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Sustainability by design: automated nanoscale 2,3,4-trisubstituted quinazoline diversity

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Green Chem., 2020, 22,2459-2467
DOI: 10.1039/D0GC00363H, Paper
Open Access
Mojgan Hadian, Shabnam Shaabani, Pravin Patil, Svitlana V. Shishkina, Harry Böltz, Alexander Dömling
Automated, one step, nanoscale synthesis of 2,3,4-trisubstituted quinazoline derivatives using positive pressure facilitated dispensing to access a very large chemical space exemplified by more than 1000 compounds.
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Novel insights into biomass delignification with acidic deep eutectic solvents: a mechanistic study of β-O-4 ether bond cleavage and the role of the halide counterion in the catalytic performance

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Green Chem., 2020, 22,2474-2487
DOI: 10.1039/C9GC02569C, Paper
André M. da Costa Lopes, José R. B. Gomes, João A. P. Coutinho, Armando J. D. Silvestre
The potentiality of acidic deep eutectic solvents for β-O-4 ether bond cleavage is herein demonstrated from a mechanistic point of view.
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Fabrication of highly proton-conductive chitosan whole-bio-membrane materials functionalized with adenine and adenosine monophosphate

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Green Chem., 2020, 22,2426-2433
DOI: 10.1039/C9GC04104D, Paper
Guanglei Zhao, Yuanyuan Chen, Xiao-Feng Li, Sihan Zhang, Yuanqiu Situ
A successful strategy to prepare novel proton-conductive chitosan membrane biomaterials functionalized with adenine and adenosine monophosphate via a one-pot grafting procedure.
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A facile solution-phase synthetic approach for constructing phenol-based porous organic cages and covalent organic frameworks

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Green Chem., 2020, 22,2498-2504
DOI: 10.1039/C9GC04033A, Paper
Lei Zhang, Rongran Liang, Cheng Hang, Haiying Wang, Lin Sun, Lei Xu, Dairong Liu, Zhenyi Zhang, Xingmin Zhang, Feifan Chang, Shengyu Zhao, Wei Huang
A general solution-phase synthetic strategy is developed to construct both porous organic cages (POCs) and covalent organic frameworks (COFs) by simply stirring and heating organic solvent/water solutions of aldehydes and amines in the presence of MOH (M = Na, K, and Cs).
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Upgrading 1-butanol to unsaturated, carbonyl and aromatic compounds: a new synthesis approach to produce important organic building blocks

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Green Chem., 2020, 22,2365-2369
DOI: 10.1039/D0GC00254B, Communication
Jorge Mora Vargas, Luiz Henrique Tofaneli Morelato, Julieth Orduna Ortega, Mauricio Boscolo, Gustavo Metzker
Conversion of 1-butanol into added-value organic building blocks was achieved using fixed-bed flow reactor and Cu-based catalyst at 550 and 600 °C with and without methanol as addictive.
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A non-phosgene process for bioderived polycarbonate with high molecular weight and advanced property profile synthesized using amino acid ionic liquids as catalysts

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Green Chem., 2020, 22,2534-2542
DOI: 10.1039/D0GC00265H, Paper
Zhencai Zhang, Fei Xu, Yaqin Zhang, Chenhao Li, Hongyan He, Zifeng Yang, Zengxi Li
Bio-based polycarbonate with high molecular weight and advanced property profile was synthesized using amino acid ionic liquids as catalysts.
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Hierarchically porous covalent organic frameworks assembled in ionic liquids for highly effective catalysis of C–C coupling reactions

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Green Chem., 2020, 22,2605-2612
DOI: 10.1039/D0GC00223B, Paper
Jikuan Qiu, Huiyong Wang, Yuling Zhao, Pengxin Guan, Zhiyong Li, Hucheng Zhang, Hongshuai Gao, Suojiang Zhang, Jianji Wang
A simple and environmentally benign strategy was reported for the synthesis of hierarchically porous COFs in ionic liquids, and the obtained materials show highly effective catalytic performance for C–C bond formation reactions.
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Solvent-free and montmorillonite K10-catalyzed domino reactions for the synthesis of pyrazoles with alkynylester as a dual synthon

