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The values that Silicon Valley brings to the table

By www.thehindubusinessline.com
Published On :: Sun, 24 Mar 2024 21:26:00 +0530

What would it take for the Indian start-up ecosystem to match the calibre of Silicon Valley


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Venture capital: On the trail of buying power

By www.thehindubusinessline.com
Published On :: Sun, 05 May 2024 20:49:00 +0530

Why VC firm Elevation Capital chooses to stay invested in consumer brands


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Digital detox for hallucinating chatbots and other AI fails

By www.thehindubusinessline.com
Published On :: Sun, 05 May 2024 21:25:00 +0530

Bengaluru start-up’s automated platform detects and fixes machine learning gone wrong


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These ‘docs’ keep solar assets fit as a fiddle

By www.thehindubusinessline.com
Published On :: Sun, 19 May 2024 20:40:00 +0530

Chennai start-up’s drone-based imaging service helps build, maintain defect-free solar plants


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Women entrepreneurs and the fear of failure

By www.thehindubusinessline.com
Published On :: Sun, 19 May 2024 20:43:00 +0530

The many ways in which women entrepreneurs are at a disadvantage compared to male peers


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Fund thesis: AI is the X-factor 

By www.thehindubusinessline.com
Published On :: Sun, 19 May 2024 21:01:00 +0530

Why VC firm Good Capital wants to be an early investor in AI-powered businesses


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SaaS: The clouds with the silver lining

By www.thehindubusinessline.com
Published On :: Sun, 02 Jun 2024 20:51:00 +0530

How software-as-a-service thrives in India even amid a downturn in the country’s start-up ecosystem


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Hovering fighters birthed in Bengaluru

By www.thehindubusinessline.com
Published On :: Sun, 02 Jun 2024 21:27:00 +0530

Start-up Zulu Defence manufactures drones geared for deployment in warfare


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Don’t let business come in the way of internal processes 

By www.thehindubusinessline.com
Published On :: Sun, 16 Jun 2024 20:26:00 +0530

Key reasons why process implementation in companies, especially startups, is delayed or dropped altogether


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Fostering the digital adoption drive in India

By www.thehindubusinessline.com
Published On :: Sun, 16 Jun 2024 20:57:00 +0530

Why 8i Ventures backs startups that are digitising the economy


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Not everyone is cut out for the entrepreneurial life

By www.thehindubusinessline.com
Published On :: Sun, 30 Jun 2024 20:49:00 +0530

Why it’s important to consider personal and family backgrounds before jumping into entrepreneurship


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How startups are expanding the EV charging network

By www.thehindubusinessline.com
Published On :: Sun, 30 Jun 2024 20:57:00 +0530

With generous funding, a host of newbie companies are revving up the expansion of the country’s EV charging network


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A budget that chose to be on the side of the angels

By www.thehindubusinessline.com
Published On :: Sun, 28 Jul 2024 20:33:00 +0530

Why the nixing of angel tax can prove a game changer for job creation in India


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A ‘PA on steroids’ for the richie-rich

By www.thehindubusinessline.com
Published On :: Sun, 28 Jul 2024 21:25:00 +0530

Concierge service startup Indulge Global sells convenience to Indians who crave the luxe life


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The unfortunate truth about ‘pedigree’ and the founder ecosystem

By www.thehindubusinessline.com
Published On :: Sun, 25 Aug 2024 21:03:00 +0530

How old school ties do matter in the Indian startup system, and why that’s a problem


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Chasing the most meaningful outcome of entrepreneurship

By www.thehindubusinessline.com
Published On :: Sun, 15 Sep 2024 20:33:00 +0530

Are there any metrics to decide if a founder is successful or not?


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The synthesis of specifically isotope labelled fluorotryptophan and its use in mammalian cell-based protein expression for 19F-NMR applications

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04789C, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Giorgia Toscano, Martina Rosati, Letizia Barbieri, Katharina Maier, Lucia Banci, Enrico Luchinat, Robert Konrat, Roman J. Lichtenecker
Combining multistep organic synthesis with mammalian cell based protein overexpression leads to isolated 13C–19F spin systems in tryptophan side chains, which represent ideal sensors to probe protein interaction and dynamics using NMR spectroscopy.
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Loss of fluorine during crosslinking by the biarylitide P450Blt proceeds due to restricted peptide orientation

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04092A, Communication
Yongwei Zhao, Jemma Gullick, Mathias H. Hansen, Laura Coe, Maxine Treisman, Ralf B. Schittenhelm, Alasdair McKay, Lauren A. M. Murray, Julien Tailhades, James J. De Voss, Elizabeth H. Krenske, Max J. Cryle
Crosslinking of the ribosomal peptide by Cytochrome P450Blt leads to the formation of a C–N bond with specific loss of fluorine during the reaction.
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Synthesis of environmentally friendly energetic cocrystal derived from commodity chemicals

