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Transient IR Spectroscopy of Optically Centrifuged CO2 (R186−R282) and Collision Dynamics for the J=244−282 States

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Faraday Discuss., 2024, Accepted Manuscript
DOI: 10.1039/D3FD00179B, Paper
Open Access
Michael E. Ritter, Simone Alexis DeSouza, Hannah Marie Ogden, Tara J Michael, Amy S Mullin
Collisions of optically centrifuged CO2 molecules with J=244-282 (Erot =22,800-30,300 cm-1) are investigated with high-resolution transient IR absorption spectroscopy to reveal collisional and orientational phenomena of molecules with hyper-thermal rotational...
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Computation-guided engineering of distal mutations in an artificial enzyme

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Faraday Discuss., 2024, Accepted Manuscript
DOI: 10.1039/D4FD00069B, Paper
Open Access
Fabrizio Casilli, Miquel Canyelles-Niño, Gerard Roelfes, Lur Alonso-Cotchico
Artificial enzymes are valuable biocatalysts able to perform new-to-nature transformations with the precision and (enantio-)selectivity of natural enzymes. Although being highly engineered biocatalysts, they often cannot reach catalytic rates akin...
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MOF-derived Co–Mo bimetallic heterostructures for the selective trapping and conversion of polysulfides in lithium–sulfur batteries

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01249F, Research Article
Rongmei Zhu, Yuxuan Jiang, Bingxin Sun, Wang Zhang, Huan Pang
Hollow CoSx/MoO3 derived from ZIF-67 shows preferred selective trapping and conversion of LiPSs as a modified separator material for LSBs.
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A solvent-free neutral cobalt complex exhibiting macroscopic polarization switching induced by directional charge transfer

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01389A, Research Article
Zi-Qi Zhou, Shu-Qi Wu, Qi-Rui Shui, Wen-Wei Zheng, Akari Maeda, Xiao-Peng Zhang, Jing Chu, Shinji Kanegawa, Sheng-Qun Su, Osamu Sato
A solvent-free neutral cobalt complex featuring a non-centrosymmetric polar structure exhibits macroscopic polarization switching induced by charge transfer.
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ZnIn2S4 nanosheets with tunable dual vacancies for efficient sacrificial-agent-free H2O2 photosynthesis

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02030H, Research Article
Chen Zhang, Gao Xu, Qifeng Liang, Li Liang, Zebo Fang, Rong Wu, Shunhang Wei, Lei Wang, Xiaoxiang Xu
ZnIn2S4 nanosheets with tunable concentration of dual vacancies were prepared. Introducing dual vacancies effectively promotes photocarrier separation, facilitates O2 adsorption, and inhibits H2O2 decomposition by increasing hydrophilicity.
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Superior energy storage performance with a record high breakdown strength in bulk Ba0.85Ca0.15Zr0.1Ti0.9O3-based lead-free ceramics via multiple synergistic strategies

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02126F, Research Article
Changhao Wang, Jiaxi Hao, Longxiao Duan, Jianfan Zhang, Wenfeng Yue, Zhenhao Fan, Dandan Han, Raz Muhammad, Fanxu Meng, Dawei Wang
A composition and structure optimization strategy combined with a two-step sintering (TSS) process is proposed to design and fabricate (1−x)Ba0.85Ca0.15Zr0.1Ti0.9O3−xBi(Mg1/2Sn1/2)O3 (BCZT-BMSx-TSS) lead-free ceramics.
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Near-infrared-II photothermal conversion and magnetic dynamic regulation in [Ln3Rad2] aggregation by rigidity modification of nitronyl nitroxide

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01952K, Research Article
Hongdao Li, Chaoyi Jin, Jing Han, Jianke Tang, Xiaofeng Han, Zhenjun Song
Nitronyl nitroxide in Ln(III) multi-spin clusters has been utilized for realizing the regulation of NIR-II photothermal conversion and magnetic dynamics.
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Water-stable zero-dimensional hybrid zinc halide modulated by π–π interactions: efficient blue light emission and third-order nonlinear optical response

