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What is the key factor affecting the cathodoluminescence intensity of europium complexes?

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02501F, Communication
Rongdeng Lu, Tinghui Huang, Alexander Goloveshkin, Dmitry Kopytov, Kseniya Orekhova, Ivan Khanbekov, Valentina V. Utochnikova
Cathodoluminescence of lanthanide coordination compounds correlates with PLQY/τ in the saturation regime and with PLQY when saturation is not reached. Understanding this, a brightly cathodoluminescent europium complex was obtained.
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Trigonal bipyramidal or square planar? Density functional theory calculations of iron bis(dithiolene) N-heterocyclic carbene complexes

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02650K, Communication
Katherine Merkel, Alyssa V. B. Santos, Scott Simpson
DFT calculations of 57 iron bis(dithiolene)-N-heterocyclic carbene adducts were conducted to determine what parameters predict their coordination. The properties were compared via regression models to see which best predict the Addison τ parameter.
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Titanosiloxanes Consisting of Tetrahedrally Coordinated Ti Cores and Branched Siloxane Cages

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02848A, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Shohei Saito, Kenta Kawamura, Naoto Sato, Takamichi Matsuno, Hiroaki Wada, Kazuyuki Kuroda, Atsushi Shimojima
Well-defined titanosiloxane molecules with tetrahedrally coordinated Ti centers are synthesized by using mono-silanol functionalized siloxane cages as building blocks. The Ti sites are modified with the OSi(OSi)3 units, which is...
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Investigating the formation of metal nitride complexes employing a tetradentate bis-carbene bis-phenolate ligand

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT01765J, Paper
Romain Kunert, Diego Martelino, Samyadeb Mahato, Nicholas Hein, Jason Pulfer, Christian Philouze, Olivier Jarjayes, Fabrice Thomas, Tim Storr
The synthesis of MnV and CrV nitride complexes of a pro-radical tetradentate bis-phenol bis-N-heterocyclic carbene ligand H2LC2O2 were investigated. Employing either azide photolysis of the MnIII precursor complex MnLC2O2(N3) or...
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Solvatomorphic Phase Transitions and Tunable Luminescence Emission in Lanthanide Metal-Organic Frameworks

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02613F, Paper
Alena A. Vasileva, Pavel A. Demakov, Tatiana Y. Guselnikova, Alexey A. Ryadun, Vladimir P Fedin, Danil N. Dybtsev
Four new metal-organic frameworks with the formulae [Sm2(phen)2(NO3)2(chdc)2]·2Solv, where Solv = N,N-dimethylformamide (DMF; 1), N,N-dimethylacetamide (DMA; 2), N,N-diethylformamide (DEF; 3), N-formylpiperidine (NFP; 4), phen = 1,10-phenanthroline and chdc2– = trans-1,4-cyclohexanedicarboxylate...
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Bicyclic (Alkyl)(Amino)Carbenes (BICAACs): Synthesis, Characteristics, and Applications

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02696A, Perspective
Ankita Sharma, Unnikrishnan Nair K, Subrata Kundu
Carbenes in general and isolable NHCs (N-heterocyclic carbenes) in particular have been useful ligands in recent years. The emergence of CAACs [cyclic(alkyl)(amino)carbenes], BICAACs [bicyclic(alkyl)(amino)carbenes], and many other carbenes has marked...
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Development of Polyoxometalate-loaded MOF for Heterogeneous Catalysis and Enhanced Dye Adsorption

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02645D, Paper
Ketan Maru, Sarita Kalla, Ritambhara Jangir
The study focuses here on the enhancement of MIL-117 functionality by incorporating well-known polyoxometalate (POM); tetrabutylammonium octamolybdate [(n-C4H9)4N]4[Mo8O26]. Using an encapsulation method with conventional heating, Mo8O264- anions were first time...
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Hydrate of neutral iron(III) complex based on pyruvic acid thiosemicarbazone ligand with abrupt spin-crossover with T1/2=340 K and wide hysteresis loop of 45 K

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02901A, Paper
Maxim Andreevich Blagov, Alexander V. Akimov, Anatoly S Lobach, Leokadiya Zorina, Sergey Simonov, Konstantin Zakharov, Alexander Vasiliev, Natalia Spitsyna
The hydrate of neutral iron(III) complex based on pyruvic acid thiosemicarbazone ligand [FeIII(Hthpy)(thpy)]·H2O (1) was synthesized and characterized using FT-IR spectroscopy, powder and single-crystal X-ray diffraction, dc magnetic measurements, EPR...
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Design and theoretical analysis of a tunable bifunctional metasurface absorber based on vanadium dioxide and photoconductive silicon

