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ISL | Punjab downs Hyderabad, continues in its merry way

The home team’s 2-0 win takes it to the top of the table with three victories from three outings; Singto’s men, languishing at the bottom with two losses in as many games, have their task cut out; HFC’s D’Cunha gets ejected for a second yellow




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ISL | FC Goa rides on Borja’s hat-trick to score over East Bengal




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Champions League returns missing Mbappé, Rodri, Barella as injury wave hits European soccer

Champions League resumes with key players sidelined due to injuries, reshaping the competition landscape




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Cuadrat quits as East Bengal continues its struggle in ISL




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Messi scores twice for Inter Miami to win his 46th career trophy —MLS Supporters Shield

Lionel Messi and Inter Miami have another trophy, along with home-field advantage throughout the Major League Soccer playoffs




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ISL 11: Mohun Bagan SG returns to form with 3-0 drubbing of Mohammedan Sporting

Mohun Bagan seemed to have got the wake-up call in its previous defeat against Bengaluru FC and went for the kill right from the start




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FIFA bans Italian player Curto for 10 games for discrimination toward South Korean opponent

Curto also must do community services and undergo training and education with an organization approved by FIFA




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Mbappé's representatives dismiss Swedish reports of a rape claim

Kylian Mbappé's representatives termed the report as “slanderous” rumors




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Calicut FC thinking big, eyes the ISL

Budget for a SLK club is almost similar to that of an I-League side, says team owner Mathews




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ISL: Bengaluru rides on Mendez’s brace against Kerala Blasters, ends two-year wait for a win in Kochi

Bengaluru FC defeated Kerala Blasters 3-1 in the Indian Super League match




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Cristiano Ronaldo misses late penalty as Al-Nassr eliminated from Saudi Cup

Ronaldo, who is yet to win a major trophy since signing for Al-Nassr, had converted all 18 of his previous penalties for the club but this time shot over the bar




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ISL: Majcen nets brace as Punjab come from behind to beat Chennaiyin

Luka Majcen, donning a mask after fracturing his jaw in its opening game versus Kerala Blasters, scored twice in three minutes while Asmir Suljic put the result beyond doubt with a third goal in the 70th minute




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ISL: Majcen nets brace as Punjab comes from behind to beat Chennaiyin




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ISL: Table-topper BFC takes on a struggling FC Goa




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ISL | Goa finally gets it act together in big win over Bengaluru




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ISL | HFC consigns Blasters to third straight loss




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Future home of standardista Estelle Weyl

At some point I will write something of interest. Today is not that day.




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A ‘symphony’ of young Chinese aspirations behind gold’s rise to record

China gold reserves went up for 16 months in a row till Feb 2024; its central bank bought the precious metal covertly



  • Gold & Silver

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Gold is glittering, but is India making the most of it?

For a moderately conservative investor, a 5-10 per cent allocation towards gold is ideal



  • Gold & Silver

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Jewellery retailers fear a lacklustre Akshaya Tritiya this year due to soaring gold prices

Akshaya Tritiya, which falls on May 10 this year, is considered auspicious to buy gold



  • Gold & Silver

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HZL is now the 3rd largest global silver producer, says the Silver Institute

The company produced 746 tonnes in 2023, LBMA recognises its Pantnagar refinery



  • Gold & Silver

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Gold soars on geopolitical risks, central bank buying

While gold displays an uptrend on the charts, much could hinge on Fed action too




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Investors flock to Sovereign Gold Bonds despite price rises, FY24 sees record subscriptions

SGBs offer a hedge against gold price fluctuations, with investors receiving the ongoing market price at redemption



  • Gold & Silver

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Despite high prices, gold demand picks up this Akshaya Tritiya

The high price for gold has also given a boost to diamond jewellers as customers look for alternatives



  • Gold & Silver

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Gold prices surge on Iran-Israel tension and US rate cut hopes

Analysts anticipate continued volatility in gold prices, fluctuating between ₹71,000 and ₹75,000 in the near term



  • Gold & Silver

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Silver likely to rule at higher levels this year on supply deficit

Supply shortage forecast to increase by 17% even as industrial demand is projected to rise 9%



  • Gold & Silver

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Gold futures rise ₹4 to ₹73,135 per 10 gm

Gold price rises in futures trade due to fresh positions on firm spot demand, reaching ₹73,135 per 10 gram