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04037F, Communication
Open Access
Kazuki Inoue, Yosuke Nishiwaki, Mieko Kumasaki, Shinya Matsumoto, Ken Okada
Ammonium nitrate/glycine (2 : 1) energetic cocrystal was synthesized to address two drawbacks of ammonium nitrate: phase transitions and hygroscopicity. The cocrystal did not show phase transitions and exhibited decreased hygroscopicity.
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Synthesis of heteroleptic bis-phosphine bis-NHC iron (0) complexes: a strategy to enhance small molecule activation

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05463F, Communication
Open Access
Christian M. Andre, Nathaniel K. Szymczak
We report low-valent iron complexes containing bis-NHC and bis-phosphine donor ligands that coordinate and strongly activate N2 and CO.
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What could be the low-temperature limit of atomic layer deposition of platinum using MeCpPtMe3 and oxygen?

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04679J, Communication
Hao Van Bui, Anh Phan Nguyen, Manh Duc Dang, Truong Duc Dinh, Patricia J. Kooyman, J. Ruud Van Ommen
Room-temperature atmospheric-pressure ALD enables the deposition of highly dispersed Pt sub-nanometer clusters on a gram-scale quantity of TiO2 nanopowder.
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Bidirectional strain release in a thermosalient organic salt crystal induced by anisotropic thermal expansion and phase transformation

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04764H, Communication
Priyasha Harsha, Dinabandhu Das
Two-way release of strain followed by jumping in an organic salt crystal can be attributed to the anisotropic thermal expansion by heating and phase transformation followed by shear deformation of the crystals by cooling.
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Alkenylation of unactivated alkanes: synthesis of Z-alkenes via dual Co-TBADT catalysis

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Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04651J, Communication
Vetrivelan Murugesan, Anagha Syam, Guru Vigknesh Anantharaj, Ramesh Rasappan
Hydroalkylation of terminal alkynes using unactivated alkanes under dual Co-TBADT catalysts is reported. Our cobalt-HAT catalysis achieves the desired Z alkene with excellent regio- and diastereoselectivity via C–H activation.
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Exploring the effect of pressure on the crystal structure and caloric properties of the molecular ionic hybrid [(CH3)3NOH]2[CoCl4]

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05125D, Communication
Open Access
Pedro Dafonte-Rodríguez, Ignacio Delgado-Ferreiro, Javier García-Ben, Angel Ferradanes-Martínez, María Gelpi, Julian Walker, Charles James McMonagle, Socorro Castro-García, María Antonia Señarís-Rodríguez, Juan Manuel Bermúdez-García, Manuel Sánchez-Andújar
The hybrid metal halide [(CH3)3NOH]2CoCl4 exhibits a first-order phase transition at T ∼ 343 K.
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Endosomolytic Peptides Enable the Cellular Delivery of Peptide Nucleic Acids

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05214E, Communication
Open Access
JoLynn B. Giancola, Ronald T. Raines
Precision genetic medicine enlists antisense oligonucleotides (ASOs) to bind to nucleic acid targets important for human disease. Peptide nucleic acids (PNAs) have many desirable attributes as ASOs but lack cellular...
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Boosting the electrochemical performance of Ni-rich LiNi0.96Co0.02Mn0.02O2 cathode by high-valence Zr/Mo dual-doping

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04275A, Communication
Hongmei Cao, Yudong Zhang, Xunzhu Zhou, Jie Yu, Xiang Chen, Lin Li
Ni-rich oxides are attractive high-energy cathodes for lithium-ion batteries but suffer from inherent instability. Herein, we employed an ectopic Zr4+/Mo6+ dual-doping strategy to reinforce the layered structure through robust M-O...
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Tunable synthesis of magnetoelectric CoFe2O4–BaTiO3 core–shell nanowires

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC03701D, Communication
Noah D. Ferson, John R. Ganiban, David P. Arnold, Jennifer S. Andrew
CoFe2O4–BaTiO3 core–shell nanowires with tunable magnetic anisotropy and magnetoelectric coupling are generated using a template-assisted synthetic procedure providing composition control.
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Engineering biotin anchored-MWCNTs as a superb carrier for facile delivery of the potent Ru(II)-N^N scaffold in breast cancer cells

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, 60,13376-13379
DOI: 10.1039/D4CC04276J, Communication
Lavanya Thilak Babu, Nilmadhab Roy, Tiasha Dasgupta, Sreejani Ghosh, Ramasamy Tamizhselvi, Priyankar Paira
This article portrays the construction of biotinylated-MWCNTs for SMVT-guided delivery of a potent Ru(II)-scaffold into MCF7 cells.
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Revealing the structural influence mechanism of intrinsic potassium/calcium elements on bio-waste-derived hard carbon for sodium-ion batteries