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02194K, Research Article
Jia-Wei Li, Wenke Dong, Yanjie Liu, Yuhan Li, Lu-Yuan Qiao, Guang-Lu Liu, Hui Zhang, Chunjie Wang, Hui-Li Zheng, Jian-Qiang Zhao
Waterproof 0D hybrid Zn halide with highly efficient blue emission and third-order nonlinear optical response was constructed by the microregulating of π–π interactions, offering new insights for designing stable multifunctional halide materials.
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Significant adsorption enhancements driven by pore microenvironment tuning for efficient C2H2/C2H4 separation in a chemically stable Ni7-cluster-based framework

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01856G, Research Article
Yunli Wang, Rizhao Zhang, Jin-Peng Xue, Yuqiao Chai, Bao Li, Jia Li
This study presents a stable Ni7-cluster MOF with enhanced adsorption through pore microenvironment tuning. Two types of guest-free frameworks achieve C2H2/C2H4 separation, providing deep insights into separation mechanisms.
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Achieving high power density and stability in aqueous Mg–air batteries using taurine electrolyte additives

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01842G, Research Article
Sha Jianchun, Wang Qiang, Li Xue, Liu Zhoulin, Bao Jiaxin, Li Lianhui, Tian Jie, Chen Weilong, Liu Wenhong, Zhang Zhiqiang
Aqueous Mg–air batteries are promising candidates for large-scale energy storage, but their practical application is significantly hindered by water-induced parasitic reactions and the chunk effect.
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Engineering a pyrene MOF composite photocatalyst toward the formation of carbon dioxide radical anions through regulating the charge transfer from type II to Z scheme via a chemical bond-modulated strategy

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02072C, Research Article
Xin Zhao, Yajun Zhao, Yuan-Peng Li, Pengbo Lyu, Chunying Chen, Zong-Wen Mo, Chao Peng, Jiewei Liu, Li Zhang
A new approach was reported for regulating the charge transfer mechanism in a pyrene-based MOF composite, transitioning from a type-II to a Z-scheme configuration.
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Synthesis and structure of chlororuthenacyclopentatriene

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01833H, Research Article
Zhenwei Chu, Zhishun Peng, Xu Cheng, Yuhui Hua, Guomei He, Jiangxi Chen, Guochen Jia
Chlororuthenacyclopentatriene, representing a new member of the ruthenaaromatic family, was successfully prepared using the reactions of RuCl2(PPh3)3 with o-phenyldiyne derivatives in the presence of excess HCl.
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Revealing the effect of host–guest complementarity in supramolecular monofunctional platinum(II) drugs

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02012J, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Shib Shankar Paul, Jan Novotný, Jakub Jakubec, Kateřina Petrláková, Pia Jurček, Klára Rašková, Michaela Kuchynka, Michal Masařík, Petr Kulhánek, Radek Marek
Host–guest complementarity is shown to influence the chemical activation by aquation and the biological activity of platinum(II) drugs.
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Heterointerface synergy between a 3 × 3 tunnel τ-MnO2 cathode and Mg2(OH)3Cl·4H2O for achieving long cycle-life aqueous zinc-ion batteries

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02572E, Research Article
Fang Xu, Jialin Zheng, Dai-Huo Liu, Ao Wang, Zhenjiang Li, Chunyan Xu, Mengqin Song, Beinuo Zhang, Zhengyu Bai, Zhongwei Chen
The prepared of τ-MnO2–Mg2(OH)3Cl·4H2O heterostructure cathode material enhances Zn-ion diffusion, increases the proportion of Mn(IV) and suppresses structural instability, thereby improving the cycling stability of τ-MnO2.
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Polar and tropical regioisomeric decanuclear cuprofullerenes

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02261K, Research Article
Jing-Xuan Sun, Ting-Ting Zou, Yi-Chun Zhang, Yu-Li Liu, Li Dang, Shun-Ze Zhan, Hong Cai, Dan Li
Two polar and tropical coordinated decanuclear regioisomeric cuprofullerenes with CuI atoms coordinating on CC bonds of the two polar zones around pentagons and the tropical zone of the equator have been successfully assembled, respectively.
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A novel cerium-based metal-organic framework supported Pd catalyst for semi-hydrogenation of phenylacetylene

