of

Highly stable chiral Cr(III)-based metal–organic frameworks for enantioadsorption separation of aromatic alcohols

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,1998-2006
DOI: 10.1039/D4QI00113C, Research Article
Mengna Li, Benlai Wu, Maochun Hong
Highly stable Cr-HMOFs Cr-HMOF-1 and Cr-HMOF-2 were synthesized for the first time directly using enantiomerically pure chiral ligands, showing excellent enantioselective separation performance for aromatic alcohol racemates.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Efficient catalysis of Knoevenagel condensation by 1D copper-containing heteropolyoxoniobate at room temperature

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,1993-1997
DOI: 10.1039/D4QI00260A, Research Article
Ya-Kun Zuo, Yan-Ru Li, Yan-Qiong Sun, Xin-Xiong Li, Cai Sun, Shou-Tian Zheng
A 1D copper-containing organic–inorganic hybrid heteropolyoxoniobate catalyst for efficient catalysis of Knoevenagel condensation at room temperature.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Carbon dots induce abundant oxygen vacancies in CeVO4 for promoting photocatalytic selective hydrogenation of functionalized nitroarenes

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,2128-2135
DOI: 10.1039/D4QI00002A, Research Article
Ernan Pang, Shijia Li, Jie Wu, Qing Chang, Ning Li, Jinlong Yang, Shengliang Hu
Carbon dots create the appropriate oxygen vacancies (OVs) in CeVO4 for the chemoselective hydrogenation of functionalized nitroarenes under light irradiation.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Gelation-induced controlled synthesis of TiO2 with tunable phase transition for efficient photocatalytic hydrogen evolution

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,2178-2186
DOI: 10.1039/D4QI00193A, Research Article
Wenwei Lei, Ying Wang, Hongji Wang, Norihiro Suzuki, Chiaki Terashima, Akira Fujishima
A facile gelation-assisted coordination self-assembly method for mediated fabrication of TiO2 photocatalysts with controlled phase structures and morphologies is presented, showing excellent photocatalytic hydrogen production performance.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Electron-deficient Co modulated by the construction of heterojunctions Co@NC boosts the electroreduction of nitrate to ammonia

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,2144-2151
DOI: 10.1039/D4QI00110A, Research Article
Bo Zhang, Fengshou Yu, Yaohua Hong, Yuzhuo Zhou, Yaheng Wang, Shaobo Zhang, Lu-Hua Zhang
Formation of electron-deficient Co by the construction of heterojunctions to promote the electroreduction of nitrate to ammonia.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Slow magnetization relaxation of a high-spin iron(III) in mayenite Ca12Al14O33

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,2098-2104
DOI: 10.1039/D4QI00480A, Research Article
Timur Z. Sharifullin, Alexander V. Vasiliev, Vladimir D. Dolzhenko, Sebastian Bette, Robert E. Dinnebier, Reinhard K. Kremer, Pavel E. Kazin
High-spin Fe3+ ion imbedded in the extended solid displays field-induced slow relaxation of magnetization with enhanced relaxation time values.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Combination of dimensional reduction and active site addition strategies for preparing unique {RE9}-cluster-based MOFs: efficient CO2 fixation and Knoevenagel condensation

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,2071-2080
DOI: 10.1039/D3QI02527F, Research Article
Ying Zhao, Dan Wu, Yidan Qiao, Guo-Ping Yang, Lu-Fang Ma, Yao-Yu Wang
A series of 2D {RE9}-cluster-based rare-earth MOFs were built by dimensional reduction and active site addition strategies. They exhibit excellent catalytic activity in CO2 fixation and Knoevenagel condensation under mild conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Reasonable regulation of flexible sulfur-based bifunctional catalytic electrodes for efficient seawater splitting

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,2152-2163
DOI: 10.1039/D3QI02575F, Research Article
Fengjing Lei, Xunwei Ma, Xinyun Shao, Ziyan Fang, Yuqin Wang, Weiju Hao
An iron-regulated three-dimensional nano-conical, economical, and flexible Fe-NiS@HA electrode exhibiting high intrinsic activity is prepared by gentle one-step electroless plating for efficient, durable hydrogen production in alkaline seawater.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Correction: In situ construction of a continuous ionic conductive coating for a high-performance Li3VO4 anode

