Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00925H, Paper

George E. P. O'Connell, Richard F. Webster, Elise Elkington, Rose Amal, Jason Scott, Emma C. Lovell
Introducing light to thermal DRM may be an effective strategy to improve catalyst stability, but light's role in the stability mechanism is not well understood.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00924J, Paper

Xihui Yang, Zekun Li, Zikun Yang, Dapeng Meng, Zhao Wang
CoNi@C core–shell catalysts from ZIF-67 were synthesized for efficient water splitting. The hydrophilic carbon shell inhibits metal oxidation. The CoNi alloy serves as the active site, while nitrogen doping promotes the electrocatalytic performance.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00719K, Paper

Open Access

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Ming Wei, Liuhua Mu, Zhiwei Liu, Feng Gao, Guangjian Song, Qiankang Si, Mao Zhang, Fangfang Dai, Min Zhang, Rui Ding, Li Yang, Zhonggui Gao, Sanzhao Song
Ultrasmall RuO₂/CoFe₂O₄ nanoparticles with strong interfacial interactions exhibit enhanced oxygen evolution reaction (OER) performance, driven by efficient charge transfer between RuO₂ and CoFe₂O₄.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00987H, Paper

Juanjo Mateu-Campos, María Gutiérrez-Blanco, Eva Guillamón, Vicent S. Safont, Rosa Llusar
Air-stable diamino Mo₃S₄ clusters are efficient catalysts for the late-stage functionalization of drugs and other valuable products containing sulfide moieties.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01031K, Paper

Xinwan Zhao, Minjun Lei, Guangbo Liu, Zhiliang Jin, Noritatsu Tsubaki
A fundamental strategy for enhancing the performance of photocatalytic water-splitting catalysts is to facilitate the efficient migration of photogenerated charge carriers to establish a heterojunction.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01029A, Paper

Haiting Ye, Takuma Sato, Taishi Nakanishi, Shigetomo Ito, Shigenobu Umemiya, Masahiro Terada
Chiral phosphoric acid catalysts were screened rationally and efficiently through the theoretical prediction model of the kinetic resolution of racemic γ-hydroxybutyrate without performing an exhaustive search for plausible lactonisation pathways.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01132E, Paper

Zaili Xiong, Jijun Guo, Yuwen Deng, Meirong Zeng, Zhandong Wang, Zhongyue Zhou, Wenhao Yuan, Fei Qi
This study investigates the oxidative coupling of methane (OCM) using a Li/MgO catalyst in a packed bed reactor.
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Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY00825A, Paper

Kanchan Sharma, Rajesh K. Yadav, Rajesh Kumar Verma, Satyam Singh, Shaifali Mishra, Rehana Shahin, Atul Pratap Singh, Chandani Singh, Navneet Kumar Gupta, Jin-Ook Baeg, Hwanhui Yun, Hyeongjoong Kim
Incorporating defects through intrinsic defect engineering has emerged as a versatile strategy for finely tuning key properties of materials, particularly the redox capacity. Defects are fundamentally important in enhancement of...
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00889H, Paper

Hanggara Sudrajat, Dmytro Lisovytskiy, Juan Carlos Colmenares
The enhancement of the partial oxidation of an aromatic alcohol to its corresponding aldehyde through the coupling of Cu₂O with CuO is comprehensively discussed.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00703D, Paper

Open Access

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Anna Vidal-López, Estefanía Díaz López, Aleix Comas-Vives
First-principles calculations show the crucial role of the Cu/Mo₂CO_x interface in enabling low-energy pathways for CO₂/CO hydrogenation to methanol via successive heterolytic H₂ cleavages.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00821A, Review Article

Toyese Oyegoke, Franck Dumeignil, Baba E.-Yakubu Jibril, Carine Michel, Robert Wojcieszak
This review explores the mechanisms and factors influencing the selective oxidation of HMF and furfural into valuable products using gold, platinum, and palladium catalysts.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00995A, Paper

Tiantian Liu, Kang Lv, Xiaoguang Bao
A detailed computational study was performed to shed light on the mechanistic differences between the Ru(II) and Zn(II)-catalyzed cross-coupling of cyclopropenes with diazo compounds.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00685B, Paper

