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Optimization of informative variables selection for quantitative analysis of heavy metal (Cu) contaminated Tegillarca granosa using laser-induced breakdown spectroscopy

J. Anal. At. Spectrom., 2024, 39,2824-2831
DOI: 10.1039/D4JA00084F, Paper
Xudong Huang, Xiaojing Chen, Guangzao Huang, Zhonghao Xie, Wen Shi, Shujat Ali, Leiming Yuan, Xi Chen
The KMRCD algorithm successfully selected 50 informative variables from the 1520 variables in the LIBS spectra.
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Evaluation and calibration of matrix effects during SIMS silicon isotope analysis in silicate glasses

J. Anal. At. Spectrom., 2024, 39,2832-2840
DOI: 10.1039/D4JA00253A, Paper
Liu-Yang Chen, Yu Liu, Di Zhang, Guo-Qiang Tang, Qiu-Li Li
A matrix effect calibration model during SIMS silicon isotope analysis based on the contents of Si, Ca, Al and Mg (SCAM model) in silicate glasses.
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Trace element determination by femtosecond LA-ICP-MS in 10 mg extraterrestrial geological samples prepared as lithium borate glasses

J. Anal. At. Spectrom., 2024, 39,2728-2736
DOI: 10.1039/D4JA00275J, Paper
Yan-Hong Liu, Ding-Shuai Xue, Wen-Jun Li, Zhong-Qiang Wang, Yan Liang, Shun Guo, Bo Wan
This method involves precise trace element determination in X-ray fluorescence (XRF) lithium borate glass prepared from 10 mg extraterrestrial geological samples using femtosecond LA-ICP-MS.
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Sodium nanoferrite-based solid phase extraction: a green method for the simultaneous determination of cadmium, copper, and lead

J. Anal. At. Spectrom., 2024, 39,2884-2892
DOI: 10.1039/D4JA00210E, Paper
Saima Perveen, Aysen Hol, Jameel Ahmed Baig, Syed Tufail Hussain Sherazi, Khalil Akhtar, Sajjad Hussain, Fahad Abbasi
A solid phase extraction (SPE) methodology utilizing sodium ferrite nanoparticles (Na2Fe4O7-NPs; SF-NPs) is presented for the simultaneous determination of heavy metals (HMs) via flame atomic absorption spectrometry (FAAS).
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First demonstration of in situ Lu–Hf dating using LA-ICP-MS/MS applied to monazite

J. Anal. At. Spectrom., 2024, 39,2703-2715
DOI: 10.1039/D4JA00258J, Technical Note
Shitou Wu, Junlong Niu, Yueheng Yang, Hao Wang, Jinhui Yang, Fuyuan Wu
Monazite is a LREE-rich accessory mineral in various igneous and metamorphic rocks; therefore, monazite geochronology has the potential to answer a range of important geological questions.
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An ensemble model for rapid quantitative determination of vanadium (V) in petroleum coke by laser-induced breakdown spectroscopy

J. Anal. At. Spectrom., 2024, 39,2841-2855
DOI: 10.1039/D4JA00300D, Paper
Hongkun Du, Tengfei Sun, Shaoying Ke, Dongfeng Qi, Wei Zhang, Juan Wei, Bing Yang, Hongyu Zheng
Precise detection and analysis of trace elements in materials are critical for various industrial applications.
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Quantification of technetium-99 in wastewater by means of automated on-line extraction chromatography – anion-exchange chromatography – inductively coupled plasma-mass spectrometry

J. Anal. At. Spectrom., 2024, 39,2774-2782
DOI: 10.1039/D4JA00270A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Maximilian Horstmann, C. Derrick Quarles, Steffen Happel, Michael Sperling, Andreas Faust, David Clases, Uwe Karst
Ultratrace concentrations of pertechnetate are determined by preconcentration on a dedicated resin and anion exchange chromatography with ICP-MS detection.
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Efficient preconcentration of ultra-trace rhenium from geological materials via induced adsorption for accurate isotope analysis

J. Anal. At. Spectrom., 2024, 39,2748-2755
DOI: 10.1039/D4JA00295D, Paper
Yumeng Liu, Tianyu Chen, Tao Li, Weiqiang Li, Qingquan Hong, Jiubin Chen
Preconcentration via induced adsorption achieves the quantitative recovery of Re and facilitates Re isotope analysis.
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Data fusion of spectral and acoustic signals in LIBS to improve the measurement accuracy of carbon emissions at varying gas temperatures