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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02225D, Research Article
Open Access
Xiangdi Zeng, Zi Wang, Meng He, Wanpeng Lu, Wenyuan Huang, Bing An, Jiangnan Li, Li Mufan, Ben Spencer, Sarah Day, Floriana Tuna, Eric J L McInnes, Martin Schroder, Sihai Yang
Phenylacetylene is a detrimental impurity in the polymerisation of styrene, capable of poisoning catalysts even at ppm levels and significantly degrading the quality of polystyrene. The semi-hydrogenation of phenylacetylene to...
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Large optical anisotropy in noncentrosymmetric phosphate with pseudo 2D intercalated layer

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02245A, Research Article
Qiao Xia, Xingxing Jiang, Lu Qi, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark G. Humphrey, Kazuyuki Tatsumi, Chi Zhang
A noncentrosymmetric phosphate (C3H5N2)(H2PO4) with pseudo 2D intercalated layers, which exhibits large birefringence and wide band gap, was successfully synthesized by simultaneously introducing the planar and tetrahedral motifs.
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Exploring the optimal post-treatment strategy for boosting the electrochemical performances of a new bimetal–organic framework-based supercapacitor

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02314E, Research Article
Xinwen Dou, Mingyue Liu, Tian Cao, Chan Wang, Yingjie Zhang, Yuhang Jia, Qiang Ju, Zhenlan Fang
Effects of four kinds of post-treatment strategies on the structures, morphologies, and electrochemical behaviors of MOF derivatives are systematically investigated for the first time.
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Unprecedented aluminum molecular ring based-layer with tailorable optical limiting effect

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02507E, Research Article
Lin Geng, Di Wang, Ran-Qi Chen, San-Tai Wang, Chan Zheng, Wei-Hui Fang, Jian Zhang
This study achieved structural modulation from 0D aluminum rings to 2D MOF via a coordination-driven self-assembly strategy. Notably, the exfoliated nanosheets showed enhanced NLO properties, highlighting their potential in optical applications.
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Facet-engineered CeO2 with Cu single atom drives photocatalytic selective oxidation of 5-hydroxymethylfurfural

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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02230K, Research Article
Yifei Li, Senyao Meng, Ping Wang, Miao He, Jiasai Yao, Cheng Yang, Fangzhou Mo, Jiang Li, Zhenxing Li
The crystal facet of CeO2 is crucial in governing the catalytic performance. However, studies on the relationship between the photocatalytic oxidation performance of CeO2 and its crystal facets are scarce....
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Fe3O4-decorated MXene for the effective removal of 133Ba and 137Cs: synthesis, characterization, and optimization via response surface methodology (RSM)

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Inorg. Chem. Front., 2024, 11,7860-7871
DOI: 10.1039/D4QI00404C, Research Article
Shalu Atri, Vipul Vilas Kusumkar, Süleyman İnan, Maros Gregor, Tomas Roch, Maria Caplovicova, Michal Galambos, Eva Viglasova, Gustav Plesch, Martin Motola, Olivier Monfort
The potential activity of Fe3O4 decorated MXenes in the removal of highly toxic 133Ba and 137Cs using a radioactive indicator method.
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Exchange of equatorial ligands in protein-bound paddlewheel Ru25+ complexes: new insights from X-ray crystallography and quantum chemistry

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Inorg. Chem. Front., 2024, 11,7803-7811
DOI: 10.1039/D4QI01846J, Research Article
Open Access
Aarón Terán, Francesca Fasulo, Giarita Ferraro, Ana Edilia Sánchez-Peláez, Santiago Herrero, Michele Pavone, Ana Belén Muñoz-García, Antonello Merlino
The reactivity of [Ru2Cl(D-p-CNPhF)(O2CCH3)3]n (D-p-CNPhF− = N,N'-bis(4-cyanophenyl)formamidinate) with the model protein RNase A has been investigated by X-ray crystallography and Quantum Chemistry.
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Al-alkyl borate salt cocatalysts for olefin polymerization: exploration of N-donor ligand variations

