is What is the key factor affecting the cathodoluminescence intensity of europium complexes? By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02501F, CommunicationRongdeng Lu, Tinghui Huang, Alexander Goloveshkin, Dmitry Kopytov, Kseniya Orekhova, Ivan Khanbekov, Valentina V. UtochnikovaCathodoluminescence of lanthanide coordination compounds correlates with PLQY/τ in the saturation regime and with PLQY when saturation is not reached. Understanding this, a brightly cathodoluminescent europium complex was obtained.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Trigonal bipyramidal or square planar? Density functional theory calculations of iron bis(dithiolene) N-heterocyclic carbene complexes By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02650K, CommunicationKatherine Merkel, Alyssa V. B. Santos, Scott SimpsonDFT calculations of 57 iron bis(dithiolene)-N-heterocyclic carbene adducts were conducted to determine what parameters predict their coordination. The properties were compared via regression models to see which best predict the Addison τ parameter.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Titanosiloxanes Consisting of Tetrahedrally Coordinated Ti Cores and Branched Siloxane Cages By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02848A, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Shohei Saito, Kenta Kawamura, Naoto Sato, Takamichi Matsuno, Hiroaki Wada, Kazuyuki Kuroda, Atsushi ShimojimaWell-defined titanosiloxane molecules with tetrahedrally coordinated Ti centers are synthesized by using mono-silanol functionalized siloxane cages as building blocks. The Ti sites are modified with the OSi(OSi)3 units, which is...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Investigating the formation of metal nitride complexes employing a tetradentate bis-carbene bis-phenolate ligand By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT01765J, PaperRomain Kunert, Diego Martelino, Samyadeb Mahato, Nicholas Hein, Jason Pulfer, Christian Philouze, Olivier Jarjayes, Fabrice Thomas, Tim StorrThe synthesis of MnV and CrV nitride complexes of a pro-radical tetradentate bis-phenol bis-N-heterocyclic carbene ligand H2LC2O2 were investigated. Employing either azide photolysis of the MnIII precursor complex MnLC2O2(N3) or...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Solvatomorphic Phase Transitions and Tunable Luminescence Emission in Lanthanide Metal-Organic Frameworks By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02613F, PaperAlena A. Vasileva, Pavel A. Demakov, Tatiana Y. Guselnikova, Alexey A. Ryadun, Vladimir P Fedin, Danil N. DybtsevFour new metal-organic frameworks with the formulae [Sm2(phen)2(NO3)2(chdc)2]·2Solv, where Solv = N,N-dimethylformamide (DMF; 1), N,N-dimethylacetamide (DMA; 2), N,N-diethylformamide (DEF; 3), N-formylpiperidine (NFP; 4), phen = 1,10-phenanthroline and chdc2– = trans-1,4-cyclohexanedicarboxylate...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Bicyclic (Alkyl)(Amino)Carbenes (BICAACs): Synthesis, Characteristics, and Applications By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02696A, PerspectiveAnkita Sharma, Unnikrishnan Nair K, Subrata KunduCarbenes in general and isolable NHCs (N-heterocyclic carbenes) in particular have been useful ligands in recent years. The emergence of CAACs [cyclic(alkyl)(amino)carbenes], BICAACs [bicyclic(alkyl)(amino)carbenes], and many other carbenes has marked...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Development of Polyoxometalate-loaded MOF for Heterogeneous Catalysis and Enhanced Dye Adsorption By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02645D, PaperKetan Maru, Sarita Kalla, Ritambhara JangirThe study focuses here on the enhancement of MIL-117 functionality by incorporating well-known polyoxometalate (POM); tetrabutylammonium octamolybdate [(n-C4H9)4N]4[Mo8O26]. Using an encapsulation method with conventional heating, Mo8O264- anions were first time...