J. Anal. At. Spectrom., 2024, 39,2756-2766
DOI: 10.1039/D4JA00287C, Paper
Shu Chai, Jie Ren, Suming Jiang, Aochen Li, Ziqing Zhao, Haimeng Peng, Qiwen Zhang, Wendong Wu
A novel mid-level data fusion method integrating spectral and acoustic signals of laser-induced plasmas was proposed to improve the measurement accuracy of carbon concentrations in flue gas at varying gas temperatures.
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Self-absorption correction of NEXAFS spectra for intermediate sample thicknesses applied to organo-sulfur model compounds

J. Anal. At. Spectrom., 2024, 39,2893-2902
DOI: 10.1039/D4JA00232F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Konstantin Skudler, Michael Walter, Michael Sommer, Matthias Müller
We present a self-absorption correction for NEXAFS which is valid for any sample thickness. The corrected spectrum is recovered in a forward calculation by fitting a model spectrum to experimental data of samples with ideally different thicknesses.
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Mg separation from samples with very high Ca/Mg ratios for Mg isotope analysis

J. Anal. At. Spectrom., 2024, 39,2767-2773
DOI: 10.1039/D4JA00266K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Niklas Keller, Michael Tatzel
We present an efficient method to separate Mg from samples with high Ca/Mg matrices for the analysis of Mg isotope ratios. By utilising the automated sample purification system prepFAST, the labour is substantially minimised.
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Accurate determination of ultra-trace REEs in seawater using a membrane desolvation Q-ICP-MS coupled with an online automatic separation system

J. Anal. At. Spectrom., 2024, 39,2870-2883
DOI: 10.1039/D4JA00240G, Paper
Ji-Hao Zhu, Feng-You Chu, Feng Liang, Xian-Ying Luo, Qiang Liu, Quan-Hui Xu, Wei Yu, Yong-Chun Li, Jiang-Gu Lu, Yun-Xiu Li, Yan-Hui Dong, Huai-Ming Li, Jun Zhao, Cai Zhang
A highly precise method, based on a traditional Q-ICP-MS coupled with an online automatic separation system and membrane desolvation sample introduction device, was developed for accurate determination of ultra-trace REEs in seawater samples.
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Research on a bimodal fusion detection method for surface defects of metal AM components based on LIBS

J. Anal. At. Spectrom., 2024, 39,2917-2928
DOI: 10.1039/D4JA00159A, Paper
Xiaomei Lin, Jiangfei Yang, Yutao Huang, Jingjun Lin, Changjin Che
A bimodal fusion method using Laser-Induced Breakdown Spectroscopy (LIBS) is proposed to identify surface defects in metal additive manufacturing (AM) samples. This method integrates LIBS spectra with plasma image data to enhance defect detection.
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Assessment of the metal grain size of 12Cr1MoV steel by LIBS coupled with acoustic wave information

J. Anal. At. Spectrom., 2024, Advance Article
DOI: 10.1039/D4JA00285G, Paper
Feiqiang Tang, Meirong Dong, Junbin Cai, Zhichun Li, Kaiqing Chen, Weijie Li, Shunchun Yao, Jidong Lu
A modelling scheme that integrates spectral and acoustic data was put forth as a means of enhancing the precision of grain size detection in 12Cr1MoV steel.
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Evaluation of miniaturized ultrasonic nebulization for high-efficiency sampling in characterization of silver nanoparticles by single particle inductively coupled plasma mass spectrometry

J. Anal. At. Spectrom., 2024, 39,2791-2798
DOI: 10.1039/D4JA00320A, Paper
Junhang Dong, Zhenli Zhu, Lujie Li, Pengju Xing, Shuyang Li, Lei Ouyang, Xing Liu, Wei Guo, Hongtao Zheng, Rong Qian
Miniaturized ultrasonic nebulization (MUN) provides high sampling efficiency for single particle inductive coupled plasma mass spectrometry (sp-ICPMS).
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Hydrophobicity induced graphene oxide based dispersive micro solid phase extraction of strontium from seawater and groundwater prior to GFAAS determination