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,2187-2187
DOI: 10.1039/D4QI90020K, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lulu Wang, Cheng Zeng, Jianing Liang, Chun Zhai, Hao Liu, Tianyou Zhai, Huiqiao Li
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Crystal structure, Bi3+ yellow luminescence, and high quantum efficiency of Ba3SbAl3Ge2O14:Bi3+ phosphor for white light-emitting diodes

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00240G, Research Article
Huihui Fei, Baolong Jing, Jin Han, Kaian Shan, Dongming Cheng, Xueqing Xu, Xinmin Zhang, Jing Wang
Bi3+ ions occupy Ba site to form one Bi3+ luminescent center, which is consistent with the trigonal structure of BSAG. This phosphor has a high quantum efficiency of 95.3% and can be used in WLEDs.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Synthesis and characterization of a CsPbCl3 perovskite doped with Nd3+: structural, optical, and energy transfer properties

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00171K, Research Article
Mariusz Stefanski, Bartosz Bondzior, Adam Basinski, Maciej Ptak, Bibo Lou, Chong-Geng Ma
The levels of Nd3+ in CsPbCl3 lie below the top of the host's VB. Consequently, Nd3+ luminescence is not observed.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Sodium ion pre-intercalation regulates the electron density and structural stability of vanadium oxide nanowires for Ca–ion batteries

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00218K, Research Article
Huajie Feng, Yize Wang, Wenda Qiu, Zixi Liu, Yaping Tao, Xihong Lu
Benefiting from the abundant resource, low cost, and high operating potential, calcium–ion batteries (CIBs) have attracted great attention as emerging energy storage devices over lithium-based systems.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Defect-rich Pd@PdOs nanobelts for electrocatalytic oxidation of ethylene glycol

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00319E, Research Article
Xianlong Wang, Xuewen Wei, Ruifan Zhang, Min Yan, Ranran Wei, Xiaoying Zhang, Zhaoyou Zhu, Yinglong Wang, Xinling Zhao, Shuli Yin
Reasonable design and development of catalysts with specific components and morphologies can effectively improve the catalytic performance of nanomaterials.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Adhesion, stability, structural and electronic properties of perovskite/BaWO4 heterostructures: first-principles and experimental characterizations

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00231H, Research Article
Yao Guo, Shiding Zhang, Zhaoyu Zhang, Yuanbin Xue, Jianxin Li, Haixiang Song, Yuhua Wang, Qing Shen
The interfacial behavior and mechanism of the CsPbBr3/BaWO4 and MAPbBr3/BaWO4 heterostructures have been extensively investigated by a combined first-principles and experimental analysis.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Rapid Joule heating synthesis of Ni doped into porous honeycomb C3N4 with greatly improved photocatalytic H2 production

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00225C, Research Article
Zehui Zhao, Guangmin Ren, Zisheng Zhang, Xiangchao Meng, Zizhen Li
Photocatalytic water splitting is one of the sustainable and environmentally-friendly methods for producing hydrogen.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Effects of weak intramolecular interactions and distortions from trigonal prismatic coordination on the magnetic properties of zero-field Co(II) single-ion magnets

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D3QI02507A, Research Article
Ben Zhang, Yang Zhou, Hao-Yi Huang, Xiao-Le Zhang, Yi Xiang, Yanbo Shi, Chennan Zhang, Aihua Yuan, Xingwei Cai, Lei Chen, Yi-Quan Zhang, Zhao-Bo Hu
The change of counter anions significantly affects the environment around Co(II) ions, leading to two zero-field single-ion magnets possessing different uniaxial anisotropies and dynamic magnetic properties.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Facile access to tetra-substituted FeIIFeII biomimetics for the oxidized state active site of [FeFe]-hydrogenases

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00773E, Research Article
Xin-Ping Gao, Shu-Fen Bai, Yan-Lan Wang, Shuang Lü, Qian-Li Li
This study presents a convenient approach to obtain two distinct types of novel tetra-substituted Fe/Se salts through a dehalogenation reaction. The objective is to advance research in mimicking the FeIIFeII oxidation state in [FeFe]-H2ases.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Synergistic role of hydrogen bonding and band degeneracy leads to enhanced X-ray detection in HPIP-(NH4)0.7Cs0.3Br3·H2O perovskites