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Hydrate of neutral iron(III) complex based on pyruvic acid thiosemicarbazone ligand with abrupt spin-crossover with T1/2=340 K and wide hysteresis loop of 45 K By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02901A, PaperMaxim Andreevich Blagov, Alexander V. Akimov, Anatoly S Lobach, Leokadiya Zorina, Sergey Simonov, Konstantin Zakharov, Alexander Vasiliev, Natalia SpitsynaThe hydrate of neutral iron(III) complex based on pyruvic acid thiosemicarbazone ligand [FeIII(Hthpy)(thpy)]·H2O (1) was synthesized and characterized using FT-IR spectroscopy, powder and single-crystal X-ray diffraction, dc magnetic measurements, EPR...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Design and theoretical analysis of a tunable bifunctional metasurface absorber based on vanadium dioxide and photoconductive silicon By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02563F, PaperChangfeng Fu, Xinke Wang, Yicheng Zhang, Jiaxin Ju, Wei Fan, Xiaobo Yan, Lianfu HanA bifunctional metasurface absorber based on vanadium dioxide (VO2) and photoconductive silicon (PSi) is proposed, which can be switched from dual- to single-broadband absorption by VO2, and the absorptivity is tunable by varying σPSi.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Extended investigation of the conductive characteristics of monoclinic tungstates with a Bi3.24Ln2W0.76O10.14 (Ln = La, Pr or Nd) composition By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02462A, PaperEkaterina I. Orlova, Yelizaveta A. Morkhova, Nikolay V. Lyskov, Anastasia V. Egorova, Egor D. Baldin, Artem A. Kabanov, Elena P. Kharitonova, Valentina I. VoronkovaMore extensive conductivity studies have been carried out on the Bi3.24Ln2W0.76O10.14 (Ln = La, Pr or Nd) Watanabe phases, resulting in a detailed understanding of the predominant oxygen-ion migration.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Accelerating the reaction kinetics of Ni1−xO/Ni(OH)2/NF by defect engineering for urea-assisted water splitting By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02871F, PaperYuan Rui, Zong Li, Miaohui Wang, Yunxia Liu, Haiping Lin, Peipei Huang, Qing LiThe reaction kinetics of Ni1-xO/Ni(OH)2/NF are accelerated through a defect engineering strategy by combining Zn doping and acid etching, leading to improved intrinsic activities for UOR.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Chemistry of organometallic nucleic acid components: personal perspectives and prospects for the future By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02634A, PerspectiveMateusz Klarek, Konrad KowalskiArticle summarizes over 12 years of studies on organometallic nucleic acid components in our laboratory. It outlines synthetic chemistry, redox, photophysical and biological properties alike. It also shows directions for future development.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Morphology-dependent Li+ ion dynamics in X-ray amorphous and crystalline Li3PS4 prepared by solvent-assisted synthesis By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02636E, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jonas Spychala, Christoph Mandl, Katharina Hogrefe, H. Martin R. Wilkening, Bernhard GadermaierIonic conductivity of Li3PS4 if synthesized by a solvent-assisted method strongly depends on overall and surface morphology. Amorphous Li3PS4 shows a rather high conductivity which is only slightly enhanced when going to the (nano-)crystalline form.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Multifunctional chiral metal hydrogen-bonded organic frameworks constructed from lanthanide ions with a trigonal prismatic coordination environment By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02131B, PaperGuo Peng, Guo-Xing Zhou, Xiang-Tao Dong, Yong-Bo Peng, Rong-Yan Zhang, Ying-Zhao Ma, Xiao-Ming RenFour multifunctional chiral lanthanide hydrogen-bonded organic frameworks with second harmonic generation, single molecule magnet behavior and proton conductive ability are reported herein.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is One-pot facile synthesis of rod-like Bi2S3 particles in deep eutectic solvent and their ppb-level selective H2S gas detection By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT03006K, CommunicationReiko Furukawa, Takuya Hasegawa, Ayahisa Okawa, Shu YinRod-like Bi2S3 particles were synthesized by one-pot reactions with choline chloride-based DESs, and showed sub-ppm level selective H2S gas detection. Acetamide-based DES yielded uniform particles with excellent gas sensitivity.