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02563F, Paper
Changfeng Fu, Xinke Wang, Yicheng Zhang, Jiaxin Ju, Wei Fan, Xiaobo Yan, Lianfu Han
A bifunctional metasurface absorber based on vanadium dioxide (VO2) and photoconductive silicon (PSi) is proposed, which can be switched from dual- to single-broadband absorption by VO2, and the absorptivity is tunable by varying σPSi.
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Extended investigation of the conductive characteristics of monoclinic tungstates with a Bi3.24Ln2W0.76O10.14 (Ln = La, Pr or Nd) composition

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02462A, Paper
Ekaterina I. Orlova, Yelizaveta A. Morkhova, Nikolay V. Lyskov, Anastasia V. Egorova, Egor D. Baldin, Artem A. Kabanov, Elena P. Kharitonova, Valentina I. Voronkova
More extensive conductivity studies have been carried out on the Bi3.24Ln2W0.76O10.14 (Ln = La, Pr or Nd) Watanabe phases, resulting in a detailed understanding of the predominant oxygen-ion migration.
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Accelerating the reaction kinetics of Ni1−xO/Ni(OH)2/NF by defect engineering for urea-assisted water splitting

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02871F, Paper
Yuan Rui, Zong Li, Miaohui Wang, Yunxia Liu, Haiping Lin, Peipei Huang, Qing Li
The reaction kinetics of Ni1-xO/Ni(OH)2/NF are accelerated through a defect engineering strategy by combining Zn doping and acid etching, leading to improved intrinsic activities for UOR.
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Chemistry of organometallic nucleic acid components: personal perspectives and prospects for the future

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02634A, Perspective
Mateusz Klarek, Konrad Kowalski
Article summarizes over 12 years of studies on organometallic nucleic acid components in our laboratory. It outlines synthetic chemistry, redox, photophysical and biological properties alike. It also shows directions for future development.
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Morphology-dependent Li+ ion dynamics in X-ray amorphous and crystalline Li3PS4 prepared by solvent-assisted synthesis

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02636E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jonas Spychala, Christoph Mandl, Katharina Hogrefe, H. Martin R. Wilkening, Bernhard Gadermaier
Ionic conductivity of Li3PS4 if synthesized by a solvent-assisted method strongly depends on overall and surface morphology. Amorphous Li3PS4 shows a rather high conductivity which is only slightly enhanced when going to the (nano-)crystalline form.
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Multifunctional chiral metal hydrogen-bonded organic frameworks constructed from lanthanide ions with a trigonal prismatic coordination environment

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02131B, Paper
Guo Peng, Guo-Xing Zhou, Xiang-Tao Dong, Yong-Bo Peng, Rong-Yan Zhang, Ying-Zhao Ma, Xiao-Ming Ren
Four multifunctional chiral lanthanide hydrogen-bonded organic frameworks with second harmonic generation, single molecule magnet behavior and proton conductive ability are reported herein.
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One-pot facile synthesis of rod-like Bi2S3 particles in deep eutectic solvent and their ppb-level selective H2S gas detection

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT03006K, Communication
Reiko Furukawa, Takuya Hasegawa, Ayahisa Okawa, Shu Yin
Rod-like Bi2S3 particles were synthesized by one-pot reactions with choline chloride-based DESs, and showed sub-ppm level selective H2S gas detection. Acetamide-based DES yielded uniform particles with excellent gas sensitivity.
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Switchable, chiral aluminium catalysts for ring opening polymerisations

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02831G, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
David T. Jenkins, Elizabeth C. Trodden, John M. Andresen, Stephen M. Mansell, Ruaraidh D. McIntosh
A switchable, solvent-free catalytic system was developed in which Al catalysts selectively initiate either the formation of polyether or polycarbonate through the application of a PPNCl (bis(triphenylphosphine)iminium chloride) cocatalyst.
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The preparation of CuM/SiO2 (M=Bi, Mg, Mn) catalysts applied in ethynylation of formaldehyde for 1,4‑butynediol synthesis: the positive interface effect of CuO and Bi2O3