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00272E, Research Article
Pengxiang Dong, Chensheng Lin, Xin Zhao, Yicong Lv, Ning Ye, Min Luo
This work shows the innovative introduction of Cs+ into molecular perovskites to co-occupy with NH4+, synthesis of the HPIP-(NH4)0.7Cs0.3Br3·H2O perovskite, and fabrication of an X-ray detector with excellent overall performance and superior environmental stability.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Large-scale fabrication of ZIF-derived electrocatalysts for industrial oxygen evolution

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00458B, Research Article
Liangjun Chen, Zhuowen Huangfu, Xuelin Yang, Hang Lei, Zilong Wang, Wenjie Mai
This study presents a methodology that enables the development of efficient and scalable ZIF-derived electrocatalysts for industrial water electrolysis, resulting in significant time and energy savings.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Controlling the structural and adsorption features of polyoxovanadate-based metal–organic clusters by adjustable template effect

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00254G, Research Article
Yan-Hu Wang, Ke-Wei Tong, Chao-Qin Chen, Jing Du, Guo-Ping Yang, Peng Yang
An adjustable template effect was employed to activate the evolution of polyoxovanadate-based metal–organic clusters, resulting in unprecedented structural archetypes as well as customized dye and iodine adsorption features.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Discovery of excellent ultraviolet nonlinear optical materials in chlorates and bromates with highly stereochemically active lone pairs

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00462K, Research Article
Chun-Li Hu, Qian-Qian Chen, Fang Kong, Jiang-Gao Mao
The long-neglected stereochemically active lone pair groups ClO3− and BrO3− are demonstrated to be important UV NLO functional motifs based on the fact that AClO3 and ABrO3 possess high SHG effects and short λPM and are promising UV NLO materials.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

The smallest endohedral borafullerene: structural isomerization, electronic properties, aromaticity and reactivity of U@C27B

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00186A, Research Article
Xinde Li, Lei Lou, Peng Jin
U@C27B has three interconvertible isomers with the highest metal oxidation state and strong covalency, obeying the 32-electron principle and Hirsch's aromaticity rule.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

An unusual reaction in nitromethane solution: use of the Cp*Rh moiety to form Prussian blue analogues

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00343H, Research Article
Huirong Ma, Liangchen Liu, Yuluan Liao, Huatian Shi, Po Sun, Weibin Yu
The direct decomposition of nitromethane into nitrile compounds is a significant challenge due to the occurrence of severe side-reactions.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Hysteretic magnetism–dielectricity switching in 2D Hofmann type spin-crossover compounds

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D3QI02660D, Research Article
Nian-Tao Yao, Meng-Jia Shang, Han-Han Lu, Qiang Liu, Wen Wen, Shi-Hui Zhang, Liang Zhao, Hiroki Oshio, Yin-Shan Meng, Tao Liu
Two 2D Hofmann type compounds {Fe(3,4-bpt)2[M(CN)4]} were synthesized. They showed reversible switching in magnetism, dielectricity, and thermochromism actuated by the spin transition of Fe(II).
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Porphyrin-based MOFs for photocatalysis in water: advancements in solar fuels generation and pollutants degradation

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,2212-2245
DOI: 10.1039/D3QI01996A, Review Article
Open Access
Fangbing Liu, Irene Rincón, Herme G. Baldoví, Amarajothi Dhakshinamoorthy, Patricia Horcajada, Sara Rojas, Sergio Navalón, Alexandra Fateeva
This review highlights the recent advances in the photocatalytic applications of porphyrin-based MOFs in aqueous environments for solar fuel generation and water remediation.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Development of In–Cu binary oxide catalysts for hydrogenating CO2via thermocatalytic and electrocatalytic routes

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,2319-2338
DOI: 10.1039/D3QI02499G, Research Article
Open Access
Marco Pietro Mezzapesa, Fabio Salomone, Hilmar Guzmán, Federica Zammillo, Roberto Millini, Letizia Bua, Gianluigi Marra, Alessandra Tacca, Rosamaria Marrazzo, Nunzio Russo, Raffaele Pirone, Simelys Hernández, Samir Bensaid
Carbon dioxide (CO2) hydrogenation to obtain valuable chemicals and fuels via thermocatalysis or electrocatalysis is a promising and sustainable method for CO2 utilization.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Selenium doping induced phase transformation and interlayer expansion boost the zinc storage performance of molybdenum disulfide

