the

And then there was power in Valley

Electrification has finally brought cheer to remote villages in the Kashmir Valley




the

From village fairs to the Internet

The pandemic has made traditional performers and artisans take to digital platforms




the

The blackboard must beckon

Covid impact: Mental health issues and children dropping out of school must be tackled urgently




the

Looms that dispel the Covid gloom

Despite the isolating pandemic, Manipur’s women strive to weave small success stories




the

‘Mentor Mothers’ raise the bar on nutrition and health

How tribal women in Chhattisgarh, Madhya Pradesh and Odisha are unlearning myths about food




the

Let the village be the forest keeper

A project in Himachal Pradesh aims to promote community involvement and sustainability at the grassroots level




the

Pedagogy despite the pandemic

How children without access to online education in Jharkhand and Bihar villages get their lessons




the

Let there be husk and light

Uninterrupted micro-grid power helped villagers in West Champaran sustain business during Covid-19




the

Craft grows more shoots at the grassroots

Women artisans start their own producer companies to shape lifestyle products




the

Israeli Strikes Kill 46 People In The Gaza Strip And 33 In Lebanon, Medics Say

In Lebanon, large explosions shook Beirut's southern suburbs — an area known as Dahiyeh, where Hezbollah has a significant presence — soon after the Israeli military issued evacuation warnings for 11 houses there.




the

Influence of polyol impurities on the transesterification kinetics, molecular structures and properties of isosorbide polycarbonate

Polym. Chem., 2024, 15,4204-4220
DOI: 10.1039/D4PY00840E, Paper
Mingfa Guo, Yaning Wang, Zhenguang Li, Jielin Xu, Qian Chen, Jing Wu, Huaping Wang
A so-called “reverse-addition” model protocol based on two kinds of polyol impurities (glycerol and 2-deoxy-D-ribose) was established to systematically demonstrate their influence on the polymerization and properties of PIC.
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the

The synthesis of tetraarylethylene-based conjugated polymers for the application of fluorescence sensing towards nitroaromatics

Polym. Chem., 2024, 15,4221-4230
DOI: 10.1039/D4PY00821A, Paper
Rentuya Wu, Xiaosong Sun, Wenyue Dong, Yanwei Li, Qian Duan, Teng Fei
Two tetraarylethylene-based conjugated polymers were synthesized and they exhibit high sensitivity and selectivity towards 2,4,6-trinitrophenol sensing.
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the

Versatile poly(N-vinylcaprolactam)-grafted-hydroxypropyl cellulose polymers with tailored thermo- and pH-responsive properties via sustainable organocatalyzed atom transfer radical polymerization

Polym. Chem., 2024, 15,4244-4254
DOI: 10.1039/D4PY00931B, Paper
Muhammad Asif Iqbal, Asif Mahmood, Waheed Al-Masry, Chan Ho Park, Sadaf Ul Hassan, Toheed Akhter
This study explores the synthesis of dual pH- and thermo-responsive poly(N-vinylcaprolactam)-grafted-hydroxypropyl cellulose (PNVCL-g-HPC) polymers via visible-light-driven, metal-free organocatalyzed atom transfer radical polymerization (O-ATRP).
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the

Emerging trends in the chemistry of polymeric resists for extreme ultraviolet lithography

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00957F, Review Article
Jie Cen, Zhengyu Deng, Shiyong Liu
Patterning materials have advanced significantly to achieve high-resolution fabrication of integrated circuits for extreme ultraviolet (EUV) lithography. Emerging trends in the chemistry of polymeric resists for EUV lithography are summarized.
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the

Green perspective drives the renaissance of anionic diene polymerization

Polym. Chem., 2024, 15,4297-4311
DOI: 10.1039/D4PY00805G, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Moritz Rauschenbach, Moritz Meier-Merziger, Holger Frey
Polymers based on 1,3-diene monomers play a pivotal role in many commercial elastomers and thermoplastic elastomers. This review summarizes the state of the art and recent developments in the living anionic polymerization of dienes.
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the

Lewis acid ionic liquid catalysed synthesis of bioderived surfactants from β-pinene

Polym. Chem., 2024, 15,4327-4338
DOI: 10.1039/D4PY00925H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Philippa L. Jacob, Fabricio Machado, Graham A. Rance, Gary Walker, Vincenzo Taresco, Daniel J. Keddie, Steven M. Howdle
Earth abundant catalysis and more sustainable post-polymerisation functionalisation have been applied in the synthesis of β-pinene derived polymeric surfactants.
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the