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Switchable, chiral aluminium catalysts for ring opening polymerisations By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02831G, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.David T. Jenkins, Elizabeth C. Trodden, John M. Andresen, Stephen M. Mansell, Ruaraidh D. McIntoshA switchable, solvent-free catalytic system was developed in which Al catalysts selectively initiate either the formation of polyether or polycarbonate through the application of a PPNCl (bis(triphenylphosphine)iminium chloride) cocatalyst.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is The preparation of CuM/SiO2 (M=Bi, Mg, Mn) catalysts applied in ethynylation of formaldehyde for 1,4‑butynediol synthesis: the positive interface effect of CuO and Bi2O3 By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02616K, PaperJiali Chen, Guihua Yang, Feng Gao, Rui WangThe ethynylation of formaldehyde reaction catalyzed by Cu-based catalysts is an important synthesis method for 1,4-butynediol relating to high value-added chemicals. In this work, a series of CuM/SiO2 ( M=Bi,...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Highly selective organo-gallium hydroxamate mediated inhibition of antibiotic resistant Klebsiella pneumoniae By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02440K, PaperRebekah N. Duffin, Jenisi Kelderman, Megan Herdman, Philip Craig AndrewsFive complexes of gallium derived from hydroxamic acids have been synthesised, characterised, and their anti-bacterial activity and mammalian cell toxicity established. These are three metal-organic complexes; [Ga(BPHA]3 1, [Ga(BHA-H]3 2,...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is A grain-like cerium oxide nanostructure: synthesis and uric acid sensing application By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17794-17802DOI: 10.1039/D4DT02056A, PaperRafiq Ahmad, Sakeena Masrat, Md. Tabish Rehman, Mohamed F. AlAjmi, Shamshad Alam, Prabhash Mishra, Byeong-Il LeeHydrothermally prepared grain-like CeO2 nanostructures were useful for creating a high-performance and non-enzymatic sensor for uric acid detection.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is An insightful study on the reduction and extraction of neptunium assisted by molybdenum By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17909-17917DOI: 10.1039/D4DT02547D, PaperHuaixin Hao, Yaoyang Liu, Hong Cao, Zhipeng Wang, Chao Xu, Jing ChenMo dramatically boosts the extraction of Np(V) by TRPO through the catalytic reduction effect in both the aqueous phase and organic phase.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Three organic–inorganic polyoxoniobate-based compounds modified with Cu(II) amine complexes: synthesis, characterization, and catalytic studies for oxidation of styrene By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17880-17892DOI: 10.1039/D4DT02544J, PaperZhi-Cheng Duan, Guanghua Li, Ke-Chang Li, Xiao-Bing CuiThree novel organic–inorganic polyoxoniobate-based compounds modified with Cu(II) amine complexes were synthesized under hydrothermal conditions. Additionally, the catalytic efficacy of these compounds in the oxidation of styrene was investigated.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Theoretical study on the concerted catalysis of Ir/Ni for amino radical transfer for C(sp2)–C(sp3) bond formation By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18047-18053DOI: 10.1039/D4DT02567A, PaperHui Li, He ZhengInsights from DFT calculations into the synergistic Ir/Ni catalysis method for the synthesis of C(sp2)–C(sp3) bonds through an amino radical transfer (ART) strategy to generate alkyl radicals.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Optimizing synergistic effects: creating oxygen vacancies in NiCoWO4via a solid-state grinding method for improved energy storage performance By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17948-17962DOI: 10.1039/D4DT02118E, PaperAnandhavalli Jeevarathinam, Arun Annamalai, Ramya Ravichandran, Kumaresan Annamalai, Sundaravadivel ElumalaiWe disclose, for the first time we report the synthesis of an oxygen vacancy-enriched NiCoWO4 electrode by a simple solid state grinding method using NaBH4 as a mild reducing agent without any solvents.