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Inorg. Chem. Front., 2024, 11,7872-7885
DOI: 10.1039/D4QI01874E, Research Article
Open Access
Gaia Urciuoli, Francesco Zaccaria, Cristiano Zuccaccia, Roberta Cipullo, Peter H. M. Budzelaar, Leonardo Tensi, Antonio Vittoria, Christian Ehm, Alceo Macchioni, Vincenzo Busico
The stability and reactivity of {[iBu2(L)Al]2(μ-H)}+[B(C6F5)4]− (AlHAl), recently identified as a promising cocatalyst for olefin polymerization, can be modulated by varying the structure of the neutral N-donor (L).
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A tetranuclear-cluster-based MOF with a low-polarity pore environment for efficient C2H6/C2H4 separation

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Inorg. Chem. Front., 2024, 11,7947-7954
DOI: 10.1039/D4QI01685H, Research Article
Meng Feng, Jiantang Li, Xirong Wang, Jingyu Wang, Dongmei Wang, Banglin Chen
Benefitting from reticular chemistry, the newly developed MOF material ZJNU-400 establishes a low-polarity environment that enables reversed ethane adsorption and facilitates the efficient separation of C2H6/C2H4.
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Design of DyIII single-molecule magnets with molecularly installed luminescent thermometers based on bridging [PtII(CN)2(C^N)]− complexes

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Inorg. Chem. Front., 2024, 11,7966-7978
DOI: 10.1039/D4QI02373K, Research Article
Pawel J. Bonarek, Mikolaj Zychowicz, Jan Rzepiela, Michal Liberka, Sebastian Baś, Jakub J. Zakrzewski, Szymon Chorazy
Dysprosium(III) single-molecule magnets are bridged within a coordination polymer by Pt(II)-cyanido metalloligands serving as their temperature sensors.
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In situ growth of δ-MnO2/C fibers as a binder-free and free-standing cathode for advanced aqueous Zn-ion batteries

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Inorg. Chem. Front., 2024, 11,8016-8024
DOI: 10.1039/D4QI01661K, Research Article
Yan Li, Fei Zhang, Miaomiao Wu, Yong Guo, Yuanyuan Liang, Reyihanguli Ababaikeri, Luyang Wang, Qiao Liu, Xingchao Wang
δ-MnO2 anchored in N-doped carbon fibers, derived from coal, was prepared using an electrospinning method, demonstrating enhanced performance in AZIBs.
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Equivalent cation-tuning to realize a new Ce(IV) fluoride with excellent comprehensive nonlinear optical performances

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Inorg. Chem. Front., 2024, 11,8130-8138
DOI: 10.1039/D4QI02088J, Research Article
Bei-Bei Zhang, Wen-Ye Gao, Wei Xu, Liang Ma, Wenlong Liu, Ru-Ling Tang, Sheng-Ping Guo
The acentric Ce(IV) fluoride NH4Ce3F13 is systematically studied, exhibiting the strong SHG effect (1.2 × KDP) and high LIDTs (39 × AGS). It also possesses the largest band gap among NLO materials containing Ce(IV).
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Mesoscopic spiral nanoplates formed by porphyrin-spaced coordination frameworks for enhanced H2O2 photosynthesis

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Inorg. Chem. Front., 2024, 11,8037-8046
DOI: 10.1039/D4QI01580K, Research Article
Liang He, Er-Xia Chen, Ju-Qiang Xiang, Yu-Jun Guo, Jian Zhang, Qipu Lin
Two-dimensional chiral bismuth–porphyrin metal–organic frameworks featuring mesoscopic square spiral terrace morphology significantly enhance H2O2 photosynthesis.
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Pyridyl–triazole ligands enable in situ generation of a highly active dihydride iridium(III) complex for formic acid dehydrogenation