Synthesis of furan-based conjugated polymers with tunable bandgaps via direct C–H arylation of oligofurans

Polym. Chem., 2024, 15,4339-4348
DOI: 10.1039/D4PY00834K, Paper
Hui Guo, Dayong Jiang, Yufan Gu, Ruixin Wang, Luoyi Wang, Xu-Hui Jin
Using long oligofurans as synthetic building blocks has been found to enable the efficient synthesis of conjugated furan-based polymers through direct C–H arylation, which exhibit excellent antimicrobial activity.
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the

Scalable design of uniform oligourethanes for impact study of chain length, sequence and end groups on thermal properties

Polym. Chem., 2024, 15,4319-4326
DOI: 10.1039/D4PY01001A, Paper
Open Access
Jens Van Hoorde, Nezha Badi, Filip E. Du Prez
A bidirectional growth-based protocol is used for the synthesis of a series of sequence-defined oligourethanes in large scale (50 g). The effect of chain length, sequence and end group functionalities on the thermal properties is evaluated.
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the

Self-healable, reprocessable and anti-flammable eugenol-derived covalent adaptable thermosets based on dynamic covalent boronic esters and thiol–ene click chemistry

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00684D, Paper
Haoxin Niu, Yu Li, Ping Zhang, Wenwen Guo, Xin Wang, Yuan Hu
Self-healable and reprocessable eugenol-derived covalent adaptable thermosets were fabricated via dynamic covalent boronic esters and thiol–ene click chemistry.
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the

The CF3TMS adduct of anthraquinone as a monomer for making polymers with potential as separation membranes

Polym. Chem., 2024, 15,4312-4318
DOI: 10.1039/D4PY01002G, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Kim Jiayi Wu, John M. Tobin, Anli Ji, Yang Shi, Chunchun Ye, Gary S. Nichol, Alessio Fuoco, Mariagiulia Longo, Johannes C. Jansen, Neil B. McKeown
The CF3TMS adduct of anthraquinone reacts with diphenyl ether via a superacid-catalysed step-growth polymerisation to give a polymer (BTFMA-DPE) with promise for making gas separation membranes.
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the

Synthesis of Asymmetric Imine Polymers for Highly Selective Sorting of Semiconducting Single-Walled Carbon Nanotubes by Two in One Strategy

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00607K, Paper
Ying Zhang, Yu Li, Yuchi Wan, Jun-Hao Wang, Yunzhen Chang, Sheng Zhu, Lan Bai, Yu Cao, Xuelei Liang, Gaoyi Han
By two in one strategy, we get three polymers of fluorene derivative with asymmetric structure functionalized with two types of arenes with different orientation and electronic properties. The polymers are...
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the

An efficient and economical degradation strategy for epoxy thermoset based on low cost transesterification catalyst

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY01137F, Paper
Zhijun Yang, Shuhan Zhang, Huan Liang, Enjian He, Yixuan Wang, Ting Lei, Zhicheng Wu, Qiulin Chen, Fusheng Zhou, Yen Wei, Yan Ji
Epoxy thermoset materials are widely used in the field of electrical engineering, including gas-insulated enclosed switches and drytype transformers. It is a challenge to degrade and recycle traditional epoxy thermoset,...
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the

Functionalization of nano-objects in living anionic polymerization-induced self-assembly and their use for improving thermal properties of epoxy resins

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY01008F, Paper
Guicun Guo, Jiali Wu, Jingwei Zhang, Peng Zhou, Ding Shen, Penghan Li, Guowei Wang
Using LAPISA or LAPICA, stabilized PDVB@(PI-b-PS) and PDVB@(PI-b-PS/PS) nano-objects were prepared, functionalized and used as additives for epoxy resin, providing improved Tgs, integrated interfaces, uniform distributions, and scalable applications.
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the

Control over membrane fluidity and biophysical properties of synthetic terpolymer stabilized complex coacervates

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00978A, Paper
Open Access
Sebastian Novosedlik, Alexander B. Cook, Tim J. F. M. Voermans, Henk M. Janssen, Jan C. M. van Hest
Cell membranes are vital barriers that regulate the composition of the intracellular environment and facilitate communication processes essential for cellular function and survival.
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the