J. Anal. At. Spectrom., 2024, Accepted Manuscript
DOI: 10.1039/D3JA00445G, Paper
Maria Sebastian, Saikrishna Devulapally, Sk. Jayabun, Noorbasha Nagula Meeravali, Shekhar Raparthi, A. C. Sahayam
A novel graphene oxide (GO) mediated dispersive micro solid phase extraction method is developed for the extraction of ultratrace level strontium (Sr) from seawater and ground water. This method involves...
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A new concept for correction of instrumental isotopic fractionation in MC-ICP-MS using a pair of monoisotopic elements: a critical evaluation

J. Anal. At. Spectrom., 2024, Advance Article
DOI: 10.1039/D4JA00117F, Paper
Open Access
Andrii Tupys, Klaudia Tetfejer, Ludwik Halicz, Ewa Bulska, Jakub Karasiński
In this research work, we investigated the possibility of using mixtures of monoisotopic elements (93Nb/89Y, 165Ho/159Tb and 209Bi/197Au) as calibrators for accurate determination of isotope ratios by multicollector mass spectrometry (MC-ICP-MS).
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INSIGHTS INTO THE ROLE OF TRANSITION AND NOBLE METALS MEDIATING PHOTOCHEMICAL VAPOR GENERATION

J. Anal. At. Spectrom., 2024, Accepted Manuscript
DOI: 10.1039/D4JA00261J, Tutorial Review
Open Access
Ralph E Sturgeon, Enea Pagliano, Gisele Simone Lopes, Renato Neto, Jane Kelly Sousa Brito
Abstract The recent expansion of the suite of elements amenable to photochemical vapor generation (PVG) is primarily linked to the addition of mg/L concentrations of selected transition metals (TMs) to...
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Combined enhancement of fiber-optic laser-induced breakdown spectroscopy coupling spatial confinement and double-pulse irradiation

J. Anal. At. Spectrom., 2024, Advance Article
DOI: 10.1039/D4JA00291A, Paper
Yan Qiu, Jinghui Li, Bowen Lu, Jian Wu, Xinyu Guo, Yuhua Hang, Yongdong Li, Xingwen Li
The mechanism of double-pulse laser irradiation under spatial confinement remains unclear due to complex plasma plume dynamics and multiple shock wave interactions.
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A single-stage purification method for the precise determination of zirconium isotopic composition in geological samples by double spike MC-ICP-MS

J. Anal. At. Spectrom., 2024, Advance Article
DOI: 10.1039/D4JA00332B, Paper
Lanping Feng, Chen Wang, Yan Han, Wen Zhang, Jing-Liang Guo, Lian Zhou, Zhaochu Hu
A simple, fast and efficient column separation method for extracting Zr from geological sample matrices using DGA resin.
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Automated detection of element-specific features in LIBS spectra

J. Anal. At. Spectrom., 2024, Advance Article
DOI: 10.1039/D4JA00247D, Paper
Open Access
Zuzana Gajarska, Anna Faruzelová, Erik Képeš, David Prochazka, Pavel Pořízka, Jozef Kaiser, Hans Lohninger, Andreas Limbeck
Comb algorithm: a novel semi-automatic approach to identify elemental lines in spectra obtained via laser-induced breakdown spectroscopy.
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Robust determination of low Ti contents in zircon using LA–ICP–MS/MS with NH3 reaction gas

J. Anal. At. Spectrom., 2024, Advance Article
DOI: 10.1039/D4JA00304G, Paper
Junlong Niu, Shitou Wu, Yueheng Yang, Hao Wang, Chao Huang, Lei Xu, Liewen Xie
Compared with the single quadrupole (SQ) mode, Triple Quadrupole (TQ) method is more robust for determining low Ti contents in zircon at high spatial resolutions (laser spot size <20 μm), making it useful for the analysis of complex zircon grains.
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Determination of boron isotopic compositions in five fractions of soil boron: traces of the environmental behavior of boron in soil

J. Anal. At. Spectrom., 2024, Advance Article
DOI: 10.1039/D4JA00286E, Paper
Xuejun Chen, Qingcai Xu, Li Yan, Xiaodong Hao, Xiaochen Guan, Xiaopeng Han, Aide Sun, Zhiqun Chen, Lihua Liu, Zihao Zhu
A stepwise extraction method established for boron isotope measurement of five fractions in soil boron showed their feathered isotopic signals.
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Fast analysis of metal components in coal dust using spark emission spectroscopy