  • Gold & Silver

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Silver futures rise on spot demand

Silver prices mainly rise due to fresh positions built up by participants on a positive domestic trend, say analysts



  • Gold & Silver

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India’s import of gold, silver from UAE rises 210% to $10.7 billion in 2023-24: GTRI

`Concessional customs duty under the India-UAE CEPA must be revised’




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The role of bullion in the event of a financial crisis 

Precious metals offer liquidity and act as hedges against economic instability, while real estate provides tangible assets with income-generating potentia



  • Gold & Silver

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Govt to decide on Sovereign Gold Bond issuance for next fiscal

No plan to stop the issuance of Sovereign Green Bonds, says a Senior official




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Sovereign Gold Bonds: Secondary market thrives amidst drought in primary issuances

Recent data reveals a significant increase in trading volume, with retail holdings growing 63 per cent year-on-year. 



  • Gold & Silver

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Gold hits near record levels, silver follows suit amidst rising demand

Gold prices surged by ₹1,150 to ₹78,500 per 10 grams, while silver prices rose by ₹1,500 to reach ₹93,000 per kg



  • Gold & Silver

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Godrej & Boyce launches ISI-certified lockers for jewellers and pawnbrokers

To improve security standards and ensure compliance with government regulations, all high-security safes are now mandated to carry an ISI mark




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Silver poised to outperform gold, expected to hit ₹1.25 lakh/kg in 12-15 months: MOFSL

Silver has shown impressive growth in 2024, recording gains of over 40 per cent year-to-date and surpassing the ₹1,00,000 mark domestically



  • Gold & Silver

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Tibetan Cuisine

Abstract: Variations in cuisine among the Tibetan minority of China are due in part to environmental diversity. Different ecologies yielded varied adaptive strategies of resource use (economies), and resulted in three main types of food production: pastoralism, agriculture, and a mixed economy with both kinds of production. These strategies in turn affect the type

The post Tibetan Cuisine appeared first on Berkshire Publishing.




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Crayfish

Abstract: First introduced into China by the Japanese in the 1930s, crayfish became popular in the Nanjing area in the early 1990s as part of a dish prepared with Sichuan pepper and spices. China is now the top consumer and producer of crayfish, which has gained acclaim as a luxury item prepared in a

The post Crayfish appeared first on Berkshire Publishing.




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Cuisine of Macau

Abstract: The cooking of the Macanese, an ethnic group originating in Macau, represents one of the earliest examples of creole cooking. What can be seen on the dining plates of these people reflects history and culture dating back to the seafaring discoveries of the Portuguese. Macanese cuisine demonstrates how Portuguese culinary traditions have been

The post Cuisine of Macau appeared first on Berkshire Publishing.




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How to Help a Tree in Distress

Karin Vaneker, a writer and activist in the Netherlands, has been helping me by tackling subjects that haven’t yet attracted much scholarly research for the second edition of the Encyclopedia of Sustainability. She’s written, for example, on including composting and community gardens - important, relevant, and yet somehow a little too close to home

The post How to Help a Tree in Distress appeared first on Berkshire Publishing.




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Home Ecology Tips in English and Chinese

Our friend and colleague Catherine ZHOU kindly translated some introductory sections from Karen Christensen's  in-progress book Home Ecology. Versions of these tips were included in some of her previous books, and she is busy compiling and writing a new guide that will focus on preparing for climate change, but also deal with other issues close

The post Home Ecology Tips in English and Chinese appeared first on Berkshire Publishing.




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Recent advances in discrete Cu complexes for enhanced chemodynamic therapy

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02380C, Frontier
Zhao-Guo Hong, Liangliang Zhang, Hong Liang, Fu-Ping Huang
Since the concept of metal ion stimulation-mediated chemodynamic therapy was proposed by Bu and Shi 's group in 2016, increasing attention has been directed toward fabricate efficient, safe and stable...
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Structural and Mechanistic Insights into Oxidative Biaryl Coupling to form Arylomycin Core by an Engineered CYP450

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02197E, Paper
Vandana Kardam, Vaibhav Bhatt, Kshatresh Dubey
Arylomycin, a potent antibiotic targeting bacterial signal peptidases, is difficult to synthesize experimentally due to its poor to moderate yields and the formation of a mixture of compounds. A recent...
The content of this RSS Feed (c) The Royal Society of Chemistry