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,2272-2280
DOI: 10.1039/D4QI00344F, Research Article
Mengfan Niu, Wenli Xin, Lei Zhang, Min Yang, Yaheng Geng, Xilin Xiao, Hui Zhang, Zhiqiang Zhu
This work synthesized Se-doped MoS2 nanosheets as a cathode for aqueous zinc-ion batteries, and they exhibited largely improved electrochemical performance owing to their high content of the 1T phase (64%) and expanded interlayer spacing (0.65 nm).
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Solvent-modulated assembly of peptide and cerium functionalized gigantic {Mo120Ce6}2 dimers for high-efficiency photocatalytic oxidation

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,2355-2364
DOI: 10.1039/D4QI00339J, Research Article
Dexiang Zhou, Bingbing Li, Qixin Zhao, Xinyu Tang, Tingya Lan, Heyang Su, Guoping Yang, Weimin Xuan
Two gigantic peptide and cerium functionalized {Mo120Ce6}2 dimers have been constructed via a solvent-modulated assembly and applied for effective photocatalytic aerobic oxidation of sulfides to sulfoxides.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Regulation of polyaniline thickness and substitution position on Cu foams to optimize hydrogen evolution and ethanol oxidation performance

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,2373-2383
DOI: 10.1039/D4QI00085D, Research Article
Haiqiang Mu, Pengyue Shan, Min Zhu, Zhenli Lv, Guorui Ma, Jiaxing Guo, Junzhuo Fang, Jin Zhang, Feng Li, Jing Li
The Cu foam decorated with integrated polyaniline (PANI/CF-210) based on direct electro-grafting technique has been successfully designed to develop for efficient hydrogen evolution and ethanol oxidation reaction.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Understanding the synthesis mechanism, chemical structures and optical properties of aromatic carbon nitride

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,2346-2354
DOI: 10.1039/D4QI00355A, Research Article
Yunhu Wang, Fangxu Dai, Yafei Tao, Kai Zhang, Bingjie Li, Mingming Zhang, Kang Liu, Jixiang Xu, Lei Wang, Jun Xing
The chemical structures and optical properties of aromatic carbon nitride and intermediates have been systematically studied; hereby the detailed synthesis mechanism of aromatic carbon nitride is explicitly proposed.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Boosting structural variety and catalytic activity of porphyrinic metal–organic frameworks by harnessing bifunctional ligands

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,2281-2289
DOI: 10.1039/D4QI00314D, Research Article
Wei Wu, Xiu-Liang Lv, Tao He, Guang-Rui Si, Hongliang Huang, Lin-Hua Xie, Yabo Xie, Jian-Rong Li
High catalytic performance of porphyrin-based MOFs has been achieved by introducing multiple functionality into their ligands and modulating their conformation.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Achieving a near-unity photoluminescence quantum yield and high stability of CsPbI3 nanoplatelets by hydroiodic acid-assisted ligand treatment

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,2392-2401
DOI: 10.1039/D4QI00168K, Research Article
Zongnan Li, Yusheng Song, Sheng Cao, Ke Xing, Zhentao Du, Bingsuo Zou, Jialong Zhao
We demonstrate a near-unity photoluminescence quantum yield and high stability of CsPbI3 nanoplatelets achieved through a hydroiodic acid-assisted ligand treatment strategy, showcasing their application in perovskite LEDs.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Enhancing the separation of C2H4/C2H6 in customized MOR zeolites

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,2427-2435
DOI: 10.1039/D4QI00236A, Research Article
Hongwei Chen, Binyu Wang, Bin Zhang, Yongheng Ren, Jiuhong Chen, Jiabao Gui, Xiufeng Shi, Wenfu Yan, Jinping Li, Libo Li
MOR zeolites synthesized with cost-effective, non-toxic materials enhance ethylene separation without Ag or Cu modification. The customized framework composition improves adsorptive properties economically.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Isostructural chiral metal–organic frameworks with metal-regulated performances for electrochemical enantiomeric recognition of tyrosine and tryptophan

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,2402-2412
DOI: 10.1039/D3QI02662K, Research Article
Ran An, Qiu-Yan Hu, Liu-Yang Song, Xu Zhang, Rui-Xuan Li, En-Qing Gao, Qi Yue
Two isostructural homochiral MOFs exhibit significantly different enantioselective recognition performances closely associated with the different coordination habits of the metal centers in the MOFs.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Selective syntheses of homoleptic Ir(III) complexes bearing di-CF3-functionalized benzoimidazol-2-ylidenes for generation of blue phosphorescence