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02616K, Paper
Jiali Chen, Guihua Yang, Feng Gao, Rui Wang
The ethynylation of formaldehyde reaction catalyzed by Cu-based catalysts is an important synthesis method for 1,4-butynediol relating to high value-added chemicals. In this work, a series of CuM/SiO2 ( M=Bi,...
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Highly selective organo-gallium hydroxamate mediated inhibition of antibiotic resistant Klebsiella pneumoniae

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02440K, Paper
Rebekah N. Duffin, Jenisi Kelderman, Megan Herdman, Philip Craig Andrews
Five complexes of gallium derived from hydroxamic acids have been synthesised, characterised, and their anti-bacterial activity and mammalian cell toxicity established. These are three metal-organic complexes; [Ga(BPHA]3 1, [Ga(BHA-H]3 2,...
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A grain-like cerium oxide nanostructure: synthesis and uric acid sensing application

Dalton Trans., 2024, 53,17794-17802
DOI: 10.1039/D4DT02056A, Paper
Rafiq Ahmad, Sakeena Masrat, Md. Tabish Rehman, Mohamed F. AlAjmi, Shamshad Alam, Prabhash Mishra, Byeong-Il Lee
Hydrothermally prepared grain-like CeO2 nanostructures were useful for creating a high-performance and non-enzymatic sensor for uric acid detection.
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An insightful study on the reduction and extraction of neptunium assisted by molybdenum

Dalton Trans., 2024, 53,17909-17917
DOI: 10.1039/D4DT02547D, Paper
Huaixin Hao, Yaoyang Liu, Hong Cao, Zhipeng Wang, Chao Xu, Jing Chen
Mo dramatically boosts the extraction of Np(V) by TRPO through the catalytic reduction effect in both the aqueous phase and organic phase.
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Three organic–inorganic polyoxoniobate-based compounds modified with Cu(II) amine complexes: synthesis, characterization, and catalytic studies for oxidation of styrene

Dalton Trans., 2024, 53,17880-17892
DOI: 10.1039/D4DT02544J, Paper
Zhi-Cheng Duan, Guanghua Li, Ke-Chang Li, Xiao-Bing Cui
Three novel organic–inorganic polyoxoniobate-based compounds modified with Cu(II) amine complexes were synthesized under hydrothermal conditions. Additionally, the catalytic efficacy of these compounds in the oxidation of styrene was investigated.
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Theoretical study on the concerted catalysis of Ir/Ni for amino radical transfer for C(sp2)–C(sp3) bond formation

Dalton Trans., 2024, 53,18047-18053
DOI: 10.1039/D4DT02567A, Paper
Hui Li, He Zheng
Insights from DFT calculations into the synergistic Ir/Ni catalysis method for the synthesis of C(sp2)–C(sp3) bonds through an amino radical transfer (ART) strategy to generate alkyl radicals.
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Optimizing synergistic effects: creating oxygen vacancies in NiCoWO4via a solid-state grinding method for improved energy storage performance

Dalton Trans., 2024, 53,17948-17962
DOI: 10.1039/D4DT02118E, Paper
Anandhavalli Jeevarathinam, Arun Annamalai, Ramya Ravichandran, Kumaresan Annamalai, Sundaravadivel Elumalai
We disclose, for the first time we report the synthesis of an oxygen vacancy-enriched NiCoWO4 electrode by a simple solid state grinding method using NaBH4 as a mild reducing agent without any solvents.
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Tunability of triplet excited states and photophysical behaviour of bis-cyclometalated iridium(III) complexes with imidazo[4,5-f][1,10]phenanthroline

Dalton Trans., 2024, 53,17934-17947
DOI: 10.1039/D4DT01996B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Katarzyna Choroba, Joanna Palion-Gazda, Mateusz Penkala, Patrycja Rawicka, Barbara Machura
The impact of cyclometalating ligands on the photophysical behaviour of heteroleptic Ir(III) complexes with imidazo[4,5-f][1,10]phenanthroline. [Ir(ppy)2(imphen)]+ is a 3MLLCT emitter, while [Ir(pybzth)2(imphen)]+ has a predominant 3LCN∩C character.
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An acidity-triggered aggregation nanoplatform based on degradable mesoporous organosilica nanoparticles for precise drug delivery and phototherapy of focal bacterial infection

