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Oxygen vacancy-dependent low-temperature performance of Ni/CeO2 in CO2 methanation

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Catal. Sci. Technol., 2024, 14,6537-6549
DOI: 10.1039/D4CY00679H, Paper
Luliang Liao, Kunlei Wang, Guangfu Liao, Muhammad Asif Nawaz, Kun Liu
The transformative power of CO2 methanation can efficiently transform greenhouse gases into high-value products, aligning with the carbon neutrality goals.
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Switching of selectivity from benzaldehyde to benzoic acid using MIL-100(V) as a heterogeneous catalyst in aerobic oxidation of benzyl alcohol

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Catal. Sci. Technol., 2024, 14,6524-6536
DOI: 10.1039/D4CY00832D, Paper
Open Access
Duygu Hacıefendioğlu, Ali Tuncel
MIL-100(V) used as a heterogeneous catalyst for tunable selective oxidation of benzyl alcohol to benzaldehyde or benzoic acid by changing only the reaction temperature.
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Copper cluster complex-catalyzed C–S bond formation

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Catal. Sci. Technol., 2024, 14,6609-6620
DOI: 10.1039/D4CY00968A, Paper
Nien-Chi Chang Liao, R. Sidick Basha, Bo-Hao Shih, Chia-Chun Liu, Miao-Han Wang, Po-Heng Lin, Chin-Fa Lee
Three distinct copper cluster complexes (A–C) were synthesized and their bonding was investigated by XRD studies. These complexes effectively catalyze the C–S coupling reaction of less reactive aliphatic thiols to synthesize thioether derivatives.
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Unsupervised pattern recognition on the surface of simulated metal nanoparticles for catalytic applications

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Catal. Sci. Technol., 2024, 14,6651-6661
DOI: 10.1039/D4CY01000K, Paper
Jonathan Y. C. Ting, George Opletal, Amanda S. Barnard
The structural patterns and catalytic activities of the surface atoms of simulated metal nanoparticles are characterised by an automatable data-driven unsupervised machine learning approach.
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Flow chemistry enhances catalytic alcohol-to-alkene dehydration

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Catal. Sci. Technol., 2024, 14,6641-6650
DOI: 10.1039/D4CY00913D, Paper
Open Access
D. J. Ward, D. J. Saccomando, F. Vilela, G. Walker, S. M. Mansell
Flow chemistry helped optimise the conversion of a branched primary alcohol to an alkene. Mass balance was achieved through the elimination of by-products, including alkene oligomers, and the setup could be optimised to give up to 98% alkene product.
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Heteroatom-assisted oxygen vacancies in cerium oxide catalysts for efficient synthesis of dimethyl carbonate from CO2 and methanol

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Catal. Sci. Technol., 2024, 14,6513-6523
DOI: 10.1039/D4CY00702F, Paper
Niladri Maity, Samiyah A. Al-Jendan, Samir Barman, Nagendra Kulal, E. A. Jaseer
Heteroatom (N, S) assisted CeO2 nanorod materials exhibited enhanced catalytic efficiency in the synthesis of dimethyl carbonate from CO2 and methanol, attributed to their superior surface acidity, basicity, Ce3+ concentration, and oxygen vacancies.
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Recyclable copper(I)-catalyzed cascade C–S and C–N bond formation between 2-iodoanilines and 2-bromobenzenethiols towards functionalized phenothiazines

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Catal. Sci. Technol., 2024, 14,6561-6572
DOI: 10.1039/D4CY00888J, Paper
Yan Wang, Chengkai Luo, Li Wei, Mingzhong Cai
Heterogeneous copper-catalyzed heterocyclization between 2-iodoanilines and 2-bromothiophenols has been developed for the assembly of substituted phenothiazines.
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Highly effective solar CO2 fixation via photocatalytic carboxylation of aromatic amines with carbon dioxide over a covalent organic framework (COF) as a photocatalyst

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Catal. Sci. Technol., 2024, 14,6670-6677
DOI: 10.1039/D4CY00949E, Paper
Chandani Singh, Jae Young Kim, No-Joong Park, Rajesh Kumar Yadav, Jin-Ook Baeg
Facile synthesis of the Tp-DAMS COF as a photocatalyst for efficient solar carboxylation of aromatic amines with CO2. The CO2 conversion efficiency into carboxylic acid is 99.9% without the necessity of using stoichiometric metallic reductants.
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Boron–pyridine nitrogen cooperative catalytic conversion of carbon dioxide and epoxides to cyclic carbonates