Ray Miyazaki, Somayeh Faraji, Sergey V. Levchenko, Lucas Foppa, Matthias Scheffler
Vibrational frequencies can be utilized as a reference to assess the reliability of the exchange–correlation functionals.
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Catal. Sci. Technol., 2024, 14,6233-6246
DOI: 10.1039/D4CY00809J, Paper

Yongkang Zhang, Yuting Fu, Kaibin Su, Yuhang Wang, Fengping Wang
Indoor formaldehyde (HCHO) removal holds paramount significance for human health, particularly in mild conditions. Fe₁/Ti₂CO₂ is an efficient catalyst that can remove indoor formaldehyde.
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Catal. Sci. Technol., 2024, 14,6215-6223
DOI: 10.1039/D4CY00639A, Paper

Wen-Wang Yu, Xiang-Guang Meng, Zi-Yu Gan, Wen Li, Yu-Lian Zhang, Jie Zhou
Highly efficient capture and conversion of CO₂ into cyclic carbonates from flue gas under atmospheric pressure.
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Catal. Sci. Technol., 2024, 14,6224-6232
DOI: 10.1039/D4CY00781F, Paper

Chen Qin, Xuheng Li, Haoyang Li, Ting Wang, Xue Zhang, Yuyao Wang, Fuping Pan, Kai-Jie Chen
The spontaneous oxidization/reduction of the Cu surface occurs during CO₂ reduction, resulting in the dynamic evolution of i-CuO_x species. The in situ formed i-CuO_x plays decisive roles in promoting C–C coupling.
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Catal. Sci. Technol., 2024, 14,6286-6297
DOI: 10.1039/D4CY00755G, Paper

Yuzheng Li, Xianbao Duan, Zhang Liu, Caoran Li, Fangwen Ye, Zhihong Zhang, Liuqing Chen, Chun Du, Qingbo Wang, Bin Shan
Pt–Rh alloy nanoparticles featuring surfaces with both Pt and Rh atoms are poised to demonstrate bifunctional catalytic prowess in the NO + CO reaction.
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Catal. Sci. Technol., 2024, 14,6207-6214
DOI: 10.1039/D4CY00564C, Paper

Kio Kawata, Shoji Iguchi, Shimpei Naniwa, Tsunehiro Tanaka, Masamu Nishimoto, Kentaro Teramura
Towards the realisation of carbon neutrality by utilising renewable energy sources, the photocatalytic conversion of CO₂ with H₂O—known as artificial photosynthesis—is important.
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Catal. Sci. Technol., 2024, 14,6411-6419
DOI: 10.1039/D4CY00808A, Paper

Manish Kumar, Bharat Singh, Sugandha Singh, Indresh Verma, Kamal K. Kar, Manas K. Ghorai
A metal-free, conjugated organic polymer (TPA-PQ)-catalyzed intramolecular C–H functionalization strategy for the synthesis of imidazolidines in the presence of light and O₂ is reported.
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Catal. Sci. Technol., 2024, 14,6112-6154
DOI: 10.1039/D4CY00425F, Review Article

Sarita Yadav, Sangeeta Yadav, Mookan Natarajan, Kamal Kishore Pant, Ravi Tomar
From materials science and polymer chemistry to organic synthesis and medicinal chemistry, cross-coupling has influenced many scientific fields.
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Catal. Sci. Technol., 2024, 14,6307-6320
DOI: 10.1039/D4CY00873A, Paper

Open Access

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Yasemen Kuddusi, Maarten R. Dobbelaere, Kevin M. Van Geem, Andreas Züttel
The effect of catalyst synthesis and reaction conditions on catalytic activity were accurately predicted with an interpretable data-driven strategy. The method is demonstrated for CO₂ methanation and is extendable to other catalytic processes.
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Catal. Sci. Technol., 2024, 14,6270-6277
DOI: 10.1039/D4CY00502C, Paper

Yao Ning, Yuqi Yang, Dongming Shan, Shuxing Mei, Yibai Yan, Linjie Ding, Ying Zhang
Ethylene oligomerization plays an important role in industrial production.
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Catal. Sci. Technol., 2024, 14,6363-6371
DOI: 10.1039/D4CY00912F, Paper

Junchao Huang, Borui Li, Jiaxing Yu, Zhan Shu, Ming Li
The Z-scheme three-dimensional flower-like shape BiOBr/ZnIn₂S₄ showed excellent efficiency to degrade Congo red.
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Catal. Sci. Technol., 2024, 14,6259-6269
DOI: 10.1039/D4CY00992D, Paper