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Green Chem., 2020, 22,2388-2393
DOI: 10.1039/D0GC00162G, Communication
Sesuraj Babiola Annes, Rajendhiran Saritha, Saravanan Subramanian, Bhaskaran Shankar, Subburethinam Ramesh
A highly regioselective, solvent-free and montmorillonite K10 clay-catalyzed domino process with an unprecedented C–C bond formation reaction is described for the synthesis of new class of tri-substituted and di-substituted pyrazole derivatives.
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Base-mediated benzannulation of α-cyanocrotonates with ynones: facile synthesis of benzonitriles and fluorenes

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Green Chem., 2020, 22,2370-2374
DOI: 10.1039/D0GC00608D, Communication
Maneesh Kumar Reddy Singam, Attunuri Nagireddy, Sridhar Reddy Maddi
Benzonitriles and cyanofluorenes have been rapidly obtained via the [3 + 3] benzannulation of readily available alkynones and α-cyanocrotonates using KOtBu as the only reagent and EtOH (and CO2) is the only by-product.
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One-pot synthesis of 1,3-butanediol by 1,4-anhydroerythritol hydrogenolysis over a tungsten-modified platinum on silica catalyst

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Green Chem., 2020, 22,2375-2380
DOI: 10.1039/D0GC00244E, Communication
Lujie Liu, Takehiro Asano, Yoshinao Nakagawa, Masazumi Tamura, Keiichi Tomishige
Chemical production of 1,3-butanediol from biomass-derived compounds was first reported by 1,4-anhydroerythritol hydrogenolysis over a Pt–WOx/SiO2 catalyst.
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Iridium-catalyzed orthogonal and regioselective synthesis of triazole disulfides in aqueous media under mild conditions

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Green Chem., 2020, 22,2394-2398
DOI: 10.1039/D0GC00555J, Communication
Ming Li, Nan Zheng, Junhao Li, Yubin Zheng, Wangze Song
Triazole disulfides were prepared in water or biological media under mild conditions by orthogonal and regioselective Ir-catalyzed reactions.
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Mechanochemical synthesis of mixed metal, mixed linker, glass-forming metal–organic frameworks

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Green Chem., 2020, 22,2505-2512
DOI: 10.1039/D0GC00546K, Paper
Michael F. Thorne, María Laura Ríos Gómez, Alice M. Bumstead, Shichun Li, Thomas D. Bennett
Methods to produce glass forming metal–organic frameworks (MOFs) rely on solvothermal syntheses which have high energy requirements, low yields and large teratogenic solvent usage. We present mechanochemical methods to overcome these issues.
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An entirely solvent-free photooxygenation of olefins under continuous flow conditions

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Green Chem., 2020, 22,2359-2364
DOI: 10.1039/D0GC00436G, Communication
Patrick Bayer, Axel Jacobi von Wangelin
Photooxygenations of alkenes with singlet oxygen have been performed under solvent-free conditions in a flow reactor under VIS irradiation. The reaction operates at very high substrate/sensitizer ratios and enables high space–time yields.
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Double-metal cyanide as an acid and hydrogenation catalyst for the highly selective ring-rearrangement of biomass-derived furfuryl alcohol to cyclopentenone compounds

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Green Chem., 2020, 22,2549-2557
DOI: 10.1039/C9GC04432A, Paper
Xiang Li, Qiang Deng, Lian Yu, Rui Gao, Zhikun Tong, Chenxi Lu, Jun Wang, Zheling Zeng, Ji-Jun Zou, Shuguang Deng
Herein, novel green synthetic routes to 4-hydroxy-2-cyclopentenone (HCP) and 2-cyclopentenone (CPE) from biomass-derived furfuryl alcohol via double-metal cyanide catalysis are proposed.
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Properties and activity of Zn–Ta-TUD-1 in the Lebedev process