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Catal. Sci. Technol., 2024, 14,6692-6700
DOI: 10.1039/D4CY01052C, Paper
Yu-Hui Luo, Sheng Tao, Fei Chen, Zhi-Hong Du, Hao Zhang, Min Li, Ning Liu
A type of N-heterocyclic carbene (NHC)-diboron adduct in combination with tetrabutylammonium iodide (TBAI) was used as a catalyst for the synthesis of cyclic carbonates from CO2 with epoxides.
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Study on the effect and mechanism of Ag and Bi2MoO6 modification on the CO2 photo-thermal reduction performance of g-C3N4 catalysts with localized surface plasmon resonance

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Catal. Sci. Technol., 2024, 14,6621-6640
DOI: 10.1039/D4CY00930D, Paper
Bin Guan, Junyan Chen, Zhongqi Zhuang, Zhan Gao, Zeren Ma, Xuehan Hu, Chenyu Zhu, Sikai Zhao, Kaiyou Shu, Hongtao Dang, Tiankui Zhu, Zhen Huang
As a promising future energy material, g-C3N4 as a CO2 photo-thermal-reduction catalyst can effectively convert CO2 to renewable fuel, but the low yield and low product selectivity significantly limit its further development and application.
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Enhancing coking resistance of nickel-based catalysts for dry reforming of methane via nitric oxide abatement: a support study

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Catal. Sci. Technol., 2024, 14,6678-6691
DOI: 10.1039/D4CY00936C, Paper
Open Access
Beatrice Senoner, Andrea Osti, Antonella Glisenti
How to enhance DRM and NO carbon-assisted coupling using a support?
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Correction: 1D Zn(II)/2D Cu(I) halogen pyridyl coordination polymers. Band gap engineering by DFT for predicting more efficient photocatalysts in water treatment

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Catal. Sci. Technol., 2024, 14,6720-6720
DOI: 10.1039/D4CY90084G, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Andrea García-Hernán, Fernando Aguilar-Galindo, Oscar Castillo, Pilar Amo-Ochoa
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Phenol Hydroxyl-Modified Imine-Based Covalent organic framework for enhanced solar-driven generation of H2O2 via Hydrogen Bonds

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Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01096E, Paper
Lang Chen, Song Qin, Jiahui Hang, Bo Chen, Jinyang Kang, yang zhao, Shan-Yong Chen, Yongdong Jin, Hongjian Yan, Yuanhua Wang, Xia Chuanqin
Photosynthesis of H2O2 have been considered an eco-friendly strategy. However, the concentration of H2O2 in reported studies is far from industrial requirement. Herein, we present a strategy by employing phenolic...
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Bifunctional catalysts based on PdZn/ZnO and hierarchical zeolites in the direct synthesis of dimethyl ether from CO-rich syngas: influence of the support and the Zn/Pd molar ratio

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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00860J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Bing Wang, Nicola Da Roit, Michael Zimmermann, Markus Boese, Thomas Zevaco, Silke Behrens
Pd/Zn-nanoparticles were used as precursors to study the influence of the molar Zn/Pd ratio and hierarchical HZSM-5 zeolites in the syngas-to-dimethyl ether process.
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Deciphering the role of chemisorbed CO in CO2 methanation: kinetic and mechanistic investigation over monometallic (Ru) and bimetallic (Ru–Ni) catalysts

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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01004C, Paper
Pavan Dongapure, Jyoti Tekawadia, V. Satyam Naidu, R. Nandini Devi
Supported metal catalysts have made prominent contributions to CO2 mitigation through conversion into useful chemicals.
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Anthracene-based covalent organic framework supported palladium nanoparticles for visible-light-mediated Suzuki-Miyaura cross-coupling

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Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01083C, Paper
Lei Li, Qiujie Shan, Jiyuan Zang, Lei Yu, David James Young, Zhi-Gang Ren, Hong-Xi Li
An anthracene-based covalent organic framework (COF) anchoring Pd(0) nanoparticles (Pd/AntCOF) photocatalyzed Suzuki-Miyaura cross-coupling of arylbromides and arylboronic acids in water under blue LED irradiation at ambient temperature. The AntCOF both...
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IBzH (IBenzhydryl): Sterically-Flexible N-Aliphatic N-Heterocyclic Carbenes (NHC) for Iron-Catalyzed C(sp3)–C(sp2) Cross-Coupling of Unactivated Haloalkanes