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Tunability of triplet excited states and photophysical behaviour of bis-cyclometalated iridium(III) complexes with imidazo[4,5-f][1,10]phenanthroline By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17934-17947DOI: 10.1039/D4DT01996B, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Katarzyna Choroba, Joanna Palion-Gazda, Mateusz Penkala, Patrycja Rawicka, Barbara MachuraThe impact of cyclometalating ligands on the photophysical behaviour of heteroleptic Ir(III) complexes with imidazo[4,5-f][1,10]phenanthroline. [Ir(ppy)2(imphen)]+ is a 3MLLCT emitter, while [Ir(pybzth)2(imphen)]+ has a predominant 3LCN∩C character.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is An acidity-triggered aggregation nanoplatform based on degradable mesoporous organosilica nanoparticles for precise drug delivery and phototherapy of focal bacterial infection By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17893-17901DOI: 10.1039/D4DT02111H, PaperYunhan Huang, Wei Guo, Xinyu Wang, Jingrui Chang, Bo LuAn acidity-triggered aggregation antibacterial nanoplatform based on biodegradable mesoporous organic silica nanoparticles, is reported. It enables precise drug release and spatial accuracy for photodynamic therapy and photothermal therapy.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Synthesis and relaxivity of gadolinium-based DOTAGA conjugated 3-phosphoglycerate By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17777-17782DOI: 10.1039/D4DT02766C, Communication Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Andrew R. Brotherton, Shifa Noor Mohamed, Thomas J. MeadeA Gd-DOTAGA based MR contrast agent conjugated to 3-phosphoglycerate for enhanced relaxivity and investigation into its metabolism.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is A bioinspired water oxidation catalyst that is ∼1/10th as active as the photosystem II oxygen evolving center at pH 7: a study of activity and stability factors By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17783-17788DOI: 10.1039/D4DT02336F, CommunicationDanijel Boskovic, Richard Terrett, Matthew Longhurst, Sabeel Basheer, Alireza Ariafard, Pawel Wagner, Ronald J. Pace, Rob Stranger, Gerhard F. SwiegersCa-doped birnessite MnOx on liquid crystalline reduced graphene oxide exhibits unprecedented performance for an abiological catalyst at pH 7, including a very low onset overpotential of 0.52 V and high activity per unit area at 0.56 V overpotential.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is The effect of second coordination sphere interactions on the magnetic anisotropy of transition metals By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02873B, PaperSofie S. Leiszner, Mauro Perfetti, Emil Damgaard-Møller, Yu-Sheng Chen, Bo B. IversenBy investigating second coordination sphere effects on the magnetic anisotropy of a Co(II) single molecule magnet (SMM), we aim to clarify their role in magneto-structural correlations to enhance the performance of transition metal SMMs.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is A mechanistic study of chiral manganese porphyrin-catalyzed enantioselective C–H hydroxylation reaction By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02452D, PaperJing-Kun Gao, Wandong Chen, Junjie Tai, Zhengwei Chen, Hang Liu, Yuxin Du, Yiting Jiang, Yuanbin She, Yun-Fang YangThis study uses DFT to explain the enantioselectivity of C–H hydroxylation by a chiral manganese porphyrin. A two-point hydrogen bonding favors pro-(S) C–H bond abstraction by 1.9 kcal mol−1, leading to (S)-hydroxylated products.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Reactions of a geminal Sc/P Lewis pair with pyridotetrazole and beyond By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02838D, PaperYiwen Guan, Xian Xu, Xin XuAn FLP pyridyl nitrene adduct was isolated from the denitrogenative reaction of the Sc/P complex with pyridotetrazole. FLP reactivity of the Sc/P complex with many small molecules were investigated with the generation of metallacyclic complexes.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Mechanistic studies of NOx reduction reactions involving copper complexes: encouragement of DFT calculations By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02420F, Frontier Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yohei Kametani, Yoshihito ShiotaMechanistic analysis of nitrite (NO2−) and nitric oxide (NO) reduction reactions promoted by copper complexes provides a reliable view of electron transfer and atom movement.