Open Access

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Greta G. Zámbó, Carla A. Esslinger, Michael J. Sauer, Isabelle Rüter, Robert M. Reich, Serhiy Demeshko, Franc Meyer, Fritz E. Kühn
Macrocyclic and abnormal NHC iron complexes are characterised, showing high catalytic activity in epoxidation reaction and potential for ligand design.
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Catal. Sci. Technol., 2024, 14,6351-6362
DOI: 10.1039/D4CY00893F, Paper

Jiaxuan Li, Xin Chen, Siyu Li, Kunrong Mei, Lequan Liu, Jinhua Ye
An O₃–Fe/TiO₂ reactor is designed for efficient air disinfection by catalytically converting ozone into reactive oxygen species (ROS).
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Catal. Sci. Technol., 2024, 14,6393-6410
DOI: 10.1039/D4CY00586D, Paper

Open Access

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Lulu Chen, Ying-Ying Ye, Rozemarijn D. E. Krösschell, Emiel J. M. Hensen, Ivo A. W. Filot
The selection of TiO₂ phase, whether anatase or rutile, for supporting small Ni clusters significantly influences the activity and selectivity in CO₂ hydrogenation to methane.
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Catal. Sci. Technol., 2024, 14,6372-6379
DOI: 10.1039/D4CY00905C, Paper

Shi-Jiao Dong, Sai Huang, Ao Wang, Yan Meng, Gang Xu, Jun-Ling Song
The electrochemical reduction of nitrate to NH₃ can be a promising and sustainable alternative for the industrially used, energy-intensive Haber–Bosch process under mild conditions and also solve the issue of nitrate nitrogen pollution in water.
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Catal. Sci. Technol., 2024, 14,6198-6206
DOI: 10.1039/D4CY00945B, Paper

Jinwon Choi, Amol Pophali, Byeongseok Kim, Kwangsuk Yoon, Thomas You-Seok Kim, Hocheol Song, Sang Eun Shim, Jaewoo Kim, Taejin Kim
RuO_x/BNNT catalysts were prepared with varying metal loadings and under oxidation and reduction conditions. RuO_x/BNNT showed superior catalytic activity than Ru/BNNT. The catalyst will be favorable to the ER mechanism over the LH mechanism.
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Catal. Sci. Technol., 2024, 14,6380-6392
DOI: 10.1039/D4CY00923A, Paper

Mengyan Huang, Bo Liu, Junwei Wu, Junfeng Gu, Yichen Zheng, Peiyan Ma, Bei Li, Zhengyi Fu
The carboxyl groups in CC-MoC@MoS₂ play a similar role to the amino acid residues in PS II.
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Catal. Sci. Technol., 2024, 14,6176-6179
DOI: 10.1039/D4CY00955J, Communication

Zhaotian Wu, Xuefei Sha, Shan Wang, Huan Yang, Shaojun Zheng, Chunhui Jiang, Shu-Yang Chen, Hongfei Lu
Visible-light-induced cross-dehydrogenative coupling between cyclic imines and diaryl phosphine oxides has been developed to afford their oxyphosphide derivatives, using rhodamine B as a photocatalyst.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00979G, Paper

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Peixue Wang, Shimin Liu, Xinjiang Cui, Feng Shi
Effectively synthesis of methyl ethyl carbamate from dimethyl carbonate and ethanol using 14 wt% KATriz/Al₂O₃ in fixed bed mode.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00697F, Paper

Qingxiu Wang, Weisong Liu, Lijing Chang, Kuncheng Zhang, Yanbing Shen, Lingling Zhang
A synthetic pathway of L-guluronic acid and rational design of galactose oxidase.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01007H, Paper

Andrew C. Chien, Corinna C. Chi
The La/Ni/SDC catalyst from one pot microwave-heating gives higher methanation activity than La–Ni/SDC and Ni–La/SDC from stepwise heating.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00758A, Paper

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Tshepo Molefe, Roy Peter Forbes, Neil John Coville
Decreasing the carbon shell thickness increased the reducibility of Co₃O₄. The reducibility of Co₃O₄ was further achieved by adding an Os promoter outside of the sphere showing that H spillover was favoured over H₂ diffusion/Co reduction by carbon.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01076K, Paper