[Ru]-Catalyzed Olefin Metathesis and Ethenolysis for the Synthesis and Recycling of Bio-Based Polycarbonates and Polycyanurates

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00940A, Paper
Dana M. Pinson, Francesca D. Eckstrom, Gregory S. Ostrom, K. Randall McClain, Lawrence Baldwin, Benjamin Grant Harvey
Eugenol, an abundant, naturally occurring phenolic compound, was converted into a thermoplastic polycarbonate by olefin metathesis followed by interfacial polymerization with triphosghene. This resulted in polymers with Mn ranging from...
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the

Expanding the poly(2-oxazoline) block copolymer possibilities through nitroxide mediated polymerisation

Polym. Chem., 2024, 15,4416-4424
DOI: 10.1039/D4PY00887A, Paper
Open Access
James Lefley, C. Remzi Becer
In recent years, poly(2-oxazoline)s (POx) have become a sought-after biomaterial to replace PEG. Endcapping POx with BlocBuilder MA enables copolymerization with a variety of vinylic monomers, producing unique POx-vinyl block copolymer combinations.
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the

A novel amine-first strategy suitable for preparing both functional and engineering bio-polyamides: furfurylamine as the sole furan source for bisfuranic diamine/diacid monomers

Polym. Chem., 2024, 15,4433-4446
DOI: 10.1039/D4PY00567H, Paper
Hong-Hui Shu, Yun Liu, Sheng-Li Han, Xiu-Qin Fang, Chang Wang, Cheng-Mei Liu
Biomass-based polyamides (bioPAs) are renewable materials that are viable alternatives to petroleum-based polyamides in the engineering field.
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the

Enhanced mechanical properties of acrylate and 5-vinyl-2-norbornene-based ethylene terpolymers: rational design and synthesis using remotely modulated phosphine–sulfonate palladium complexes

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00722K, Paper
Yong-Qing Li, Gui-Ping Cao, Yu-Cai Cao
From a practical perspective, it is important to maintain or increase the mechanical properties of functional ethylene copolymers to those of nonpolar polyethylene (PE).
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the

Bisbenzothieno[b]-fused BODIPYs in panchromatic photoinitiating for the free radical and cationic photopolymerization and application in 3D printing

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00926F, Paper
Yangyang Xu, Wenlong Tang, Hui Deng, Jianjun Zhang, Zhongquan Zhu, Changjiang Yu, Haiguang Zhu, Ke Sun, Jiazhu Li, Jacques Lalevée
Abstract: Polymerization reactions induced by lights occupy an increasing share in the area of polymer synthesis; however, the effective photopolymerization under visible light emitting diodes (LEDs) rather than UV still...
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the

Fully Bio-Based Acetal Diepoxy Monomers: High Modulus, Good Thermal Stability and Readily Degradability

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY01038H, Paper
Zidie Song, Li Liu, Pengbo Zhang, Kangle Xue, Zibo Hua, Tao You, Yiqi Wu, Hong Cui, Zhen Hu, Yudong Huang
Degradable epoxy resins are designed to address the environmental pollution caused by traditional epoxy resins. However, incorporating the degradability of dynamic covalent bonds in the design of degradable resins often...
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the

Mesomorphic and photochromic luminescent behaviour of side-chain liquid crystalline polymers containing di-substituted cyanostilbene groups with the different number of alkyl tail chain

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00889H, Paper
Juan Luo, Juan Wang, Junde Zhang, Huizi Cao, Xiaofang Chen
In this work, side-chain luminescent liquid crystalline polymers (SCLLCPs) that contain di-substituted cyanostilbene (CS) groups with the different substituted number of terminal alkyl chain, which are PNB-Z-4, PNB-Z-34, and PNB-Z-345,...
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the

Diversified synthesis of poly(sulfonyl isourea)s by multicomponent polymerizations of isocyanides, sulfonyl azides, and alcohols/phenols

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00953C, Paper
Dongyang Fan, Fenggang Chen, Dong Wang, Ting Han, Ben Zhong Tang
A novel multicomponent polymerization strategy using diverse monomer combinations of isocyanides, sulfonyl azides, and alcohols/phenols was developed to synthesize thermally and morphologically stable and heteroatom-rich poly(sulfonyl isourea)s.
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the

Reducing Agent Triggered Templated Synthesis of Dynamic Covalent Poly(disulfide)s Nanonetwork: Remarkable Tuning in Noncovalent Encapsulation Stabilities and Cargo Release