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Synthesis of organo-uranium(II) species in the gas-phase using reactions between [UH]+ and nitriles By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02508C, PaperJustin G. Terhorst, Theodore A. Corcovilos, Samuel J. Lenze, Michael J. van StipdonkA series of gas-phase, σ-bonded [U–R]+ species (R = CH3, C2H3, C2H5, C3H7, or C5H6) can be generated by using preparative tandem mass spectrometry (PTMSn) via ion-molecule reactions between [UH]+ and neutral nitriles.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Modular synthesis of triphenylphosphine-derived cage ligands for rhodium-catalyzed hydroformylation applications By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02627F, PaperWenlong Wang, Cunyao Li, Wenhao Wang, Yuqin Qiu, Hongguang Liu, Jinlong Lu, Yizhou Zhan, Li Yan, Yunjie DingCage ligands can be easily synthesized via dynamic imine chemistry, and a specific cage ligand exhibits excellent performance in Rh-catalyzed hydroformylation reaction (TOF up to 2665 h−1 and the l/b ratio reaches 2.6).To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Cationic first-row transition metal saccharinate complexes with tris(2-pyridylmethyl)amine: synthesis, structures and anticancer studies By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02258K, PaperCeyda Icsel, Seyma Aydinlik, Muhittin Aygun, Veysel T. YilmazHighly cytotoxic dinuclear oxo-bridged Fe(III) saccharinate complex with tris(2-pyridylmethyl)amine induces excessive ROS generation, mitochondrial and DNA damage in HT29 colon cancer cells.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Asymmetric triply bridged lanthanide binuclear clusters with distinctly different magnetic behaviors By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02652G, CommunicationYue Yang, Yu-Xia Wang, Yu-Zhe Lei, Peng ChengIsomorphic binuclear clusters Gd and Dy with antiferromagnetic and ferromagnetic couplings are separately exhibiting single-molecule magnetic behavior and strong magnetocaloric entropy.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Thieno[3,2-b]thiophene based-bridged BODIPY dimer: synthesis, e-chem, one- and two-photon photophysical properties By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02655A, PaperZ. Chai, Tingting Gu, Annaelle Beau, Frederic Bolze, Claude P Gros, Liang Xu, Donghai Shi, Hai-Jun XuFour BODIPY dyes (6a ~ 6d) with electron-donating or electron-withdrawing groups at the meso-position were synthesized by Sonogashira coupling reaction of thieno[3,2-b]thiophene with mono-iodo-BODIPY moiety. All compounds were fully characterized...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Detailed mechanism of DNA/RNA nucleobase substituting bridging ligand in diruthenium (II,III) and dirhodium (II,II) tetraacetato paddlewheel complexes: Protonation of the leaving acetate is crucial By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02621G, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Iogann Tolbatov, Tiziano Marzo, Paolo Umari, Diego La Mendola, Alessandro MarronePaddlewheel complexes of bimetallic scaffolds are emerging metallic agents in the bioinorganic chemistry landscape. In the most commonly employed construct, these complexes are decorated by carboxylate moiety, prompting their possible...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
is Single-ion magnetism in novel Btp-based cobalt complexes of different charge By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02338B, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Gustavo Rama-Martínez, Marcelo Osorio-Celis, Yolanda Sabater-Algarra, Diego Sánchez-Brunete, Antonio L. Llamas-Saiz, Eugenia P. Quirós-Díez, M. Eugenio Vázquez, Miguel Vázquez López, María del Carmen Giménez LópezBy deprotonating Btp-derived ligands, precise control over counterions in the outer-coordination sphere is achieved in both neutral and charged anisotropic CoII complexes exhibiting field-induced single-ion magnetism.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
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