Dalton Trans., 2024, 53,17893-17901
DOI: 10.1039/D4DT02111H, Paper
Yunhan Huang, Wei Guo, Xinyu Wang, Jingrui Chang, Bo Lu
An acidity-triggered aggregation antibacterial nanoplatform based on biodegradable mesoporous organic silica nanoparticles, is reported. It enables precise drug release and spatial accuracy for photodynamic therapy and photothermal therapy.
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Synthesis and relaxivity of gadolinium-based DOTAGA conjugated 3-phosphoglycerate

Dalton Trans., 2024, 53,17777-17782
DOI: 10.1039/D4DT02766C, Communication
Open Access
Andrew R. Brotherton, Shifa Noor Mohamed, Thomas J. Meade
A Gd-DOTAGA based MR contrast agent conjugated to 3-phosphoglycerate for enhanced relaxivity and investigation into its metabolism.
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A bioinspired water oxidation catalyst that is ∼1/10th as active as the photosystem II oxygen evolving center at pH 7: a study of activity and stability factors

Dalton Trans., 2024, 53,17783-17788
DOI: 10.1039/D4DT02336F, Communication
Danijel Boskovic, Richard Terrett, Matthew Longhurst, Sabeel Basheer, Alireza Ariafard, Pawel Wagner, Ronald J. Pace, Rob Stranger, Gerhard F. Swiegers
Ca-doped birnessite MnOx on liquid crystalline reduced graphene oxide exhibits unprecedented performance for an abiological catalyst at pH 7, including a very low onset overpotential of 0.52 V and high activity per unit area at 0.56 V overpotential.
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The effect of second coordination sphere interactions on the magnetic anisotropy of transition metals

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02873B, Paper
Sofie S. Leiszner, Mauro Perfetti, Emil Damgaard-Møller, Yu-Sheng Chen, Bo B. Iversen
By investigating second coordination sphere effects on the magnetic anisotropy of a Co(II) single molecule magnet (SMM), we aim to clarify their role in magneto-structural correlations to enhance the performance of transition metal SMMs.
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A mechanistic study of chiral manganese porphyrin-catalyzed enantioselective C–H hydroxylation reaction

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02452D, Paper
Jing-Kun Gao, Wandong Chen, Junjie Tai, Zhengwei Chen, Hang Liu, Yuxin Du, Yiting Jiang, Yuanbin She, Yun-Fang Yang
This study uses DFT to explain the enantioselectivity of C–H hydroxylation by a chiral manganese porphyrin. A two-point hydrogen bonding favors pro-(S) C–H bond abstraction by 1.9 kcal mol−1, leading to (S)-hydroxylated products.
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Reactions of a geminal Sc/P Lewis pair with pyridotetrazole and beyond

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02838D, Paper
Yiwen Guan, Xian Xu, Xin Xu
An FLP pyridyl nitrene adduct was isolated from the denitrogenative reaction of the Sc/P complex with pyridotetrazole. FLP reactivity of the Sc/P complex with many small molecules were investigated with the generation of metallacyclic complexes.
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Mechanistic studies of NOx reduction reactions involving copper complexes: encouragement of DFT calculations

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02420F, Frontier
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yohei Kametani, Yoshihito Shiota
Mechanistic analysis of nitrite (NO2) and nitric oxide (NO) reduction reactions promoted by copper complexes provides a reliable view of electron transfer and atom movement.
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Synthesis of organo-uranium(II) species in the gas-phase using reactions between [UH]+ and nitriles

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02508C, Paper
Justin G. Terhorst, Theodore A. Corcovilos, Samuel J. Lenze, Michael J. van Stipdonk
A series of gas-phase, σ-bonded [U–R]+ species (R = CH3, C2H3, C2H5, C3H7, or C5H6) can be generated by using preparative tandem mass spectrometry (PTMSn) via ion-molecule reactions between [UH]+ and neutral nitriles.
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Modular synthesis of triphenylphosphine-derived cage ligands for rhodium-catalyzed hydroformylation applications

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02627F, Paper
Wenlong Wang, Cunyao Li, Wenhao Wang, Yuqin Qiu, Hongguang Liu, Jinlong Lu, Yizhou Zhan, Li Yan, Yunjie Ding
Cage ligands can be easily synthesized via dynamic imine chemistry, and a specific cage ligand exhibits excellent performance in Rh-catalyzed hydroformylation reaction (TOF up to 2665 h−1 and the l/b ratio reaches 2.6).
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Cationic first-row transition metal saccharinate complexes with tris(2-pyridylmethyl)amine: synthesis, structures and anticancer studies