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Green Chem., 2020, 22,2558-2574
DOI: 10.1039/D0GC00103A, Paper
Open Access
Guillaume Pomalaza, Pardis Simon, Ahmed Addad, Mickaël Capron, Franck Dumeignil
A zinc and tantalum-containing mesoporous silica catalyst highly active and selective in the Lebedev process has been prepared using the one-pot TUD-1 methodology. Characterization established a correlation between acidity and butadiene formation.
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Evaluating lignin valorization via pyrolysis and vapor-phase hydrodeoxygenation for production of aromatics and alkenes

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Green Chem., 2020, 22,2513-2525
DOI: 10.1039/C9GC04245H, Paper
Open Access
Alireza Saraeian, Alvina Aui, Yu Gao, Mark M. Wright, Marcus Foston, Brent H. Shanks
Lignin valorization to chemicals is an important component of creating economically viable biofuels production from lignocellulosic biomass.
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Improving process efficiency of gold-catalyzed hydration of alkynes: merging catalysis with membrane separation

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Green Chem., 2020, 22,2598-2604
DOI: 10.1039/D0GC00498G, Paper
Tahani A. C. A. Bayrakdar, Fady Nahra, Oihane Zugazua, Lies Eykens, Dominic Ormerod, Steven P. Nolan
In this report, we investigate the integration of a membrane separation protocol in line with the gold-catalyzed hydration of alkynes.
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A review of sustainable and intensified techniques for extraction of food and natural products

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Green Chem., 2020, 22,2325-2353
DOI: 10.1039/C9GC03878G, Tutorial Review
Open Access
Farid Chemat, Maryline Abert Vian, Anne-Sylvie Fabiano-Tixier, Marinela Nutrizio, Anet Režek Jambrak, Paulo E. S. Munekata, Jose M. Lorenzo, Francisco J. Barba, Arianna Binello, Giancarlo Cravotto
This review presents innovative extraction techniques and their role in promoting sustainable ingredients for the food, cosmetic and pharmaceutical industries.
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Introducing deep eutectic solvents as flux boosting and surface cleaning agents for thin film composite polyamide membranes

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Green Chem., 2020, 22,2381-2387
DOI: 10.1039/D0GC00762E, Communication
Nidhi Maalige R., Sweedal A. Dsouza, Matheus M. Pereira, Veerababu Polisetti, Dibyendu Mondal, Sanna Kotrappanavar Nataraj
This study introduced DESs as versatile and multi-tasking agents to modify the surface roughness and wettability of a TFC-PA membrane to boost the permeate flux rate and they also proved to be cleaning agents for organically fouled TFC-PA membranes.
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Scalable synthesis of hydroxymethyl alkylfuranoates as stable 2,5-furandicarboxylic acid precursors

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Green Chem., 2020, 22,2399-2402
DOI: 10.1039/D0GC00770F, Communication
Martin Jæger Pedersen, Arminas Jurys, Christian Marcus Pedersen
Hydroxymethyl furanoic acid and its derivatives have been synthesized in high yields and purity from gluconolactone.
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Bio-based benzoxazine surfactant from amino acid

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Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00218F, Paper
Zheng Wang, Shu Yao, Kun Song, Xinjian Gong, Sujuan Zhang, Sheng Gao, Zaijun Lu
A novel bio-based benzoxazine (Ca-g) surfactant was synthesized via a Mannich reaction using renewable glycine and cardanol as raw materials. The structure of Ca-g was characterized by NMR, FT-IR, and...
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Computer-aided Nanotoxicology: Risk Assessment of Metal Oxide Nanoparticles via nano-QSAR

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Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00933D, Paper
Jiakai Cao, Yong Pan, Yanting Jiang, Ronghua Qi, Beilei Yuan, Zhenhua Jia, Juncheng Jiang, Qingsheng Wang
Since the applications of nanomaterials have been expanded to serve as a therapeutic methodology, the cytotoxicity accompanying with the nanomaterials drew lots of attention during the therapeutic process. It is...
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Visible-light-promoted oxidative desulphurisation: a strategy for the preparation of unsymmetrical ureas from isothiocyanates and amines using molecular oxygen