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, 60,13380-13383
DOI: 10.1039/D4CC03546A, Communication
Yinghao Zhang, Chun Wu, Qinghang Chen, Chuangchuang Li, Wenjie Huang, Qianxiong Wen, Xiang-Xi He, Xingqiao Wu, Shu-Lei Chou
The evolution mechanism of hard carbon structures in terms of graphitization and pore structure caused by K/Ca has been clarified.
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Employing a PhI(OAc)2-mediated domino reaction to assemble nitrogen-containing heterocyclic derivatives and assessing their anti-inflammatory activity

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, 60,13352-13355
DOI: 10.1039/D4CC03245D, Communication
Xinyue Li, Yuhua Fang, Yuanyuan Zhao, Shenshen Luo, Yuhui Xue, Tingting Yong, Bin Wang
Metal-free radical cascade synthesis of substituted pyrazole derivatives was initiated by PhI(OAc)2 at 23 °C.
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A polychloride-enabled synthesis of [NEt3Me][PCl6] serving as a potential PCl3-storage and PCl5-reagent

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, 60,13372-13375
DOI: 10.1039/D4CC04319G, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Moritz J. Ernst, Merlin Kleoff, Patrick Voßnacker, Günther Thiele, Christian Müller, Sebastian Riedel
The reaction of the ionic liquid [NEt3Me][Cl3] with white phosphorus (P4) gives, quantitatively, hexachlorophosphate [NEt3Me][PCl6], which shows similar reactivity as PCl5 and can be used as a potential PCl3-storage material.
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Sb nanoparticles embedded uniformly on the surface of porous carbon fibres for high-efficiency sodium storage

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, 60,13428-13431
DOI: 10.1039/D4CC04806G, Communication
Yafei Zhao, Kai Xue, Xinyu Liu, Zhiyuan Gao, Junhao Zhang, Yuanjun Liu, Xiangjun Zheng, ZhongYao Duan, Qianqian Fan, Xingmei Guo
Sb nanoparticles (∼5 nm) are embedded uniformly on the surface of carbon fibers to prepare Sb NPs–SCFs, which exhibit excellent sodium storage with a stable capacity of 381.9 mA h g−1 at 1.0 A g−1 after 200 cycles, due to their unique structure.
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Pivotal role of starch in restoring the photocatalytic performance of chitosan films for eliminating water pollutants

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Published On ::

Chem. Commun., 2024, 60,13364-13367
DOI: 10.1039/D4CC04759A, Communication
Aman Chauhan, Archana Negi, Kirti, Moondeep Chauhan, Ajeet Kaushik, Ganga Ram Chaudhary
The enhanced adsorption properties of chitosan films after starch impregnation combined with the excellent charge-transfer traits of the CdS@CuS catalyst restore the reduced photocatalytic activity towards ciprofloxacin degradation.
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Solution plasma synthesis of α-amino acids

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Published On ::

Chem. Commun., 2024, 60,13408-13411
DOI: 10.1039/D4CC04482G, Communication
Changhua Wang, Yutong Zhang, Yuanyuan Li, Yinhe Rong, Xintong Zhang
This work uses solution plasma for easier control of amino acid synthesis, successfully producing rare serine, achieving green and low-carbon synthesis from small molecules to amino acids.
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Universal synthesis of pure-phase IB-group Sn-based alloys with modulable electrocatalytic CO2 reduction products

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, 60,13436-13439
DOI: 10.1039/D4CC05317F, Communication
Luyao Yang, Wenqing Zhang, Ximei Lv, Qianqian Zhao, Xiaojing Liu, Shulin Zhao, Yuhui Chen
A universal method for synthesizing a range of pure-phase IB-group Sn-based alloy catalysts (Cu3Sn, Ag4Sn, and AuSn) for electrochemical reduction of CO2.
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Solid-state synthesis of ligand-assisted lead halide nanoclusters

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Published On ::

Chem. Commun., 2024, 60,13396-13399
DOI: 10.1039/D4CC04623D, Communication
David C. Zeitz, Kai-Chun Chou, Jin Z. Zhang
A solid-state synthesis of blue-emitting lead halide nanoclusters has been demonstrated for the first time.
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Atomistic insight into the promising thermoelectric performance of the copper-based ternary phosphide CaCuP

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, 60,13400-13403
DOI: 10.1039/D4CC04660A, Communication
Un-Gi Jong, Chol Ryu, Ji-Min Hwang, Su-Hyang Kim, Il-Gwang Ju, Chol-Jun Yu
We provide a valuable atomistic insight into the thermoelectric properties of hexagonal CaCuP, revealing that nano-structuring can double the thermoelectric figure of merit by further reducing lattice thermal conductivity.
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Enhancing the performance of ionic conductivity for solid-state electrolytes: an effective strategy of injecting lithium ions within anionic metal–organic frameworks

