thing on? After eight months or working out how to plug in our USB microphones, we finally figured it out and are back with 45 glorious minutes of chat!

In this episode, we learn all about “New Kieran” — new job, new house, and a new laptop. We also discuss a great post on lessons learned running a subscription-based newsletter, discuss Hanno’s great online playbooks for remote working and end on a new Maus that neither of us wants.

Next up is our 50th episode — let us know what we should discuss via Twitter.




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Gujarat clears ordinance for labour reforms

In the wake of exodus of thousands of migrant workers who are leaving the state, the Gujarat cabinet has approved a new ordinance where existing stringent labour laws will be liberalised to ensure smooth functioning of industries in the post lockdown period.




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Gujarat HC allows an accused bail for Ramzan

The Gujarat high court has granted temporary bail to a murder accused to observe fasts during the holy month of Ramzan. He will have to surrender to jail on May 25, after Eid-ul-Fitr.​




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Gujarat HC restores land to civic body from royals

The Gujarat high court rebuked the erstwhile royal family of the princely state of Bhavnagar for its "dishonest intention" to claim a land parcel in an unauthorized manner from the Bhavnagar Municipal Corporation.




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Rajkot achieves another techno feat

In what could be a major breakthrough for N95 masks production in India, two Rajkot-based engineering firms have developed the machine indigenously to make this medically crucial masks. Most companies making N95 masks have been procuring the manufacturing machines from China, Japan and South Korea.




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Ahmedabad: 3,175 beds arranged in 104 hotels

The Ahmedabad Municipal Corporation, which had marked four hotels as Covid care centres till now, will now have 100 more hotels with a bed capacity of 3,175 for the purpose. In another important development, the civic body has planned a massive sanitization campaign in AMC areas from Saturday.




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Migrant workers clash with police in Surat

Demanding a return passage to their home states, hundreds of agitated migrant workers clashed with the police at Mora village in Gujarat's Surat district on Saturday, an official said.




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Synthesis of lignin-functionalized phenolic nanosphere supported Ag nanoparticles with excellent dispersion stability and catalytic performance

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04311J, Paper
Shilin Chen, Guanhua Wang, Wenjie Sui, Ashak Mahmud Parvez, Chuanling Si
This work presents a novel and green lignin-based nanocomposite and highlights the synergism of lignin's multiple functions (surfactant, sacrificial template, and reducing agent) in the material preparation process.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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One-pot hydrodeoxygenation of biomass furan derivatives into decane under mild conditions over Pd/C combined with phosphotungstic acid

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00428F, Paper
Song Li, Long Yan, Qiying Liu, Jianguo Liu, Qiyu Liu, Wei Fan, Xuelai Zhao, Xinghua Zhang, Chenguang Wang, Longlong Ma, Qi Zhang
One-pot hydrodeoxygenation of δ-furfurylidenelevulinic acid over Pd/C combined with phosphotungstic acid through successive hydrogenolysis and HDO of furans and lactones.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Water Effects in the Heterogeneous Catalytic Valorization of Levulinic Acid into γ-Valerolactone and its Derivatives

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC01082K, Critical Review
Rengui Weng, Zhihao Yu, Jian Xiong, Xuebin Lu
Levulinic acid (LA), which has been hailed as a versatile biomass-derived platform molecular, typically occupy a core position in the cellulosic biorefinery system. The heterogeneous catalytic valorization of LA for...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Humin based resin for wood modification and property improvement

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC03620B, Paper
Open Access
Anna Sangregorio, Anitha Muralidhara, Nathanael Guigo, Lisbeth G. Thygesen, Guy Marlair, Carlo Angelici, Ed de Jong, Nicolas Sbirrazzuoli
Focus on humins, a co-product from sugar conversion, to highlight their capacity to impregnate wood cell walls for making durable wood products.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Methylation-triggered fractionation of lignocellulosic biomass to afford cellulose-, hemicellulose-, and lignin-based functional polymers via click chemistry

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00451K, Paper
Kentaro Miki, Hiroshi Kamitakahara, Arata Yoshinaga, Yuki Tobimatsu, Toshiyuki Takano
This paper reports a new concept for the biorefinery of lignocellulosic biomass where the derivatisation and fractionation of lignocellulose are accomplished at the same time.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Sustainable synthesis of cobalt and cobalt oxide nanoparticles and their catalytic and biomedical applications

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00885K, Critical Review
Siavash Iravani, Rajender S. Varma
Recent advances and essential challenges as well as catalytic and biomedical applications of cobalt oxide and cobalt nanoparticles are highlighted.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Ni-Catalyzed hydrocyanation of alkenes with formamide as the cyano source

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04275J, Communication
Xiao Shu, Yuan-Yuan Jiang, Lei Kang, Luo Yang
A novel Ni-catayzed hydrocyanation of various alkenes to provide aliphatic nitriles is developed by generating hydrocyanic acid in situ from safe and readily available formamide.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Ni-Based Heterogeneous Catalysts for the Transformation of Fatty Acids into Higher Yields of O-Free Hydrocarbons

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00853B, Paper
Diego Valencia, Citlalli Zenteno, Diana Gomora-Herrera, María Teresa Gómez-Pérez, Jorge Aburto
A series of novel catalytic materials were synthesized by changing the chemical compounds in the impregnation solutions. A rigid, aromatic and bidentate molecule 1,10-phenanthroline (PhN) was used as a ligand...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Aqueous miscible organic layered double hydroxides as catalyst precursors for biodiesel synthesis

