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Amphipathic Emulsion Binder for Enhanced Performance of Lithium-Sulfur Batteries

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01037J, Paper
Yuan He, Xulong Jing, Tianxing Lai, Dong Jiang, Chao Wan, Pavel S Postnikov, Olga Guselnikova, Lixin Xu, Xiaojun He, Yusuke Yamauchi , Biyu Jin
The application of polyvinylidene fluoride (PVDF) binder in lithium-sulfur batteries faces challenges due to inadequate adhesion, undesirable conductivities, limited lithium polysulfides absorbability, and its dependence on the use of toxic...
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Constructing vacancy-rich metal phosphates by the spatial effect of ionic oligomers for enhanced OER activity

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01706D, Paper
Yida Zhao, Xinyu He, Xiaoming Ma, Zhengxi Guo, Menghui Qi, Zhaoming Liu, Ruikang Tang
By rationally selecting ionic oligomers as building blocks, sub-nano-sized gaps can be constructed in the solid structure of catalysts. This can overcome the inherent limitations associated with vacancy formation of the traditional nucleation pathway.
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S-doped TiN supported N, P, S-tridoped TiO2 with hetero-phase junctions for fuel cell startup/shutdown durability

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01475H, Paper
Mitsuharu Chisaka, Jubair A. Shamim, Wei-Lun Hsu, Hirofumi Daiguji
A platinum group metal-free S-doped TiN-supported N, P, S-tridoped TiO2 catalyst with anatase/rutile TiO2 hetero-phase junctions is revealed to display a high durability against fuel cell startup/shutdown cycles not to lose its anion dopants.
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Efficient first principles based modeling via machine learning: from simple representations to high entropy materials

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00982G, Paper
Kangming Li, Kamal Choudhary, Brian DeCost, Michael Greenwood, Jason Hattrick-Simpers
Generalization performance of machine learning models: (upper panel) generalization from small ordered to large disordered structures (SQS); (lower panel) generalization from low-order to high-order systems.
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Insight into piezoelectricity modulation mechanism of ZnO doped with Y ions

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01317D, Paper
Zihan Wang, Yue Sun, Shenglong Wang, Da Xiong, Guo Tian, Longchao Huang, Boling Lan, Long Jin, Weiqing Yang, Weili Deng
ZnO is a performance-rich material due to its unique coupling of piezoelectricity and semiconductor properties. However, the intrinsic piezoelectric screening effect of ZnO weakens the electromechanical conversion efficiency and greatly...
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The Role of Mn in Boosting Wide Potential Window on Solid Solution Derived Electrodes for Aqueous Supercapacitors

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00979G, Paper
Ziying Shi, Enzuo Liu, Biao Chen, Junwei Sha, Lihua Qian, Zhijia Zhang, Xiaopeng Han, Wenbin Hu, Chunnian He, Naiqin Zhao, Jianli Kang
The interaction mechanism of the multi-element oxide electrodes remains a challenge, despite the fact that their synergy can not only improve the electronic structure, but also broaden the working potential...
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Highly selective and high-performance sulfonated poly(ether ether ketone)-based hybrid membrane enabled by complexed UiO-66-NH2 and sulfonated graphitic carbon nitride for vanadium flow battery

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00988F, Paper
Caiyuan Zhao, Haixia Wang, Lang Li, Liping Liu, Xinrui Cui, Haifeng Shi
A series of sulfonated poly(ether ether ketone) (SPEEK) hybrid membranes (SPEEK/NF) with a constant 1 wt% complexed nanofillers (NF) comprising of UiO-66-NH2 and sulfonated graphitic carbon nitride (s-g-C3N4) are prepared...
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Enhanced surface reconstruction of V-Doped Ni3N driven by strong OH adsorption to boost 5-hydroxymethylfurfural electrooxidation for energy-saving H2 production

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01543F, Paper
Qi Zhou, Juan Wang, Ga Jin, Huiling Liu, Cheng Wang
Coupling biomass electrooxidation with hydrogen evolution reaction (HER) provides an alternative approach for simultaneously increasing the energy efficiency of H2 production and producing high value-added chemicals. Here, a V-doped Ni3N...
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Toward record high Zn2+ storage in carbon electrodes via pore confinement engineering

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01191K, Paper
Xiubo Zhang, Chang Yu, Yuanyang Xie, Jinhe Yu, Yingbin Liu, Yi Yang, Jianjian Wang, Shuqin Lan, Siyi Hou, Kunlun Liu, Jieshan Qiu
The effective specific surface area is proposed and well correlated with Zn2+ storage, guiding maximum Zn2+ storage within carbon. Multiple in situ spectroscopy techniques clarify the co-adsorption mechanism of hydrated Zn2+, SO42−, and H+.
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Kirk Cousins has right shoulder, right elbow injuries

Falcons quarterback Kirk Cousins has worked hard to fully overcome the Achilles injury that ended his 2023 season prematurely.