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02258K, Paper
Ceyda Icsel, Seyma Aydinlik, Muhittin Aygun, Veysel T. Yilmaz
Highly cytotoxic dinuclear oxo-bridged Fe(III) saccharinate complex with tris(2-pyridylmethyl)amine induces excessive ROS generation, mitochondrial and DNA damage in HT29 colon cancer cells.
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Asymmetric triply bridged lanthanide binuclear clusters with distinctly different magnetic behaviors

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02652G, Communication
Yue Yang, Yu-Xia Wang, Yu-Zhe Lei, Peng Cheng
Isomorphic binuclear clusters Gd and Dy with antiferromagnetic and ferromagnetic couplings are separately exhibiting single-molecule magnetic behavior and strong magnetocaloric entropy.
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Thieno[3,2-b]thiophene based-bridged BODIPY dimer: synthesis, e-chem, one- and two-photon photophysical properties

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02655A, Paper
Z. Chai, Tingting Gu, Annaelle Beau, Frederic Bolze, Claude P Gros, Liang Xu, Donghai Shi, Hai-Jun Xu
Four BODIPY dyes (6a ~ 6d) with electron-donating or electron-withdrawing groups at the meso-position were synthesized by Sonogashira coupling reaction of thieno[3,2-b]thiophene with mono-iodo-BODIPY moiety. All compounds were fully characterized...
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Detailed mechanism of DNA/RNA nucleobase substituting bridging ligand in diruthenium (II,III) and dirhodium (II,II) tetraacetato paddlewheel complexes: Protonation of the leaving acetate is crucial

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02621G, Paper
Open Access
Iogann Tolbatov, Tiziano Marzo, Paolo Umari, Diego La Mendola, Alessandro Marrone
Paddlewheel complexes of bimetallic scaffolds are emerging metallic agents in the bioinorganic chemistry landscape. In the most commonly employed construct, these complexes are decorated by carboxylate moiety, prompting their possible...
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Single-ion magnetism in novel Btp-based cobalt complexes of different charge

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02338B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Gustavo Rama-Martínez, Marcelo Osorio-Celis, Yolanda Sabater-Algarra, Diego Sánchez-Brunete, Antonio L. Llamas-Saiz, Eugenia P. Quirós-Díez, M. Eugenio Vázquez, Miguel Vázquez López, María del Carmen Giménez López
By deprotonating Btp-derived ligands, precise control over counterions in the outer-coordination sphere is achieved in both neutral and charged anisotropic CoII complexes exhibiting field-induced single-ion magnetism.
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Achieving gender parity is still a dream

Antiquated stereotypes about the roles and responsibilities of women are a pain




is

Shedding light on local history

It’s the lifeblood of community identities and is vital for preserving cultural heritage




is

Self-care is the best healing

Work on building your network, wear a smile and genuinely thank those who assist in your daily work




is

Real is rational and rational is real

They may seem inextricably intertwined, but their relationship is a complex interplay of a myriad forces




is

Rising stars: Chani Nava and Will Chen

Interview with early-career scientists in astronomy and quantitative ecology




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Rising stars: Anzar Abbas and Katie Wu

Interview with early-career scientists in immunology and neuroscience




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Rising stars: Sadie Witkowski and Michael Graw

Interview with early-career scientists in psychology and oceanography




is

J&K students in Holenarasipur complain against nursing college; HIMS director says issue resolved




is

Karnataka byelection: It is a proxy war between Lad and Reddy in mineral-rich Sandur

Though Sandur has been the hotbed of mining activities, often hitting the headlines for illegal mining, this issue is barely resonating in the campaign




is

Meeting on Nirmala Tungabhadra Abhiyana organised in Shivamogga




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Siddaramaiah, Shivakumar term PM’s allegations of raising ₹700 cr. to fund Maharashtra polls as a ‘lie’




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Cheluvarayaswamy accuses HDK of collecting ₹1,000 cr. from steel industries to fund elections; JD(S) terms it a strategy to divert attention from ‘excise scam’

After Prime Minister Narendra Modi accused the Congress government of collecting ₹700 crore from excise sources to fund the Maharashtra elections, it was the turn of N. Cheluvarayaswamy