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Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01315H, Communication
Marlena Kardela, Błażej Dziuk, Roman Szostak, Michal Szostak, Elwira Bisz
Iron-catalyzed cross-coupling has emerged as a pivotal concept for the synthesis of valuable products across various facets of chemical research, including pharmaceuticals, organic materials and biological probes. In this respect,...
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Two-dimensional silicene-based technologies in oncology: an emerging avenue

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Nanoscale, 2024, 16,20048-20059
DOI: 10.1039/D4NR03565H, Minireview
Joydip Sengupta, Chaudhery Mustansar Hussain
Silicene-based technologies can be applied in photonic hyperthermia and drug delivery for oncology treatment.
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BP/GaN and BP/GaP core/shell nanowires: theoretical insights into photovoltaic and gas-sensing abilities

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Nanoscale, 2024, 16,20235-20251
DOI: 10.1039/D4NR02602K, Paper
Rishit S. Shukla, Vidit B. Zala, Sanjeev K. Gupta, P. N. Gajjar
BP/GaN and BP/GaP core/shell nanowires (CSNWs) show good sensitivity for some small oxide gases. Also, BP/GaP CSNWs show >33% photovoltaic conversion efficiency.
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An eco-friendly polycaprolactone/graphite composite as a robust freestanding electrode platform for supercapacitive energy storage

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Nanoscale, 2024, 16,20155-20167
DOI: 10.1039/D4NR03113J, Paper
Rajeev Gupta, Monika Singhal
A novel eco-friendly composite electrode/current collector made from polycaprolactone and graphite filler offers bulk conductivity, is freestanding, cost-effective, and shows supercapacitive energy storage potential with electrodeposited polyaniline.
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Morphology–electronic effects in ultra-model nanocatalysts under the CO oxidation reaction: the case of ZnO ultrathin films grown on Pt(111)

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Nanoscale, 2024, 16,20216-20227
DOI: 10.1039/D4NR02935F, Paper
Hang Liu, Lei Zhang, Sébastien Lebègue, Fabrice Bournel, Jean-Jacques Gallet, Ahmed Naitabdi
Thickness-dependent morphology and electronic properties of ZnO ultrathin films grown on Pt(111) under the CO oxidation reaction at 1 mbar.
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Ni,S co-doped Cu dendrites decorated with core–shell architecture assisted by MOF and Fe0.92Co0.08S nanoflakes on nanocellulose/graphene fibers for fabrication of flexible wire-type micro-supercapacitor

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Nanoscale, 2024, 16,20260-20279
DOI: 10.1039/D4NR02283A, Paper
Leila Naderi, Saeed Shahrokhian
A flexible 1D micro-SC was fabricated based on a multidimensional nanoarchitecture derived from MOF on foam-like microwires and FeCoS nanoflakes on nanocellulose/graphene fibers and exhibited high energy storage capability.
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Metamagnetic transition and meta-stable magnetic state in Co-doped Fe3GaTe2

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Nanoscale, 2024, 16,20252-20259
DOI: 10.1039/D4NR02622E, Paper
Hyo-Bin Ahn, Hyunjong Lim, Jaegu Song, Jisung Lee, Seung-Young Park, Minwoong Joe, Chang-Jong Kang, Kyoung-Whan Kim, Tae-Eon Park, Tuson Park, Changgu Lee
The phase diagram and M–H curves of the metamagnetic regime of (Fe1−xCox)3GaTe2 with x = 0.19–0.26 at various temperatures were studied.
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Nanoscopic visualization of microgel-immobilized cytochrome P450 enzymes and their local activity

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Nanoscale, 2024, 16,20194-20201
DOI: 10.1039/D4NR03435J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lukas Schubert, Chiara Nenninger, Maximilian Nöth, Thomke Belthle, Robert Dirk de Lange, Andrij Pich, Ulrich Schwaneberg, Dominik Wöll
The distribution and local catalytic activity of Cytochrome P450 enzymes immobilized in microgels by electrostatic interaction has been determined with a combination of in situ super-resolution fluorescence microscopy experiments.
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High sensing performance flexible nanocomposite sensor with a hybrid nanostructure constructed via nanoscale confined motion of nanofibers and nanoplatelets