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LDH-derived Co0.5Ni0.5Te2 Dispersed in 3D Carbon Sheets as Separator Modifier to Enable Kinetics-Accelerated Lithium-Sulfur Batteries

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02619E, Paper
Chunmei Li, kan Mi, Kai Xu, Zhuo Jia, Xiaolei Jiang, Huili Peng, Xiuwen Zheng, Hongjiao Nie
Lithium-sulfur battery is considered as a powerful candidate for the next generation of advanced energy storage systems relying on its high energy density and theoretical specific capacity. However, its practical...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Rhenium(I) and technetium(I) complexes with megazol derivatives: towards the development of a theranostic platform for Chagas disease

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02714K, Paper
Ana Cristina Resende Gonçalves, Silvia Helena Libardi, Júlio Cesar Borges, Ronaldo Junio de Oliveira, Carla Gotzmann, Olivier Blacque, Sergio Albuquerque, Carla Duque Lopes, Roger Alberto, Pedro Ivo da Silva Maia
The diagnosis and treatment of Chagas disease (CD) in the chronic phase remains a challenge. With that in mind, a potential theranostic device based on the trypanocidal agent known as...
The content of this RSS Feed (c) The Royal Society of Chemistry




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An octanuclear 3-phenyl-5-(2-pyridyl)pyrazolate/phenylsilsesquioxane complex: synthesis, unique structure, and catalytic activity

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02690J, Communication
Alexey Bilyachenko, Victor N Khrustalev, Zhibin Huang, Lidia S. Shul'pina, Pavel Dorovatovskii, Elena Shubina, Nikolay S. Ikonnikov, Nikolai N. Lobanov, Karim G. Rahimov, Di Sun
First metallasilsesquioxane bearing pyrazolylpyridine ligands, Cu8-based complex 1, adopts cage structure with two zigzag-like copper tetramers sandwiched by two cyclic Si5 silsesquioxane ligands. Four 3-phenyl-5-(2-pyridyl)pyrazolate ligands in 1 exhibit dual...
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Achieving isopropenyl-enriched polyisoprene: unraveling the role of bidentate vs. tridentate iron precatalysts through ligand framework design

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02659D, Paper
Sunny Sohail, Yanping Ma, Qaiser Mahmood, Zexu Hu, Yizhou Wang, Tongling Liang, Wen-Hua Sun
The coordination sphere and steric variations in iron catalysts present a fascinating strategy for adjusting monomer regio- and stereoselective enchainment, leading to the development of novel polymer structures in isoprene polymerization.
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Zn(II) coordination influences the secondary structure, but not antimicrobial activity of the N-terminal histatin 3 hydrolysis product

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02274B, Paper
Emilia Dzień, Joanna Wątły, Aleksandra Hecel, Aleksandra Mikołajczyk, Agnieszka Matera-Witkiewicz, Miquel Adrover, Miquel Barceló-Oliver, Alicia Domínguez-Martín, Magdalena Rowińska-Żyrek
Histatin 3 and 4 have greater activity against Gram(+) than Gram(−) bacteria, and Cu(II) or Zn(II) binding can moderately increase their antimicrobial activity. The N-terminal part of histatin 3 becomes α-helical upon Zn(II) binding.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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High-pressure synthesis and crystal structure analysis of PbTeO4, a UV transparent material

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02697G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Michael Hladik, Armin Penz, Felix R. S. Purtscher, Thomas S. Hofer, Gunter Heymann, Matthias Weil
Crystal structure of PbTeO4 with presumed position of the PbII lone-pair electrons (turquoise spheres). The electron localization function was used to emphasize the presence of the electron lone pair E.
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The mechanism of Mo-nitrogenase: from N2 capture to first release of NH3

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02606C, Paper
Ian Dance
I describe how nitrogenase catalyses N2 → HNNH → HNNH2 → NH3 + NH and how the calculated dynamics explain recent kinetics data.
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Oxaphosphiranes: isolable phosphorus-containing epoxide rings

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02915A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Niklas Volk, Antonio García Alcaraz, Selvakumar Balasubramaniam, Jannik Heumann, Gregor Schnakenburg, Arturo Espinosa Ferao, Rainer Streubel
A new efficient protocol for the synthesis of isolable oxaphosphiranes based on easy decomplexation is described. Theoretical studies unveil a singlet carbene-like FMO situation at phosphorus explaining the reactions with oxidants, acids and bases.
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