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Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00070A, Paper
Ziyu Gan, Guoqing Li, Qiuli Yan, Weiseng Deng, Yuan-Ye Jiang, Daoshan Yang
A green and efficient visible-light promoted oxidative desulphurisation protocol has been proposed for the construction of unsymmetrical ureas under mild conditions with broad substrate scope and good functional group tolerance.
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Photocatalytic transfer hydrogenolysis of aromatic ketones using alcohols

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Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00732C, Paper
Hongji Li, Zhuyan Gao, Lijun Lei, Huifang Liu, Jianyu Han, Feng Hong, Nengchao Luo, Feng Wang
A mild method of photocatalytic deoxygenation of aromatic ketones to alkyl arenes was developed, which utilized alcohols as the green hydrogen donor. No hydrogen evolution during this transformation suggested a...
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Sustainable remediation with an electroactive biochar system: mechanisms and perspectives

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Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00717J, Critical Review
Zhonghao Wan, Yuqing Sun, Daniel C. W. Tsang, Deyi Hou, Xinde Cao, Shicheng Zhang, Bin Gao, Yong Sik Ok
Biochar-based carbocatalysis is synergized from electroactive components including reactive-active moieties, metals, defective sites, heteroatoms, and graphitic structure for sustainable remediation.
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Continuous hydroformylation of 1-decene in an aqueous biphasic system enabled by methylated cyclodextrins

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Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00820F, Paper
Open Access
K. U. Künnemann, L. Schurm, D. Lange, T. Seidensticker, S. Tilloy, E. Monflier, D. Vogt, J. M. Dreimann
Long-term applications of cyclodextrins in the aqueous biphasic hydroformylation of higher olefins with high selectivities and simultaneous catalyst recycling.
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Boron-doped CuO nanobundles for electroreduction of carbon dioxide to ethylene

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Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00730G, Communication
Qiang Wan, Jianling Zhang, Bingxing Zhang, Dongxing Tan, Lei Yao, Lirong Zheng, Fanyu Zhang, Lifei Liu, Xiuyan Cheng, Buxing Han
Herein, we synthesize B-doped CuO nanobundles for electrocatalytic CO2 reduction. Ethylene is the only multi-carbon product and a maximum ethylene faradaic efficiency (FE) of 58.4% can be achieved at −1.1 V (versus the reversible hydrogen electrode).
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Chemoselective O-formyl and O-acyl protection of alkanolamines, phenoxyethanols and alcohols catalyzed by nickel(II) and copper(II)-catalysts

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Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00520G, Paper
Rahul B. Sonawane, Swapnali R. Sonawane, Nishant K. Rasal, Sangeeta V. Jagtap
A crucial chemoselective O-formyl and O-acyl protection of alkanolamines, phenoxyethanols, and alcohols in the presence of amines catalyzed by Ni(II) and Cu(II) complexes with 8-hydroxyquinoline in a homogeneous medium is achieved.
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Nickel-catalyzed and Li-mediated regiospecific C–H arylation of benzothiophenes

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Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00917B, Paper
Yorck Mohr, Gaëlle Hisler, Léonie Grousset, Yoann Roux, Elsje Alessandra Quadrelli, Florian M. Wisser, Jérôme Canivet
A sustainable nickel-catalyzed direct C–H arylation of benzothiophenes, benzofuran and selenophene is reported for the first time.
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Mechanochemical Cleavage of Lignin Models and lignin via Oxidation and Subsequent Base-Catalyzed Strategy

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Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00372G, Paper
Weike Su, Chen Sun, Lei Zheng, Wenhao Xu, Alexandr V. Dushkin
Mechanochemical cleavage of lignin dimer model compounds to phenolic monomers has been developed via a two-step strategy under milling conditions. In the first step of this process, the secondary benzylic...
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Outstanding Reviewers for Green Chemistry in 2019

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Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC90042G, Editorial

We would like to take this opportunity to highlight the Outstanding Reviewers for Green Chemistry in 2019, as selected by the editorial team for their significant contribution to the journal.
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Photocatalytic Hydrogen Atom Transfer: the Philosopher’s Stone for Late-Stage Functionalization?