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Nanoscale, 2024, 16,20288-20303
DOI: 10.1039/D4NR02541E, Paper
Zhenghui Xie, Feiran Meng, Junlong Yang, Yuhong Wang, Chul B. Park, Pengjian Gong, Guangxian Li
Hybrid 1D nanofiber/2D nanoplatelet nanocomposite foam sensor and Monte-Carlo modelling of complex 1D/2D sensing nanostructure.
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Preparation and application of high thermal conductivity phase change microcapsules with fluorescence characteristics based on a ZnWO4 shell

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Nanoscale, 2024, 16,20331-20341
DOI: 10.1039/D4NR02691H, Paper
H. Cheng, B. Tang, H. Y. Bao, F. Shan, C. X. Lu
This method produces microcapsules that possess a high thermal rate and good UV absorption and fluorescence properties, making them suitable for use in fluorescent buildings, textiles, coatings, and other applications.
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Rationalization of the light-induced electron injection mechanism in a model 1D ZnO nanowire-dye complex: insights from real-time TD-DFTB simulations

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Nanoscale, 2024, 16,20280-20287
DOI: 10.1039/D3NR06557J, Paper
Dalma M. Márquez, Carlos R. Lien-Medrano, Germán J. Soldano, Cristián G. Sánchez
Zinc oxide nanowires (ZnO NWs) possess a unique one-dimensional (1D) morphology that offers a direct pathway for charge transport.
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A negative photoconductivity photodetector based on two-dimensional Nb3Cl8

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Nanoscale, 2024, 16,20312-20318
DOI: 10.1039/D4NR03376K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Bom Lee, Xiaojie Zhang, Jinsu Kang, Byung Joo Jeong, Sooheon Cho, Kyung Hwan Choi, Jiho Jeon, Sang Hoon Lee, Dahoon Kim, Yeong Hyeop Kim, Ji-Hee Kim, Hak Ki Yu, Jae-Young Choi
We developed a Nb3Cl8-based photodetector with negative photoconductivity from 400 to 1050 nm, featuring high electron mobility, a strong Ion/Ioff ratio, and high responsivity, making it ideal for energy-efficient optoelectronic applications.
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N-Heterocyclic carbene-stabilized gold–copper nanoclusters: synthesis, bonding and mechanochromism

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Nanoscale, 2024, 16,20228-20234
DOI: 10.1039/D4NR03320E, Paper
Dongjie Zuo, Huifang Guo, Qinghua Xu, Ayisha He, Zilin Li, Simin Li, Hui Shen
The first gold–copper alloy cluster protected by both NHC and alkyne ligands was reported. The cluster displays interesting mechanochromic properties, highlighting the bright future of NHC-functionalized metal nanoclusters in materials science.
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Interplay between superconducting fluctuations and weak localization in disordered TiN thin films

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Nanoscale, 2024, 16,20319-20330
DOI: 10.1039/D4NR02639J, Paper
Sachin Yadav, Bikash Gajar, R. P. Aloysius, Sangeeta Sahoo
The interplay between superconducting fluctuations (SFs) and weak localization (WL) has been probed by temperature dependent resistance [R(T)] and magnetoresistance (MR) measurements in two-dimensional disordered superconducting TiN thin films.
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Effect of SiO2 nanofluid concentration on micro-mechanical weakening behavior of coal

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Nanoscale, 2024, 16,20100-20117
DOI: 10.1039/D4NR03750B, Paper
Quanle Zou, Bochao Xu, Weizhi Wang, Yulin Hu, Ting Liu, Qingsong Li, Tengfei Ma, Haolong Zheng, Zixuan Huo
The SiO2 nanofluids enhance coal wettability by promoting hydrogen bond formation, increasing hydrophilicity and water absorption. This weakens coal cohesion, causing softening.
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Photomanipulatable colloidal clusters from the aggregation of azo molecular glass spheres

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Nanoscale, 2024, 16,20060-20066
DOI: 10.1039/D4NR03618B, Communication
Bo Tang, Lier Wang, Xitong Ai, Chuyi Liao, Zhiyuan Xiong, Yaning He, Xiaogong Wang
Controllable fabrication of photoresponsive colloidal clusters with a wide range of adjustable sizes and complex architectures are fabricated through the aggregation, fusion and photoinduced deformation of azo colloidal spheres.
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Dual metal centers within a water-stable Co/Ni bimetallic metal-triazolate framework contribute to durable photocatalysis for water treatment