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Inorg. Chem. Front., 2024, 11,7921-7929
DOI: 10.1039/D4QI01818D, Research Article
Miriam Abán, J. Marco Cuenca, Irene Embid, Alba de Toro, Pilar Gómez-Sal, Ernesto de Jesús, Marta Valencia, Cristina G. Yebra
[CpIr(CO)H2] efficiently catalyses formic acid dehydrogenation, forming in situ from pyridyl-triazole pre-catalysts [Cp*Ir(k2-NN)(Cl)][OTf]. Neat formic acid is dehydrogenated with a TON of up to 26876 and a TOF exceeding 10700 h−1.
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Highly defective and conductive Cu-doped 1T/2H-MoS2 nanosheets as high-capacity cathode materials for enhanced magnesium-ion storage

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Inorg. Chem. Front., 2024, 11,7831-7842
DOI: 10.1039/D4QI02064B, Research Article
Ao Xu, Yan Liu, Jiahui Wang, Yijing Wang, Fuyi Jiang, Yanli Zhou
Limited by the poor electronic conductivity and strong interaction between Mg2+ and MoS2, the 2H phase of MoS2 as a cathode material exhibits low capacity and poor rate capability.
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Research progress in optical materials with cationic organic planar π-conjugated groups containing CN bonds

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Inorg. Chem. Front., 2024, 11,7756-7774
DOI: 10.1039/D4QI02232G, Review Article
Hangwei Jia, Xueling Hou, Shilie Pan
The calculated polarizability anisotropy, hyperpolarizability and HOMO–LUMO gap of optically active groups.
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Shooting short-wavelength nonlinear optical materials with targeted balance performances in hydroxyborates through first-principles high-throughput screening

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Inorg. Chem. Front., 2024, 11,7843-7852
DOI: 10.1039/D4QI02234C, Research Article
Chenxu Li, Abudukadi Tudi, Huanhuan Cheng, Qingyu Liu, Zhihua Yang, Shilie Pan
High-throughput screening of 222 hydroxyborates identified three as promising short-wavelength ultraviolet nonlinear optical. with phase-matching second harmonic generation capacity extending to the solar blind region (200–280 nm).
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Metal–organic framework micro-nano reactors as armour of Escherichia coli for hydrogen production in air

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Inorg. Chem. Front., 2024, 11,8070-8077
DOI: 10.1039/D4QI02119C, Research Article
Yun Fan, Junyang Yan, Siyao Zhang, Ruifa Su, Baoli Zha, Weina Zhang
The MOF shell of an E. coli@ZIF-8 micro–nano reactor, used as armour for E. coli, not only protects the internal E. coli and improves its survival rate, but also delays the transport of oxygen to enable E. coli to produce hydrogen in air.
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Linker engineering in mixed-ligand metal–organic frameworks for simultaneously enhanced benzene adsorption and benzene/cyclohexane separation

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Inorg. Chem. Front., 2024, 11,8101-8109
DOI: 10.1039/D4QI01796J, Research Article
Yong-Zheng Zhang, Xin-Dan Zhang, Yan-Kai Zhang, Fu-Tian Wang, Longlong Geng, Hui Hu, Zhen Li, Da-Shuai Zhang, Hongliang Huang, Xiuling Zhang
A novel mixed-ligand metal–organic framework, featuring naphthalene rings in its secondary linker, exhibits exceptional benzene adsorption and separation capacities.
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Modulating the birefringence of two-dimensional hybrid lead bromide perovskites using pyridine derivative cations

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Inorg. Chem. Front., 2024, 11,7853-7859
DOI: 10.1039/D4QI01547A, Research Article
Li-Ling Zhang, Hua Huang, Qingran Ding, Hui-Ping Xiao, Qing-Yan Liu, Yu-Ling Wang
Crystal structures and optoelectronic performance of hybrid two-dimensional lead bromide halide perovskites are elaborately regulated by pyridyl cations, which achieve a significantly enhanced birefringence of 0.315 (550 nm) for crystal 2.
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Ru-anchoring Co-MOF-derived porous Ru-Co3O4 nanomaterials for enhanced oxygen evolution activity and structural stability