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,2413-2426
DOI: 10.1039/D4QI00454J, Research Article
Open Access
Jie Yan, Yi Pan, I-Che Peng, Wen-Yi Hung, Bingjie Hu, Guowei Ni, Shek-Man Yiu, Yun Chi, Kai Chung Lau
Di-CF3-functionalized benzo[d]imidazol-3-ium pro-chelates were employed in the selective syntheses of fac-coordinated Ir(III) carbene emitters for efficient blue electroluminescence and hyperphosphorescence.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Bulk single crystal growth and optoelectronic properties of the quasi-two-dimensional perovskites (CH3NH3)3Bi2X9 (X− = Br− and I−)

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,2442-2456
DOI: 10.1039/D3QI02687F, Research Article
Zhiyuan Li, Xiangjun Wang, Peng Zhao, Jingquan Liu, Xiangxin Tian
Single crystals of MA3Bi2X9 (X = Br, I) with quasi-two-dimensional structures were successfully grown and the relationship between the compositions, dimensionality, and properties were discussed.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Ultrathin 2D–2D NiFe LDH/MOF heterojunction nanosheets: an efficient oxygen evolution reaction catalyst for water oxidation

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,2489-2497
DOI: 10.1039/D4QI00090K, Research Article
Haoran Yin, Shibiao Su, Di Yao, Lixia Wang, Xinqiang Liu, Tayirjan Taylor Isimjan, Xiulin Yang, Dandan Cai
An ultrathin NiFe LDH/MOF catalyst is grown on carbon paper by an in situ self-dissociation–assembly strategy. Studies reveal that the strong electronic interaction between Fe and Ni species with rich active sites results in good OER and OWS performance.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Electrochemical conversion of 5-hydroxymethylfurfural over CuNi bimetallic catalysts: the synergistic effect of interfacial active sites

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,2479-2488
DOI: 10.1039/D4QI00145A, Research Article
Yiwei Zhao, Chao Zhang, Shuangxi Xing, Zuhang Jin, Tingting Xiao
ECO of HMF to FDCA and ECR to BHMF with high yield have been studied on CuNi-based bimetallic catalysts. The presence of the Cu–O–Ni interfacial area was beneficial for promoting the catalytic performance in ECO.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

sp2–sp cross-carbanion coupling at a rare-earth center leading to the formation of carbon–carbon double bonds

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,2312-2318
DOI: 10.1039/D4QI00178H, Research Article
Zhengqi Chai, Ze-Jie Lv, Wei Liu, Jinxiao Yang, Junnian Wei, Wen-Xiong Zhang
The reaction of rare-earth azametallacyclopentadienes with terminal alkynes provides rare-earth metallacycles with cumulated double bonds in three steps: alkynyl C–H bond activation, sp2–sp cross-carbanion coupling and subsequent isomerization.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Competition mechanism of self-trapped excitons and Te4+ ions emission in the Te4+ doped vacancy-ordered double perovskite Rb2HfCl6 and its excellent properties

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,2457-2470
DOI: 10.1039/D4QI00109E, Research Article
Ruxin Liu, Kaishun Zou, Guanglu Zhang, Min Feng, Mingxuan Li, Juncheng Liu
The luminescence mechanism of Te4+-doped VODPs is reported. Te4+-doped Hf-based VODPs exhibit luminescence characteristics that are more in line with those of Te4+ ions, while Te4+-doped Sn- and Zr-based VODPs have STEs emission characteristics.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Effect of -OH on the Thermal Enhancement Properties of NIR-II Lanthanide Doped Nanoparticles in Water

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00147H, Research Article
Yingping Huang, Jie Hu, Yongwei Guo, Zihao Wang, Fulin Lin, Haomiao Zhu
Thermal enhanced nanothermometry has attracted great attention due to its high thermal sensitivity, however, most of studies are focused on the upconversion nanoparticles (NPs) in forms of powder. In the...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Efficient photocatalytic hydrogen evolution of g-C3N4/Vs-SnS2/CdS through a sulfur vacancy-rich SnS2 induced charge storage effect