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Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC01035A, Tutorial Review
Luca Capaldo, Lorenzo Lafayette Quadri, Davide Ravelli
An overview about the potentialities of photocatalytic Hydrogen Atom Transfer (HAT) for the Late-Stage Functionalization (LSF) of complex molecules is offered. The examined approach allows the smooth homolytic cleavage of...
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Development and validation of an ecofriendly HPLC-DAD method for the determination of oleuropein and its applicability to several matrices: olive oil, olive leaf extracts and nanostructured lipid carriers.

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Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00965B, Paper
Amaia Huguet-Casquero, Tania Belen Lopez-Mendez, Eusebio Gainza, Jose Luis Pedraz
Oleuropein is a natural ingredient largely used in nutritional supplements. This study reports on the development, validation and application of an HPLC method based on UV-vis detection for determining oleuropein...
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Transparent, flexible and recyclable nanopaper-based touch sensors fabricated via inkjet-printing

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Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00658K, Paper
Hao Ling, Ruwei Chen, Quanbo Huang, Feng Shen, Yuyuan Wang, Xiaohui Wang
Using an eco-friendly PEDOT:PSS ink formula, a transparent and flexible nanopaper-based touch sensor was fabricated via inkjet-printing.
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Sulfonic acid modified hollow polymer nanospheres with tunable wall-thickness for improving biodiesel synthesis efficiency

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Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00905A, Paper
Wenliang Song, Yu Zhang, Anuraj Varyambath, Ji Su Kim, Il Kim
Precisely designing the morphology and size of nanostructures is vital in green chemistry as various advanced applications depend upon the shapes and dimensions of the functionalised materials. Herein, we report...
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MOFs come up to scratch: an environmentally benign route to oxidative [4 + 2] cycloaddition on maleimides solely via MOFs in water

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Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00619J, Paper
Masoumeh Abbasnia, Mehdi Sheykhan, Mona Bahmani, Parvaneh Taghizadeh
The first Diels–Alder reaction of vinyl arenes with ene systems catalyzed by MOFs is reported.
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Tandem catalytic aromatization of volatile fatty acids

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Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00964D, Paper
Open Access
Egor V. Fufachev, Bert M. Weckhuysen, Pieter C. A. Bruijnincx
The transition towards a circular economy requires closing the carbon loop, e.g. by the development of new synthesis routes to valuable intermediates and products from organic-rich waste streams.
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Scalable synthesis and polymerisation of a β-angelica lactone derived monomer

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Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00338G, Paper
Open Access
Andrea Dell'Acqua, Bernhard M. Stadler, Sarah Kirchhecker, Sergey Tin, Johannes G. de Vries
A new bio-based norbornene polymer was prepared starting from β-angelica lactone, prepared in a sustainable and scalable manner from the platform chemical levulinic acid. The new material displays transparency comparable to petrochemical-derived polynorbornene.
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Yb(OTf)3 and Visible Light Relay Catalyzed [3+2] Cycloaddition/[3,3]-Rearrangement/[4+2] Cycloaddition in One Pot to Prepare Oxazonine-Fused Endoperoxides

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Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00929F, Paper
Xiao-Pan Ma, Cai-Mei Nong, Yu-Feng Liang, Pei-Pei Xu, Xiu-Yun GUO, Cui Liang, Chengxue Pan, Gui-Fa SU, Dong-Liang Mo
We report a relay catalysis for the highly stereoselective synthesis of densely substituted oxazonine-fused endoperoxides in good yields. This domino reaction is based on a Yb(OTf)3 and visible light promoted...
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Microwave-assisted aqueous carbon–carbon cross-coupling reactions of aryl chlorides catalysed by reduced graphene oxide supported palladium nanoparticles

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Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00833H, Paper
Qingxiao Zhang, Zhan Mao, Kaixuan Wang, Nam Thanh Son Phan, Fang Zhang
Microwave-assisted reduced graphene oxide supported palladium nanoparticles can efficiently promote aqueous Ullmann and Suzuki coupling reactions of aryl chlorides.
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Functionalized magnetic nanosized materials for efficient biodiesel synthesis via acid–base/enzyme catalysis

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Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00924E, Critical Review
Anping Wang, Putla Sudarsanam, Yufei Xu, Heng Zhang, Hu Li, Song Yang
This critical review introduces the preparation methods, structural and performance control, protection, and functionalization of magnetic nanoparticles as easily recyclable and efficient heterogeneous catalysts for biodiesel synthesis.
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CO2-switchable non-Newtonian fluids