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Inorg. Chem. Front., 2024, 11,8139-8145
DOI: 10.1039/D4QI02061H, Research Article
Nan Li, Lujiao Mao, Yuting Fu, Haoran Wang, Yuchang Shen, Xuemei Zhou, Qipeng Li, Jinjie Qian
This study demonstrates a new approach for Ru-anchoring CoOF-1-derived porous Ru-Co3O4 nanomaterials with high activity and durability, showcasing great potential in the field of practical energy storage and conversion.
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Critical metal recovery from spent lithium-ion batteries’ leaching solution using electrodialysis technologies: strategies and challenges

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Inorg. Chem. Front., 2024, 11,7775-7792
DOI: 10.1039/D4QI01978D, Review Article
Tianshu Zhang, Yijun Qian, Changyong Zhang, Tao Qian, Chenglin Yan
This review overviews the recent advances in electrodialysis (ED) in extracting critical metals from spent battery leachate. In addition, strategies and challenges regarding ED techniques toward battery recycling are pointed out.
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Stable solid-state potassium metal batteries enabled by a KB11H14·2Me3NBH3 complex electrolyte

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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02372B, Research Article
Guo-guo Zhang, Pengtao Qiu, Jiaxin Kang, Zhiwei Lu, An-qi Zhu, Xiaohu Yu, Xuenian Chen
Solid-state potassium metal batteries have increasingly gained attention as promising alternatives in large-scale energy storage due to their safety and low cost. However, these batteries usually suffer from a lack...
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Hierarchical FeCo LDH/NiSe heterostructure electrocatalysts with rich heterointerfaces for robust water splitting at industrial-level current density

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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02426E, Research Article
Weiwei Han, Wenyi Wang, Jiahong Liao, Yi He, Xingwang Zhang, Chunlin Yu
Sustainable hydrogen production by electrocatalytic water splitting is a promising energy storage technology yet challenging due to the sluggish kinetics of the oxygen evolution reaction (OER). Rationally designed robust and...
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Naphthalene diimide-based crystalline hybrid photochromic materials: Structural types, photochromic mechanism, and applications

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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02653E, Review Article
Li Li, Jian-Ge Zeng, Ning-Ning Zhang, Yu Yang-Tao, Shu-Hao Li, Yang Hua
The multifunctional stimuli-responsive photochromic materials significantly expand their application fields, including molecular switching, information storage and encryption, detection and sensing, etc. 1,4,5,8-naphthalenediimides (NDIs) have been widely used for the construction...
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Enhancing CO2 electroreduction with decamethylcucurbit[5]uril-alkaline earth metal modified Pd nanoparticles

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02135E, Research Article
Tao Shao, Xianmeng Song, Zongnan Wei, Shuaibing Yang, Siying Zhang, Rong Cao, Minna Cao
Pd NP modification with Me10CB[5]–M capsules boosted CO2RR by enhancing CO2 adsorption, tuning Pd's electronic structure, and optimizing *COOH/*CO binding.
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Advances in nanoengineering of cathodes for next-generation solid oxide fuel cells

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02451F, Review Article
Chunwen Sun
The progress of nanoengineering of electrodes fabricated by various methods for SOFCs operating at low and intermediate temperatures is reviewed. Future research directions on nanoengineering of cathodes for next-generation SOFCs are also provided.
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Li3V2(PO4)3 particles embedded in N and S Co-doped porous carbon cathode for high performance lithium storage：An experimental and DFT study

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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI01916D, Research Article
Jinggao Wu, Canyu Zhong, Xiaofan Chen, Jing Huang
Li3V2(PO4)3 (LVP)-coated with N and S co-doped carbon (NSC) is investigated by DFT calculation, suggesting that NSC significantly enhances electronic conductivity and lowers Li+ migration energy barrier in comparison to...
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Pentagonal-bipyramidal Dysprosium(III) complexes with two apical phosphine oxide ligands and equatorial pentadentate N3O2 Schiff-base ligands: Breakdown of the apical magnetic axiality by strong equatorial crystal field†