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Nanoscale, 2024, 16,20082-20088
DOI: 10.1039/D4NR03940H, Communication
Minling Zheng, Yubo Liu, Qifu Zhang, Wenjing Li, Yong Zhang, Guangxue Feng, Yating Hu, Shaoming Huang
A bimetallic CoNi-MET with fixed metal occupancy combines the strong water resistance of Co-MET with the high porosity of a Ni-MET.
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Modulating the photodynamic modality of Au22 nanoclusters through surface conjugation of arginine for promoted healing of bacteria-infected wounds

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Nanoscale, 2024, 16,20089-20099
DOI: 10.1039/D4NR03278K, Paper
Xinyue Dou, Sariah Saalah, Chel-Ken Chiam, Jianping Xie, Coswald Stephen Sipaut
An Au nanocluster (NC)-based photodynamic antibacterial is designed by conjugating arginine on the surface of Au22 NCs, achieving healing of bacteria-infected wounds via producing reactive oxygen species (ROS) and reactive nitrogen species (RNS).
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Folic acid-targeted redox responsive polylactic acid-based nanoparticles co-delivering pirarubicin and salinomycin suppress breast cancer tumor growth in vivo

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Nanoscale, 2024, 16,20131-20146
DOI: 10.1039/D4NR02365J, Paper
Priya Gupta, Ankushi Bansal, Harshdeep Kaur, Mohd Anees, Neetu Singh, Harpal Singh
Schematic illustration of design, administration, and mechanism of action of Pira/Sal dual-loaded FA-conjugated redox responsive [S-(PLA-b-PEG-CONH)]2 block copolymeric nanoparticles.
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Correction: Ce6-Conjugated and polydopamine-coated gold nanostars with enhanced photoacoustic imaging and photothermal/photodynamic therapy to inhibit lung metastasis of breast cancer

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Nanoscale, 2024, 16,20354-20355
DOI: 10.1039/D4NR90194K, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ziwei Li, Fan Yang, Di Wu, Yanhong Liu, Yang Gao, Haichen Lian, Hongxin Zhang, Zhibin Yin, Aiguo Wu, Leyong Zeng
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Retraction: Enhanced activity of vancomycin by encapsulation in hybrid magnetic nanoparticles conjugated to a cell-penetrating peptide

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Nanoscale, 2024, 16,20356-20356
DOI: 10.1039/D4NR90195A, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Wenjie Zhang, Reza Taheri-Ledari, Zoleikha Hajizadeh, Ehsan Zolfaghari, Mohammad Reza Ahghari, Ali Maleki, Michael R. Hamblin, Ye Tian
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Glycosylated AIE-active Fe (III) photosensitizer activated by tumor microenvironment for synergistic type I photodynamic and chemodynamic therapy

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Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03871A, Paper
Gai-li Feng, Wei Zhou, Jinping Qiao, Guang-Jian Liu, Guo-Wen Xing
Photodynamic therapy (PDT) and chemodynamic therapy (CDT) are both promising cancer treatments to inhibit tumor cells by generating highly cytotoxic reactive oxygen species (ROS). Herein, we report a novel tumor...
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HKUST-1 MOF Nanoparticles: Non-classical Crystallization Route in Supercritical CO2

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Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03070B, Communication
Ji Feng, Almond Lau, Igor V. Novosselov
Reducing MOF particles to the nanoscale size range is beneficial due to their increased surface-to-volume ratio, higher defects exposing metals and ligands, and short diffusion path. While great efforts have...
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Applications of nanotheranostics in the second near-infrared window in bioimaging and cancer treatment

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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03058C, Review Article
Huimin Li, Pengju Li, Jiarui Zhang, Ziyi Lin, Lintao Bai, Heyun Shen
This review summarized the application of the second near-infrared nano-platform in the field of nano-agents design, optical imaging and cancer treatment, aiming at providing profound insights into its development status and future challenges.
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Recent advances in MXene-based composites for piezoelectric sensors

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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03233K, Review Article
Long Jin, Yong Ao, Tianpei Xu, Yulin Zou, Weiqing Yang
This review systematically discusses various MXene composites, exploring the impact of incorporating different materials on the piezoelectric properties and the overall efficiency of sensors. Images reproduced with permission, full details in paper.
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Minimizing defect states through multidentate coordination and morphology regulation for enhancing the performance of inverted perovskite solar cells