J. Anal. At. Spectrom., 2024, Advance Article
DOI: 10.1039/D4JA00322E, Paper
Jialin Li, Jing Huang, Lina Zheng, Shakila Naz, Xutong Liu
We present a fast method based on spark emission spectroscopy to quantify metal components such as Al, Si, Fe, Ca, and Ti in airborne coal dust.
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A miniaturized microplasma excitation source coupled with photochemically induced volatile species generation as a cost-effective tool for in situ mercury pollution analyses

J. Anal. At. Spectrom., 2024, Advance Article
DOI: 10.1039/D4JA00306C, Technical Note
Open Access
Tymoteusz Klis, Pawel Pohl, Anna Dzimitrowicz, Piotr Jamroz
A portable, miniaturized atmospheric microplasma discharge system coupled with the photochemical vapour generation was developed for the sensitive Hg determination in water samples using OES.
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Investigation of direct simultaneous uranium isotopic determination and age dating of micrometer-sized uranium particles by laser ablation – multi-collector ICPMS

J. Anal. At. Spectrom., 2024, Advance Article
DOI: 10.1039/D4JA00280F, Paper
Anne-Claire Humbert, Fabien Pointurier, Amélie Hubert
The proposed method offers to the analytical community an alternative technique for uranium particle aged dating more widely available than LG SIMS. Moreover, working on μm-sized particles reduces issues with laser-induced fractionation.
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A Gaussian Spot Overlap Ablation Model for Prediction of Aluminium Alloy Spectral Peak Intensity in High Pulse Repetition Frequency LIBS

J. Anal. At. Spectrom., 2024, Accepted Manuscript
DOI: 10.1039/D4JA00298A, Paper
Dongming Qu, Bohao Su, Zhongshu Bai, Biye Liu, Xueying Jin, Guanyu Chen, Yuting Fu, Tingwen Gu, Guang Yang, Qingkai Li
The use of microjoule high pulse repetition frequency (PRF) lasers as excitation sources is an important direction in the miniaturisation of laser-induced breakdown spectroscopy (LIBS) instruments. However, high PRF LIBS...
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Magneto-electrical fusion enhancement of LIBS signal: A case of Al and Fe emission lines’ characteristic analysis in soil

J. Anal. At. Spectrom., 2024, Accepted Manuscript
DOI: 10.1039/D4JA00223G, Paper
Zihan Yang, Mengyu Pang, Jincheng Ma, Yanru Zhao, Keqiang Yu, Y. He
Soil is a vital resource for human survival. In particular, aluminum (Al) and iron (Fe) metal elements in soil play significant roles in stabilizing soil organic matter. Therefore, the rapid...
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Sensitive and Rapid Determination of Iodine/Calcium Ratio in Carbonate Rock Samples by ICP-MS Based on Solution Cathode Glow Discharge Sampling

J. Anal. At. Spectrom., 2024, Accepted Manuscript
DOI: 10.1039/D4JA00264D, Paper
Xuan Wang, Xing Liu, Lanlan Jin, Zhenli Zhu, Junhang Dong, Pengju Xing, Linjie Chen, Yuanhui Geng, Jingwen Zhang, Hao Tong, Hongtao Zheng, Min Zhang, Shenghong Hu
The iodine-to-calcium ratio (I/Ca) in carbonate rocks has been extensively used to indicate marine oxidation states. However, the low-iodine and high-calcium characteristics of carbonate samples pose challenges in achieving rapid...
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High-precision MC-ICP-MS measurements of Cd isotopes using a novel double spike method without Sn isobaric interference

J. Anal. At. Spectrom., 2024, Accepted Manuscript
DOI: 10.1039/D4JA00357H, Paper
Jin Li, Suohan Tang, Xiangkun Zhu, Jianxiong Ma, Zhi-Yong Zhu, Bin Yan
Previous studies have reported that even low concentrations of Sn can lead to biased Cd isotopic measurements using MC-ICP-MS. In this paper, we propose a novel method of Cd isotopic...
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Laser-Induced Breakdown Spectroscopy (LIBS): calibration challenges, combination with other techniques, and spectral analysis using data science