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Breaking the Trade-off Between ∆EST and Oscillator Strength in Hybrid LR/SR-CT Compounds for Enhanced TADF Performance

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC04549A, Paper
Nikhitha R., Anirban Mondal
Achieving an ideal thermally activated delayed fluorescence (TADF) emitter requires balancing a minimal singlet-triplet energy gap (∆EST) with a considerable oscillator strength (f), which are typically mutually exclusive. By strategically...
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Stronger Polar Ferromagnetism and Narrower Optical Band Gaps in Two-Dimensional Hybrid Copper Perovskites Induced by Bromine-Substitution

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC03532A, Paper
Ceng Han, Jason Allan McNulty, Alasdair Bradford, Alexandra Slawin, Stephen Lee, Philip Lightfoot
Two-dimensional (2D) organic–inorganic hybrid perovskites are attracting great interest due to their structural tunability and rich functional characteristics. Here, we report a series 2D layered hybrid copper (II) halide perovskites...
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Giant Magnetocaloric Effect in Fe doped Rare earth Orthochromite GdCr0.5Fe0.5O3

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC03873H, Paper
Abinash Prusty, Sudipta Mahana, B. Sheetal Priyadarshini, Andrei Gloskovskii, Dinesh Topwal, Unnikrishnan Manju
In this manuscript we present the magnetic and magnetocaloric property investigations of Fe doped orthochromite system GdCr0.5Fe0.5O3, along with the structural, electronic and thermal properties. Manifestations of orbital mediated electron-phonon...
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Nifty prediction today – November 13, 2024: Bearish. Go short now and on a rise

Nifty 50 November futures can fall to 23,400




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A cafe in Coimbatore pays an ode to the riding community with a nutritious menu




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Two prison staff placed under suspension in Salem




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Beneficiaries receive ₹22.15 lakh in loans from TAMCO for minority welfare




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Coimbatore District Police arrest two men for robbing Kerala jeweller of ₹54 lakh




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Waste-free Kerala: 97,000 children to take part in Haritha Sabhas on Thursday

To create awareness of waste management among children and incorporate their ideas in achieving the goal of waste-free Kerala




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State Library Council Awards declared, M. Leelavathy wins I.V. Das award for overall contributions




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Food prices rising due to failed policies of Modi govt., says Congress

Tomatoes, onions, and potatoes disappearing from common man’s plate, says Jairam Ramesh




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Pilgrims visiting Sabarimala to get nowcast from Nov. 15

Hygrometers to measure humidity and thermometers will be installed on the shrine premises soon to provide weather services to pilgrims, says IMD Director




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BJP accuses Congress of releasing election manifesto during “silence” period in Jharkhand

Mr. Patra claimed that the Congress wanted to give 4% reservation to the Muslim organisations and contractors in public tenders




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NIFT’s craft cluster projects enriching J&K’s artisans, crafts: L-G Manoj Sinha

He described J&K as “a repository of Indian creative traditions




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KTR in Delhi to strike a deal with BJP to escape Formula-E probe: Bhatti

Deputy Chief Minister points to BRS call to Maharashtra voters not to vote for Congress




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Global fossil emissions to reach record high in 2024; India's share to rise by 4.6%: Report

According to a UN report released last month, India's greenhouse gas emissions surged by 6.1 per cent in 2023, contributing to 8 per cent of the global total




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Indian households accumulated USD 9.7 trillion in wealth over last ten years: Morgan Stanley




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EU, Belgium, Denmark and Germany envoys visit Adani's Khavda, Mundra businesses, Gautam Adani says It was a privilege




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Vegetable prices sky-rocket in October, food inflation at 10.87%, CPI at 6.21 %




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India's index of industrial production shows 3.1 per cent growth in September 2024




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FSSAI discusses various sets of compliances with e-commerce food operators




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Integrated manufacturing cluster to be developed in Bihar's Gaya




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India among top 10 countries in patents, trademarks, and industrial designs: WIPO 2024 report




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LTIMindtree expands footprint in US with new innovation facility




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India set to become 'major producer' of electric vehicles like China: Mark Mobius




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Coal import for blending purposes in power generation declines by 8.5% during April-Sept 2024




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India could save 91,000 crore rupees on import bill through biofuel blending: Hardeep Singh Puri




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Gaining the Molecular Design Principles for Efficient Diarylethene Photoacid and Photohydride Generators Based on Photochemical Reaction Mechanism

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06202G, Edge Article
Open Access
Yifan Su, Dexin Zheng, Lingfeng Ge, Le Yu, David Lee Phillips, Jiani Ma, Yu Fang
Abstract: Photoacid generators (PAGs) and photohydride generators (PHGs) are specific photolabile protecting groups that release acid and hydride, respectively. Over the past decade, great efforts have been devoted to developing...
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'PM Modi's govt gives highest priority to over 35 mn Indian diaspora', says EAM Jaishankar on website launch for Pravasi Bharatiya Divas




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$19 mn Loss & Damage funding pledged by Sweden at COP29, bringing total pledged funding to $720 mn




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Providing better healthcare biggest priority: PM Modi ahead of Darbhanga AIIMS inauguration




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India's CO2 emissions account 8pc of global total, to rise by 4.6pc in 2024: Report




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UP: Devotees celebrate 'Tulsi Vivah' at Balua Ghat in Prayagraj, marking sacred union of Lord Vishnu, Vrinda




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Defence Space Agency hosts first ever space exercise 'Antariksha Abhyas - 2024' in Delhi




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Rajnath Singh stresses on adaptive defence to cope with Age of Grey Zone, hybrid warfare




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Indian Coast Guard evacuates critically ill fisherman off Diu coast




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All cases related to loan fraud at Perumbavoor Urban Cooperative Society to be handed over to Crime Branch

Police say 29 cases have been registered. Probe by district joint registrar of Cooperative department finds 26 persons, mostly members of previous director boards, accountable for irregularities to the tune of ₹33.33 crore




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‘Anti-war’ comedy play riles Bulgarian nationalists

Last week’s premiere of Arms and the Man by renowned Irish-born playwright George Bernard Shaw sparked raucous protests by nationalist groups




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Cold War-era H-6 bomber enhances China’s ability to strike U.S. bases

The H-6 long-range bomber was used in China’s October war games around Taiwan; it flew close to the U.S. mainland for first time in June




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COP29: India, other developing countries demand fair climate finance commitments

India, LMDCs advocate for equitable climate finance at COP29, pushing for transparency, fairness, and flexibility in financial commitments