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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03140G, Paper
Himangshu Baishya, Mayur Jagdishbhai Patel, Ramkrishna Das Adhikari, Deepak Yadav, Parameswar Krishnan Iyer
The interaction between CO and Pb2+ regulated grain growth, enhanced crystallinity that effectively passivated non-radiative recombination centres and CF3 group stabilizes the perovskite structure by interacting with FA and Pb cationic defects.
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Interfacial coupling of NiSe in heterostructures promotes electrocatalytic hydrolysis of MoS2

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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03180F, Paper
Feng Jiao, Jun Tang, Jinzhao Huang, Zehui Liu, Jing Xiao
NiSe@MoS2 was prepared using a hydrothermal method. Interfacial effects between the two phases lead to electronic restructuring of the interfacial region, resulting in more active sites.
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Oxygen electrode catalysis in N-doped graphene: the role of nitrogen coordination and solvation effects

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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03645J, Paper
Junxian Liu, Yun Wang, Yuantong Gu, Liangzhi Kou
The significance of explicit solvents in describing the adsorption behaviors of ORR/OER intermediates is emphasized. A higher HOMO level of active sites enhances binding to oxygen intermediates, thereby improving ORR/OER activity.
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Macroscopic chiral symmetry breaking in gelation of Fmoc-amino acids: homochiral selective secondary nucleation promoted by the choice of solvent or stirring

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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR04011B, Communication
Kentaro Tashiro
Homochiral selective secondary nucleation, promoted by the choice of solvent or stirring, was suggested as the key process for the emergence of macroscopic chiral symmetry breaking in the gelation of Fmoc amino acids.
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Controlling TiO2 photocatalytic behaviour via perhydropolysilazane-derived SiO2 ultrathin shell

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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03566F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Darya Burak, Jae Hyun Han, Joon Soo Han, In Soo Kim, Md Abdur Rahman, Joel K. W. Yang, So-Hye Cho
PHPS was transformed via TiO2 photocatalytic properties into ultrathin SiO2 shells, passivating TiO2 activity while retaining its whiteness and high refractive index—perfect for cosmetics, paints, and optical coatings.
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Facile synthesis of defective ZnS-ZnO composite nanosheets for efficient piezocatalytic H2 production

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Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03733B, Paper
Xiaoxiao Lu, Xiaojing Zhao, Xiangyu Chen, Miaoqiong Xu, Miaoling Huang, Wen-Jie Chen, Yubin Liu, Xiaoyang Pan
A facile approach was developed for the synthesis of ultrathin ZnS-ZnO nanosheets. By simply manipulating the synthetic temperature, ZnS-ZnO composite nanosheets with sulfur vacancy are successfully obtained using ZnS(en)0.5 as...
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DON encapsulated carbon dot–vesicle conjugate in therapeutic intervention of lung adenocarcinoma by dual targeting of CD44 and SLC1A5

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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR00426D, Paper
Afreen Zaman, Aparajita Ghosh, Anup Kumar Ghosh, Prasanta Kumar Das
HACD–TMAV, a carbon dot–vesicle conjugate, selectively delivered glutamine inhibitor DON to CD44-enriched cancer cells, inducing ROS triggered apoptosis by dual targeting CD44 and SLC1A5 through downregulation of PI3K/AKT/mTOR signalling cascade.
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Photoemission spectroscopy and microscopy for Ta@Si16 superatoms and their assembled layers

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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR02778G, Paper
Open Access
Masahiro Shibuta, Tsutomu Ohta, Toshiaki Kamoshida, Kana Yamagiwa, Hironori Tsunoyama, Tomoya Inoue, Tsugunosuke Masubuchi, Atsushi Nakajima
An alkaline-like Ta-encapsulating Si16 superatom film was fabricated on a C60 substrate. Charge transfer between Ta@Si16 and C60 lowers the work function. In the multilayer film, the central Ta atom's positive charge is compensated by the Si16 cage.
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Polylactic acid/chitosan-IKVAV Janus film serving as a dual functional platform for spinal cord injury repair

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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR02248C, Paper
Liyang Yu, Haoyong Jin, He Xia, Xiaoxiong Wang, Liang Wang, Dezheng Li, Jiangli Zhao, Yuanhua Sang, Jichuan Qiu, Ning Lu, Hong Liu, Ning Yang
Schematic showing the PLA/CS-IKVAV Janus film for promoting neuronal differentiation and SCI repair.
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