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, 60,13416-13419
DOI: 10.1039/D4CC04515G, Communication
Lu Shi, Xin Wang, Zhiliang Liu
An ionotropic MOF (Li+[Cu-BTC]) with lithium ions in the pores of the lattice was synthesized, which displays outstanding lithium ionic conducting properties over a wide temperature range.
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Bioinspired hydrogels: polymeric designs towards artificial photosynthesis

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, 60,13314-13324
DOI: 10.1039/D4CC04033C, Feature Article
Open Access
Reina Hagiwara, Ryo Yoshida, Kosuke Okeyoshi
This Feature Article outlines the design of polymer networks for water splitting induced by visible light to develop artificial chloroplasts. The network serves as a mediator for photoinduced electron transfer among precisely organised molecules.
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Investigations of the interactions between ZnO nanorods and H2 with 17O NMR spectroscopy

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05371K, Communication
Benteng Song, Fang Wang, Qin Zhu, Ling-Hai Xie, Luming Peng
Schematic diagram for the interaction of H2 with ZnO nanorods under different conditions.
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Intramolecular cyclization of N-aryl amides for the synthesis of 3-amino oxindoles

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Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05259E, Communication
Haitao Yang, Yu Pan, Yijing Tian, Kaili Yu, Yifeng Bai, Yonggang Jiang, Hongbin Zhang, Guogang Deng, Xiaodong Yang
A mild and efficient strategy to synthesize pharmaceutically important 3-amino oxindoles from readily available N-aryl amides has been developed.
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Origin of anisotropic thermal transport in CsPbBr3

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05037A, Communication
Open Access
Wilarachchige D. C. B. Gunatilleke, Oluwagbemiga P. Ojo, George S. Nolas
We reveal the specific structural and bonding features that result in anisotropic thermal transport for CsPbBr3 by directional single-crystal measurements and elucidate the bases for the low Debye temperature and speed of sound.
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Synthesis of substituent-free dioxadiaza[8]circulene to investigate intermolecular interactions and photophysical properties

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Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05539J, Communication
Aoi Nakagawa, Wataru Ota, Takumi Ehara, Yusuke Matsuo, Kiyoshi Miyata, Ken Onda, Tohru Sato, Shu Seki, Takayuki Tanaka
Substituent-free dioxadiaza[8]circulene has been synthesized and its dense packing structure and optical properties were analyzed in detail.
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Ceria-based supported metal catalysts for the low-temperature water-gas shift reaction

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04072D, Feature Article
Xin-Pu Fu, hui zhao, Chun-Jiang Jia
Water-gas shift (WGS) reaction is a crucial step for the industrial production of hydrogen or upgrading hydrogen generated from fossil or biomass sources by removing the residual CO. However, current...
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Base-Promoted Cascade 5-exo-dig Annulation/Carboxylation of o-(1-Alkynyl)benzenesulfonamides with CO2: Divergent Synthesis of Mono- or Gem-dicarboxylic Esters

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05239K, Communication
Yang Yao, Junxue Bai, Peidong Cheng, Han Yang, Jianwei Sun, Song Sun
A base-promoted cascade 5-exo-dig cyclization/carboxylation of o-alkynylsulfamides with CO2 has been accomplished, furnishing a variety of benzosultams-containing acrylates in good yields by using CO2 as the carboxylic source. Notably, in...
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Synthesis of Aryl Fluorocyclopropanes from Aryl Fluorodiazirines and Alkenes in Continuous Flow

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC01881H, Communication
Hoang-Minh To, Shima Mirakhorli, Thierry Ollevier
Photochemically induced generation of aryl fluorocarbene from arylfluorodiazirines and their subsequent [2 + 1] cycloaddition with alkenes was developed in continuous flow. The in situ generated electrophilic aryl fluorocarbene reacted...
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Positional effects of electron-donating and withdrawing groups on the photophysical properties of single benzene fluorophores

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04451G, Communication
Dopil Kim, Jun Yeong Kim, Haein Kim, Eunjin Jeong, Minhyuk Lee, Dongwook Kim, JunWoo Kim, Myung Hwan Park, Min Kim
We investigated how the positional arrangement of electron-donating (amino) and electron-withdrawing (ester) groups in single benzene-based fluorophores influences their emission properties. By synthesizing 26 regioisomeric fluorophores, we achieved wavelength modulation...
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For the love of legiyam

By www.thehindu.com
Published On :: Fri, 28 Oct 2016 16:49:22 +0530

SRINIVASA RAMANUJAM queues up to find out what goes into this Deepavali preparation at the iconic Dabba Chetty Shop in Mylapore


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Karnataka on the antarjaala

By www.thehindu.com
Published On :: Fri, 28 Oct 2016 18:25:33 +0530

An online space for products from small and rural entrepreneurs of Karnataka, Total Karnataka is all set to reach out to the world


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