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY01109K, Paper
Arun Mondal, S. K. Sujauddin, Dhiman Mondal, Soumya Kolay, Shuvajyoti Sarkar, Mijanur Rahaman Molla
Here, we demonstrated a new methodology for the templated synthesis of cross-linked poly(disulfide)s based dynamic covalent nanonetwork as highly stable potential delivery vehicle in the field of chemotherapeutic applications. The...
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the

Axial-phenyl Constrained Bis(imino)acenaphthene-Nickel Precatalysts Enhancing Ethylene Polymerization

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY01110D, Paper
Quanchao Wang, Qiuyue Zhang, Yizhou Wang, Song Zou, Yanping Ma, Tongling Liang, Wen Hua Sun
To enhance the performance of the bis(imino)acenaphthene-nickel precatalyst, the axial phenyl group is introduced on the acenaphthenyl backbone forming five analogues, bis(aryl)imino-5-phenylacenaphthene nickel bromides (aryl: 2,6-dimethylphenyl, Ni1; 2,6-diethylphenyl, Ni2; 2,6-diisopropylphenyl,...
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the

Synthesis of degradable polyester with high molecular weight and excellent mechanical properties through copolymerization modification of poly(butylene succinate)

Polym. Chem., 2024, 15,4570-4579
DOI: 10.1039/D4PY01050G, Paper
Hongji Wang, Xiaojun Ma, Hanyu Yao, Haohao Chang, Yin Lv, Zhong Wei
The degradable copolymer of polybutylene succinate (PBS) modified with tricyclodecane dimethanol (TCD) presented significantly enhanced tensile strength and elongation at break.
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the

Dibenzobarrelene-Derived Pd-NHCs: Efficient Precatalysts for the Suzuki-Miyaura Polycondensations of Dichloroarenes Monomers

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY01026D, Paper
Yuman Guo, Hao Wu, Meng-Jiao Zhang, Feng-Shou Liu
The Pd-catalyzed Suzuki-Miyaura polycondensations (SMPs) has emerged as a powerful method for synthesizing conjugated polymers (CPs). While numerous reports have utilized dibromoarene and diiodoarene derivatives as monomers, research on the...
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the

Crystallization ripening and erosion of calcium oxalate under the effect of bacteria and a polymer materials surface

J. Mater. Chem. B, 2024, 12,10893-10901
DOI: 10.1039/D4TB01780C, Paper
Xiran Shen, Wentao Chen, Li Guo, Huayu Li, Hong Chen, Fan Liu
New insights into the role of bacteria in pathological biomineralization inspire novel anti-encrustation polymer material design for biomedical use.
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the

Phase-separated structures of tunable thermoresponsive and matrix polymers for large-scale temperature monitoring coatings

J. Mater. Chem. B, 2024, 12,10886-10892
DOI: 10.1039/D4TB01743A, Paper
Risako Shibata, Satoru Matsuda, Hirofumi Kawakubo, Hiroaki Imai, Yuya Oaki
Layered polydiacetylene (PDA) exhibits a thermoresponsive color change. The thermoresponsivity and large-scale coatability are controlled for medical applications by the intercalated guests and matrix polymer, respectively.
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the

Mitigating intubation stress, mucosa injury, and inflammatory response in nasogastric tube intubation via suppression of the NF-κB signaling pathway by engineering a hydration lubrication coating

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01171F, Paper
Xi Liao, Meng-Han Bai, Yu-Wei Liu, Yu-Qing Wei, Jun-Yang Wang, Zhi-Guo Wang, Rui Hong, Ju-Xiang Gou, Jia-Zhuang Xu, Zhong-Ming Li, Ka Li
The hydrated micelle coating, composed of hyaluronic acid and Pluronic, demonstrated superior hydrophilicity and aqueous lubricity to effectively alleviate mucosal lesions and inflammation caused by NGT insertion.
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the

Decellularization of caprine forestomach rumen tissue modified with silver nanowires as an antibacterial skin substitute scaffold in wound care therapeutics

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01560F, Paper
Athmana P. A., Asna Jaleel K. I., Sinduja Malarkodi Elangovan, Riza Paul, Naveen Subbaiyan, Parthiban Shanmugam, Gopal Shankar Krishnakumar
Caprine forestomach native collagen (CFNC) modified with silver nanowires (AgNWs) as a new class of biomimetic xenograft for skin regeneration with strong antimicrobial properties.
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the