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00602J, Research Article
Fangyuan Xing, Junyan Li, Chengzhi Wang, Shaohua Jin, Haibo Jin, Jingbo Li
Photocatalytic hydrogen production using semiconductors is one of the most promising routes for sustainable energy production.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Chelating Coordination Modulation Method for the Synthesis of Ti-MOF Single Crystals

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00436A, Research Article
Hui-Zi Li, Shangda Li, Fei Wang, Jian Zhang
Despite titanium-based metal-organic frameworks (Ti-MOFs) are promising as efficient photocatalysts, the high reactivity of titanium ions makes the synthesis and structure determination of new Ti-MOFs quite challenging. In this study,...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

A wheel-like polyoxometalate for haloperoxidase inspired antibiofouling with H2O2 in-situ provided by electrocatalysis

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00482E, Research Article
Yumeng Bian, Runze Wang, xinxin xu, Jin Chen, Qiang Wang
Biofouling is adhering of micro-organisms on submerged surfaces, which is a common phenomenon presents serious hazard to industry and public health. Nanozymes with haloperoxidase mimic activity are promising options to...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Radiochromic Semiconductive MOF with High Sensitivity and Fast Photochromic Response for Dual-mode X-ray Direct Detection

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00771A, Research Article
Xuying Yu, Jia-Rong Mi, Qiu-Pei Qin, Xin-Ping Fang, Yong-Fang Han, Li-Zhen Cai, Ming-Sheng Wang, Guo-Cong Guo
X-ray direct detectors, which may directly convert X-rays into electrical signals through semiconductors, are highly desirable for early cancer screening and other applications. Prevailing commercial amorphous Se detectors still suffer...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Large enhancement of electrochemical biomass oxidation by optimizing the competitive adsorption of HMF and OH− on doped CoOx

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00519H, Research Article
Tianqi Nie, Guihao Liu, Ziheng Song, Tianyang Shen, Xiaoliang Sun, Tianrui Yu, Sha Bai, Lirong Zheng, Yu-Fei Song
By doping transition metals into CoOx, we can regulate the deintercalation capacity of OH−. The CoCuOx with enriched oxygen vacancies allowed the optimization of the competitive adsorption between HMF and OH−, and accelerated the kinetics of HMFOR.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Disruption of lipid metabolism to induce ferroptosis using multifunctional fibrate-Pt(IV) prodrugs for cancer treatment

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00386A, Research Article
Peng Sun, Jia-Qian Wang, Qiang Xie, Xuan-Lin Ren, Xin Qiao, Jing-Yuan Xu
Two multifunctional fibrate-Pt(IV) prodrugs, 1 and 3, bearing lipid-modulating agents, exhibited impressive anticancer activity by triggering ferroptosis and apoptosis.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Post-synthetic modification of a covalent organic framework via a thiol–ene reaction for improving fluorescence detection and removal of cationic crystal violet carcinogenic dye

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00419A, Research Article
Ke Li, Bing Yan
Based on a thiol–ene reaction, a covalent organic framework containing olefins (COF-A) is modified with 2-mercaptoacetic acid to prepare COF-S-COOH for the first time, which greatly improves the sensing and adsorption capacity for crystal violet.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Incorporation of One-Dimensional Electron-Rich Chain in Viologen-based Coordination Polymers for Super Photochromic Properties and Improved Optical Applications in Polyvinyl Alcohol Film

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00200H, Research Article
Yong-Sheng Shi, Tong Xiao, Dong-Dong Yang, Xiangjun Zheng
A viologen derivative- and a carboxylic acid -based one-dimensional (1D) cocrystal Zn(Ⅱ) coordination polymer, {[Zn(bcbpy)2][Zn(sip)Cl]·4H2O}n (1, bcbpy = 1,1'-bis (3-carboxybenzyl)-4,4'-bipyridinium, sip = 5-Sulfoisophthalate) has been produced solvothermally and structurally characterized....
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

of

Insights into the modulation mechanisms of multiple active sites in a conjugated small molecule towards organic cathode capacity from first-principles

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00547C, Research Article
Zhaopeng Sun, Hao Tian, Meng Zhang, Yi Zhang, Zhiping Li, Weiwei Huang
The modulation mechanisms of Na+ within the redox-active sites of the two-dimensional conjugated organic small-molecule 3BQ, and their impact on the initial capacity of a 3BQ cathode for Na-ion batteries, were investigated using first-principles calculations.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article