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Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00877J, Paper
Xiang Hao, Zejian Leng, Hairong Wang, Feng Peng, Qiang Yan
We report a new class of CO2-regulated non-Newtonian polymeric fluids that can switch between shear thinning and shear thickening states.
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Clean synthesis of linear and star amphiphilic poly(ε-caprolactone)-block-poly(ethyl ethylene phosphonate) block copolymers: assessing self-assembly and surface activity

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Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00819B, Paper
Payal Baheti, Timo Rheinberger, Olinda Gimello, Cécile Bouilhac, Frederik R. Wurm, Patrick Lacroix-Desmazes, Steven M. Howdle
Synthesis by ROP of star-like amphiphilic block copolymer surfactants composed of PCL hydrophobic segments and poly(phosphonate) as biodegradable segments.
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Metal-catalysed selective transfer hydrogenation of α,β-unsaturated carbonyl compounds to allylic alcohols

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Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00855A, Critical Review
Ronald Alvaro Alvaro Farrar Tobar, Andrea Dell'Acqua, Sergey Tin, Johannes G. de Vries
Allylic alcohols are highly important compounds which are used in a variety of processes. They can be obtained from α,β-unsaturated carbonyl compounds via stoichiometric or catalytic reductions. Catalytic transfer hydrogenation...
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Molecular engineering low-surface energy membranes by grafting perfluoro-tert-butoxy chains containing fluorous silica aerogels

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Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00593B, Paper
Vicki Man-Wai Yim, Angel See-Wing Lo, Bhaskar Jyoti Deka, Jiaxin Guo, Jehad A. Kharraz, István T. Horváth, Alicia Kyoungjin An
Environmentally benign fluorous aerogels have been synthesized and electrospun on commercial PVDF membrane imparting superhydrophobicity and enabling the membrane undergo a stable, non-wetting 10-day DCMD operation with 0.1 mM SDS and 3.5% NaCl feed.
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Highly efficient oxidation of alcohols to carboxylic acids using a polyoxometalate-supported chromium(III) catalyst and CO2

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Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00388C, Paper
Ying Wang, ZhiKang Wu, Han Yu, Sheng Han, Yongge Wei
A green and highly efficient oxidation of alcohols to carboxylic acids using a polyoxometalate-supported chromium(III) catalyst and CO2.
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A safe and compact flow platform for the neutralization of a mustard gas simulant with air and light

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Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC01142H, Communication
Noémie Emmanuel, Pauline Bianchi, Julien Legros, Jean-Christophe M. Monbaliu
Intensified chemical neutralization of a chemical warfare agent simulant CEES with air and light under continuous flow conditions.
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Reporting the unreported: the reliability and comparability of the literature on organic solvent nanofiltration

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Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00775G, Perspective
Hai Anh Le Phuong, Christopher F Blanford, Gyorgy Szekely
Organic solvent nanofiltration (OSN) is an energy-efficient separation technique that has the potential to improve environmental sustainability in many industrial sectors, including food processing, biorefineries, and in the production of...
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Humidity-responsive Molecular Gate-opening mechanism for Gas Separation in Ultraselective Nanocellulose/IL Hybrid Membranes

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Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00544D, Paper
Saravanan. Janakiram, Luca Ansaloni, Soo Ah Jin, Xinyi Yu, Zhongde Dai, Richard J Spontak, Liyuan Deng
Nanofibrillated cellulose (NFC) represents an important class of bio-based nanomaterials that possess favorable properties including hydrophilicity, 1D structure, biodegradability, and surface tunability. Although widely known for its effective gas-barrier attributes...
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A direct conversion of blast furnace slag to a mesoporous silica–calcium oxide composite and its application in CO2 captures

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Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00722F, Paper
Yasutaka Kuwahara, Aiko Hanaki, Hiromi Yamashita
A facile and cost-effective approach is presented that converts blast furnace slag into a mesoporous silica-CaO composite possessing high CO2 adsorption performance.
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