Cell-specific spatial profiling of targeted protein expression to characterize the impact of intracortical microelectrode implantation on neuronal health

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01628A, Paper
Open Access
Lindsey N. Druschel, Niveda M. Kasthuri, Sydney S. Song, Jaime J. Wang, Allison Hess-Dunning, E. Ricky Chan, Jeffrey R. Capadona
Multiplex immunochemistry for proteins examining neuronal structure or function in NeuN+ regions adjacent intracortical microelectrodes (MEA) more closely matched historic intracortical MEA recording performance than traditional IHC quantification.
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the

Porous helical supramolecular columns self-organized via the fluorophobic effect of a semifluorinated tapered dendron

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01951B, Paper
Open Access
Dipankar Sahoo, Mihai Peterca, Mohammad R. Imam, Devendra S. Maurya, Virgil Percec
Fluorophobic effect enhances supramolecular microsegregation.
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the

Expression of concern: Surface modification engineering of two-dimensional titanium carbide for efficient synergistic multitherapy of breast cancer

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB90175D, Expression of Concern
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lei Bai, Wenhui Yi, Taiyang Sun, Yilong Tian, Ping Zhang, Jinhai Si, Xun Hou, Jin Hou
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the

Recent Advances of Versatile Fluorophores for Multifunctional Biomedical Imaging in the NIR-II Region

J. Mater. Chem. B, 2024, Accepted Manuscript
DOI: 10.1039/D4TB01957A, Review Article
Kaiming Ma, Qunying Jiang, Yang Yang, Fan Zhang
Fluorescence imaging in the second near-infrared region (NIR-II, 1,000-1,700 nm) enables high-resolution visualization of deep-tissue biological architecture and physiopathological events, due to the reduced light absorption, scattering and tissue autofluorescence....
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the

Efficient bionic nanozyme based on AuPt NPs@ZIF-90 used for cyclic catalysis multimodal tumor therapy

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01987C, Paper
Wan Huang, Song Zhang, Li Luo, Yalong Pan, Lijun Han, Yao Yu
Novel efficient bionic nanozyme based on AuPt NPs@ZIF-90 used for cyclic catalysis multimodal tumor therapy.
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the

Tuning the affinity of probes with transmembrane proteins by constructing peptide-conjugated cis/trans isomers based on molecular scaffolds

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01801J, Paper
Jing-Jing Hu, Juliang Yang, Yiheng Liu, Guangwen Lu, Zujin Zhao, Fan Xia, Xiaoding Lou
Peptide-conjugated cis/trans isomers were designed. cis-RTP interacts more stably with cell membranes than trans-RTP, and it has shown more excellent properties in inhibiting cell migration and killing cells.
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the

Electronic band structure modulation for sonodynamic therapy

J. Mater. Chem. B, 2024, Accepted Manuscript
DOI: 10.1039/D4TB01679C, Review Article
Yafang Shi, Chengzhilin Li, Linquan Li, Qingbin He, Qingyi Zhu, Ziang Xu, Yanzi Liu, Nianlei Zhang, Meng Zhang, Jianwei Jiao, Runxiao Zheng
Sonodynamic therapy (SDT) is a burgeoning and newfangled therapy modality with great application potential. Sonosensitizers are most essential factors to ensure the effectiveness of SDT. For the past few years,...
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the

Multi-scale in silico analysis of the phase separation behavior of FUS mutants

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01512F, Paper
Kalindu S. Fernando, Ying Chau
The computational model predicts the aggregation propensity of intrinsically disordered proteins and their mutants efficiently.
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the

Reconfiguring the endogenous electric field of a wound through a conductive hydrogel for effective exudate management to enhance skin wound healing

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01349B, Communication
Yukun Yan, Yuanyuan Chen, Hanqing Dai, Wanlu Zhang, Ruiqian Guo
In this work, we proposed a mechanism for hydrogel-based dressings to respond to endogenous electric fields through exudate absorption and conducted a verification study using polyacrylamide and sodium alginate (PAM–SA) hydrogels.
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the

Photoresponsive prodrug-based liposomes for controllable release of the anticancer drug chlorambucil

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01620C, Paper
Xiaoting Wang, Guangtian Suo, Shinan Ma, Chunxi Yang, Chunyan Bao
A photoresponsive lipid prodrug was designed to form nanomedicines for accurate and controllable drug release in response to light irradiation.
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