J. Anal. At. Spectrom., 2024, Accepted Manuscript
DOI: 10.1039/D4JA00250D, Critical Review
Dennis Ferreira, Diego Victor De Babos, Mauro Henrique Lima-Filho, Heloisa Froehlick Castello, Alejandro C. Olivieri, Fabiola Manhas Verbi Pereira, Edenir Rodrigues Pereira-Filho
Laser-Induced Breakdown Spectroscopy (LIBS) is a versatile and powerful analytical technique widely used for rapid, in-situ elemental analysis across various fields, from industrial quality control to planetary exploration. This review...
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Fundamental studies of laser ablation ICPMS using a nitrogen plasma source and helium, argon and nitrogen as carrier gas

J. Anal. At. Spectrom., 2024, Advance Article
DOI: 10.1039/D4JA00327F, Paper
Open Access
Dylan Käser, Ralf Kägi, Bodo Hattendorf, Detlef Günther
Nitrogen as alternative carrier gas for LA-ICPMS showed similar sensitivities and quantification capabilities as using helium in combination with a N2 plasma. The role of the gas and of the ablation cell design on the aerosol structure was studied.
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Applying standard addition to determine antimony isotopes in low-Sb samples using HG-MC-ICP-MS

J. Anal. At. Spectrom., 2024, Advance Article
DOI: 10.1039/D4JA00333K, Paper
Honggang Zhu, Jian-Ming Zhu, Decan Tan, Zhuo Lu, Hongfei Liao, Yiwei Ma
The δ123Sb value of BCR-2 obtained by the standard addition (SA) method.
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Trace xenon detection in ambient helium by double-pulse laser-induced breakdown spectroscopy

J. Anal. At. Spectrom., 2024, Accepted Manuscript
DOI: 10.1039/D4JA00358F, Paper
Open Access
Londrea Garrett, Milos Burger, Yunu Lee, Hyeongbin Kim, Piyush Sabharwall, Sungyeol Choi, Igor Jovanovic
Safe operation of next-generation nuclear reactors is contingent on developing and effectively operating new diagnostics methods. For helium-cooled fast reactors, one important safety concern is the onset of fuel-cladding failure,...
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New expectations

RICS report places ethics at the core of professional values and figures out challenges for the future in real estate.




io

Reactions to the Real Estate Bill




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Creating cohesion out of fragmentation

Governments need to look at alternate methods of sourcing and developing land such as land pooling, says Rohan Sharma




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Waiting too long for a price correction?

Buyer indecisiveness is usually the result of confusion, not certainty




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Birth of Salk and death of polio

Google doodle celebrated Jonas Salk's birthday yesterday




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Dr. Reddy’s closes acquisition of Novartis’ Habitrol brand




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FDA invites Indian regulators to join inspections




io

Repurposed antibiotic shows promise

In its old form, the antibiotic is very safe for use but it lacks the necessary antibacterial activity against many bacterial pathogens.




io

India flooded with unsafe fixed dose combination drugs

Many unapproved FDC formulations contain banned, restricted, or never approved drugs




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Gene mutations link to leishmaniasis




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Hallucinations linked to differences in brain structure

The effect was observed regardless of whether hallucinations were auditory or visual in nature, consistent with a reality monitoring explanation.




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IISc receives its single largest private donation of Rs 425 crore

The unique school and the 800-bed multispeciality hospital on campus will create ‘physician-scientists’




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Baby with ‘Tessier Facial Cleft’ gets complete face reconstruction in Bengaluru through crowdfunding

The baby from Ballari district in Karnataka has undergone three complex surgeries in Bengaluru through crowdfunding




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Compulsory rural service: Nearly 2,000 senior resident doctors in Karnataka await specialist counselling and posting

They say they wrote their exams in May and have been living with uncertainty for the last two months




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Centre to give in-principle approval for AIIMS in Kozhikode: Union Minister

‘State government has to acquire land and hand it over to Centre’




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Chikkamagaluru district hospital facilitates organ donation of 17-year-old brain-dead student

Rakshitha, a native of Somanahalli in Kadur taluk, suffered a head injury on September 18 after a fall while getting off a bus in Chikkamagaluru