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00571A, Paper
Chunping Chen, Maxwell Greenwood, Jean-Charles Buffet, Dermot O'Hare
Surface area and basicity density dependence of base-catalysed transesterification of sunflower oil by potassium salt prepared AMO-layered double hydroxides.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Eco-friendly and sustainable synthesis of biocompatible nanomaterials for diagnostic imaging: current challenges and future perspectives

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00734J, Critical Review
Ghazaleh Jamalipour Soufi, Siavash Iravani
Current advancements, important challenges and future perspectives of biocompatible nanomaterials for diagnostic imaging are discussed as well as their greener synthesis.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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New biobased-zwitterionic ionic liquids: efficiency and biocompatibility for the development of sustainable biorefinery processes

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC01002B, Paper
Gaël Huet, Monica Araya-Farias, Ranim Alayoubi, Sylvain Laclef, Benjamin Bouvier, Isabelle Gosselin, Christine Cézard, Romain Roulard, Matthieu Courty, Caroline Hadad, Eric Husson, Catherine Sarazin, Albert Nguyen Van Nhien
A combination of experiments and modeling reveals the influence of alkyl chain lengths in biobased ZILs on the biocompatibility towards various microorganisms.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis of amorphous Geobacter-manganese oxide biohybrid as efficient water oxidation catalysts

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/C9GC04353E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Shafeer Kalathil, Krishna Katuri, Pascal Saikaly
The development of low cost and efficient oxygen evolution reaction (OER) catalyst has paramount importance to meet future sustainable energy demand. Nature’s photosynthetic machinery deploy manganese-based complex in photosystem II...
The content of this RSS Feed (c) The Royal Society of Chemistry




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A Strategy for The Assembly of Glypromate® and Structure-Related Analogues by Tandem Sequential Peptide Coupling

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00143K, Paper
Ivo E Sampaio-Dias, Luís Pinto da Silva, Sandra G Silva, Xerardo Garcia-Mera, José Enrique Rodriguez-Borges
This work describes an improved and greener methodology in solution-phase synthesis for the preparation of Glypromate® (glycyl-L-prolyl-L-glutamic acid, GPE), a potent neuropeptide with applications in neurodegenerative conditions such as Huntington's,...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Thermophilic bio-electro CO2 recycling into organic compounds

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00320D, Paper
Open Access
Laura Rovira-Alsina, Elisabet Perona-Vico, Lluís Bañeras, Jesús Colprim, M. Dolors Balaguer, Sebastià Puig
Many industrial combustion processes produce carbon dioxide (CO2) at high temperature, which may be electrically recycled into valuable chemicals using microorganisms as catalysts.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Solvent-free hydrogenation of levulinic acid to γ-valerolactone using a Shvo catalyst precursor: optimization, thermodynamic insights, and life cycle assessment

Green Chem., 2020, 22,2443-2458
DOI: 10.1039/C9GC02088H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Christian A. M. R. van Slagmaat, Marie A. F. Delgove, Jules Stouten, Lukas Morick, Yvonne van der Meer, Katrien V. Bernaerts, Stefaan M. A. De Wildeman
We studied the solvent-free hydrogenation of levulinic acid to γ-valerolactone with the Shvo catalyst involving comparative catalysis, DFT, and LCA.
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Ga/ZSM-5 catalyst improves hydrocarbon yields and increases alkene selectivity during catalytic fast pyrolysis of biomass with co-fed hydrogen

Green Chem., 2020, 22,2403-2418
DOI: 10.1039/C9GC03408K, Paper
Kristiina Iisa, Yeonjoon Kim, Kellene A. Orton, David J. Robichaud, Rui Katahira, Michael J. Watson, Evan C. Wegener, Mark R. Nimlos, Joshua A. Schaidle, Calvin Mukarakate, Seonah Kim
An integrated experimental and computational study to understand the catalytic upgrading of biomass vapors into high yield of alkenes.
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Insights into pressure tunable reaction rates for electrochemical reduction of CO2 in organic electrolytes

Green Chem., 2020, 22,2434-2442
DOI: 10.1039/D0GC00013B, Paper
Charles I. Shaughnessy, David J. Sconyers, Hyun-Jin Lee, Bala Subramaniam, James D. Blakemore, Kevin C. Leonard
Modeling and simulation reveal the mechanistic basis for the pressure-tunable rates of CO2 reduction at elevated pressures of CO2.
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Dioxomolybdenum complex as an efficient and cheap catalyst for the reductive depolymerization of plastic waste into value-added compounds and fuels

Green Chem., 2020, 22,2419-2425
DOI: 10.1039/C9GC04206G, Paper
Beatriz F. S. Nunes, M. Conceição Oliveira, Ana C. Fernandes
Several types of PCL, PLA, PDO, PET and PBT plastic waste were efficiently converted into value-added compounds and fuels catalyzed by MoO2Cl2(H2O)2.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis of renewable C–C cyclic compounds and high-density biofuels using 5-hydromethylfurfural as a reactant

Green Chem., 2020, 22,2468-2473
DOI: 10.1039/D0GC00195C, Paper
Taimei Cai, Qiang Deng, Hailong Peng, Jin Zhong, Rui Gao, Jun Wang, Zheling Zeng, Ji-Jun Zou, Shuguang Deng
Renewable C–C six-membered ring compound and high-density biofuel are synthesized using 5-hydromethylfurfural as a reactant.
The content of this RSS Feed (c) The Royal Society of Chemistry