Zhaochun He, Yonghua Liu, Tao Wang
We computationally identified Ni₃Fe as a promising catalyst for the quinoline (QL) selective hydrogenation to 1,2,3,4-tetrahydroquinoline (py-THQL) using density functional theory calculations and microkinetic modeling.
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Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY00775A, Paper

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Ettore Bianco, Fabrizio Sordello, Francesco Pellegrino, Valter Maurino
In hydrogen production through water splitting, two reactions are involved: Hydrogen Evolution Reaction (HER) and Oxygen Evolution Reaction (OER), both with efficiency issues. In previous works, our group demonstrated the...
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01035C, Paper

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Matthew E. Potter, Lucas Spiske, Philipp N. Plessow, Evangeline B. McShane, Marina Carravetta, Alice E. Oakley, Takudzwa Bere, James H. Carter, Bart D. Vandegehuchte, Kamila M. Kaźmierczak, Felix Studt, Robert Raja
Using a model microporous catalyst, the influence of acid site density and partial pressure is explored in alkane isomerisation. Combining with DFT calculations shows the role of olefins in this industrially important catalytic process.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01098A, Paper

Luohe Wang, Junnan E, Xiubin Bu, Jing Zeng, Xiaobo Yang, Hua Fu, Zhen Zhao
RhCOF-SYNU-1 serves as a transition-metal catalyst, photocatalyst, and metal ligand, enabling regioselective C(sp²)–H bond functionalization and offering a sustainable approach for Rh(III) catalysis.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01115E, Paper

Xinyu Zhang, Chunlei Zhang, Siyu Gao, Xinyu Chen, Siyuan Chen, Shengran Zhou, Di Yu, Lanyi Wang, Xiaoqiang Fan, Xuehua Yu, Zhen Zhao
A series of Co₃O₄ catalysts with different morphologies were prepared by a hydrothermal method. Among them, the sea urchin shaped Co₃O₄ catalyst exhibits the best catalytic performance for soot combustion.
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01070A, Review Article

Deyu Chu, Jinjing Ma, Qishun Liu, Jie Fu, Heng Yin
Optimizing the production process of high value-added chemicals derived from renewable biomass holds immense promise for clean energy utilization and environmental sustainability.
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Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01056F, Paper

Ruitao Nie, Xiaolong Deng, Haoyu Yang, Hongwei Chen, Jie Yang, Meiyi Lu, Keqi Peng, Xiaoyu Zhou, Yang Chen, Juan Xie, Hu Wang
Electrocatalytic selective reduction of CO₂ to liquid phase products, particularly methanol, is a promising technique for CO₂ utilization. However, the challenge is daunting because the reduction of carbon dioxide to...
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Catal. Sci. Technol., 2024, 14,6503-6512
DOI: 10.1039/D4CY00760C, Paper

Bruce A. Lobo Sacchelli, Suellen M. P. Onguene, Ruben S. M. Almeida, Alexandra M. M. Antunes, Dmytro S. Nesterov, Leandro H. Andrade, Elisabete C. B. A. Alegria, Martin H. G. Prechtl
Tuning selectivities with oxidants: O₂ oxidises methanol to the carboxylate level and N₂O oxidises it to the formaldehyde level.
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Catal. Sci. Technol., 2024, 14,6443-6465
DOI: 10.1039/D4CY00822G, Review Article

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Shuang Deng, Nannan Wang, Yanqiu Zhu, Kunyapat Thummavichai
Nowadays, the excessive use of fossil fuels has led to a global energy shortage and exacerbated the greenhouse effect.
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Catal. Sci. Technol., 2024, 14,6573-6583
DOI: 10.1039/D4CY00969J, Paper

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Andrea García-Hernán, Fernando Aguilar-Galindo, Oscar Castillo, Pilar Amo-Ochoa
The study utilizes density functional theory to enhance the design and efficiency of coordination polymers for sustainable photocatalytic applications.
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Catal. Sci. Technol., 2024, 14,6584-6591
DOI: 10.1039/D4CY00970C, Paper

Chengyang Sun, Yong Guo, Xiaohui Liu, Yanqin Wang
A heterogeneous oxidative upcycling strategy converting polystyrene (PS) waste into benzoic acid.
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