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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02262A, Research Article
Tamara A. Bazhenova, Vyacheslav Kopotkov, Denis V. Korchagin, Elena Yureva, Michael V. Zhidkov, Alexey I Dmitriev, Ilya Yakushev, N. N. Efimov, Konstantin Andreevich Babeshkin, Vladimir Sergeevich Mironov, Eduard B. Yagubskii
A series of three new seven-coordinate pentagonal-bipyramidal (PBPY-7) Dy(III) complexes [Dy(LCH3)(Cy3PO)2]ClO4∙CH3CN (1), [Dy(L2(t-Bu))(Ph3PO)2]ClO4∙0.63C2H5OH (2), [Dy(LOCH3)(Ph3PO)2]ClO4∙2H2O (3) including various chelating pentadentate ligands with a [N3O2]2− binding node in the equatorial plane,...
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Metal Node Exchange-Driven Ligand-Strain Modulation Strategy for One-Dimensional Crystalline Coordination Polymers

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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02422B, Research Article
Gengxin Wu, Yong-Kang Zhu, Dongxia Li, Jia-Rui Wu, Yan Wang, Zhiquan Zhang, Ying-Wei Yang
Engineering ideal functional coordination polymers (CPs) via post-synthetic modification has emerged as a powerful synthetic strategy to achieve desirable functionalities and superior properties. In this work, we report a versatile...
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Capturing of extracellular vesicles derived from single cells of Escherichia coli

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Lab Chip, 2024, 24,2049-2057
DOI: 10.1039/D3LC00707C, Paper
Open Access
Fumiaki Yokoyama, André Kling, Petra S. Dittrich
A microdevice with narrow winding channels is introduced to trap and culture single bacterial cells. It is used to study growth patterns of the cells and to monitor secretion of extracellular vesicles under treatment with an antibiotic drug.
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Test strip coupled Cas12a-assisted signal amplification strategy for sensitive detection of uracil-DNA glycosylase

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Lab Chip, 2024, 24,1987-1995
DOI: 10.1039/D4LC00096J, Paper
Bin Guo, Chong Hu, Zeping Yang, Chu Tang, Chuanxian Zhang, Fu Wang
In this study, we employed Cas12a protein and enzyme-assisted cycle amplification technology with a test strip to establish a precise platform for the detection of UDG enzyme.
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Microfluidic impedance cytometry with flat-end cylindrical electrodes for accurate and fast analysis of marine microalgae

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Lab Chip, 2024, 24,2058-2068
DOI: 10.1039/D3LC00942D, Paper
Xiaoming Chen, Mo Shen, Shun Liu, Chungang Wu, Liangliang Sun, Zhipeng Song, Jishun Shi, Yulong Yuan, Yong Zhao
We develop a novel microfluidic impedance cytometer for analysis of marine microalgae by inserting ground flat-end cylindrical electrodes into microchannels.
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Multifunctional cardiac microphysiological system based on transparent ITO electrodes for simultaneous optical measurement and electrical signal monitoring

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Lab Chip, 2024, 24,1903-1917
DOI: 10.1039/D3LC00908D, Paper
Zhangjie Li, Kai Niu, Chenyang Zhou, Feifan Wang, Kangyi Lu, Yijun Liu, Lian Xuan, Xiaolin Wang
We developed a multifunctional cardiac microphysiological system on transparent electrodes, enabling simultaneous electrical signal monitoring and optical observations of cardiac tissue, holding promise for applications in cardiac drug development.
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Multifunctional flexible magnetic drive gripper for target manipulation in complex constrained environments

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Lab Chip, 2024, 24,2122-2134
DOI: 10.1039/D3LC00945A, Paper
Meiying Zhao, Ye Tao, Wenshang Guo, Zhenyou Ge, Hanqing Hu, Ying Yan, Chaoxia Zou, Guiyu Wang, Yukun Ren
A multifunctional flexible magnetic drive gripper is synthetically designed to achieve active steering and carry out operations on different targets in a constrained environment by changing the external magnetic field.
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